CN1279823C - Composition for controlling pest parasitic on tree - Google Patents
Composition for controlling pest parasitic on tree Download PDFInfo
- Publication number
- CN1279823C CN1279823C CNB028144554A CN02814455A CN1279823C CN 1279823 C CN1279823 C CN 1279823C CN B028144554 A CNB028144554 A CN B028144554A CN 02814455 A CN02814455 A CN 02814455A CN 1279823 C CN1279823 C CN 1279823C
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- Prior art keywords
- tree
- pine
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
Abstract
A composition for controlling pests parasitic on trees which contains as the active ingredient S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate; a method of controlling the pests; and a method of protecting trees.
Description
Technical field
The present invention relates to S-sec-butyl O-ethyl 2-oxo-1,3-thiazoles alkane-3-base thiophosphate (common name: thiazolone phosphorus; Fosthiazate), use the method for preventing and treating of pest of said composition and the guard method of trees as the composition for preventing and controlling tree parasitic pest for tree of active ingredient.
Background technology
The spy opens and discloses the organophosphorus compound that comprises thiazolone phosphorus among the clear 60-136590 is useful as desinsection, the active ingredient of killing mite, nematocide.
On the other hand, the spy opens among the flat 2-88590, discloses (-) optical isomer of thiazolone phosphorus and as the serviceability of noxious animal agent for preventing and eliminating.Wherein, as plant parasitic nematodes, illustration pine wood nematodes., do not see concrete record for their control.
If pest colonizes on the trees, then can cause damage owing to getting the growth of influences such as food or generation toxin to trees, can make trees withered.For this problem, take always be to processing, burning disposal that trunk injects medicament think by the trees of parasitism part or all and so on prevent the countermeasure of encroaching on, be in the state of also not finding more effective countermeasure now.
The objective of the invention is, the method for the pest of parasitism on the high efficiency control trees is provided.
Disclosure of an invention
Present inventors have carried out conscientious research in order to solve above-mentioned problem, found that by using specific active ingredient can reach desired purpose, have finished the present invention thus.
Promptly; the present invention contains the composition for preventing and controlling tree parasitic pest for tree (be designated hereinafter simply as composition) of thiazolone phosphorus as active ingredient, uses thiazolone phosphorus as the method for preventing and treating (being designated hereinafter simply as the method for control) of the tree parasitic pest for tree of active ingredient and use the guard method (be designated hereinafter simply as guard method) of thiazolone phosphorus as the trees of active ingredient.
The best mode that is used to carry out an invention
There is optical isomer in the thiazolone phosphorus, comprises various isomer, both uses of isomer mixture among the present invention.
There is no particular limitation for the trees that become object of protection, can enumerate for example forest of pine tree, Chinese fir, cypress etc.; The fruit tree of citrus, apple, pears, fig, persimmon, peach, grape, chestnut, cherry, plum, wild cherry, loquat, oleaster, plum etc.; The landscape tree of cuckoo, azalea, tea plum, japanica, the rose of Sharon, oriental cherry, sweet osmanthus, maple etc.Wherein can effectively prevent and treat the pest of forest parasitism, particularly effectively prevent and treat pest parasitic on the pine tree.And, become the pine tree of object of protection, be not limited only to the pine tree in the mountain forest, also comprise the pine tree of the multiple different places of park, garden, pine forest, golf course etc.
As the pest that becomes controlling object, what can enumerate is that for example pine wood nematodes etc. produces the Turbatrix of baneful influence to arboreal growth; Ponderous borer as Japanese ponderous borer etc. belongs to, cuts as adit Dendroctonuses such as tip bark beetle; The boring insect of getting the food infringement among the trees that enters as the Curculio of hickie Song Xiang etc. etc.; As sucking insects such as Aphis, shell Eimeria, lecanium genus such as the white aphids of dragon spruce frost; Tetranychus as pine needle mite etc.; Belong to as flies such as loose gallfly, China fir gallflys; Get the feeding habits insect as leaf roller genus, geometrid moth genus, tea bagworm genus, gamasid genus, Tetranychus etc.In the control of Turbatrix, boring property insect, be effectively wherein, special effective for the control of pine wood nematodes, Japanese ponderous borer.
Because composition of the present invention can doublely be controlled Turbatrix and boring property insect, therefore can protect trees expeditiously and not be subjected to the harm of pest.For example, for the withered problem of trunk generation of pine tree, chief reason is that pine wood nematodes colonizes on the pine tree, causes the physically different of pine tree, if therefore pine wood nematodes is prevented and treated, then can prevent the withered of pine tree.; pine wood nematodes and Japanese ponderous borer are symbiosis, because Japanese ponderous borer is by being media with the pine wood nematodes, its parasitic scope expands very wide scope to; therefore only carry out control, also can't obtain basic solution as the pine wood nematodes that causes the withered main cause of pine tree.Therefore, can get rid of main cause (for example preventing and treating pine wood nematodes) as obstruction arboreal growths such as pine tree wither, and, the composition of the present invention that can get rid of less important reason (for example also preventing and treating Japanese ponderous borer) as the media worm, because under few usage amount, can obtain large-scale effect, be very useful and practical therefore.
To the processing method of composition of the present invention, there is no particular limitation, and what for example can enumerate is that the tree body injects processing, soil treatment under the tree crown, and cauline leaf is handled, coating is handled etc.Inject as above-mentioned tree body and to handle, what for example can enumerate is the method handled in the trunks of trees or root system etc.As soil treatment under the tree crown, what for example can enumerate is the thinner suitably spreading liquid of the various preparations of dilution or the method that aqueous preparation itself is handled soil of water etc., solid pharmaceutical preparation itself processing soil surface or excavate soil and count the method for handling about cm.In the above-mentioned processing method, soil treatment under the preferred tree crown, the more preferably suitably spreading liquid or the aqueous preparation itself of the various preparations of dilution of the thinner of water etc. wherein, soil-perfusion processing under the tree crown of soil is handled in perfusion.Can handle with sprayer during processing, also can handle by manual.To handle be the processing method with various advantages in soil-perfusion under the tree crown, but in the art also not in the processing method of commercial successful example.For example can enumerate as above-mentioned advantage: 1) be not need special technical ability, the easy processing method that gets final product of the soil-perfusion soup around the trees only, 2) to processing time of medicament without limits, 3) 1 trees necessary operations processing time, injecting processing with this area at the more trunk of commercial enforcement compares and will lack, 4) do not need trunk inject to handle recycling bottles after the processing of needs, 5) do not need trunk to inject and handle necessary perforate on trunk, thereby damage the outward appearance of trees, can not cause the corruption that causes trees from entering of the germ of medicament hand-hole or wind and snow or resistance reduction etc.
The present composition, because the infiltration of thiazolone phosphorus in trees as active ingredient shifted, can obtain desired effect by Local treatment, but pass through as soil treatment under the above-mentioned tree crown, more preferably soil-perfusion is handled under the tree crown, thiazolone phosphorus as active ingredient can shift and obtain desired effect to trunk penetration from root, so particularly useful.For example, as above-mentioned pine wood nematodes or, the trees inside of Japanese ponderous borer etc. in pine tree, in particular in trunk inside, the pest of branch inside and/or root parasitism by the Local treatment of the such present composition of soil treatment under the tree crown, can prevent and treat.
Composition of the present invention in addition can obtain to prevent and treat the effect of two aspects.Promptly, trees be compromised before the generation or confirm parasitic pest handle in the period arbitrarily before existing the method that obtains desired effect and, after the infringement of trees takes place or confirm that parasitic pest handles the method both of the desired effect of acquisition and become possibility in any period after existing.
The processing of the present composition; kind and size according to the trees that constitute object of protection; constitute kind or the situation occurred of the pest of controlling object, further according to the difference of the condition of meteorology or soil, processing period, preparation form etc. can not be without exception regulation.Among the present invention, the concentration of thiazolone phosphorus in trees as active ingredient is 0.1-100ppm usually, is preferably 1-10ppm.Its treating capacity, if for example to the trees about people's breastheight degree diameter (near the diameter of trunk about 1m on the ground) 10cm, the thiazolone phosphorus of one tree wood is 5-400g, in the scope of preferred 20-100g.But optimal concentration of treatment or treating capacity can be investigated above-mentioned various conditions, carry out suitable preliminary experiment etc. and indivedual decision.
The method of preventing and treating of the present invention is the thiazolone phosphorus as active ingredient to be modulated into above-mentioned concentration of treatment or treating capacity handle the method for control pest to around the trees that constitute object of protection or its.The processing method that can adopt is the whole bag of tricks of above-mentioned explanation, and its processing time can be selected the time arbitrarily.Guard method of the present invention is for preventing and treating above-mentioned pest like this, the method for object of protection trees.
Among the present invention, can use or use simultaneously thiazolone phosphorus and other preventing and controlling tree parasitic pest for tree composition with.And can use or use simultaneously other agricultural chemicals (insecticide, nematocide, miticide, kill soil pests agent, bactericide, antivirotic, attractant, antibiotics, plant hormone, weed killer herbicide, plant growth regulator etc.), fertilizer, soil conditioner, poisoning palliative, soil permeability agent etc. as required with.And thiazolone phosphorus and above-mentioned other various compositions can be distinguished preparation separately, when handling, mix and handle, also can both together formulated handle.
Among the present invention, thiazolone phosphorus can be mixed with the preparation of various dosage forms according to the various formulation methods of this area, but the preparation that is fit to soil treatment under the tree crown, dosage form that more preferably soil-perfusion is handled under the tree crown is useful.As this dosage form, what for example can enumerate is pulvis, granule, granula subtilis, tablet, wetting powder, wettable granula, water solube powder, water-soluble granule, suspending agent, opacifier, microemulsion, suspension emulsion, emulsion, aqua, gel, smears, capsule etc.Wherein preferred granula or aqua, more preferably aqua.
As operable various auxiliary agents when preparation is prepared, what can enumerate is following example.The solid carrier of kaolin, diatomite, calcium carbonate, talcum, Emathlite, bentonite, pyrophyllite, attapulgite, kaolinite, perlite, vermiculite, zeolite, silica sand, silica, pumice, white carbon black, gypsum, saltcake, sodium carbonate, niter cake, ammonium sulfate, sodium chloride, urea, sucrose, glucose, flour, starch etc.; The solvent of dimethylbenzene, trimethylbenzene, durol, cyclohexane, solvent naphtha, kerosene, chlorobenzene, carrene, acetone, MEK, cyclohexanone, ethanol, isopropyl alcohol, ethylene glycol, propane diols, polyethylene glycol, polypropylene glycol, methyl proxitol, dipropylene glycol methyl ether, propylene glycol butyl ether, dimethylacetylamide, dimethyl sulfoxide (DMSO), N-N-methyl-2-2-pyrrolidone N-, water etc.; As soap, benzoate, alkyl sulfo succinate, dialkyl sulfosuccinates, polycarboxylate, alkyl sulfate salt, alkyl sulfate, alkyl aryl sulfate, alkyl diethylene glycol ether sulfate, the alcohol sulfuric acid, alkylsulfonate, alkylaryl sulfonates, arylsulphonate, lignosulfonates, alkyl diphenyl base ether disulfonate, poly styrene sulfonate salt, alkyl phosphate salt, alkylaryl phosphate, the styryl aryl orthophosphate, the polyoxyethylene alkyl ether sulfuric acid, polyoxyethylene alkylaryl ether sulphate, the polyoxyethylene alkylaryl ether sulfuric acid, polyoxyethylene alkyl ether phosphate, polyxyethylated aryl phosphate ester salt, the surfactant of anionic species such as the salt of naphthalene sulfonic acid-formaldehyde condensation product; As fatty acid esters of sorbitan, fatty acid glyceride, fatty acid polyglycerol ester, the fatty acid alcohol polyglycol ether, acetylenediol, acetenyl alcohol, the alkylene oxide block polymer, polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene styryl aryl ether, the polyoxyethylene glycol alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, the polyoxyethylene fatty acid glyceride, polyoxyethylene hardened castor oil, the surfactant of the nonionic class of polyoxypropylene fatty acid ester; The vegetable oil or the mineral wet goods of olive oil, kopok oil, castor oil, palm oil, Chinese toon oil, cocoa butter, sesame oil, corn oil, rice bran oil, peanut oil, cottonseed oil, soybean oil, rapeseed oil, linseed oil, tung oil, atoleine etc.
In addition, can use solvent, tackifier, sedimentation to prevent that agent, antifreezing agent, dispersion stabilizer, mould inhibitor, antipoison, anticoagulant, fluidity amendment, defoamer, decomposition from preventing normally used various auxiliary agents such as agent.Under the limit that does not break away from the object of the invention, can further select to use auxiliary agent known in the art.The mixed proportion of thiazolone phosphorus and various auxiliary agents is generally 0.01: 99.99～95: 5, is preferably 0.1: 99.9～90: 10.These preparations can directly use when reality is used, or thinner that can water etc. is diluted to predetermined concentration, and use after adding various solvents as required.In addition, thiazolone phosphorus can utilize commercially available thiazolone phosphorus.
Below put down in writing particularly preferred scheme among the present invention.
When [1] tree parasitic pest for tree is nematoda parasitic on the pine tree, above-mentioned composition, prevent and treat method or guard method.
When [2] tree parasitic pest for tree is boring insect parasitic on the pine tree, above-mentioned composition, prevent and treat method or guard method.
When [3] tree parasitic pest for tree is nematoda parasitic on the pine tree and boring property insect, above-mentioned composition, prevent and treat method or guard method.
[4] by soil treatment under the tree crown, parasitic nematoda above-mentioned prevents and treats method or guard method on the control pine tree.
[5] by soil treatment under the tree crown, parasitic boring insect above-mentioned prevents and treats method or guard method on the control pine tree.
[6] by soil treatment under the tree crown, parasitic nematoda and boring property insect above-mentioned prevents and treats method or guard method on the control pine tree.
[7] processing method is above-mentioned [4], the method for preventing and treating or the guard method of [5] or [6] that the soil-perfusion under the tree crown is handled.
[8] nematoda be above-mentioned [1], [3], [4] or [6] of pine wood nematodes composition, prevent and treat method or guard method.
[9] boring property insect be above-mentioned [2], [3], [5] or [6] of Japanese ponderous borer composition, prevent and treat method or guard method.
[10] use thiazolone phosphorus, the nematoda of parasitism and/or boring property insect on the control pine tree.
[11] use thiazolone phosphorus, parasitic pine wood nematodes and/or Japanese ponderous borer on the control pine tree.
[12] soil treatment thiazolone phosphorus under the tree crown, the nematoda of parasitism and/or boring property insect on the control pine tree, or protection pine tree.
[13] thiazolone phosphorus is carried out soil treatment under the tree crown, control endoparasitic nematoda of pine tree and/or boring property insect.
[14] thiazolone phosphorus is carried out soil treatment under the tree crown, parasitic pine wood nematodes and/or Japanese ponderous borer on the control pine tree.
[15] thiazolone phosphorus is carried out soil treatment under the tree crown, control endoparasitic pine wood nematodes of pine tree and/or Japanese ponderous borer.
Below put down in writing embodiments of the invention, but the present invention is not subjected to the restriction of following embodiment.At first, put down in writing preparation preparation embodiment.
Example of formulations 1
The thiazolone phosphorus that mixes 10.5g, the polyoxyethylene styryl phenyl ether of 4g and the mixture of dodecyl benzene sulfonate (trade name: ソ Le Port-Le 355; Dong Bang chemical industrial company makes) and the high boiling organic solvent (trade name: DBE, E.I.Du Pont Company's manufacturing) of 85.5g, aqua obtained.
Example of formulations 2
The thiazolone phosphorus that mixes 31.6g, the polyoxyethylene styryl phenyl ether of 8g (trade name: ノ イ ゲ Application EA-137; The first industrial drugmaker makes) and the dipropylene glycol methyl ether (trade name: ダ ワ ノ-Le DPM of 60.4g; ダ ウ ケ ミ カ Le Japanese firm makes), obtain aqua.
Example of formulations 3
The thiazolone phosphorus that mixes 52.6g, the polyoxyethylene styryl phenyl ether of 20g and the mixture of dodecyl benzene sulfonate (trade name: ソ Le Port-Le 355H; Dong Bang chemical industrial company makes) and the tripropylene glycol methyl ether (trade name: ダ ワ ノ-Le TPM of 27.4g; ダ ウ ケ ミ カ Le Japanese firm makes), obtain aqua.
Example of formulations 4
Mix the thiazolone phosphorus of 2.1g and 20～50 purpose silica granules (manufacturing of East Sea industrial group) of 197.9g, obtain granule.
Example of formulations 5
The polyoxyethylene styrene phenyl ether (trade name: ノ イ ゲ Application EA-177 of having mixed 20 weight % with respect to thiazolone phosphorus; The manufacturing of the first industrial drugmaker) 6.6g product is with the mineral grain (trade name: Network ニ ミ ネ fine grained of 93.4g; Network ニ ミ ネ industrial group makes) absorb, obtain granule.
Example of formulations 6
16～50 purpose graininess gypsum (trade name: ア グ ソ-Block CN at 89.5g; OIL DRI company makes) the middle thiazolone phosphorus that absorbs 10.5g, obtain granule.
Example of formulations 7
The thiazolone phosphorus that mixes 21.1g, the polyoxyethylene styryl phenyl ether of 6g (trade name: ソ Le Port-Le T15; Dong Bang chemical industrial company makes), the Emulsifier EL-60 of 4g (trade name: ソ Le Port-Le CA50, Dong Bang chemical industrial company makes) and 68.9g aromatic solvent (trade name: ソ Le ベ Star ソ 150; エ Network ソ Application ジ ヤ パ Application company makes), obtain emulsion.
Below, put down in writing the test example.
Test example 1
In having cultivated the 9ml suspension of pine wood nematodes, (comprise 1250-1300 pine wood nematodes), add the aqueous solution that 1ml contains the thiazolone phosphorus of normal concentration, put it in the timing ware after, placed 24 hours when remaining on 23 ℃.
Then, the counting inertia worm pine wood nematodes of few activity (motionless fully or) is obtained inertia worm rate by following formula, obtains the result of table 1.
Inertia worm rate (%)=[the whole pine wood nematodes numbers before inertia borer population/thiazolone phosphorus is handled] * 100
Table 1
| Active ingredient | Concentration of treatment (ppm) | Inertia worm rate (%) |
| Thiazolone phosphorus | 100 | 100 |
| 50 | 100 | |
| 10 | 100 | |
| 5 | 100 | |
| Be untreated | - | 0 |
Test example 2
On the withered wood chip (5g) that decreases wood of the pine tree of pine wood nematodes parasitism, spraying 5ml contains the aqueous solution of the thiazolone phosphorus of normal concentration, will be covered after filter paper puts into culture dish by water-moistened wood chip, remains on 22 ℃ and places 10 days.
Then, carry out the inspection of pine wood nematodes by the graceful method of Bel, counting has the borer population alive of activity, obtains the result of table 2.And the survival number of pine wood nematodes is the mean value of three wood chip survival numbers.
Table 2
| Active ingredient | Concentration of treatment (ppm) | Pine wood nematodes survival number (head) |
| Thiazolone phosphorus | 50 | 13 |
| 100 | 0 | |
| Be untreated | - | 190 |
Test example 3
The soil of the following peripheral of the trunk of the Korean pine seedling of will be in the greenhouse planting in No. 12 plastic basin (diameter 1.3cm) excavates number cm, use handle according to the granule of the thiazolone phosphorus of above-mentioned example of formulations 6 preparations after, soil is buried.The treating capacity of thiazolone phosphorus is 600mga.i./strain.Handle after 2 days and after 16 days with 20 purpose nylon insect protected squares on branch, respectively put into several Japanese ponderous borer adults therein.At any time observe after putting worm, investigate dead borer population and obtain dead worm rate, obtain the result of table 3 with following formula.
Dead worm rate (%) [dead borer population/put borer population] * 100
Table 3
| Put worm | Investigation | Dead worm rate (100%) |
| Handle after 2 days | Put worm after 3 days | 80 |
| Put worm after 9 days | 100 | |
| Handle after 16 days | Put worm after 3 days | 100 |
Test example 4
The Cheng Mu of pine tree (under the tree crown of the diameter of a cross-section of a tree trunk 1.3 meters above the ground 9～24cm), 1. will be according to the regulation dose of the aqua of the thiazolone phosphorus of above-mentioned example of formulations 2 preparations, use to be connected to pressure and to be adjusted into 20kg/cm
3Motor atomizer on soil-perfusion machine (trade name: Port ア-ノ ズ Le field is forever made manufacturing), pour into processing (groundwater increment is per 1 place 2 liters) at 4 or 8 places (dark 15cm) that with the trunk are the concentric circles at center, in addition, 2. will be according to the granule of the thiazolone phosphorus of above-mentioned example of formulations 6 preparations, be about the dark 15cm of concentric circles that digs out of center with the trunk, in the ditch about wide 20cm, bury after spreading down particle.
After handling about 70 days, near the trunk the about 1m of portion,, on per 1 strain pine tree Cheng Mu, inoculate 30000 pine wood nematodes on the ground with the drill bit punching of diameter 6mm.
Inoculate after 6 months,, confirm whether detect pine wood nematodes, obtain the withered rate of pine tree Cheng Mu simultaneously by the graceful method of Bel with boring the wood powder of respectively taking 10g from the Cheng Mu of pine tree.Table 4 ecbatic.
Table 4
| Reagent agent | The treating capacity of thiazolone phosphorus | For trying into wooden number | Average diameter at breast height (cm) | Check out the one-tenth wood number of pine wood nematodes | Withered rate (10%) |
| The wooden number of withered one-tenth/confession tries into wooden number | |||||
| Aqua | 40g(a.i.) | 5 | 15.0 | 0 | 0 |
| 0/5 | |||||
| 80g(a.i.) | 5 | 16.6 | 0 | 0 | |
| 0/5 | |||||
| Granule | 40g(a.i.) | 5 | 15.2 | 0 | 0 |
| 0/5 | |||||
| 80g(a.i.) | 5 | 14.2 | 0 | 0 | |
| 0/5 | |||||
| Non-processor | - | 5 | 14.8 | 5 | 60 |
| 3/5 |
From above-mentioned result of the test as can be known, by composition of the present invention is carried out soil treatment under the tree crown, can prevent and treat the endoparasitic pest pine wood nematodes of trees.
Industrial practicality
The invention provides and contain thiazolone phosphorus as the new composition for preventing and controlling tree parasitic pest for tree of active ingredient; use thiazolone phosphorus as the method for preventing and treating of the new tree parasitic pest for tree of active ingredient, and use thiazolone phosphorus as the guard method of the new trees of active ingredient.
Claims (3)
1. soil treatment S-sec-butyl O-ethyl 2-oxo-1,3-thiazoles alkane under the tree crown-3-base thiophosphate, the method for preventing and treating of the tree parasitic pest for tree of parasitic pine wood nematodes and/or Japanese ponderous borer on the control pine tree.
2. the method for claim 1 record is prevented and treated endoparasitic pine wood nematodes of pine tree and/or Japanese ponderous borer.
3. S-sec-butyl O-ethyl 2-oxo-1,3-thiazoles alkane-3-base thiophosphate is carried out soil treatment under the tree crown, prevents and treats the method that pine wood nematodes parasitic on the pine tree and/or Japanese ponderous borer are protected pine tree.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP226283/2001 | 2001-07-26 | ||
| JP2001226283 | 2001-07-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1533244A CN1533244A (en) | 2004-09-29 |
| CN1279823C true CN1279823C (en) | 2006-10-18 |
Family
ID=19059125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028144554A Expired - Lifetime CN1279823C (en) | 2001-07-26 | 2002-07-04 | Composition for controlling pest parasitic on tree |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2003104813A (en) |
| KR (1) | KR100883253B1 (en) |
| CN (1) | CN1279823C (en) |
| TW (1) | TWI311466B (en) |
| WO (1) | WO2003011032A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4471264B2 (en) * | 2003-01-27 | 2010-06-02 | 日本化薬株式会社 | Mixed fumigant |
| TWI401028B (en) * | 2006-12-27 | 2013-07-11 | Ishihara Sangyo Kaisha | Control the composition of tree parasitic pests |
| MX352271B (en) | 2011-10-07 | 2017-11-16 | Ishihara Sangyo Kaisha | Mixed agrochemical emulsion composition comprising organic phosphorous pesticide and chlorpicrin. |
| CN102388912A (en) * | 2011-10-19 | 2012-03-28 | 广东中迅农科股份有限公司 | Fosthiazate aqueous emulsion and preparation method thereof |
| CN102696673B (en) * | 2012-06-01 | 2013-05-22 | 北京明德立达农业科技有限公司 | Fosthiazate insecticide composition and application thereof |
| CN103039513B (en) * | 2012-12-27 | 2014-12-31 | 广东中迅农科股份有限公司 | Fosthiazate nematicide granules and preparation method thereof |
| WO2016159547A1 (en) * | 2015-04-01 | 2016-10-06 | 대구대학교 산학협력단 | Novel composition for pine wilt disease prevention containing aggregation pheromone 2-(dodecyloxy)ethanol isolated and purified from korean monochamus alternatus and method for preparing same |
| CN107156172A (en) * | 2017-06-14 | 2017-09-15 | 江苏辉丰农化股份有限公司 | Composition pesticide containing fosthiazate and methoxyfenozide |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5661305A (en) * | 1979-10-25 | 1981-05-26 | Kyowa Sangyo Kk | Extermination of bursaphelenchus lignicolus |
| JPS58113111A (en) * | 1981-12-26 | 1983-07-05 | Japan Carlit Co Ltd:The | Agent and method for exterminating bursaphelenchus lignicolus |
| NZ210046A (en) * | 1983-11-11 | 1987-09-30 | Ishihara Sangyo Kaisha | 2-ox(or thi-)azolidinone(or thione) derivatives of thiophosphoric acid and pesticidal compositions |
| JPH0818936B2 (en) * | 1987-07-06 | 1996-02-28 | 住友化学工業株式会社 | Organophosphorus insecticidal composition for controlling forest pests |
| JP2556363B2 (en) * | 1988-09-22 | 1996-11-20 | 石原産業株式会社 | Optically active organophosphorus compounds, their production method and pest control agents containing them |
-
2002
- 2002-06-25 JP JP2002184955A patent/JP2003104813A/en active Pending
- 2002-07-04 CN CNB028144554A patent/CN1279823C/en not_active Expired - Lifetime
- 2002-07-04 WO PCT/JP2002/006802 patent/WO2003011032A1/en active Application Filing
- 2002-07-04 KR KR1020047000968A patent/KR100883253B1/en active IP Right Grant
- 2002-07-10 TW TW091115316A patent/TWI311466B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1533244A (en) | 2004-09-29 |
| KR100883253B1 (en) | 2009-02-10 |
| JP2003104813A (en) | 2003-04-09 |
| TWI311466B (en) | 2009-07-01 |
| WO2003011032A1 (en) | 2003-02-13 |
| KR20040019348A (en) | 2004-03-05 |
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