CN104553430B - Preparation method of high temperature-resistant corrosion-resistant heat transfer printing film - Google Patents
Preparation method of high temperature-resistant corrosion-resistant heat transfer printing film Download PDFInfo
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- CN104553430B CN104553430B CN201410808138.4A CN201410808138A CN104553430B CN 104553430 B CN104553430 B CN 104553430B CN 201410808138 A CN201410808138 A CN 201410808138A CN 104553430 B CN104553430 B CN 104553430B
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Abstract
The invention provides a preparation method of a high temperature-resistant corrosion-resistant heat transfer printing film. The preparation method particularly comprises the following steps: preparing various layers of materials; coating; printing a pattern; carrying out intaglio printing; carrying out precoating adhesion; carrying out high temperature-resistant testing; carrying out water-resistant testing; and carrying out alcohol-resistant testing. The preparation method provided by the invention has the advantages of simpleness and convenience for preparation; the obtained heat transfer printing film has excellent high temperature steaming-resistant property, corrosion-resistant property, scraping-resistant property and abrasion-resistant property; and in addition, the preparation method provided by the invention can be used for outstandingly enhancing the economic benefit of an enterprise.
Description
Technical field
The invention belongs to polymeric material field, and in particular to it is a kind of can high temperature resistant, ethanol-tolerant and scratch resistance it is wear-resisting
Thermal transfer spends the manufacture method of film.
Background technology
Thermal transfer flower film is moisture-proof, big airtight, soft, intensity, acid and alkali-resistance grease and solvent, high/low temperature is not afraid of
Polar material.Thermal transfer flower film in the market is typically constituted by three layers, respectively basalis, printing layer and adhesive layer；
Release layer and PUR bisque can also be increased according to special demand.And glassware thermal transfer flower film is then used to be transferred to glass
Glass product surface.But the corrosion resistance of existing thermal transfer flower film is poor, when being boiled by high-temperature water or organic solvent is invaded
During erosion, its ink easily comes off, and causes the resolution reduction of institute's impression text.
Therefore, develop a kind of high-temperature resistant water boil, ethanol-tolerant, corrosion resistant thermal transfer flower film be those skilled in the art institute
Urgent need to solve the problem.
The content of the invention
To solve the above problems, the invention discloses it is a kind of being capable of high temperature resistant, ethanol-tolerant and the wear-resisting thermal transfer of scratch resistance
The manufacture method of flower film.
In order to achieve the above object, the present invention provides following technical scheme：
The thermal transfer that a kind of high temperature resistant is anti-corrosion spends the manufacture method of film, concretely comprises the following steps：
（1）Layers of material prepares：Prepare basalis, release layer, protective layer, waterproof layer and resistance to thermal barrier layer, and will be each
Layer is trimmed to equal size on demand；
（2）Coating：Release layer, protective layer, waterproof layer and resistance to thermal barrier layer are coated respectively using PET base material；
（3）Printing figure message：The printing-ink between any two-layer in protective layer, waterproof layer and resistance to thermal barrier layer, forms
Ink layer；
（4）Intaglio printing：According to being respectively from the bottom to top：Basalis, release layer, protective layer, waterproof layer and resistance to thermal resistance
The order of interlayer is stacked, and carries out intaglio printing；
（5）Precoating bonding：In the surface spraying adhesive linkage of resistance to thermal barrier layer, the anti-corrosion thermal transfer flower film of high temperature resistant is obtained；
（6）High temperature resistant is tested：By step（5）The thermal transfer flower film that the high temperature resistant that obtains is anti-corrosion is positioned on bottle with 180
DEG C temperature toast 10-20 minute, in placing into baking oven, toasted 10 minutes with 180 DEG C of temperature, to toast and observe ink after terminating
Whether the color of layer changes；
（7）Water resistance test：The anti-corrosion thermal transfer flower film of the high temperature resistant tested by high temperature resistant is immersed in the water 72 hours
Afterwards, taking-up is dried, and tests adhesive force：
（8）Ethanol-tolerant is tested：It is small by the anti-corrosion thermal transfer flower film immersion alcohol of the high temperature resistant by water resistance test 3
When, taking-up is dried and with alcohol wipe.
The invention provides the manufacture method that a kind of anti-corrosion thermal transfer of high temperature resistant spends film, respectively substrate from the bottom to top
Layer, release layer, protective layer, waterproof layer and resistance to thermal barrier layer, each layer are molded using intaglio printing, and in protective layer, waterproof
Printing-ink between any two-layer, forms ink layer in layer and resistance to thermal barrier layer.
Prepare layers of material during manufacture first, the size according to required thermal transfer flower film is pruned to layers of material；
Then release layer, protective layer, waterproof layer and resistance to thermal barrier layer are coated with using PET base material respectively, can be effectively improved release
The intaglio printing performance of layer, protective layer, waterproof layer and resistance to thermal barrier layer, increases glossiness；After coating is completed, in protection
Printing-ink between any two-layer, forms ink layer in layer, waterproof layer and resistance to thermal barrier layer；After ink layer is completed for printing, enter
Row intaglio printing is molded, and in the surface spraying adhesive linkage of resistance to thermal barrier layer, forms thermal transfer flower film；The heat that will finally obtain
Turn printed film carries out the test of high temperature resistant test, water resistance test and ethanol-tolerant respectively.
Preferably, basalis be PET without treatment basement membrane；Release layer is aqueous parting agent layer；Protective layer is anti-scratching wearproof
Mute film；Waterproof layer is waterproof membrane；Resistance to thermal barrier layer is high barrier film.
The present invention uses PET without treatment basement membrane as basalis, using aqueous mould release as release layer, using anti-scratch resistance to
Mute film is ground as protective layer, using waterproof membrane as waterproof layer, and high barrier film is used as resistance to thermal barrier layer.
Preferably, the constituent of aqueous parting agent layer and the mass percent shared by each composition are respectively：Go from
Sub- water：55-68%, modified aqueous acrylic acid resin：25-35%, ethylene glycol：1-6%, crosslinking agent：1-4%, defoamer：1-3%.
Preferably, step（3）In ink be PP ink or ABS ink.
Ink selection in the present invention is PP ink or ABS ink；Dawdling for PP ink is uniform, and pigment-dispersing is good,
With good water resistance and chemical proofing；ABS ink blooms are gorgeous, and ethanol-tolerant, scratch resistance excellent wear-resisting property.
Preferably, adhesive linkage is glass cement.
It is of the invention with existing thermal transfer flower film manufacture method compared with, have the beneficial effect that：（1）Method is simple, manufacturer
Just；（2）The thermal transfer flower film for obtaining has excellent digestion resistant, anti-corrosion and scratch resistance anti-wear performance；（3）It is obviously improved enterprise
The economic benefit of industry.
Specific embodiment
The technical scheme that the present invention is provided is described in detail below with reference to specific embodiment, it should be understood that following specific
Implementation method is only illustrative of the invention and is not intended to limit the scope of the invention.
Embodiment 1：
The thermal transfer that a kind of high temperature resistant is anti-corrosion spends the manufacture method of film, concretely comprises the following steps：
（1）Layers of material prepares：Using PET without treatment basement membrane as basalis, aqueous parting agent layer as release layer, anti-
Scrape wear-resisting mute film as protective layer, waterproof membrane as waterproof layer, high barrier film as resistance to thermal barrier layer, and by each layer on demand
Ask and be trimmed to equal size；Mass percent shared by the constituent and each composition of wherein aqueous parting agent layer is respectively：
Deionized water：68%th, modified aqueous acrylic acid resin：25%th, ethylene glycol：2%th, crosslinking agent：2%th, defoamer：3%.
（2）Coating：Release layer, protective layer, waterproof layer and resistance to thermal barrier layer are coated respectively using PET base material；
（3）Printing figure message：PP ink, shape are printed between any two-layer in protective layer, waterproof layer and resistance to thermal barrier layer
Into ink layer；
（4）Intaglio printing：According to being respectively from the bottom to top：Basalis, release layer, protective layer, waterproof layer and resistance to thermal resistance
The order of interlayer is stacked, and carries out intaglio printing；
（5）Precoating bonding：Resistance to thermal barrier layer surface spraying glass cement as adhesive linkage, obtain the anti-corrosion heat of high temperature resistant
Turn printed film；
（6）High temperature resistant is tested：By step（5）The thermal transfer flower film that the high temperature resistant that obtains is anti-corrosion is positioned on bottle with 180
DEG C temperature toast 10 minutes, in placing into baking oven, toasted 10 minutes with 180 DEG C of temperature, baking observes ink layer after terminating
Color whether change；
（7）Water resistance test：The anti-corrosion thermal transfer flower film of the high temperature resistant tested by high temperature resistant is immersed in the water 72 hours
Afterwards, taking-up is dried, and tests adhesive force：
（8）Ethanol-tolerant is tested：It is small by the anti-corrosion thermal transfer flower film immersion alcohol of the high temperature resistant by water resistance test 3
When, taking-up is dried and with alcohol wipe.
The thermal transfer obtained by above step spends film, lifting 33%, the water resistance deduction 40%, alcohol resistance of its heat-resisting quantity
Deduction 65%, ink layer definition retention time extension 66%.
Embodiment 2：
The thermal transfer that a kind of high temperature resistant is anti-corrosion spends the manufacture method of film, concretely comprises the following steps：
（1）Layers of material prepares：Using PET without treatment basement membrane as basalis, aqueous parting agent layer as release layer, anti-
Scrape wear-resisting mute film as protective layer, waterproof membrane as waterproof layer, high barrier film as resistance to thermal barrier layer, and by each layer on demand
Ask and be trimmed to equal size；Mass percent shared by the constituent and each composition of wherein aqueous parting agent layer is respectively：
Deionized water：62%th, modified aqueous acrylic acid resin：30%th, ethylene glycol：3%th, crosslinking agent：2%th, defoamer：3%.
（2）Coating：Release layer, protective layer, waterproof layer and resistance to thermal barrier layer are coated respectively using PET base material；
（3）Printing figure message：Printed between any two-layer in protective layer, waterproof layer and the resistance to thermal barrier layer PP ink or
ABS ink, forms ink layer；
（4）Intaglio printing：According to being respectively from the bottom to top：Basalis, release layer, protective layer, waterproof layer and resistance to thermal resistance
The order of interlayer is stacked, and carries out intaglio printing；
（5）Precoating bonding：Resistance to thermal barrier layer surface spraying glass cement as adhesive linkage, obtain the anti-corrosion heat of high temperature resistant
Turn printed film；
（6）High temperature resistant is tested：By step（5）The thermal transfer flower film that the high temperature resistant that obtains is anti-corrosion is positioned on bottle with 180
DEG C temperature toast 15 minutes, in placing into baking oven, toasted 10 minutes with 180 DEG C of temperature, baking observes ink layer after terminating
Color whether change；
（7）Water resistance test：The anti-corrosion thermal transfer flower film of the high temperature resistant tested by high temperature resistant is immersed in the water 72 hours
Afterwards, taking-up is dried, and tests adhesive force：
（8）Ethanol-tolerant is tested：It is small by the anti-corrosion thermal transfer flower film immersion alcohol of the high temperature resistant by water resistance test 3
When, taking-up is dried and with alcohol wipe.
The thermal transfer obtained by above step spends film, lifting 43%, the water resistance deduction 52%, alcohol resistance of its heat-resisting quantity
Deduction 77%, ink layer definition retention time extension 92%.
Embodiment 3：
The thermal transfer that a kind of high temperature resistant is anti-corrosion spends the manufacture method of film, concretely comprises the following steps：
（1）Layers of material prepares：Using PET without treatment basement membrane as basalis, aqueous parting agent layer as release layer, anti-
Scrape wear-resisting mute film as protective layer, waterproof membrane as waterproof layer, high barrier film as resistance to thermal barrier layer, and by each layer on demand
Ask and be trimmed to equal size；Mass percent shared by the constituent and each composition of wherein aqueous parting agent layer is respectively：
Deionized water：55%th, modified aqueous acrylic acid resin：35%th, ethylene glycol：5%th, crosslinking agent：4%th, defoamer：1%.
（2）Coating：Release layer, protective layer, waterproof layer and resistance to thermal barrier layer are coated respectively using PET base material；
（3）Printing figure message：Printed between any two-layer in protective layer, waterproof layer and the resistance to thermal barrier layer PP ink or
ABS ink, forms ink layer；
（4）Intaglio printing：According to being respectively from the bottom to top：Basalis, release layer, protective layer, waterproof layer and resistance to thermal resistance
The order of interlayer is stacked, and carries out intaglio printing；
（5）Precoating bonding：Resistance to thermal barrier layer surface spraying glass cement as adhesive linkage, obtain the anti-corrosion heat of high temperature resistant
Turn printed film；
（6）High temperature resistant is tested：By step（5）The thermal transfer flower film that the high temperature resistant that obtains is anti-corrosion is positioned on bottle with 180
DEG C temperature toast 20 minutes, in placing into baking oven, toasted 10 minutes with 180 DEG C of temperature, baking observes ink layer after terminating
Color whether change；
（7）Water resistance test：The anti-corrosion thermal transfer flower film of the high temperature resistant tested by high temperature resistant is immersed in the water 72 hours
Afterwards, taking-up is dried, and tests adhesive force：
（8）Ethanol-tolerant is tested：It is small by the anti-corrosion thermal transfer flower film immersion alcohol of the high temperature resistant by water resistance test 3
When, taking-up is dried and with alcohol wipe.
The thermal transfer obtained by above step spends film, lifting 60%, the water resistance deduction 75%, alcohol resistance of its heat-resisting quantity
Deduction 92%, ink layer definition retention time extension 115%.
It is last it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and non-limiting technical side
Case, it will be understood by those within the art that, those modify or equivalent to technical scheme, and
The objective and scope of the technical program are not departed from, all should be covered in the middle of scope of the presently claimed invention.
Claims (5)
1. a kind of anti-corrosion thermal transfer of high temperature resistant spends the manufacture method of film, it is characterised in that：Concretely comprise the following steps：
（1）Layers of material prepares：Prepare basalis, release layer, protective layer, waterproof layer and resistance to thermal barrier layer, and each layer is pressed
Demand is trimmed to equal size；
（2）Coating：Release layer, protective layer, waterproof layer and resistance to thermal barrier layer are coated respectively using PET base material；
（3）Printing figure message：Printing-ink between protective layer and waterproof layer or between waterproof layer and resistance to thermal barrier layer, forms ink
Layer；
（4）Intaglio printing：According to being respectively from the bottom to top：Basalis, release layer, protective layer, waterproof layer and resistance to thermal barrier layer
Order stacked, and carry out intaglio printing；
（5）Precoating bonding：In the surface spraying adhesive linkage of resistance to thermal barrier layer, the anti-corrosion thermal transfer flower film of high temperature resistant is obtained；
（6）High temperature resistant is tested：By step（5）The thermal transfer flower film that the high temperature resistant that obtains is anti-corrosion is positioned on bottle with 180 DEG C
Temperature is toasted 10-20 minutes, is placed into baking oven, is toasted 10 minutes with 180 DEG C of temperature, and baking observes ink layer after terminating
Whether color changes；
（7）Water resistance test：By after the anti-corrosion thermal transfer flower film of the high temperature resistant that high temperature resistant is tested is immersed in the water 72 hours, take
Go out to dry, test adhesive force：
（8）Ethanol-tolerant is tested：By 3 hours in the anti-corrosion thermal transfer flower film immersion alcohol of the high temperature resistant by water resistance test, take
Go out and dry and with alcohol wipe.
2. a kind of anti-corrosion thermal transfer of high temperature resistant according to claim 1 spends the manufacture method of film, it is characterised in that：It is described
Basalis is PET without treatment basement membrane；The release layer is aqueous parting agent layer；The protective layer is the mute film of anti-scratching wearproof；It is described
Waterproof layer is waterproof membrane；The resistance to thermal barrier layer is high barrier film.
3. a kind of anti-corrosion thermal transfer of high temperature resistant according to claim 2 spends the manufacture method of film, it is characterised in that：It is described
Mass percent shared by the constituent of aqueous parting agent layer and each composition is respectively：Deionized water：It is 55-68%, modified
Water-based acrylic resin：25-35%, ethylene glycol：1-6%, crosslinking agent：1-4%, defoamer：1-3%.
4. a kind of anti-corrosion thermal transfer of high temperature resistant according to claim 1 spends the manufacture method of film, it is characterised in that：It is described
Step（3）In ink be PP ink or ABS ink.
5. a kind of anti-corrosion thermal transfer of high temperature resistant according to claim 1 spends the manufacture method of film, it is characterised in that：It is described
Adhesive linkage is glass cement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410808138.4A CN104553430B (en) | 2014-12-23 | 2014-12-23 | Preparation method of high temperature-resistant corrosion-resistant heat transfer printing film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410808138.4A CN104553430B (en) | 2014-12-23 | 2014-12-23 | Preparation method of high temperature-resistant corrosion-resistant heat transfer printing film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104553430A CN104553430A (en) | 2015-04-29 |
| CN104553430B true CN104553430B (en) | 2017-05-24 |
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| CN201410808138.4A Expired - Fee Related CN104553430B (en) | 2014-12-23 | 2014-12-23 | Preparation method of high temperature-resistant corrosion-resistant heat transfer printing film |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107458105A (en) * | 2017-09-07 | 2017-12-12 | 山东尚品家居配饰制造有限公司 | A kind of Double-layered printing technique |
| CN110819037A (en) * | 2019-11-21 | 2020-02-21 | 东莞市悠悠美居家居制造有限公司 | Plain frosted embossed PVC tablecloth and production process thereof |
| CN110978839B (en) * | 2019-12-03 | 2021-11-09 | 佛山市长盛兴隆装饰材料有限公司 | Waterproof and antifouling thermal transfer paper, preparation method and printing stock |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02251486A (en) * | 1989-03-27 | 1990-10-09 | Toppan Printing Co Ltd | Forming method for image receiving layer by heat sensitive transferring method |
| JPH05177963A (en) * | 1991-12-27 | 1993-07-20 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| CN1644391A (en) * | 2005-01-18 | 2005-07-27 | 林日胜 | Printing method on glass and ceramic products |
| CN1648091A (en) * | 2004-03-02 | 2005-08-03 | 汕头市东田转印有限公司 | Transfer film and method for directly transfering on glass product surface thereof |
| CN101508222A (en) * | 2009-03-23 | 2009-08-19 | 郑佩玲 | Pattern printing method on shell and decorative panel of electronic products |
| CN102173250A (en) * | 2011-01-30 | 2011-09-07 | 焦作市卓立烫印材料有限公司 | Thermal transfer printing conductive foil and preparation method thereof |
-
2014
- 2014-12-23 CN CN201410808138.4A patent/CN104553430B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02251486A (en) * | 1989-03-27 | 1990-10-09 | Toppan Printing Co Ltd | Forming method for image receiving layer by heat sensitive transferring method |
| JPH05177963A (en) * | 1991-12-27 | 1993-07-20 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| CN1648091A (en) * | 2004-03-02 | 2005-08-03 | 汕头市东田转印有限公司 | Transfer film and method for directly transfering on glass product surface thereof |
| CN1644391A (en) * | 2005-01-18 | 2005-07-27 | 林日胜 | Printing method on glass and ceramic products |
| CN101508222A (en) * | 2009-03-23 | 2009-08-19 | 郑佩玲 | Pattern printing method on shell and decorative panel of electronic products |
| CN102173250A (en) * | 2011-01-30 | 2011-09-07 | 焦作市卓立烫印材料有限公司 | Thermal transfer printing conductive foil and preparation method thereof |
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| CN104553430A (en) | 2015-04-29 |
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