CN1288288C - Animal protein artificial hair and its production method - Google Patents
Animal protein artificial hair and its production method Download PDFInfo
- Publication number
- CN1288288C CN1288288C CN 200510040450 CN200510040450A CN1288288C CN 1288288 C CN1288288 C CN 1288288C CN 200510040450 CN200510040450 CN 200510040450 CN 200510040450 A CN200510040450 A CN 200510040450A CN 1288288 C CN1288288 C CN 1288288C
- Authority
- CN
- China
- Prior art keywords
- protein
- artificial hair
- acrylic acid
- acid derivative
- animal protein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 235000021120 animal protein Nutrition 0.000 title claims abstract description 15
- 235000018102 proteins Nutrition 0.000 claims abstract description 25
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 25
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 25
- 238000009987 spinning Methods 0.000 claims abstract description 20
- 102000011782 Keratins Human genes 0.000 claims abstract description 15
- 108010076876 Keratins Proteins 0.000 claims abstract description 15
- 238000002166 wet spinning Methods 0.000 claims abstract description 12
- 238000010382 chemical cross-linking Methods 0.000 claims abstract description 10
- 102000002322 Egg Proteins Human genes 0.000 claims abstract description 9
- 108010000912 Egg Proteins Proteins 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 19
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 12
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 12
- 238000007385 chemical modification Methods 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 10
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 235000014103 egg white Nutrition 0.000 claims description 8
- 210000000969 egg white Anatomy 0.000 claims description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 7
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical group OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 6
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 230000001112 coagulating effect Effects 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000012460 protein solution Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 4
- 235000005074 zinc chloride Nutrition 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 3
- 238000010612 desalination reaction Methods 0.000 claims description 3
- 238000005470 impregnation Methods 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulphite Substances [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 210000000038 chest Anatomy 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 241001416149 Ovis ammon Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses an animal protein artificial hair and a production method thereof, wherein the product mainly comprises a chemical cross-linking agent and chemically modified blended protein, wherein the chemically modified blended protein is prepared by taking keratin and egg white protein as protein raw materials. The production method comprises the steps of spinning solution synthesis, wet spinning, solidification forming, solvent removal, stretching, chemical crosslinking and the like. The product of the invention overcomes the defects of hard skin and hollow core of the original similar products, has soft hair, no melting, high moisture return rate, smooth and tidy dredging, soft luster, good hand feeling, good quality, long service life, easy operation of production process, low production cost and high spinning speed.
Description
Technical field:
The present invention relates to a kind of artificial hair and production method.
Background technology:
Because the hair products industrial expansion increases greatly to the kind of artificial hair and the demand of quantity.Except that true sending out, the artificial hair that hair products industry is used in a large number is synthetic material, such as: polyester, polyamide, polypropylene, modified polyacrylonitrile, polyvinyl chloride and polyvinyl alcohol.
In recent years, the regeneration collagen protein fibre comes out.This protein hair be collagenic protein solution through wet spinning, this after chemical crosslinking modify.This hair is in initial period at present, because the low production cost that causes of spinning speed improves.
Protein earlier through chemical modification wet spinning again, can improve spinning speed.But the fiber number that disclosed so far patent documentation only limits to fiber is the textile fabric scope of 0.6～6dtex.
The present inventor once disclosed the patent documentation CN1508303A of a kind of blend protein chemistry modification and wet spinning, and this technology is applicable to the manufacturing of the following Fang Mountain sheep of 3dtex fiber.
Artificial hair is thick doubly a lot of, mostly is the special tow of rough segmentation of 40～70dtex greatly.
Spin thick monofilament with making the textile fiber processes wet method, exist cortex and solidify earlier, hinder the problem of sandwich layer solvent removal than the cortex of consolidation.
Here it is makes the crin bundle that makes exist like the straw the hard core of skin to dredge empty defective.In addition, the fiber heat resistance made of method can also be improved thus, also has frit during burning.
Summary of the invention:
The object of the present invention is to provide a kind of good product quality, artificial hair made from animal protein that spinning speed is fast and production method.
Technical solution of the present invention is:
A kind of artificial hair made from animal protein is characterized in that: mainly be made up of the blend protein of chemical cross-linking agent and chemical modification, wherein the blend protein of chemical modification is to be that protein raw material is made with keratin protein, albumen protein.
Chemical cross-linking agent is a hydrazine hydrate.The dressing agent of the blend protein of chemical modification is an acrylonitrile.The dressing agent of the blend protein of chemical modification is the mixture of acrylonitrile and other acrylic acid derivative monomers.Described other acrylic acid derivative monomers are one or both in vinyl chloride, vinylidene chloride, methyl acrylate, butyl methacrylate, the hydroxyethyl methylacrylate.
The blend protein of chemical modification mainly is to be made by the raw material of following composition by weight:
Keratin protein 30～40%
Albumen protein 10～20%
Acrylonitrile 40～50%
Other acrylic acid derivative monomers 0～10%, above-mentioned component sum is 100%.
The fiber number of hair is 30～90dtex.
A kind of production method of artificial hair made from animal protein is characterized in that: comprise the following steps: 1. the egg white of 10～20% weight portions and the soluble keratin matter of 30～40% weight portions to be dissolved in the liquor zinci chloridi;
2. in the above-mentioned protein solution that obtains, add the acrylonitrile of 40～50% weight portions and other acrylic acid derivative monomers of 0～10% weight portion, add the redox series initiators again, addition is 0.1～5% of acrylonitrile and other acrylic acid derivative monomer total amounts, react spinning solution;
3. spinning solution is carried out wet spinning, during wet spinning, above-mentioned spinning solution is pressed into through spinneret orifice contains in the coagulating bath that concentration is 10～30% liquor zinci chloridi, be frozen into the tow of gel state;
4. the above-mentioned attitude tow that solidifies is put into the acid rinse bath desalination of PH1～3 and removed the residual zinc chloride of tow;
5. will stretch in boiling water bath and/or in steam chest after the tow washing of above-mentioned processing, draw ratio is 3～16 times;
6. the tow behind the drawn is dipped in concentration and is 0.5～20%, temperature is to do chemical crosslinking in 70～100 ℃ the hydrazine hydrate aqueous solution to handle, product.
6. the product that obtains through step is also through the sodium carbonate liquor impregnation process.
The spinning solution that 2. step obtains is before carrying out wet spinning, also after filtration, deaeration handles.
Product of the present invention has overcome the defective that skin is hard, core is dredged sky that original like product exists, the hair softness, and molten, the moisture content height is unclogged and readjusted smoothness, and gloss is soft, good hand touch, quality is good, long service life, and production technology is easy to operate, and production cost is low, and spinning speed is fast.
The invention will be further described below in conjunction with embodiment.
The specific embodiment:
Embodiment 1:
1. be in the liquor zinci chloridi of 45～67% (examples 45%, 55%, 67%) 5～40 ℃ of following stirring and dissolving in concentration with the egg white of 20% weight portion and the soluble keratin matter of 30% weight portion, the amount of solder(ing)acid is 30～60 times (30 times, 45 times, 60 times of examples) of egg white and keratin protein sum by weight;
2. in the above-mentioned protein solution that obtains, add the acrylonitrile of 40% weight portion and other acrylic acid derivative monomer (vinyl chloride of 10% weight portion, vinylidene chloride, methyl acrylate, butyl methacrylate, any two kinds mixture in the hydroxyethyl methylacrylate, and the ratio of both consumptions is 1～5: 5～1), add redox series initiators Ammonium Persulfate 98.5-sodium sulfite again, Ammonium Persulfate 98.5 wherein: sodium sulfite (weight ratio) is 1: 1～3 (examples 1: 1,1: 2,1: 3) (or initator adopts hydrogen peroxide-ferrous sulfate, hydrogen peroxide: ferrous sulfate is 1: 1～3), the addition of initator is 0.1～a 5% (example 0.1% of acrylonitrile and other acrylic acid derivative monomer total amounts, 3%, 5%), it (can be 10 ℃ that reaction temperature is 10～50 ℃, 30 ℃, 50 ℃), reaction time is 1～6 hour (example 1,3,6 hours), react spinning solution, more after filtration, the back set aside for use is handled in deaeration;
3. will be after filtration, the spinning solution handled of deaeration carries out wet spinning, during wet spinning, is that the spinneret orifice of 0.15～0.5mm (routine 0.15mm, 0.3mm, 0.5mm) is pressed into and contains in the coagulating bath of liquor zinci chloridi that concentration is 10～30% (examples 10%, 20%, 30%) with above-mentioned spinning solution through micro-pore diameter, the temperature of coagulating bath is 0～25 ℃ (0 ℃, 15 ℃, 25 ℃ of examples), is frozen into the tow of gel state;
4. the above-mentioned attitude tow that solidifies is put into the acid rinse bath desalination of PH1～3 (example 1,2,3) and removed the residual zinc chloride of tow, the temperature of water-bath is 15～70 ℃ (15 ℃, 40 ℃, 70 ℃ of examples);
5. will stretch in 90～100 ℃ of boiling water baths and in 100～110 ℃ of steam chests after the tow washing of above-mentioned processing, draw ratio is 3～16 times (3 times, 9 times, 16 times of examples);
6. the tow behind the drawn is dipped in concentration and is 0.5～20% (example 0.5%, 10%, 20%), temperature and be and do chemical crosslinking in the hydrazine hydrate aqueous solution of 70～100 ℃ (70 ℃, 85 ℃, 100 ℃ of examples) and handle 6 minutes～2 hours (example 6 minutes, 1 hour, 2 hours), product.
After the product washing that 6. step obtains is dried is impregnation process in 2～10% (example 2%, 6%, 10%) sodium carbonate liquor in concentration also, dipping temperature is 40～100 ℃ (40 ℃, 70 ℃, 100 ℃ of examples), and dip time is 6 minutes～3 hours (example 6 minutes, 1.5 hours, 3 hours).The product fiber number that obtains is 30～90dtex, and regain is 12～18%, sends out close with the people.
The above-mentioned product that obtains also can be gone up silicone oil and heat treatment according to a conventional method.Example is a silicone oil on 1% by last oil mass, and in the following 110 ℃ of oven dry of tension force.
Egg white, keratin protein, acrylonitrile and other acrylic acid derivative raw material monomer component sums are 100% in the present embodiment.
Embodiment 2:
Egg white, keratin protein, acrylonitrile and other acrylic acid derivative raw material monomer consumptions are by weight:
Keratin protein 40%
Albumen protein 10%
Acrylonitrile 45%
Other acrylic acid derivative monomers (in vinyl chloride, vinylidene chloride, methyl acrylate, butyl methacrylate, the hydroxyethyl methylacrylate any one) 0～10%;
Above-mentioned component sum is 100%.All the other are with embodiment 1.
Embodiment 3:
Egg white, keratin protein, acrylonitrile and other acrylic acid derivative raw material monomer consumptions are by weight:
Keratin protein 35%
Albumen protein 15%
Acrylonitrile 50%
Other acrylic acid derivative monomers 0%;
Above-mentioned component sum is 100%.All the other are with embodiment 1.
Embodiment 4:
The 0.28kg egg-white powder is dissolved in the 1.4kg water, gets solution A; The 0.600kg keratin is dissolved in the 0.6kg water, gets solution B; Again with solution A, B slowly adds in the liquor zinci chloridi of 14kg66% concentration, stir, keep 15 ℃ and the following 0.9kg of adding of stirring condition acrylonitrile, after 30 minutes, in this solution, add the liquor zinci chloridi that 130ml contains 66% concentration of 5g sodium sulfite, also add 120ml simultaneously and contain 66% concentration liquor zinci chloridi of 2.5g ammonium persulfate, after 45 minutes, add 130ml again and contain the liquor zinci chloridi of 66% concentration of 5g sodium sulfite and the 66% concentration liquor zinci chloridi that 120ml contains the 2.5g ammonium persulfate, react after 90 minutes, make thick liquid, filter through conventional method, 60 ℃ of insulations 20 hours, get spinning solution (spinning pulp) after the deaeration;
The above-mentioned spinning pulp that obtains from being the spinneret orifice of 0.25mm, is extruded micro-pore diameter, enter temperature and be in 0 ℃ of coagulating bath that contains 18% liquor zinci chloridi, the tow of solidification forming removes residual zinc chloride in the acid rinse bath of PH=3, after the washing, tow stretches in 90 ℃ of hot baths and 110 ℃ of steam chests, the total stretching 12 times, the tow fineness that makes thus is 51dtex, is called the artificial hair intermediate; The above-mentioned artificial hair intermediate that obtains was handled 45 minutes with 4% hydrazine hydrate aqueous solution down at 95 ℃, the venting raffinate, washing is dried, and handles 45 minutes with 10% aqueous sodium carbonate down at 95 ℃ then, and washing is dried, and last silicone oil is in 110 ℃ of oven dry down.
The artificial proteins hair fiber number of making thus is 64dtex, moisture content 16%, and not molten, cardability is good.
Claims (9)
1, a kind of artificial hair made from animal protein is characterized in that: mainly be made up of the blend protein of chemical cross-linking agent and chemical modification, wherein the blend protein of chemical modification is to be that protein raw material is made with keratin protein, albumen protein.
2, artificial hair made from animal protein according to claim 1 is characterized in that: chemical cross-linking agent is a hydrazine hydrate.
3, artificial hair made from animal protein according to claim 1 and 2 is characterized in that: the dressing agent of the blend protein of chemical modification is an acrylonitrile.
4, artificial hair made from animal protein according to claim 1 and 2 is characterized in that: the dressing agent of the blend protein of chemical modification is the mixture of acrylonitrile and other acrylic acid derivative monomers; Described other acrylic acid derivative monomers are one or both in methyl acrylate, butyl methacrylate, the hydroxyethyl methylacrylate.
5, artificial hair made from animal protein according to claim 1 and 2 is characterized in that: the blend protein of chemical modification mainly is to be made by the raw material of following composition by weight:
Keratin protein 30～40%
Albumen protein 10～20%
Acrylonitrile 40～50%
Other acrylic acid derivative monomers 0～10%, above-mentioned component sum is 100%;
Described other acrylic acid derivative monomers are one or both in methyl acrylate, butyl methacrylate, the hydroxyethyl methylacrylate.
6, artificial hair made from animal protein according to claim 1 and 2 is characterized in that: the fiber number of hair is 30～90dtex.
7, a kind of production method of artificial hair made from animal protein is characterized in that: comprise the following steps: 1. the egg white of 10～20% weight portions and the soluble keratin matter of 30～40% weight portions to be dissolved in the liquor zinci chloridi;
2. in the above-mentioned protein solution that obtains, add the acrylonitrile of 40～50% weight portions and other acrylic acid derivative monomers of 0～10% weight portion, add the redox series initiators again, addition is 0.1～5% of acrylonitrile and other acrylic acid derivative monomer total amounts, react spinning solution; Described other acrylic acid derivative monomers are one or both in methyl acrylate, butyl methacrylate, the hydroxyethyl methylacrylate;
3. spinning solution is carried out wet spinning, during wet spinning, above-mentioned spinning solution is pressed into through spinneret orifice contains in the coagulating bath that concentration is 10～30% liquor zinci chloridi, be frozen into the tow of gel state;
4. the above-mentioned attitude tow that solidifies is put into the acid rinse bath desalination of PH1～3 and removed the residual zinc chloride of tow;
5. will stretch in boiling water bath and/or in steam chest after the tow washing of above-mentioned processing, draw ratio is 3～16 times;
6. the tow behind the drawn is dipped in concentration and is 0.5～20%, temperature is to do chemical crosslinking in 70～100 ℃ the hydrazine hydrate aqueous solution to handle, product.
8, the production method of artificial hair made from animal protein according to claim 7 is characterized in that: the product that 6. obtains through step is also through the sodium carbonate liquor impregnation process.
9, according to the production method of claim 7 or 8 described artificial hair made from animal protein, it is characterized in that: the spinning solution that 2. step obtains is before carrying out wet spinning, also after filtration, deaeration handles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510040450 CN1288288C (en) | 2005-06-06 | 2005-06-06 | Animal protein artificial hair and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510040450 CN1288288C (en) | 2005-06-06 | 2005-06-06 | Animal protein artificial hair and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1699646A CN1699646A (en) | 2005-11-23 |
| CN1288288C true CN1288288C (en) | 2006-12-06 |
Family
ID=35475884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510040450 Expired - Fee Related CN1288288C (en) | 2005-06-06 | 2005-06-06 | Animal protein artificial hair and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1288288C (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100540760C (en) * | 2006-12-12 | 2009-09-16 | 新华锦集团有限公司 | A kind of modified polyacrylonitrile fiber and manufacture method thereof and purposes |
| CN102174741B (en) * | 2011-01-27 | 2012-12-12 | 河南瑞美真发股份有限公司 | Methods for preparing keratin surfactant and wigs |
| CN103088456B (en) * | 2011-11-01 | 2014-10-15 | 陈福库 | Protein-polyacrylonitrile composite fiber for hairpiece and manufacturing method of composite fiber |
| CN102732987B (en) * | 2012-06-21 | 2015-03-04 | 保利源(南通)实业有限公司 | Artificial sub-gloss high temperature resistant polyacrylonitrile hair and its preparation method |
| CN102732986A (en) * | 2012-06-21 | 2012-10-17 | 精源(南通)化纤制品有限公司 | High temperature resistant chlorine-containing polymer artificial hair and its preparation method |
| CN102732988A (en) * | 2012-06-21 | 2012-10-17 | 精源(南通)化纤制品有限公司 | High temperature resistant polyacrylonitrile artificial hair and its preparation method |
| CN102787381A (en) * | 2012-06-25 | 2012-11-21 | 精源(南通)化纤制品有限公司 | Flame-retardant animal protein artificial hair and preparation method thereof |
| CN102719925B (en) * | 2012-06-25 | 2015-03-04 | 保利源(南通)实业有限公司 | Dull artificial honed animal protein hair and preparation method thereof |
| CN102719924A (en) * | 2012-06-25 | 2012-10-10 | 精源(南通)化纤制品有限公司 | Tail reeling prevention animal protein artificial hair and preparation method thereof |
| CN108265342A (en) * | 2018-01-19 | 2018-07-10 | 安徽富泰发饰文化股份有限公司 | A kind of processing method of artificial hair modified composite fiber |
-
2005
- 2005-06-06 CN CN 200510040450 patent/CN1288288C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1699646A (en) | 2005-11-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1288288C (en) | Animal protein artificial hair and its production method | |
| CN100540760C (en) | A kind of modified polyacrylonitrile fiber and manufacture method thereof and purposes | |
| CN1078509A (en) | The fiber-spinnable solutions of silk-fibroin | |
| EP1016740B1 (en) | Acrylonitrile-based precursor fiber for carbon fiber, process for producing the same, and its use for forming a carbon fiber | |
| CN1974894A (en) | Modified polyacrylonitrile fiber and its prepn and use | |
| CN1807712A (en) | Process for preparing antibacterial polyacrylonitrile fiber | |
| CN101654813A (en) | Protein and alginate composite fiber and manufacturing method thereof | |
| CN111910282B (en) | Waste feather regenerated pure keratin fiber and preparation method thereof | |
| CN103005932A (en) | Method for producing silk quilt by utilizing sericin | |
| CN1811020A (en) | Mixed soybean protein-viscose fiber | |
| EP1698718B1 (en) | Acrylic shrinkable fiber and method for production thereof | |
| CN1370856A (en) | Regenerated protein fiber and its production process | |
| CN103556465B (en) | Method for compounding natural protein fiber powder on surfaces of polymer filaments | |
| CN1297699C (en) | Collagen-polyvinyl alcohol composite fiber modified by metallic ion, and preparation method | |
| CN109440212A (en) | The preparation method of the highly oriented tough regenerated celulose fibre of height and the highly oriented tough regenerated celulose fibre of height | |
| CN1632194A (en) | Regenerated eiderdown filament fiber and method of manufacture | |
| CN1492087A (en) | Collagen protein composite fiber and its producing method | |
| CN1041540C (en) | Manufacture of regenerated cellulosic fibre by zinc free viscose process | |
| CN1654719A (en) | Method for on-line modifying chemical fiber surface property | |
| CN1243141C (en) | Natural high-polymer polymer modified fibre and filament preparing method | |
| CN1044627C (en) | Pupa albumen for spinning and its producing method | |
| CN1255589C (en) | Production method of silkworm chrysalis protein-acrylonitrile graft copolymer fibre | |
| CN1876903A (en) | Broussonetia papyrifera adhesive filament and preparation method thereof | |
| CN1587458A (en) | Bamboo pulp regenerated cellulose viscose filament rayon and preparing method | |
| CN1245542C (en) | Synthetic fiber containing animal hair protein and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20061206 Termination date: 20140606 |