CN1280014A

CN1280014A - Deodorizing composition

Info

Publication number: CN1280014A
Application number: CN 99110426
Authority: CN
Inventors: 鸟居国司; 松田良藏
Original assignee: FUJIHARA HIDEGO
Current assignee: FUJIHARA HIDEGO
Priority date: 1999-07-07
Filing date: 1999-07-07
Publication date: 2001-01-17
Anticipated expiration: 2019-07-07
Also published as: CN1193797C

Abstract

A deodorant composite contains persimmon juice and persimmon leaf water-extracting liquid in the form of liquid or concentrated solid. It may contain an optional non-toxic vehicle, such as dextrin.

Description

Deodorant compositions

The present invention relates to be used for living space deodorization as toilet and kitchen, and extensive stock, as deodorant deodorant compositions such as food, cosmetics, yarn fabrics.

United States Patent (USP) 4,681,757 disclose a kind of deodorant compositions that contains Fructus Kaki (Diospyros kaki) fruit juice as active component.The deodorization mechanism that it is believed that this compositions is that various polyphenol and the condensed tannins class in the Fructus Kaki fruit juice has the ability of adsorbing or sheltering various abnormal smells from the patients.Yet, find this class deodorant compositions, some is used also not exclusively satisfied.Itself just has a kind of abnormal smells from the patient of uniqueness Fructus Kaki fruit juice, and when allowing its spontaneous fermentation, tunning has produced a kind of abnormal smells from the patient of uniqueness again.When using this based composition of high concentration, these abnormal smells from the patients are to make us insupportable.

Therefore, need to eliminate or improved the deodorant compositions of the above-mentioned type of the problems referred to above.

Have been found that Folium Kaki aqueous extract can not only in and the fermentative smell of the uniqueness of Fructus Kaki fruit juice, and when itself and Fructus Kaki fruit juice are united, also strengthened its deodorization.Therefore, the invention provides the deodorant compositions of associating Fructus Kaki fruit juice and Folium Kaki aqueous extract.

Known Folium Kaki contains vitamin C and keampferol, Quercetin and so on flavone compound, knows that also Folium Kaki has weak antibacterial activity.It is believed that these materials and other unknown materials in the Folium Kaki extract have caused above-mentioned synergy.

United States Patent (USP) 4,681 discloses the processing and the preparation of Fructus Kaki fruit juice in 757, is incorporated herein by reference.Method is the Fructus Kaki fruit of breaking immaturity into pieces or sending out puckery preferably, then squeezing.With the fruit juice spontaneous fermentation in a hermetic container that makes, remove desaccharide part again.

Can adopt conventional method to make the Folium Kaki extract, for example extract the Folium Kaki of doing at about 50 ℃ with 10% glycerine water solution.

Deodorant compositions of the present invention can adopt the several different methods preparation.A kind of method comprises evaporates fruit juice and leaf extract respectively under the decompression, obtain concentrated solution separately, then they is mixed.Another kind method also is the best way, is included in to merge fruit juice and the leaf extract of collecting in the hermetic container, and this mixture is spontaneously fermented, and adds a certain amount of non-toxic excipients, then this mixture of spray drying.The better excipient example that is used for this purpose has, and water-soluble saccharides is as lactose, dissolving starch or dextrin.The ratio of each component can be different in the deodorant compositions, generally by non-volatile part or evaporated residue, per 1 weight portion Folium Kaki extract, about 1 to 10 weight portion Fructus Kaki fruit juice.

Embodiment

Further confirmed the present invention by the following examples.Herein unless otherwise indicated, part and percent are by weight.

Embodiment 1

200 parts of dried Folium Kaki are immersed in 200 parts 50 ℃ 10% glycerine water solution 24 hours, remove by filter leaf, obtain the aqueous extraction liquid of Folium Kaki.

This extract mixes with the fruit juice of collecting from 800 parts of immaturity Fructus Kaki fruits (about 400 parts).This mixture is placed a hermetic container, kept 6 months under the room temperature, make its spontaneous fermentation.

Mixture vapourisation under reduced pressure after handling like this is to doing.Obtain about 60 parts pale powder.This product can be used for the deodorizing test of embodiment 2 and 3.

In order to compare purpose, be raw material only respectively with Fructus Kaki fruit juice and Folium Kaki extract, the dehydration of duplication similarity obtains the concentrate of doing.

The deodorant compositions preparation method of another kind of form is, adds 5 to 10 parts of dextrin in the spontaneous fermenting mixture of 100 portions of fruit juice and leaf extract, and spray drying has added the mixture of dextrin then.

Embodiment 2

The drying that is made by embodiment 1 concentrates the test specimen below the powder preparation.

The aqueous solution of the sample A:3% present composition.

The aqueous solution of the sample B:1% present composition.

The aqueous solution of sample C:5% Fructus Kaki concentration of juices liquid.

The aqueous solution of the spissated Folium Kaki extract of sample D:5%.

The 500ml conical flask of every kind of test specimen of a plurality of 1ml of containing is provided.Respectively add 500ppm ammonia in these flasks, airtight at once each flask behind the adding ammonia left standstill 30 minutes.Measure the residual concentration of ammonia in the bottle then with Kitagawa gas detecting test tube.Residual concentrations in the comparative test sample and the blank residual concentrations of measuring when not having test specimen are calculated the percent that removes deammoniation.

Add 20ppm trimethylamine, 15ppm methanthiol, 20ppm hydrogen sulfide and 20ppm isovaleric acid respectively, carry out same test.

The results are shown in table 1.

Table 1: abnormal smells from the patient is removed percent

Abnormal smells from the patient	Sample
	Sample				????A	????B	????C	????D
	Ammonia	????100	????90	????75	????A	????B	????C	????D	????5
Trimethylamine	Ammonia	????100	????90	????75	????100	????95	????70	????10	????5
Trimethylamine	Methanthiol	????100	????90	????65	????100	????95	????70	????10	????0
Hydrogen sulfide	Methanthiol	????100	????90	????65	????100	????95	????70	????5	????0
Hydrogen sulfide	Isovaleric acid	????100	????90	????80	????100	????95	????70	????5	????0

Table 1 shows that when only using the Folium Kaki extract, it does not have or only have very little deodorization, but it has strengthened the deodorization of blended with it Fructus Kaki fruit juice.Comparative sample B and sample C have confirmed this point.The sample B that only contains 1% present composition has stronger deodorization than containing the 5% sample C that concentrates Fructus Kaki fruit juice.

Embodiment 3

Three groups of healthy adult experimenters, every group comprises three male and three women, and oral respectively 100ml contains the aqueous suspensions that contains ground garlic granules of 0.1%w/v and the spissated Fructus Kaki fruit juice of 5%w/v (B group) of the aqueous suspensions (A group) of the ground garlic granules of 0.1%w/v and the 1%w/v present composition, same volume and the aqueous suspensions (matched group) that same volume only contains the ground garlic granules of 0.1%w/v.After taking 15 hours, according to following scoring, by the intensity of abnormal smells from the patient in 6 evaluation expert's evaluation test personnel expiration.

0: odorlessness

1: feel a kind of faint abnormal smells from the patient, can not differentiate to be Bulbus Allii

2: feel slight garlic smell.

3: feel medium garlic smell.

4: feel intensive garlic smell.

5: feel very intensive garlic smell.

Table 2 has been listed the average score of each group testing crew being made by every expert.

Table 2

Expert's numbering	Average rank
	Average rank			The A group	The B group	Matched group
	????1	????0．2	????0．2	The A group	The B group	Matched group	????4．4
????2	????1	????0．2	????0．2	????0	????0	????4．2	????4．4
????2	????3	????0	????0	????0	????0	????4．2	????4．0
????4	????3	????0	????0	????0．2	????0．4	????4．2	????4．0
????4	????5	????0	????0．2	????0．2	????0．4	????4．2	????4．0
????6	????5	????0	????0．2	????0．4	????0．4	????4．4	????4．0

Table 2 shows, the deodorant activities of the present composition can with in addition the deodorant activities that concentrates five times concentrated Fructus Kaki fruit juice match in excellence or beauty.

Embodiment 4

According to following prescription, the preparation granular preparation:

3.0 parts of deodorant compositions of the present invention

5.0 parts of Sorbitols

2.0 parts of Fructus Citri junoris fibers

20.0 parts of glucoses

69.9 parts in dextrin

0.1 part of flavoring

Amount to 100.0 parts

Above-mentioned material and low amounts of water are mediated, and are shaped to granule and dry.Zhi Bei deodorizer is suitable for orally like this, is used for oral cavity deodorization or Excreta (excreted faeces) deodorization.

Embodiment 5

According to following prescription, the preparation spray agent:

1.0 parts of deodorant compositions of the present invention

1.0 parts of benzalkonium chlorides

20.0 parts of sodium lauryl sulfates

Purify waste water 78.0 parts

100.0 parts of total amounts

This preparation can be used for the spraying deodorization of kitchen waste, shoe chest, toilet.

Claims

1. deodorant compositions, it comprises the Fructus Kaki fruit juice of liquid concentration or dry conc forms and the mixture of Folium Kaki aqueous extraction liquid.

2. deodorant compositions as claimed in claim 1 is characterized in that, the ratio of described Fructus Kaki fruit juice and described Folium Kaki extract according to the non-volatile matter meter, is 1: 1 to 1: 10 weight ratio.

3. deodorant compositions as claimed in claim 1 is characterized in that, described deodorant compositions also comprises a kind of non-toxic excipients that is selected from saccharide or polysaccharide.

4. deodorant compositions as claimed in claim 3 is characterized in that described excipient is a dextrin.

5. a method for preparing deodorant compositions comprises the following steps:

Mix Fructus Kaki fruit juice and Folium Kaki aqueous extraction liquid;

Make this mixed liquor spontaneous fermentation time enough in a hermetic container, remove its sugar part basically;

In described mixed liquor, add a certain amount of dextrin;

Spray drying adds the mixed liquor of dextrin.

6. method as claimed in claim 5 is characterized in that, from immaturity Fructus Kaki fruit or send out Fructus Kaki puckery and really collect described fruit juice.

7. method as claimed in claim 5 is characterized in that, described Folium Kaki extract makes by extract exsiccant Folium Kaki with glycerine water solution.

8. method as claimed in claim 5 is characterized in that, the amount of described dextrin is that the described mixture of per 100 weight portions adds 5 to 10 weight portion dextrin.