CN1284489C - Chlorophyll copper sodium salt treatment method for acidic beverage - Google Patents
Chlorophyll copper sodium salt treatment method for acidic beverage Download PDFInfo
- Publication number
- CN1284489C CN1284489C CN 200410035721 CN200410035721A CN1284489C CN 1284489 C CN1284489 C CN 1284489C CN 200410035721 CN200410035721 CN 200410035721 CN 200410035721 A CN200410035721 A CN 200410035721A CN 1284489 C CN1284489 C CN 1284489C
- Authority
- CN
- China
- Prior art keywords
- acid
- chlorophyll copper
- copper sodium
- acidic
- chlorophyll
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229930002875 chlorophyll Natural products 0.000 title claims abstract description 38
- 235000019804 chlorophyll Nutrition 0.000 title claims abstract description 38
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 title claims abstract description 38
- ZIALXKMBHWELGF-UHFFFAOYSA-N [Na].[Cu] Chemical compound [Na].[Cu] ZIALXKMBHWELGF-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 5
- 230000002378 acidificating effect Effects 0.000 title abstract description 16
- 235000013361 beverage Nutrition 0.000 title abstract description 7
- 235000013373 food additive Nutrition 0.000 claims abstract description 26
- 239000002778 food additive Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000003672 processing method Methods 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims description 34
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 22
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 14
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 14
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 14
- HWDGVJUIHRPKFR-UHFFFAOYSA-I copper;trisodium;18-(2-carboxylatoethyl)-20-(carboxylatomethyl)-12-ethenyl-7-ethyl-3,8,13,17-tetramethyl-17,18-dihydroporphyrin-21,23-diide-2-carboxylate Chemical compound [Na+].[Na+].[Na+].[Cu+2].N1=C(C(CC([O-])=O)=C2C(C(C)C(C=C3C(=C(C=C)C(=C4)[N-]3)C)=N2)CCC([O-])=O)C(=C([O-])[O-])C(C)=C1C=C1C(CC)=C(C)C4=N1 HWDGVJUIHRPKFR-UHFFFAOYSA-I 0.000 claims description 14
- 235000011090 malic acid Nutrition 0.000 claims description 14
- 239000001630 malic acid Substances 0.000 claims description 14
- 229940079841 sodium copper chlorophyllin Drugs 0.000 claims description 14
- 235000013758 sodium copper chlorophyllin Nutrition 0.000 claims description 14
- 239000011975 tartaric acid Substances 0.000 claims description 14
- 235000002906 tartaric acid Nutrition 0.000 claims description 14
- 235000015165 citric acid Nutrition 0.000 claims description 13
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 9
- 239000007788 liquid Substances 0.000 abstract description 7
- 239000012535 impurity Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 2
- 239000001056 green pigment Substances 0.000 abstract description 2
- 239000012267 brine Substances 0.000 abstract 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 6
- 238000005496 tempering Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000003086 colorant Substances 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000020535 bottled fortified water Nutrition 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
The present invention discloses a processing method of chlorophyll copper sodium salt containing acidic beverages, which comprises the following steps: selecting the chlorophyll copper sodium salt to prepare a chlorophyll copper sodium brine solution; tempering the chlorophyll copper sodium brine solution by acidic food additive to make the pH value less than 7 and prepare an acidic chlorophyll copper sodium brine solution; removing impurities in a water solution, comprising undissolved substances, etc. in a suitable process; finally, obtaining a purified acidic chlorophyll copper sodium brine solution which can be directly added into the acidic beverages. The purified acidic chlorophyll copper sodium brine solution can be completely dissolved into acidic liquid. The purified acidic chlorophyll copper sodium brine solution is used for coloring when transparent acidic beverages are produced. Thus, qualified transparent green acidic beverages can be produced, and chemosynthesis green pigment used by the acidic beverages all the time can be replaced.
Description
Technical field
The present invention relates to a kind of natural colorant that is applicable to acid drink, particularly the processing method of this based colorant.
Background technology
According to " food additives are practical complete works of " record of publishing house of Beijing University of Technology in January, 1999 version, sodium copper chlorophyllin is a water-soluble natural green colourant unique in the present food additives.The pH value of this natural colorant is 9.0～10.7, be alkalescent, in containing acid, calcic or hard water environment, easily generate insoluble salt, as when using sodium copper chlorophyllin to produce acid transparency liquid drink as green colourant, in drink liquid, easily generate floccule, influence the painted and color of drink.Therefore, people almost can't see usefulness natural edible sodium copper chlorophyllin as colouring agent on market at present, the acid drink that " green " produced is transparent.The above-mentioned attribute of this natural colorant has brought great restriction for its painted application.
Summary of the invention
The object of the present invention is to provide a kind of chlorophyll copper sodium salt processing method that is used to contain acid drink, the chlorophyll copper sodium saline solution that obtains through this processing method can better be applicable to brilliant painted of drink such as acidity.
A kind of chlorophyll copper sodium salt processing method that is used to contain acid drink of the present invention is characterized in that may further comprise the steps:
A, choose sodium copper chlorophyllin, add demineralized water and produce the chlorophyll copper sodium saline solution, leave standstill and it was fully dissolved in 2 to 4 hours, and remove by filter insoluble matter with 320 mesh filter screens;
B, adopt the acid food additive to be in harmonious proportion above-mentioned chlorophyll copper sodium saline solution, said acid food additive is by citric acid, tartaric acid, malic acid and other suitable food additives are formed, each composition weight content is citric acid 5-40%, tartaric acid 1-70%, malic acid 3-60%, other suitable food additives 20-91%, fully stir in the harmonic process, mixing time is 40-50 minute, make its pH value less than 7, make acid chlorophyll copper sodium saline solution, precipitate after 12 to 48 hours, the mode that adds extruding with filter cloth removes by filter insoluble matter, obtains directly adding the pure acid chlorophyll copper sodium saline solution of acid drink at last.
Processing method of the present invention, to be weakly alkaline natural chlorophyll copper sodium by the dilution dissolving, and the pH value of the adding acid food additive mediation aqueous solution, make the chlorophyll copper sodium saline solution that is acid, and remove the insoluble matter impurity such as (as solids such as undissolved solute or other flocculates) of each the stage aqueous solution or the inferior after-stage aqueous solution etc. through mode such as filtration, make pure chlorophyll copper sodium saline solution at last, make it possess the characteristic that is dissolved in acidic liquid fully.In producing transparent acid drink crystalline substance, be used for painted, the green acid drink that can produce pure (glittering and translucent) is brilliant, the chemical synthesis green pigment that alternative this class acidic beverages uses always helps satisfying that the growing pursuit of consumers in general is natural, green, the demand of environment protection health drink.Adopt demineralized water dilution dissolving sodium copper chlorophyllin, be beneficial to the abundant dissolving of sodium copper chlorophyllin, reduce the generation of solids such as flocculate, reduce consuming sodium copper chlorophyllin.Though these food additives may play some catalysis, transformation effect, but the inherent characteristic that still can keep sodium copper chlorophyllin at aspects such as color and luster, smell, mouthfeels, big change does not take place in the physicochemical characteristic of the food additives that added yet, simultaneously, make the pure acid chlorophyll copper sodium saline solution that makes at last have the characteristic that is dissolved in acidic liquid fully.
The specific embodiment
Embodiment 1, the present invention is used to contain the chlorophyll copper sodium salt processing method of acid drink, with sodium copper chlorophyllin at fruity water, fruit syrup, maximum use amounts such as carbonated drink assembled alcoholic drinks are that example is carried out relevant explanation, use sanitary standard according to food additives, the maximum use amount of this based food is per kilogram 0.5 gram, as produce 1000 kilograms of such acid transparent drinks, can choose sodium copper chlorophyllin 500 grams, distilled water 500 grams, demineralized water 6500 grams: in the molten device of dissolving, at first sodium copper chlorophyllin is measured in choosing and be diluted to paste with above-mentioned choosing amount distilled water, secondly with choosing amount demineralized water it is diluted to the chlorophyll copper sodium saline solution, chlorophyll copper sodium saline solution after this dilution can leave standstill 2 hours, 2.5 hour, 3 hours, 3.5 hour or 4 hours, treat that sodium copper chlorophyllin fully dissolves; Above-mentioned chlorophyll copper sodium saline solution is filtered with 320 mesh filter screens, remove undissolved sodium copper chlorophyllin in this aqueous solution, insoluble matter (solid content) impurity such as other flocculates, obtain chlorophyll copper sodium saline solution to be in harmonious proportion: be selected from by following component content proportioning by the acid food additive citric acid, tartaric acid, malic acid, a kind of in the composite acid that other suitable food additives are formed, 1 citric acid 5%, tartaric acid 1%, malic acid 3%, other suitable food additives 90%, 2 citric acids 5%, tartaric acid 70%, malic acid 3%, other suitable food additives 22%, 3 citric acids 40%, tartaric acid 1%, malic acid 3%, other suitable food additives 56%, 4 citric acids 5%, tartaric acid 1%, malic acid 60%, other suitable food additives 34%, 5 citric acids 10%, tartaric acid 20%, malic acid 40%, other suitable food additives 30%, 6 citric acids 20%, tartaric acid 35%, malic acid 10%, other suitable food additives 35%, 7 citric acids 5%, tartaric acid 15%, malic acid 60%, other suitable food additives 20%, with this composite acid mediation chlorophyll copper sodium saline solution above-mentioned to be in harmonious proportion, in harmonic process, can fully stir, mixing time can be controlled in 30 minutes, 35 minutes, 40 minutes, 45 minutes, 50 minutes or 60 minutes etc., make its pH value less than 7, make acid chlorophyll copper sodium saline solution; With above-mentioned acid chlorophyll copper sodium saline solution place container precipitate 12 hours, 15 hours, 16 hours, 24 hours, 30 hours, 40 or 48 hours, collect the liquid on container top, removal falls to the impurity such as insoluble matter of container bottom, then, filter one time with filter cloth (can select 10 * 10 canvas for use) impressed pressure (as the pressure that adds 3 kilograms gets final product) extruding is smart, further the degree of purity of fortified water solution makes pure acid chlorophyll copper sodium saline solution; Will this pure acid chlorophyll aqueous solution during use directly add in the acidic liquid to be colored of selected amount and go, just can produce and contain acid green transparent drink crystalline substance.
Embodiment 2, except that following technology contents, the other technologies part can be identical with the counterpart in the embodiment 1.Select distilled water 7000 grams for use, need not demineralized water.
Embodiment 3, except that following technology contents, the other technologies part can be identical with the counterpart in the embodiment 1.Select demineralized water 7000 grams for use, need not distilled water.
Embodiment 4, except that following technology contents, the other technologies part can be identical with the counterpart in the embodiment 1.Above-mentioned food additives can be selected any in citric acid, tartaric acid and the malic acid for use.
Embodiment 5, except that following technology contents, the other technologies part can be identical with the counterpart in the embodiment 1.Above-mentioned food additives can be selected citric acid, tartaric acid and malic acid simultaneously for use.
The present invention also can directly produce other pure acid chlorophyll copper sodium saline solutions of setting content (concentration), and requires to calculate the actual demand amount according to the sour drink that contains to be produced, adds to get final product.Take stage and mode that the present invention removes impurity not only refer to the mode that above-mentioned embodiment is cited, also comprise other conspicuous implementations, as long as can make the pure acid chlorophyll copper sodium saline solution that makes at last, directly add and produce the qualified transparent drink of green pure acidity and get final product.
Claims (1)
1, a kind of chlorophyll copper sodium salt processing method that is used to contain acid drink is characterized in that may further comprise the steps:
A, choose sodium copper chlorophyllin, add demineralized water and produce the chlorophyll copper sodium saline solution, leave standstill and it was fully dissolved in 2 to 4 hours, and remove by filter insoluble matter with 320 mesh filter screens;
B, adopt the acid food additive to be in harmonious proportion above-mentioned chlorophyll copper sodium saline solution, said acid food additive is by citric acid, tartaric acid, malic acid and other suitable food additives are formed, each composition weight content is citric acid 5-40%, tartaric acid 1-70%, malic acid 3-60%, other suitable food additives 20-91%, fully stir in the harmonic process, mixing time is 40-50 minute, make its pH value less than 7, make acid chlorophyll copper sodium saline solution, precipitate after 12 to 48 hours, the mode that adds extruding with filter cloth removes by filter insoluble matter, obtains directly adding the pure acid chlorophyll copper sodium saline solution of acid drink at last.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410035721 CN1284489C (en) | 2004-09-03 | 2004-09-03 | Chlorophyll copper sodium salt treatment method for acidic beverage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410035721 CN1284489C (en) | 2004-09-03 | 2004-09-03 | Chlorophyll copper sodium salt treatment method for acidic beverage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1596766A CN1596766A (en) | 2005-03-23 |
| CN1284489C true CN1284489C (en) | 2006-11-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410035721 Expired - Fee Related CN1284489C (en) | 2004-09-03 | 2004-09-03 | Chlorophyll copper sodium salt treatment method for acidic beverage |
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| Country | Link |
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| CN (1) | CN1284489C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643560B (en) * | 2012-04-11 | 2014-06-25 | 山东广通宝医药有限公司 | Sodium copper chlorophyllin product capable of being used in acidic condition and preparation method thereof |
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2004
- 2004-09-03 CN CN 200410035721 patent/CN1284489C/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1596766A (en) | 2005-03-23 |
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