CN1269979A - 复合型饲料防霉剂 - Google Patents
复合型饲料防霉剂 Download PDFInfo
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- CN1269979A CN1269979A CN99105058A CN99105058A CN1269979A CN 1269979 A CN1269979 A CN 1269979A CN 99105058 A CN99105058 A CN 99105058A CN 99105058 A CN99105058 A CN 99105058A CN 1269979 A CN1269979 A CN 1269979A
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- feed
- organic acid
- inhibitor
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- mildew preventive
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- 230000003449 preventive effect Effects 0.000 title description 4
- 150000001875 compounds Chemical class 0.000 title description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 13
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 12
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims abstract description 7
- 235000019253 formic acid Nutrition 0.000 claims abstract description 7
- 235000010241 potassium sorbate Nutrition 0.000 claims abstract description 7
- 239000004302 potassium sorbate Substances 0.000 claims abstract description 7
- 229940069338 potassium sorbate Drugs 0.000 claims abstract description 7
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019260 propionic acid Nutrition 0.000 claims abstract description 6
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims abstract description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- 239000003112 inhibitor Substances 0.000 claims description 13
- -1 organic acid salt Chemical class 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- 238000005649 metathesis reaction Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 3
- 230000002147 killing effect Effects 0.000 abstract description 2
- 235000019629 palatability Nutrition 0.000 abstract description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
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- Fodder In General (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及一种用于饲料防霉的化学制剂,它由山梨酸钾或苯酸钠与甲酸或乙酸或丙酸经反应制得,具有安全可靠、品质稳定、适口性好等优点,对危害饲料的微生物具有较强的抑制和杀灭作用。合理使用本发明,可使饲料保质期达两个月以上。
Description
本发明涉及一种用于各种饲料在运输和贮存过程中防腐防霉的化学制剂。
当前，饲料工业蓬勃发展，其在整个国民经济中占有的比例越来越大。但是，由于微生物的污染，饲料工业一直为腐败霉变所困扰。为防止腐败霉变的发生，必须在饲料中加入防腐防霉剂进行保质保鲜。目前，普遍采用的防腐防霉剂大致可分为单一型和复配型两类。单一型产品主要以有机酸盐(如甲酸盐、乙酸盐、丙酸盐、山梨酸盐及苯甲酸盐等)和有机酸(如甲酸、乙酸、丙酸、山梨酸及苯甲酸等)为代表，其用量占全部防腐防霉剂用量的90％以上，其主要缺陷是抗菌谱窄，抑菌效果不太理想。复配型产品近年有较大的发展，但由于基本上都采用机械物理方法进行复配，各组分间的协同作用不十分理想，其抑菌活性不能得到充分的发挥，因而有待进一步改进。
本发明的目的在于采用化学方法制得一种高度复合的新型饲料防霉剂，利用该防霉剂中各组分分子间的相互作用，增强协同效果，使其杀菌抑菌活性得到充分的发挥，并取长补短，拓宽抗菌谱，从而减少投入，降低成本。
本发明所述的复合型饲料防霉剂系采用有机酸盐与有机酸经复分解反应制得，所用有机酸盐为山梨酸钾(CH3CH＝CHCH＝CHCOOK)或苯甲酸钠或它们之间的任意组合，所用的有机酸为甲酸(HCOOH)或乙酸(CH3COOH)或丙酸(CH3CH2COOH)或它们之间的任意组合。该防霉剂按有机酸盐∶有机酸＝1.0∶0.3-1.0(质量比)进行反应。先将定量的有机酸盐粉碎至60-150目的细度，加入定量的有机酸，在常温条件下反应至完全，经粉碎至适当目数后即得所需的复合型饲料防霉剂。
本发明防霉剂对危害饲料的主要细菌和霉菌均有较强的抑制和杀灭作用，并具有一定的抗氧化功效，试验表明，合理使用本发明可使饲料的保质期达两个月以上。此外，由于本发明所采用的原料均为国家许可采用的食品添加剂，因此安全可靠，品质稳定，且适口性好。
实施例1：
将100g山梨酸钾粉碎至100目后，置于容器中，加入30g甲酸，在常温常压下反应至完全，粉碎，得成品。
实施例2：
将100g山梨酸钾粉碎至100目后，置于容器中，加入80g乙酸，在常温常压下反应至完全，粉碎，得成品。
实施例3：
将100g山梨酸钾粉碎至100目后，置于容器中，加入50g丙酸，在常温常压下反应至完全，粉碎，得成品。
实施例4：
将50g山梨酸钾与50g苯甲酸钠混合并粉碎至100目后，置于容器中，加入20g甲酸与20g丙酸的混合物，在常温常压下反应至完全，粉碎，得成品。
Claims (3)
1.根据权利要求1所述的复合型饲料防霉剂，其特征在于该防霉剂按有机酸盐∶有机酸＝1.0∶0.3-1.0(质量比)进行复分解反应制得。
2.根据权利要求1所述的复合型饲料防霉剂，其特征在于生产该防霉剂所用的有机酸盐为山梨酸钾或苯甲酸钠或它们之间的任意组合。
3、根据权利要求1或2所述的复合型饲料防霉剂，其特征在于生产该防霉剂所用的有机酸为甲酸或乙酸或丙酸或它们之间的任意组合。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991050584A CN1133376C (zh) | 1999-04-09 | 1999-04-09 | 复合型饲料防霉剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991050584A CN1133376C (zh) | 1999-04-09 | 1999-04-09 | 复合型饲料防霉剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1269979A true CN1269979A (zh) | 2000-10-18 |
| CN1133376C CN1133376C (zh) | 2004-01-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991050584A Expired - Fee Related CN1133376C (zh) | 1999-04-09 | 1999-04-09 | 复合型饲料防霉剂 |
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| Country | Link |
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| CN (1) | CN1133376C (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101647595B (zh) * | 2009-08-28 | 2011-10-05 | 南通中牧生物科技有限公司 | 丙酸铵复合防霉剂及其制造方法 |
| CN103053868A (zh) * | 2013-02-01 | 2013-04-24 | 上海三维同力生物科技有限公司 | 一种青贮饲料用复合酸度调节剂及其使用方法 |
| CN105746904A (zh) * | 2016-02-22 | 2016-07-13 | 湖南晶天科技实业有限公司 | 一种丙酸·乙酸盐与一种添加剂 |
-
1999
- 1999-04-09 CN CNB991050584A patent/CN1133376C/zh not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101647595B (zh) * | 2009-08-28 | 2011-10-05 | 南通中牧生物科技有限公司 | 丙酸铵复合防霉剂及其制造方法 |
| CN103053868A (zh) * | 2013-02-01 | 2013-04-24 | 上海三维同力生物科技有限公司 | 一种青贮饲料用复合酸度调节剂及其使用方法 |
| CN105746904A (zh) * | 2016-02-22 | 2016-07-13 | 湖南晶天科技实业有限公司 | 一种丙酸·乙酸盐与一种添加剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1133376C (zh) | 2004-01-07 |
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Granted publication date: 20040107 Termination date: 20180409 |
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| CF01 | Termination of patent right due to non-payment of annual fee |