CN1295173C - Transfer film and method for directly transfering on glass product surface thereof - Google Patents
Transfer film and method for directly transfering on glass product surface thereof Download PDFInfo
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- CN1295173C CN1295173C CNB2004100155901A CN200410015590A CN1295173C CN 1295173 C CN1295173 C CN 1295173C CN B2004100155901 A CNB2004100155901 A CN B2004100155901A CN 200410015590 A CN200410015590 A CN 200410015590A CN 1295173 C CN1295173 C CN 1295173C
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- 239000011521 glass Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000010410 layer Substances 0.000 claims abstract description 84
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 239000007822 coupling agent Substances 0.000 claims abstract description 24
- 238000010023 transfer printing Methods 0.000 claims description 29
- 238000007639 printing Methods 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 239000011241 protective layer Substances 0.000 claims description 13
- 238000007731 hot pressing Methods 0.000 claims description 10
- -1 aldehyde ketone Chemical class 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims description 2
- 238000010285 flame spraying Methods 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 claims description 2
- 238000003475 lamination Methods 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 239000005337 ground glass Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000012790 adhesive layer Substances 0.000 abstract 2
- 238000010276 construction Methods 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000741 silica gel Substances 0.000 description 6
- 229910002027 silica gel Inorganic materials 0.000 description 6
- 238000002203 pretreatment Methods 0.000 description 4
- 229920002799 BoPET Polymers 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
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- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000005269 aluminizing Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
Images
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- Decoration By Transfer Pictures (AREA)
Abstract
The present invention provides a transferring film capable of directly transferring patterns to glass surfaces and a method for directly transferring patterns to glass surfaces by the transferring film. The transferring film of the present invention comprises a carrier film, a form separating layer, a decorative layer and an adhesive layer, wherein the adhesive layer is mainly made from adhesive with active groups, a polar or low-polar film forming agent and a coupling agent. The method for directly transferring patterns to glass surfaces by the transferring film comprises: a transferring film is firstly prepared, the surface of a glass product is cleaned, and finally, the pattern on the decorative layer on the transferring film is directly transferred to the surface of the glass product by using a thermal transferring method. The transferring film and the method for transferring patterns of the present invention can be used for directly transferring the pattern on the transferring film to the surface of the glass product in a short time without pretreating the surface of the glass product in a resinifying mode, so that the surface of the glass product is decorated by the pattern so as to shorten the construction period and save a great amount of apparatus investment.
Description
Technical field
The present invention relates to a kind of transfer film, relate in particular to a kind of transfer film that can carry out direct transfer printing, the invention still further relates to the method that adopts this transfer film glass article surface to be carried out direct transfer printing glass article surface.
Background technology
Glass Containers is owing to have the feature of sparkling and crystal-clear thorough, non-toxic sanitary, often being used as edible, containers for medical use or cosmetics containers uses, in order to solve the too single style of glass article surface, need decorate glass article surface, way in the past is to adopt silk screen printing, spray patterns or utilize abrasive tool, etching mode to grind, be etched in pattern on glass at glass article surface, all these modes, all more time-consuming, take a lot of work, corresponding manufacturing cost also improves thereupon.Industrialization along with the hot transfer technique of China, applying of heat transfer film, a large amount of plastics all obtain the decoration of picture and text easily by transfer printing, so people also wish and can carry out pattern decoration to glass article surface by transfer printing, but because the polarity of glass surface is bigger, the following layer of existing transfer film mostly is nonpolar or the low-pole tackiness agent, can't combine closely with glass surface, thereby can't carry out direct transfer printing to glass article surface.Existing way is the transparent resin that can form big cohesive force earlier at glass surface spraying one deck with glass surface, and resin is heating and curing, by the hot pressing transfer printing picture and text on the transfer film are transferred on the resin layer again, make glass surface obtain decorating, this way must be carried out the resinifying pre-treatment to glass article surface, not only increase operation, also must drop into by increase equipment, cause glasswork to obtain this technology of pattern decoration and can not get applying by transfer printing.
Summary of the invention
The purpose of this invention is to provide and a kind ofly need not carry out the resinifying pre-treatment, be suitable for the transfer film that directly glass article surface carried out hot transfer printing glass article surface.
Another object of the present invention provides a kind of method that adopts above-mentioned transfer film glass surface to be carried out direct transfer printing.
For realizing above purpose, transfer film of the present invention comprises that a carrier film, at least one release layer that carrier film peels off, that makes can break away from and transfer to the ornament layer and the following layer of cohesive action together on the stock by heat and/or pressure from carrier film; It is characterized in that: the main component of above-mentioned following layer is: the tackiness agent, polarity or low-pole membrane-forming agent and the coupling agent that have active group; Above-mentioned tackiness agent preferred epoxy, aldehyde ketone resin or the polyvinyl butyral resin that has active group, the weight percent of this tackiness agent in following layer is 50%-90%; Above-mentioned polarity or low-pole membrane-forming agent preferred alcohols acid resin, acrylic resin or silicone resin, polarity or the weight percent of low-pole membrane-forming agent in following layer are 5%-40%; The preferred titanate coupling agent of above-mentioned coupling agent, silane coupling agent, the weight percent of this coupling agent in following layer is 1%-8%.
The preferred 60%-80% of the weight percent of above-mentioned tackiness agent in following layer; Polarity or the preferred 10%-30% of the weight percent of low-pole membrane-forming agent in following layer; The preferred 2%-5% of the weight percent of coupling agent in following layer.
Above-mentioned ornament layer includes protective layer and picture and text layer.
Above-mentioned ornament layer also comprises a vacuum aluminium coated layer.
Transfer film of the present invention is because the main component of following layer is the tackiness agent that has active group, polarity or low-pole membrane-forming agent and coupling agent, the tackiness agent that has active group has good adhesive to glass, and in the presence of coupling agent, sticking power to glass is increased greatly, and polarity or low-pole membrane-forming agent have similar molecular structure to general printing-ink, there is good interface to combine with printing-ink, and can improve the flexibility of following layer, therefore, adopt transfer film of the present invention to carry out direct transfer printing, need not carry out the resinifying pre-treatment glass surface to glass surface.
The present invention also provides a kind of method that glass article surface is carried out direct transfer printing, and this method in turn includes the following steps:
(1) preparation heat transfer film: a. applies the parting agent that one deck can make carrier film peel off at least on a carrier film surface; B. on release layer, cover with paint, lacquer, colour wash, etc. an ornament layer at least; C. on ornament layer, apply a following layer; D. cut rolling after the drying or cut into and open;
The main component of above-mentioned following layer is: the tackiness agent, polarity or low-pole membrane-forming agent and the coupling agent that have active group; Have tackiness agent preferred epoxy, aldehyde ketone resin or the polyvinyl butyral resin of active group, the weight percent of tackiness agent in following layer is 50%-90%; Polarity or low-pole membrane-forming agent preferred alcohols acid resin, acrylic resin or silicone resin, polarity or the weight percent of low-pole membrane-forming agent in following layer are 5%-40%; The preferred titanate coupling agent of coupling agent, silane coupling agent, the weight percent of coupling agent in following layer is 1%-8%;
(2) glass article surface is carried out clean;
(3) hot transfer printing processing: the transfer film that a. makes step (1) is contained on the heat transfer machine tool of unwinding and rewinding device, with glasswork be placed on hot pressing perm the below worktable on, transfer film is permed from hot pressing pass, and the area of the pattern of transfer film is aimed at the surface of glasswork with glasswork is middle; B. utilize hot pressing to perm and the ornament layer on the transfer film directly is transferred to the surface of glasswork; C. with rolling rod traction carrier film it is peeled off from glass surface; D. glasswork is taken off from worktable.
Above-mentioned printing transferring method, in the step (1), the preferred 60%-80% of the weight percent of tackiness agent in following layer; Polarity or the preferred 10%-30% of the weight percent of low-pole membrane-forming agent in following layer; The preferred 2%-5% of the weight percent of coupling agent in following layer.
The temperature that hot pressing is permed in the above-mentioned printing transferring method, step (3) is 150-240 ℃, and pressure is 0.4-0.7MPa.
In order to make the compactness that improves glass article surface and ornament layer, aforesaid method also comprises step (4), and the glasswork that is about to ornament layer in the transfer printing toasted 1-25 minute down at temperature 90-130 ℃.
Above-mentioned printing transferring method, step (2) preferably use solvent abstergent, acidic cleaning agent, flame spraying or grind glass article surface is handled;
Above-mentioned printing transferring method, the b of step (1) is printed with protective layer and picture and text layer in the step successively on release layer.
Above-mentioned printing transferring method, the c of step (1) be in the step, and vacuum plates an aluminium lamination on the picture and text layer side being printed on earlier before stamping following layer.
Printing transferring method of the present invention, owing to adopt above-mentioned transfer film, can be at short notice with the direct transfer printing of the pattern on the transfer film at glass article surface, make glass article surface obtain pattern decorative, omitted in the past and must carry out this operation of resinifying pre-treatment, not only shortened the duration glass article surface, and saved a large amount of equipment inputs, and utilize the existing sophisticated production technique of transfer film, and need not increase any operation, just can generate pattern miscellaneous at glass article surface easily.The figured plate glass that adopts printing transferring method of the present invention to make, stable performance, adaptability is good, and production cost is reduced greatly.
Description of drawings
Fig. 1 is the structural representation of a kind of transfer film of the present invention.
Fig. 2 is the structural representation of the another kind of transfer film of the present invention.
Fig. 3 is the present invention carries out hot transfer printing at glass surface a synoptic diagram.
Fig. 4 is the present invention carries out the hot transfer printing of another kind of mode at glass surface a synoptic diagram.
Embodiment
Example 1
As shown in Figure 1; this transfer film is to adopt printing press to have on the PET film 11 of release character the full width face one to be coated with and to stamp the parting agent layer 12 that solid content is 0.001-0.003%; on release layer, be coated with seal one protective layer 13; on protective layer, pass through many plates of intaglio plate machine printing figure message 14 again; be coated with on picture and text layer and the protective layer that do not covered by picture and text at last and stamp following layer 15, the thickness of following layer is 1-3 μ m.
Composition of above-mentioned each layer and proportioning (by weight):
Polyethylene wax 6
Dimethylbenzene 4000
Polyurethane resin 150
Linking agent 50
Nitro-cotton 40
Poly-diallyphthalate fat 100
Butanone 560
Pimelinketone 100
Picture and text layer 14
Urethane resin printing ink 1000
Stiffening agent 40
Thinner (butanone: toluene: Virahol=50: 30: 20) 350
Following layer 15
Modification aldehyde ketone resin 33.4
Hydroxylated acrylic resin 6
Amine silane coupling agent 0.6
Solvent (butanone: toluene=40: 20) 66
Example 2
As shown in Figure 2; this transfer film is earlier to go out actual pattern than the big 1-2 millimeter of picture and text feature edge at the big statuette according to the independent picture and text shape of continuity of being coated with on the tin graphed sheet rod of gravure printing machine; adopting this to be coated with the tin graphed sheet rod then has one and is coated with the protective layer 23 that seal one has release effect on the PET film 21 of release character; the thickness of this protective layer is in the 1-2 mu m range; on protective layer, pass through many plates of intaglio plate machine printing figure message 24; alignment picture and text position again is coated with and stamps the adhesion agent layer 25 identical with the protective layer area at last.
Composition of above-mentioned each layer or prescription (in weight ratio):
Protective layer 23
Methymethacrylate resin 1000
Polyethylene wax 30
Butanone 2000
Toluene 1500
Picture and text layer 24
Urethane resin printing ink 1000
Thinner (butanone: toluene: Virahol=40: 40: 20) 300
Following layer 25
Polyvinyl butyral resin 24
Hydroxylated acrylic resin 5.4
Phthalate ester coupling agent 0.6
Solvent (butanone: toluene=40: 30) 70
Example 3
Glass surface is carried out direct transfer printing, comprising:
(1) transfer film of example 1 or 2 is adopted in the preparation of transfer film;
(2) adopt acidic cleaning agent that clean is carried out on glasswork 4 surfaces, drying remains on about 30 ℃ its surface temperature;
(3) hot transfer printing processing, as shown in Figure 3, the transfer film of the example 2 of rolling is contained on the special machinery of unwinding and rewinding rod 31,32, it is the hot silica gel wheel 34 of 10cm that a diameter is arranged on this special machinery, the rotation of hot silica gel wheel energy, and can move up and down, glasswork is placed on the worktable of silica gel wheel below, transfer film is passed in the middle of silica gel wheel and glasswork, and the area of the pattern of transfer film is attached to the surface of glasswork; The silica gel wheel moves upward and accepts thermal radiation, its surface temperature is reached about 180 ℃, hot silica gel wheel moves downward, press transfer film and glass article surface, its pressure is about 0.5MPa, and the pattern on the transfer film, literal can be separated from the PET film fast and adhere to the surface of glasswork like this, with rolling rod traction carrier film 21 it are peeled off from glass surface, its pulling speed is relevant with the temperature of glass article surface, is generally 1-10mm/s; Take off glasswork from worktable at last, finish transfer printing.
As shown in Figure 4, above-mentioned transfer printing also can be adopted another kind of thermoprint mode, i.e. hot pressing is permed and is lithographic plate 5 forms, and the stressed promotion of glasswork is pressed in lithographic plate with transfer film and perms and go up transfer printing image-text.
Via the glasswork that present method transfer printing obtains, alcohol is adopted on its thermoprint surface, and wiping is more than 50 times back and forth, and pattern does not still come off.
For the pattern that makes transfer printing is adjacent to glass article surface better, can be with the figuratum glasswork of transfer printing temperature 90-130 ℃ of baking 1-25 minute down.
More than just transfer film of the present invention reaches specifying the glass article surface several embodiment of direct transfer printing; but this embodiment is not in order to restriction protection scope of the present invention; can produce transfer film miscellaneous according to existing processes as transfer film; such as the transfer film of aluminizing; mute light transfer film; bright mute alternate transfer films etc., all equivalences that does not break away from technical solution of the present invention are implemented or change, all should be included in the scope of the present invention.
Claims (11)
1, a kind of transfer film, it comprises that a carrier film, at least one release layer that carrier film peels off, that makes can break away from and transfer to the ornament layer and the following layer of cohesive action together on the stock by heat and/or pressure from carrier film; It is characterized in that: the main component of described following layer is tackiness agent, polarity or low-pole membrane-forming agent and the coupling agent that has active group; The described tackiness agent that has active group is Resins, epoxy, aldehyde ketone resin or polyvinyl butyral resin, and the weight percent of this tackiness agent in following layer is 50%-90%; Described polarity or low-pole membrane-forming agent are Synolac, acrylic resin or silicone resin, the weight percent of this membrane-forming agent in following layer is 5%-40%, described coupling agent is titanate coupling agent, silane coupling agent, and the weight percent of this coupling agent in following layer is 1%-8%.
2, transfer film according to claim 1 is characterized in that: the weight percent of described tackiness agent in following layer is 60%-80%; Polarity or the weight percent of low-pole membrane-forming agent in following layer are 10%-30%; The weight percent of coupling agent in following layer is 2%-5%.
3, transfer film according to claim 1 and 2 is characterized in that: described ornament layer includes protective layer and picture and text layer.
4, transfer film according to claim 3 is characterized in that: described ornament layer also comprises a vacuum aluminium coated layer.
5, a kind of method that glass article surface is carried out direct transfer printing, this method in turn includes the following steps:
(1) prepares transfer film as claimed in claim 1: a. and apply the parting agent that one deck can make carrier film peel off at least on a carrier film surface; B. on release layer, cover with paint, lacquer, colour wash, etc. an ornament layer at least; C. on ornament layer, apply a following layer; D. cut rolling after the drying or cut into and open;
Above-mentioned following layer main component is: the tackiness agent, polarity or low-pole membrane-forming agent and the coupling agent that have active group; The tackiness agent that has active group is Resins, epoxy, aldehyde ketone resin or polyvinyl butyral resin, and the weight percent of this tackiness agent in following layer is 50%-90%; Polarity or low-pole membrane-forming agent are Synolac, acrylic resin or silicone resin, and the weight percent of this membrane-forming agent in following layer is 5%-40%; Coupling agent is titanate coupling agent, silane coupling agent, and the weight percent of this coupling agent in following layer is 1%-8%;
(2) glass article surface is carried out clean;
(3) hot transfer printing processing: the transfer film that a. makes step (1) is contained on the heat transfer machine tool of unwinding and rewinding device, with glasswork be placed on hot pressing perm the below worktable on, transfer film is permed from hot pressing pass, and the area of the pattern of transfer film is aimed at the surface of glasswork with glasswork is middle; B. utilize hot pressing to perm and the ornament layer on the transfer film is transferred to the surface of glasswork; C. with rolling rod traction carrier film it is peeled off from glass surface; D. glasswork is taken off from worktable.
6, printing transferring method according to claim 5 is characterized in that: in the step (1), the weight percent of tackiness agent in following layer is 60%-80%; Polarity or the weight percent of low-pole membrane-forming agent in following layer are 10%-30%; The weight percent of coupling agent in following layer is 2%-5%.
7, according to claim 5 or 6 described printing transferring methods, it is characterized in that: in the described step (3), the temperature that hot pressing is permed is 150-240 ℃, and pressure is 0.4-0.7Mpa.
8, according to claim 5 or 6 described printing transferring methods, it is characterized in that: described method also comprises step (4), and the glasswork that is about to ornament layer in the transfer printing toasted 1-25 minute down at temperature 90-130 ℃.
9, according to claim 5 or 6 described printing transferring methods, it is characterized in that: described step (2) is used solvent abstergent, acidic cleaning agent, flame spraying or is ground glass article surface is handled.
10, according to claim 5 or 6 described printing transferring methods, it is characterized in that: the b of described step (1) is printed with protective layer and picture and text layer successively as ornament layer in the step on release layer.
11, printing transferring method according to claim 10 is characterized in that: the c of step (1) is in the step, and before stamping following layer, vacuum plates an aluminium lamination on the picture and text layer side being printed on earlier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100155901A CN1295173C (en) | 2004-03-02 | 2004-03-02 | Transfer film and method for directly transfering on glass product surface thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100155901A CN1295173C (en) | 2004-03-02 | 2004-03-02 | Transfer film and method for directly transfering on glass product surface thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1648091A CN1648091A (en) | 2005-08-03 |
| CN1295173C true CN1295173C (en) | 2007-01-17 |
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| CNB2004100155901A Expired - Lifetime CN1295173C (en) | 2004-03-02 | 2004-03-02 | Transfer film and method for directly transfering on glass product surface thereof |
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| CN101423001B (en) * | 2007-10-31 | 2012-05-30 | 焦作市卓立烫印材料有限公司 | Glass thermal transfer foil and preparation method thereof |
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| CN101722782A (en) * | 2009-03-27 | 2010-06-09 | 禹辉(上海)转印材料有限公司 | Method for manufacturing glass transfer film |
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| CN108215553B (en) * | 2017-12-31 | 2020-08-18 | 施莹莺 | Method for manufacturing glass surface thermoprint finishing film |
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- 2004-03-02 CN CNB2004100155901A patent/CN1295173C/en not_active Expired - Lifetime
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0655896A (en) * | 1992-06-19 | 1994-03-01 | Beiersdorf Ag | Adherent transfer film |
| JP2002103890A (en) * | 2000-09-29 | 2002-04-09 | Ichiro Suematsu | Image transfer method |
| CN1383992A (en) * | 2001-04-17 | 2002-12-11 | 韩国化学株式会社 | Hot transfer piece and its making process |
| CN2562976Y (en) * | 2002-08-19 | 2003-07-30 | 澄海市东田转印有限公司 | Transfer printing film |
| CN1403303A (en) * | 2002-09-06 | 2003-03-19 | 澄海市东田转印有限公司 | Production process and product of transferring film |
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| Publication number | Publication date |
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| CN1648091A (en) | 2005-08-03 |
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Address after: 515022 Guangdong city in Shantou Province, the new town Longhu District Jin Xin Lu Jin Yuan Industrial Zone Patentee after: GUANGDONG DONGTIAN TRANSFER NEW MATERIAL Co.,Ltd. Address before: 515822 Guangdong city in Shantou Province, the new town Longhu District Jin Xin Lu Jin Yuan Industrial Zone Patentee before: DONGTIAN TRANSFER MATERIALS Co.,Ltd. |
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Granted publication date: 20070117 |