CN1286914A - Mixture of inorganic antibiotic agent and RE mineral and glasses and ceramic tableware containing the mixture - Google Patents

Mixture of inorganic antibiotic agent and RE mineral and glasses and ceramic tableware containing the mixture Download PDF

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Publication number
CN1286914A
CN1286914A CN00121081A CN00121081A CN1286914A CN 1286914 A CN1286914 A CN 1286914A CN 00121081 A CN00121081 A CN 00121081A CN 00121081 A CN00121081 A CN 00121081A CN 1286914 A CN1286914 A CN 1286914A
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China
Prior art keywords
inorganic antiseptic
mixture
tourmaline
rare
earth
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CN00121081A
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Chinese (zh)
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金海龙
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Individual
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Individual
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    • G—PHYSICS
    • G02—OPTICS
    • G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C5/00—Constructions of non-optical parts
    • G02C5/008—Spectacles frames characterized by their material, material structure and material properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/30—Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant

Abstract

Three kinds of matters, including inorganic antibiotic agent in 0.5-10 wt%, tourmaline in 5-10 wt% and magnetite in 3-10 wt%, are mixed into material for some articles. When they are mixed into material for glasses or sprayed onto to surface of glasses, glasses with antibiotic capacity and eye fatigue eliminating function may be manufactured. When they are used in porcelain table ware, the table ware may have antibiotic capacity and thus relatively longer food preserving period.

Description

Inorganic antiseptic and rare-earth like mine mixture and sneak into glasses, the crockery of this mixture
The present invention relates to inorganic antiseptic and rare-earth like mine mixture and use glasses, the crockery that this mixture is made.
Rapid variation and fast development along with science and technology; people need use computer at work in large quantities; and when leisure be unable to do without more see TVs for a long time; and the influence that is subjected to various air environmental pollutions, make modern's eyes aggravation tired, eyesight also descends gradually; and the effect of common spectacles at present can only reach the effect of improvement and vision protection and light; it is only finished by attached property eyeglass, and it is single that result of use still shows, and do not attain ideal.
Though existing people produces the glasses with antimicrbial power through the survey showed that, its making method is with the powder of Crab skin or the organic system antimicrbial power technology of liquid handling, but when extruding plastics mould shape, its antimicrbial power is subdued by melt temperature or is gushed, so do not reach expected effect, still remain to be improved.
For this reason, main purpose of the present invention promptly is to provide a kind of inorganic antiseptic and rare-earth like mine mixture at the deficiencies in the prior art, this mixture mix or jet surface in frame, can be made into tool antimicrbial power and elimination and alleviate the glasses of eye fatigue.
Another object of the present invention provides a kind ofly uses above-mentioned inorganic antiseptic and rare-earth like mine mixture and having antimicrbial power and can borrowing little magnetoelectricity ripple to promote the ocular blood circulation of making, and alleviates and eliminates eyeball fatigue, the glasses of vision protection.
But a further object of the present invention provides a kind of antimicrbial power long period that has of using above-mentioned inorganic antiseptic and rare-earth like mine mixture and making and preserves the crockery of food.
This inorganic antiseptic of the present invention and rare-earth like mine mixture are to comprise inorganic antiseptic, tourmaline, three kinds of materials of magnetic iron ore, this material joins with following ratio respectively to be desired to make in the article: inorganic antiseptic 0.5-10 weight %, tourmaline (Tourmaline) 5-10 weight %, magnetic iron ore 3-10 weight %.
Above-mentioned inorganic antiseptic is to be or the inorganic series antibacterial agent of calcium system (Calcium) inorganic matter and metal ion displacement formation for zeolite (Zeolite); The chemical composition of zeolite be contain alkaline earth metal such as alkalinous metals such as sodium, potassium and/or calcium can be hydrone (H 2O) silicate mineral that vulcanizes with the contained aluminium of water of crystallization form.Natural mineral species is various, and their chemical composition is also complicated different, and in the mineral that generally utilize, main ore is as follows now:
The ore name Form
Analcime Analcime NaAlSi 2O 8·H 2O
Clinoptilolite Clinoptilolite (Na 2·K 2·Ca) 3Al 6Si 36O 72·24H 2O
Modenite Mordenite (Na 2·K 2Ca)Al 2Si 10·7H 2O
Most alkali metal that zeolite contained (as Na, K) or alkaline earth metal (Ca) in the aqueous solution, have the character of displacement with other cation, this is alkaline displacement capacity (cation replacement capacity C ationexchange capacity), is called for short C.E.C.Its antibacterial mechanisms is: the micro-antibacterial metal ions (Ag that ionization is come out from zeolite 1+, Zn 2+, Cu 2+) reach cell membrane in the diffusion, at this moment in the time of by protein adsorption such as cell membranes cell structure is destroyed, by the antibacterial metal ions of protein adsorption such as cell membrane and yeast again with the combining of the Systoin-SLL of Amion acid, and change into sulphide the energy metabolism of block cell the time, thereby play antibacterial action.It is different with organic antibacterial agent be at high temperature still very safety and stability do not have the characteristic of volatilization and crystallization effusion again, so it can keep long antibacterial action.There is " ANBIGENT " product of (strain) KOSMOS manufacturer production in Korea S at present.
Chemical formula and the composition of holding the mineral dust tourmaline (Tourmaline) of permanent electrode are: (Na, and Ca) (Mg, Fe, Mn, Li, Al) 3(Al, Mg, Fe 3+) 6(Sl 6O 18) (BO 3) 3(O, OH) 3(OH, F) wherein, SiO 2: 37.55%, Al 2O 3: 26.32%, Fe 2O 3: 9.76%, MnO:0.04%, CaO:2.57%, MgO:7.89%, Na 2O:1.47%, Li:1.32%, B:0.35%, other 0.99%, loss on drying 11.74%;
The kind difference of tourmaline, their chemical formula also has multiple class, more than exemplifies one of them example and explains.
Magnetic iron ore is an iron ore of holding magnetic force, and it is for containing the strong magnetic force magnetic iron ore of rare earth metal.Its chemical formula is: Fe 3O 4, wherein iron content (Fe) should be isometric system more than 72%, proportion 4.0～5.2, and color is iron black look russet, ferromagnetism is relatively known to change into mineral deposit, contact deposit etc.It is because the electron motion in the atom produces magnetic field, can oneself not disappear mutually again, thereby forms magnetic naturally.Why the reason with magnetic iron ore is: it plays positive effect that long-time energy continues and the characteristic of safeguarding inorganic antiseptic to the electric boundary of the magnetic field that taken place in the tourmaline or formation; the magnetic field that produces by the electron institute in the atom can not disappear mutually; thereby can keep nonvolatil magnetic force, this magnetic can be protected permanent to the wave field (electric field) that inorganic antiseptic and tourmaline produced.
In metal and plastic spectacle frame production process, produce the glasses that have antimicrbial power and produce faint magnetism electric current utilizing powder and liquid phase glazing to handle when gold-plated and painted, the glazing operation of glasses production process after the powder of above-mentioned inorganic antiseptic, tourmaline, magnetic iron ore and the liquid phaseization.
But the principle of the present invention's anti-eye strain, vision protection is: because two utmost points in tourmaline, magnetic iron ore three rooms or six rooms are asymmetric up and down mutually, then form faint magnetism electric current, form of the stimulation of electric boundary's generation magnetic force because of having faint magnetism electric current to eyeball surrounding skin blood flow, thereby has the unimpeded effect that stimulates circulation, it can form electric field, form the magnetic field film around making food, can keep the freshness of food; Simultaneously because of being that magnetic iron ore (magnetic force rare earth metal by force) is added by suitable (3-10%) ratio with the pulverulence that is ground into 5 μ m granularities, composite force according to them under the free electron that water in the human body (human body 70% is a water) is formed according to faraday (Faraday) rule through the glasses handled the like this effect of the ion of hydrone (Ion) just produces the destruction of hydrogen molecule combination, thereby hydrogen ion and compound hydrone is scatter separately cause long in conjunction with becoming simple short combination from complexity.The destruction of the combination of H2 will cause the generation of certain variation surely, and the water that resembles this state is unsettled, has reactivity, can improve blood thus, promote the normalization of eyesight.
The present invention can make the manufacturing technology of glasses and function from merely for eyeglass is installed; manufacture with plastics and metal material in the straightforward procedure of spectacle frame and break away from; by in the material of spectacle frame or the surface add/film inorganic antiseptic and rare-earth like mine mixture; make and to pass through wear a pair of spectacles; and to suppressing soaking into of various bacteriums around the eyeball; also produce faint magnetism electric current (little magnetoelectricity ripple) simultaneously; stimulate the blood flow of eyeball surrounding skin; the smoothness that stimulates circulation, thus reach the fatigue of eliminating eyes, the beneficial effect of vision protection.
Mix with inorganic antiseptic of the present invention and rare-earth like mine mixture and to make plastics in plastics or the clay silica sand or the method for porcelain container is: in plastic containers extrusion molding process, mix 0.5～10% antibacterial agent, 5～10% tourmaline, 3～10% magnetic iron ores (strong magnetic force terres rares) by accounting for gross weight with antibiotic effect.
The container tool of making thus can prevent soaking into of various bacteriums in use, to be suppressed at hold the various bacteriums in tool the inside perch and effect is played in breeding, can keep food to never degenerate for a long time, be placed on general appearance tool the inside such as the apple of cutting, variable color can be seen in its surface, the left and right sides after an hour approximately, can keep surperficial nondiscolouring in 5 hours but be placed on when fusion has the made container of mixture of the present invention the inside, keep the effect of its freshness as can be seen.
Further elaborate the present invention below by several specific embodiments.(except that specifying, the percentage among the present invention is meant percentage by weight)
Spectacle frame manufacturing process mentioned among the present invention is:
(1) adopts plastic raw materials (as ABS resin, cellulose cellulose system, acetate Acetate, propionic acid Propionate, epoxy Epoy resin, siloxanes Silicone, nylon or the like)
(1) making → (4) plastic tree lipid sclerosis (curing agent 25%+ synthetic resin 75%) → (5) chemicals (IPD50%+TND50%) of making → (3) siloxanes (Silicone) model of model selected → (2) metal pattern mixes the back and adds 25% → (6) (50 ℃ → 80 ℃ → 100 ℃) dissolving back → injection siloxanes model → drying → craft of heating gradually and once grind → the automatic regrind of machine → selection color → glazing → assemble → go out process of finished product, when the plastic hardening operation, all or partly all inorganic antiseptics, tourmaline, all fusion and when light-plated (Coating) and after the light-plated solvent, spray light-plated of magnetic iron ore.
Its production process is when the sclerosis operation of the spectacle frame of making plastic material, nose holder, leg of spectacles, leg skin, the powder of inorganic antiseptic, tourmaline, magnetic iron ore or liquid condition, feedstock property requirement by plastics (ABS resin, cellulose, acetate Acetate, propionic acid Propionate, epoxy Epoy resin, siloxanes Silicone, nylon etc.), crush by cracker, and form by a firing with high temperature (800-1200 ℃) with tourmaline, magnetic iron ore.
In the production process of embodiment one (example that mixes with plastic raw materials) plastic products, when progressively heating (50 ℃ → 80 ℃ → 100 ℃) dissolving after under plastic tree lipid sclerosis (curing agent 25%, resin 75%) state, adding chemicals (IPD50%+TND50%) 25%, be mixed together sclerosis in the ratio ranges by inorganic antiseptic 10%, tourmaline 10%, magnetic iron ore 10%, resinae 70%.
(2) adopt metal material (nickel alloy, SPM, Monel, stainless steel, duralumin, aluminium, titanium, gold below is referred to as metal) little welding (earpiece is fixing to be welded) → (13) rectification work → (14) the once automatic regrind of grinding → (15) machine by hand → (16) the gold-plated and color of showing in welding → (12) of cut-out → (11) earpiece hinged joint of welding → (10) ring of welding → (9) nose (horizontal stroke) beam of welding → (6) operations for forming → (7) bending operation (camber of picture frame) → (8) nose holder of making the cutting out of selected → (3) picture frame → (4) operations for forming (use mould) → (5) rings (Ring) of selected → (2) part of (1) model in the spectacle frame production process, making of rectification → (19) color trade mark that glazing → (17) part assembling → (18) are last etc. → go out finished product; In the above production process in gold-plated and colouring, last light time, on the picture frame of glasses and leg of spectacles, leg skin, nose holder surface, 5% inorganic antiseptic that accounts for the spray liniment gross weight, 5% tourmaline, 5% magnetic iron ore mixing jetting light-plated.
Embodiment two (at the cooperation ratio of metal material surface injection)
Gold-plated and the colouring, the last light time, light solvent Binder (cementing agent BBS1000) and curing agent stir by 3: 1 ratio mixing, take chemicals water fusion, heating (80 ℃) dissolving back to spray glazing with suffering by 5: 5 ratio again, in its mixed process, the inorganic antiseptic that accounts for gross weight 0.5%, 5% tourmaline, 5% magnetic iron ore (BBS1000) are mixed the back with 89.5% smooth solvent Binder (cementing agent) spray glazing.
The common spectacles that is made of plastics is to adopt thermoplastic resin and two kinds of method making spectacle frame and annexes that only adopt heating, pressure or add catalyzer of thermosetting resin, the present invention has taked to be incorporated in inorganic antiseptic 0.5-10%, tourmaline 5-10%, magnetic iron ore 3-10% in the plastic raw materials and to pass through special mixing and blending machine device and mix, with spectacle frame and the picture frame in the Metal Eyeglasses and the annex of this special material making.
The desirable cooperation ratio of the addition of inorganic antiseptic is 0.5-10% (weight) among the present invention, thereby not only Escherichia coli, general bacterium had antimicrbial power, the test agent of by 0%, 0.5%, 1% ratio the inorganic antiseptic admixture being manufactured respectively according to the weight of plastic raw materials cellulose (cellulose system), antimicrbial power to Escherichia coli and general bacterium is tested respectively, its as a result example in table one.
Table one
Example one (0%) Example two (0.5%) Example three (1%)
Rigidly connect when touching 5.8×10 3 5.8×10 3 5.8×10 3
After 24 hours 1.4×10 5 1.1×10 2 4.3×10 4
Sterilizing rate (%) 82.8 99.9 99.9
As shown in Table 1, by the present invention made Plastic eyeglasses and annex, under the effect of its antibacterial functions, can remove eyeball extremely and various polluted bacterias take place, generable bacterial skin infections and damage in the time of also can preventing because of skin and plastics Long contact time simultaneously on every side during use.
The present invention has mainly solved following technical barrier:
Mix example when finishing (1) with plastic raw materials and only adopt plastic raw materials, when extruding glasses and annex, do not go wrong, the antimicrbial power of Escherichia coli and general bacterium is reached 80% approximately, but little magnetoelectricity ripple occurs almost with the fusion of 250 ℃ of temperature.
When pressing the listed condition extrusion molding of table two, because mineral dust self has heat generation, the product that melting temperature is extruded when rising to 300-600 ℃, moulding occurs and split the shape phenomenon, current density height because of inorganic antiseptic, tourmaline, magnetic iron ore, after adding too much, the product elastic force, the nerve that are extruded obviously descend, and the color and luster muddiness.
Table two
Melting temperature Add ratio (%)
Inorganic antiseptic Tourmaline Magnetic iron ore Resin Add up to
Content 250℃ 8 10 10 72 100
Particle diameter 10μm 10μm 10μm
Press the ratio that table three constitutes, consider that mineral dust itself has heat generation, melting temperature is reduced 20-30 ℃, adjusted the interpolation ratio of inorganic antiseptic, tourmaline, magnetic iron ore, when density is 5 μ m, above-mentioned problem do not occur, promptly almost do not have flowability, color and luster when mixing with pigment simultaneously, the nerve of product, elastic force and surface fracture phenomenon are also good, just occurred when using transparent plastic resin, opaque to some extent, but it can not influence the making finished product.
Table three
Melting temperature Add ratio (%)
Inorganic antiseptic Tourmaline Magnetic iron ore Resin Add up to
Content 220-230℃ 1 5 3 91 100
Density 5μm 5μm 5μm
Light time on the jet surface of metal and Plastic eyeglasses
Example 1
Gold-plated colouring, go up photoreduction process be light solvent Binder (cementing agent (BBS1000) and curing agent after mixing with 3: 1 ratios, add the hot water (solvent or diluent) of taking of chemicals by 5: 5 ratios again, heat 80 ℃ of fusions after the injection glazing finish.In mixed process, the light solvent Binder[(cementing agent (BBS1000) that inorganic antiseptic 0.5% and glazing are used] 89.5% mix glazing is sprayed in the back with spraying machine result, do not dissolve because of mineral powders, surperficial disengaging and surface imperfection phenomenon have occurred and stopped up the firmly problem of injector mouthpiece.
Gold-plated colouring, go up photoreduction process glazing solvent Binder (cementing agent BBS1000) and curing agent and mix by 3: 1 ratio and stir, add the hot water (solvent or diluent) of taking of chemicals by 5: 5 ratios again, heat 70 ℃ and fuse the injection glazings and finish.In mixed process, inorganic antiseptic 0.5%, tourmaline 5%, magnetic iron ore 5% and chemical industry medicine Binder (cementing agent) when being mixed into aqueousization again with light solvent Binder (after cementing agent (BBS1000) 89.5% mixes, spray the result of glazing by spraying machine, the surface of appearance to break away from, surface color is ten minutes gloss also, and interior calorific intensity is also good.
The Another application field of inorganic antiseptic of the present invention and rare-earth like mine mixture is, in the production process of ceramic (as home-use pot, bowl, dish, dish or the like), the powder of inorganic antiseptic of the present invention and tourmaline, magnetic iron ore and liquid raw material admixture heated to fire after stir clay (ceramic raw material) lining finish, make the utensil of making itself have antimicrbial power, can suppress of the corrosion of airborne various bacterium, the freshness of food and extend and resting period to food.
Example 2 is made porcelain and is held tool
Use raw clay and silica sand commonly used when (one) making porcelain, even stirring back by 0.5% inorganic antiseptic, 5% tourmaline, 5% magnetic iron ore, 84.5% clay silica sand, 5% water forms the clay thing, after then making the appearance tool apperance of different shape with such clay thing handwork, through 8～72 hours fire (temperature is at 800～1500 ℃), be coated with on the surface of burned material then that gloss varnish is to be dried to be finished.
(2) make the clay thing with following proportioning, wherein inorganic series antibacterial agent 0.5%, tourmaline 5%, magnetic iron ore (strong magnetic force rare earth metal) 3%, clay silica sand 76.5%, water 15% pour in the gypsum mold, reburn after the moulding and produce finished product.

Claims (5)

1, a kind of inorganic antiseptic and rare-earth like mine mixture, it is characterized in that comprising inorganic antiseptic, tourmaline, three kinds of materials of magnetic iron ore, this material joins with the following ratio that accounts for gross weight respectively to be desired to make in the article: inorganic antiseptic 0.5-10 weight %, tourmaline (Tourmaline) 5-10 weight %, magnetic iron ore 3-10 weight %.
2, mixture according to claim 1 is characterized in that above-mentioned inorganic antiseptic is to be or the inorganic series antibacterial agent of calcium system (Calcium) inorganic matter and metal ion displacement formation for zeolite (Zeolite); The chemical formula and the composition of tourmaline are:
(Na, and Ca) (Mg, Fe, Mn, Li, Al) 3(Al, Mg, Fe 3+) 6(S L6O 18) (BO 3) 3(O, OH) 3(OH, F) SiO wherein 2: 37.55%, Al 2O 3: 26.32%, Fe 2O 3: 9.76%, MnO:0.04%, CaO:2.57%, MgO:7.89%, Na 2O:1.47%, Li:1.32%, B:0.35%, other 0.99%, loss on drying 11.74%;
Magnetic iron ore is for containing the strong magnetic force magnetic iron ore of rare earth metal.
3, a kind of application rights requires the made glasses of 2 described mixtures, it is characterized in that: spectacle frame be by fusion the plastics of described inorganic antiseptic and rare-earth like mine mixture make, or it is made to have sprayed the metal of described inorganic antiseptic and rare-earth like mine mixture by the surface.
4, glasses according to claim 3, it is characterized in that inorganic antiseptic and rare-earth like mine mixture be with 0.5 weight % inorganic antiseptic, 5 weight % tourmaline, 5 weight % magnetic iron ores and chemical industry medicine cementing agent be mixed into aqueous again with the mixing of 89.5 weight % light solvent BBS1000, spray in metal mirror holder surface by spraying machine.
5, a kind of application rights requires the made crockery of 2 described mixtures, it is characterized in that this crockery be by fusion the clay of described inorganic antiseptic and rare-earth like mine mixture fire and form; Perhaps in ceramic product surface this inorganic antiseptic of spraying and rare-earth like mine mixture.
CN00121081A 1999-09-07 2000-07-18 Mixture of inorganic antibiotic agent and RE mineral and glasses and ceramic tableware containing the mixture Pending CN1286914A (en)

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Application Number Priority Date Filing Date Title
KR2019990018913U KR200169471Y1 (en) 1999-09-07 1999-09-07 The spectacle frame mixed of the inorganic-based antibiotic agent and the rare-earth mineral
KR1999-18913 1999-09-07

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101513188A (en) * 2008-02-20 2009-08-26 北京亚都科技股份有限公司 Bactericide and preparation method thereof
CN111458900A (en) * 2020-05-07 2020-07-28 江鸿特材科技（深圳）有限公司 Method for manufacturing epidemic-resistant nose pad and epidemic-resistant nose pad

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010088897A (en) * 2001-05-14 2001-09-29 남승우 generating anions monitor case composition
KR102166042B1 (en) * 2020-06-02 2020-10-15 김태헌 Method of preparing antimicrobial spectable frame and antimicrobial spectable frame prepared by the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101513188A (en) * 2008-02-20 2009-08-26 北京亚都科技股份有限公司 Bactericide and preparation method thereof
CN111458900A (en) * 2020-05-07 2020-07-28 江鸿特材科技（深圳）有限公司 Method for manufacturing epidemic-resistant nose pad and epidemic-resistant nose pad

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