CN1264665C - Fiber reinforced epoxy resin product and method for manufacture thereof - Google Patents
Fiber reinforced epoxy resin product and method for manufacture thereof Download PDFInfo
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- CN1264665C CN1264665C CNB00808176XA CN00808176A CN1264665C CN 1264665 C CN1264665 C CN 1264665C CN B00808176X A CNB00808176X A CN B00808176XA CN 00808176 A CN00808176 A CN 00808176A CN 1264665 C CN1264665 C CN 1264665C
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/467—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements during mould closing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
- B32B2262/0269—Aromatic polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2363/00—Epoxy resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- Mechanical Engineering (AREA)
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Bridges Or Land Bridges (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Refuge Islands, Traffic Blockers, Or Guard Fence (AREA)
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Abstract
A fiber reinforced epoxy resin product and a method for manufacturing the epoxy resin product is provided. The fiber reinforced epoxy resin product comprises a hardened epoxy resin mixture which includes epoxy resin, silica and a fibrous material, wherein the fibrous material is a material selected from the group consisting of glass fiber, carbon fiber, aramid fiber and Kevlar fiber or a mixture of these fibers, and at least one layer of glass fiber roving cloth is arranged parallel to each other in the hardened epoxy resin mixture. The method for manufacturing a fiber reinforced epoxy resin product comprises the steps of providing a mold for the product, applying a release agent to inner surfaces of the mold, providing at least one layer of glass fiber roving cloth in the mold, casting an unhardened epoxy resin mixture in the mold, pressing the epoxy resin mixture in the mold, hardening the epoxy resin mixture in the mold under a temperature between about 20 DEG C and about 80 DEG C for more than 30 minutes, releasing the hardened epoxy resin mixture from the mold, and curing the hardened epoxy resin mixture under a temperature between about 20 DEG C and 35 DEG C for about 24 hours to form the product.
Description
Technical field
The present invention relates to a kind of fiber reinforced epoxy resin product and manufacture method thereof, more particularly, relate to a kind of fiber reinforced epoxy resin product and manufacture method thereof that comprises the hardening epoxy resin mixture, wherein contain epoxy resin, silica and reinforcing material such as glass fibre, carbon fiber, aramid fibre and Kafra fiber in this mixture, and one deck fibre glass roving fabric at least.
Background technology
Usually, can adopt the whole bag of tricks such as steel plate Method for bonding, prestress method and cross section growth method to be used for strengthening and the mending concrete member.
Adopt the steel plate Method for bonding to strengthen the bending strength of bridge floor or the shear strength of bridge pier.When prestressed size adopts electrothermal prestressing during less than desired value in cast in concrete.When the cross section size that strengthens excellent quantity and concrete component is not enough, adopt cross section to strengthen method.
Recently, the steel plate Method for bonding is the most a kind of method that is used in the above-mentioned method of mentioning.In the method, steel plate is adhered to concrete surface by cement material such as epoxy resin, can guarantee the transmission of shear stress between concrete surface and steel plate and have enough bonding strengths.
Yet, in this method, need to continue to safeguard to keep the bonding strength between concrete surface and the steel plate.And, when concrete component is exposed in the seawater, because the corrosion of steel plate or the problem relevant with the cement materials ' durability are difficult to strengthen fully or keep in repair.And along with the increase member load of steel plate quantity also increases, wherein steel has higher relatively proportion.In addition, steel plate is bonded on the bottom surface of member usually.Therefore, need a large amount of man-hour and workman, increased cost thus.
By utilizing fibre reinforced plastics (FRP) plate to replace steel plate, the problem that is caused by corrosion will be avoided.But the FRP plate has low intensity like this so that its effect can only be the covering as concrete surface.
In order to address these problems, several improved methods had once been proposed, for example exercise question is the Korea S public publication No.174 that is submitted to by the applicant of " being used to strengthen the epoxy resin board and the manufacture method thereof of concrete component ", 161 or exercise question be the described method of Japanese public publication No.4-67946 of " thermoset ting resin composite plate ".The resin plate that proposes in these methods comprises the metal wire as reinforcing material.But metal wire can be corroded after using a period of time, and the bonding strength between resin material and the metal wire is descended, and can make crack or delamination expansion in the resin plate.In addition, the weatherability of metal wire and chemical resistance are abundant inadequately, and in most cases, physical property such as hot strength or compressive strength are destroyed because of bonding strength weakens.
Summary of the invention
Therefore, an object of the present invention is to provide a kind of fiber reinforced epoxy resin product, by epoxy resin is mixed the back with short fiber and with the mixture casting in the mould that is furnished with one deck fibre glass roving fabric at least, make this product have improved physics and chemical property and have better weather and chemical resistance.Another object of the present invention provides a kind of method of making this fiber reinforced epoxy resin product.
Fiber reinforced epoxy resin plate of the present invention can be used on various fields; as; 1) strengthens and keep in repair various concrete components; 2) protection is in the surface of the concrete component in seawater, sewage, freezing-thawing destruction or other chemical actions; 3) enhancing of tunnel lining; 4) the angle cast sheet of container binding post, 5) the vehicle slide block or the like.
According to the preferred embodiments of the invention, a kind of method of making fiber reinforced epoxy resin product is provided, may further comprise the steps: for product provides mould; Releasing agent is applied to the inner surface of mould; In mould, place layer of glass rove fabric at least; With a kind of unhardened epoxy resin composition casting in mould; In mould, compress epoxy resin composition; Between about 20 ℃-Yue 80 ℃, make epoxy resin composition in mould, harden more than 30 minutes; With the demoulding from mould of hardening epoxy resin mixture; Between about 20 ℃-35 ℃, the hardening epoxy resin mixture solidified was formed product in about 24 hours then.
Another preferred embodiment according to the present invention, a kind of fiber reinforced epoxy resin product is provided, comprise the hardening epoxy resin mixture, comprise epoxy resin, silica and fibrous material in this mixture, wherein fibrous material is a kind of material that is selected from glass fibre, carbon fiber, aramid fibre and Kafra fiber or their mixture, and is placed on the fibre glass roving of one deck at least fabric in the hardening epoxy resin mixture according to parallel each other position.
The invention summary
By the description of preferred embodiment being carried out below in conjunction with accompanying drawing, above-mentioned and other purpose of the present invention and feature will become apparent, wherein:
Figure 1A-1F represents to make the illustrative methods of fiber reinforced epoxy resin product of the present invention;
Fig. 2 represents is the sectional view of the fiber reinforced epoxy resin plate made according to the inventive method;
What Fig. 3 described is that fiber reinforced epoxy resin plate of the present invention is bonded in the sectional view that surface of concrete structure strengthens;
What Fig. 4 A represented is an application of fiber reinforced epoxy resin product of the present invention, the i.e. plane of angle cast sheet;
Fig. 4 B is the side view of angle cast sheet shown in Fig. 4 A;
What Fig. 4 C showed is the installation diagram of plate of the present invention;
What Fig. 5 A-5C showed is the vehicle slide block of making according to the inventive method;
Fig. 6 is the upward view of mounted vehicle slide block;
What Fig. 7 described is the sectional view that obtains along Fig. 6 line I-I.
The description of specific embodiments
What Figure 1A-Fig. 1 F represented is the illustrative methods of making fiber reinforced epoxy resin product according to the present invention.
Step (a): the rectangular mould (10) of a pre-sizing is provided and removes top dirt or other unnecessary materials.Purposes mould (10) according to final products has all size and shape.Preferably, mould (10) form by the metal of durability and clear up inner surface after can utilize once more.
Step (b): the current version releasing agent is coated on uniform thickness on the inner surface of mould (10), and releasing agent (20) is easy to make final products and mold separation.
Step (c): the ground floor fleece (30A) that will have predetermined width of mesh is arranged on the middle releasing agent (20) of mould (10).Before this, ground floor fleece (30A) be cut into suitable for mould suitable dimension and can be by epoxy resin impregnated to strengthen intensity.Preferably, the epoxy resin that is used to flood has following physical property: viscosity is less than or equal to 380mPas (380csp), about 15 minutes of gel time, and compressive strength is more than or equal to 1000kg/cm
2, bending strength is more than or equal to 500kg/cm
2, shear strength is more than or equal to 800kg/cm
2, bonding strength is more than or equal to 130kg/cm
2, the tension failure strain rate is more than or equal to 0.02, and the coefficient of expansion is 1.0 * 10
-5-2.0 * 10
-5Cm/cm/ ℃, heat distortion temperature 50-70 ℃.
Step (d): epoxy resin and reinforcing fiber materials are proportionally mixed at 9: 1 and the mixture casting is gone up (the first casting step) at the ground floor fleece (30A) that flooded epoxy resin.This mixture comprises the reinforcing fiber materials after epoxy resin, a small amount of cement, silica and the cutting.Reinforcing fiber materials is selected from glass fibre, carbon fiber, aramid fibre and Kafra fiber or its mixture.
Preferably, the epoxy resin in this step has following performance: proportion 1.15-1.20, and hardness M70-M80, viscosity 19,000-24,000cps, absorptivity is less than or equal to 0.14%, and shrinkage factor is less than or equal to 1.1%, and epoxide equivalent is 180-230.The preferred properties of silica is as follows: purity is more than or equal to 95%, proportion 2.25-2.65, Mohs' hardness 6.5-7.0 and pH value 7-9.
Step (e): after the first casting step, the second layer fleece (30B) identical with shape with the size of ground floor fleece (30A) is placed in the mould, and with epoxy resin composition casting (the second casting step) thereon.After the second casting step is finished, with the 3rd layer of fleece (30C) according to (30A, 30B) parallel direction is configured in the mould with first and second fleeces.The number of fiber web layer can change according to the purposes of final epoxy resin product.When being used for enhancing and repairing concrete component, final epoxy resin product preferably has multilayer, and for example the number of plies and fiber number can determine according to the required intensity increase situation that is obtained by structural analysis.
After the first and second casting steps are finished, by vibrator mould (10) is applied vibration and make network of fibers be moved in the epoxy resin composition shown in Fig. 1 E like this.
After vibrating step was finished, epoxy resin composition hardened 30 minutes down at 60 ℃, used the 1000kg load compression then.Next step, epoxy resin composition hardened 3 hours down at 80 ℃.
Step (f): the epoxy resin composition of sclerosis is solidified one section scheduled time formation fiber reinforced epoxy resin product (1) from mould (10) demoulding and between 25 ℃-30 ℃.After removing, the dirt of mould (10) on it can be used again.
Fig. 2 represents the sectional view according to the fiber reinforced epoxy resin plate of the inventive method manufacturing.
Fig. 3 is the sectional view that is bonded in the fiber reinforced epoxy resin plate that surface of concrete structure is used to strengthen.
At first, concrete component (80) is surperficial pretreated.Determine the surface area that is enhanced and repairs and measure the compressive strength of concrete component.The size of reinforcement plate is determined according to desirable strength.Remove the damage parts and the pretreating surface of concrete component.If desired, repair the steel enhancing batten of corrosion.
Secondly, fiber reinforced epoxy resin plate (1) is fixed on the surface of concrete component (80) by anchor bolt or chemical anchoring bolt (84).Leave the gap of the about 6mm of about 2-between epoxy resin board (1) and the surface that is anchored.Epoxy bonded is expelled to plate and the two gap, surface.Space between preferred plate and surface is as much as possible littler.The head of anchor bolt (84) is removed or covers preventing with anchor bolt lid and is corroded.The length that preferred anchor bolt (84) is no more than 100mm and anchor bolt to the distance between panel edges be at least the destroyed parts degree of depth 2-3 doubly.Every square metre install approximately 9 anchor bolts and generally the spacing between two anchor bolts be 30cm.
Subsequently, epoxy bonded (90) is expelled in the space.Before injection, the periphery of plate (1) seals with fluid sealant, and preferred fluid sealant and epoxy bonded are of the same type.Preferably, epoxy bonded (90) has identical performance with the epoxy resin that constitutes epoxy resin composition but its viscosity is lower.Preferably check the performance and the condition of work of epoxy bonded (90) with model test.Epoxy bonded (90) under certain injection pressure as 0.5-2.5kg/cm
2Be injected in the space.Initiation pressure is low in the injection process slowly pressurizes then to avoid producing bubble.This step is carried out under 5-30 ℃.
After this injecting step was finished, epoxy bonded was cured 3 days, and epoxy resin board uses coverings such as vinyl sheet material or other materials in case rainwater or dirt.Head for removal anchor bolt attractive in appearance.
Fig. 4 A shows the plane as the angle cast sheet of an application of fiber reinforced epoxy resin product of the present invention.Fig. 4 B represents its side view, the assembling of Fig. 4 C display plate.
Angle cast sheet (100) is to be used to protect container joint surface (110) to avoid the goods that the container case corner assembly destroys.Place these plates (100) and be used for each angle of supporting container case.
These angle cast sheets just will comprise more fiber web layer and make the composition of some components different for gaining in strength with aforesaid same step manufacturing.Plate can be made into all size, as: { 420mm * 1350mm * 20mm}, { 420mm * 600mm * 20mm} or { 1000mm * 1350mm * 20mm}.
Fig. 5 A-5C represents the vehicle slide block according to the inventive method manufacturing.
(200,200A 200B) uses with above-mentioned and makes by all size with quadrat method these vehicle slide blocks.(200,200A has through hole (212) on 200B) and is used for fixing bolt (210) the vehicle slide block.Preferably, set bolt (210) than vehicle slide block (200,200A, height 200B) is big more than 2 times.The quantity of through hole (212) can change according to the length of slide block.
Fig. 6 is the upward view of assembling vehicle slide block.Fig. 7 represents the sectional view got along Fig. 6 center line I-I.
These vehicle slide blocks are to use with above-mentioned same method to make, just epoxy resin composition preferably has following composition: the cobble of the epoxy resin of 10-30 weight %, the silica of 20-39wt%, 30-68% and the enhancing substance of 0.01-0.1 weight %, and more preferably epoxy resin, 39.59 weight % silica, cobble and the 0.07 weight % reinforcing fiber materials of 46.70 weight % of 13.64 weight %.
Preferably, fleece has following performance: weight 550-610g/m
2, density is more than or equal to 6.3, and hot strength is more than or equal to 1500kg/mm
2With bending strength more than or equal to 1295kg/mm
2
And epoxy resin composition can comprise and has fire-resistant and put out the inorganic material of characteristic certainly, as aluminium hydroxide, antimony oxide, hydrogen bromide.For retaining member intensity, the inorganic material that the preferred epoxy mixture comprises can not surpass 5 weight % for the epoxy resin composition gross weight.
As shown in drawings, and the vehicle slide block (200,200C) arranged with predetermined space.This depends on the width of vehicle at interval, and the vehicle slide block (200B) with inclined plane is arranged in the two ends of vehicle slide block line.
After surface of position (300) cleaning with required fixedly slide block, vehicle slide block (200) is fixed on this position with bolt (210).Next step, the periphery of every slide block forms resin cast gate and air outlet slit with fluid sealant sealing back.Epoxy bonded (220) is injected into interface between surface and the slide block with the infiltration that prevents water and guarantee that slide block is fixed on this surface firmly.Preferably, the about 2mm-6mm of the thickness of epoxy bonded layer.Injecting step starts from lower injection pressure, and being increased to the elevated pressures purpose then little by little, at leisure is in order to prevent to produce bubble.Preferred injection pressure 0.5-2.5kg/cm
2Epoxy bonded is identical with above-mentioned epoxy bonded performance, and just this epoxy bonded had than low viscosity and about 3 hours of setting time.
After injecting step was finished, epoxy bonded was cured more than 3 hours.The epoxy radicals lacquer can be coated on the surface of vehicle slide block.Above-mentioned steps also can be used in the cast sheet manufacturing of angle.
Embodiment
The embodiment that makes concrete reinforcement plate and vehicle slide block is described below.
Embodiment 1
Prepare the mould of big or small 1000mm * 1000mm * 11mm,, in mould, place at least three layers of fleece at the inner surface coating releasing agent of mould.Subsequently, the epoxy resin composition casting of short fiber that will comprise the silica of cement, 69.3 weight % of 30.1% epoxy resin, 0.5 weight % and 0.1 weight % swing die then in the mould.After 30 minutes, use 1000kg load compression epoxy resin composition in sclerosis under 60 ℃.Under 80 ℃, reharden the in addition epoxy resin composition 3 hours and the demoulding from mould.The epoxy resin composition of sclerosis is to solidify 3 days under the 40-50% at 25-30 ℃, humidity.Test the performance of final epoxy resin board and obtain following result:
Table 1
| Mechanical property | Test result | Remarks | ||
| Compressive strength (kg/cm 2) | 800 | Breaking strain speed 0.017 | ||
| Direct hot strength (kg/cm 2) | 340 | Breaking strain speed 0.017 | ||
| Bending strength (kg/cm 2) | 400 | |||
| Elastic modelling quantity | Compression (kg/cm 2) | 74.000 | ||
| (kg/cm stretches 2) | 34.000 | |||
| Poisson's ratio | Compression | 0.34 | ||
| Stretch | 0.22 | |||
| Breaking strain speed | Compression | 0.020 | 0.017-0.037 | |
| Stretch | 0.010 | 0.010-0.014 | ||
| Thermal coefficient of expansion | 6.5×10-6 | |||
| Weatherability | Solidify in the water | Substantially unaffected | 3 months | |
| Place air | Substantially unaffected | 3 months | ||
| Chemical resistance | Very strong acidproof and alkali resistance | |||
As shown in table 1, the compressive strength of fiber reinforced epoxy resin plate and hot strength are than concrete height, and bending strength is also quite high.
Sample that from water, solidifies and the sample that places Cryogenic air, the performance of epoxy resin product of the present invention is not subjected to weather conditions such as humidity, places the influence of water time, and epoxy resin product also has very strong acidproof and alkaline resistance properties.Therefore prove epoxy resin product be applicable to have harsh conditions such as seawater, the place of sewage, this class of Vehicular exhaust.
Embodiment 2
Make the mould of big or small 800mm * 1500mm * 11mm,, in mould, place at least three layers of fleece at the inner surface coating releasing agent of mould.Subsequently, the epoxy resin composition casting of short fiber that will comprise the silica of cement, 74.5 weight % of 23.9% epoxy resin, 1.5 weight % and 0.1 weight % swing die then in the mould.After 30 minutes, use 1000kg load compression epoxy resin composition in sclerosis under 60 ℃.80 ℃ of further hardening epoxy resin mixture 3 hours and demouldings from mould down.The epoxy resin composition of sclerosis is to solidify 3 days under the 40-50% at 25-30 ℃, humidity.It is basic identical with table 1 to test the result that the performance of final epoxy resin board obtains.
Embodiment 3
Make the mould of big or small 170mm * 150mm * 1000mm, at the inner surface of mould coating releasing agent for example 700-NC or PS-100, placement of multiple layers fleece in mould.Subsequently, the epoxy resin composition casting that will comprise epoxy resin, silica, fortifying fibre, cobble and inorganic material is in mould and remove bubble in the mould, and the bubble residual volume will be lower than 4%.To apply load be the pressure of 800-1000kg and hardened the demoulding from mould then 1-3 hour to epoxy resin composition.The epoxy resin composition of sclerosis is to solidify 24 hours under the 40-50% at 25-30 ℃, humidity.It is as follows to test the result that the performance of final epoxy resin vehicle slide block obtains:
Table 2
| Performance | Test result | Concrete | |
| Compressive strength (kg/cm 2) | 1128 | 300 | |
| Direct hot strength (kg/cm 2) | 360 | 340 | |
| Bending strength (kg/cm 2) | 450 | 400 | |
| Weatherability | Solidify in the water | Substantially unaffected | Influential |
| Place air | Substantially unaffected | Influential | |
| Chemical resistance | Very strong acidproof and alkali resistance | Relatively poor | |
As shown in Figure 2, the compressive strength of fiber reinforced epoxy resin vehicle slide block and hot strength are also quite higher than concrete height and bending strength.And persistence is better than concrete.Sample that from water, solidifies and the sample that places Cryogenic air, the influence that epoxy resin product is not subjected to weather conditions such as temperature and humidity and places the time of water substantially among the present invention.Epoxy resin product also has very strong acidproof and alkali resistance.Therefore prove that epoxy resin product is suitable for being used in harsh conditions such as this class place of seawater, sewage and Vehicular exhaust.
Represented and described the present invention with reference to embodiment preferred.But it will be apparent to those skilled in that under the situation that does not break away from the aim of the present invention that limits as following claim and scope, can carry out various changes and modifications.
Claims (17)
1, a kind of method of making fiber reinforced epoxy resin product comprises the steps:
(a) provide mould for product;
(b) inner surface to mould is coated with releasing agent;
(c) in mould, provide layer of glass rove fabric;
(d) a kind of unhardened epoxy resin composition of fibre glass roving fabric top casting in mould;
(e) swing die is to remove the bubble in the unhardened epoxy resin composition;
(f) between 20 ℃-80 ℃, harden the epoxy resin composition in the mould more than 30 minutes;
(g) with epoxy resin composition demoulding from mould of hardening; With
(h) will be between 20 ℃-35 ℃ hardening epoxy resin mixture solidified 24 hours.
2, the process of claim 1 wherein that epoxy resin composition comprises epoxy resin, silica and reinforcing fiber materials, this reinforcing fiber materials is selected from glass fibre, carbon fiber, aramid fibre, Kafra fiber and their mixture.
3, the method for claim 2, wherein epoxy resin composition also comprises cement.
4, the method for claim 2, wherein epoxy resin composition also comprises and has fire-resistant and put out the inorganic material of characteristic certainly.
5, the method for claim 4, wherein inorganic material is selected from aluminium hydroxide, antimony oxide and hydrogen bromide.
6, the method for claim 1, this method also comprise the step with the epoxy resin impregnated fibre glass roving of one deck at least fabric.
7, the process of claim 1 wherein that described fiber reinforced epoxy resin product is a kind of fiber reinforced epoxy resin plate, and repeating step (c) and (d) so that at least two layers of fibre glass roving fabric to be provided.
8, the method for claim 7, wherein epoxy resin composition comprises epoxy resin, silica and reinforcing fiber materials, and this reinforcing fiber materials is selected from glass fibre, carbon fiber, aramid fibre, Kafra fiber and their mixture.
9, the method for claim 7, this method also comprises the step with epoxy resin impregnated described at least two layers of fibre glass roving fabric.
10, the method for claim 1, repeating step (c) and wherein (d) so that at least two layers fibre glass roving fabric to be provided, cure step is carried out 1-3 hour between 60 ℃-80 ℃, and curing schedule between 20 ℃-35 ℃ and humidity under the condition of 30%-60%, carried out 24 hours.
11, the method for claim 10, wherein bubble quantity and bubble remains on below 4% in unhardened epoxy resin composition.
12, the method for claim 10, wherein epoxy resin composition comprises epoxy resin, silica, cobble and reinforcing fiber materials, and this reinforcing fiber materials is selected from glass fibre, carbon fiber, aramid fibre, Kafra fiber and their mixture.
13, the method for claim 12, wherein epoxy resin also contains and has fire-resistant and put out the inorganic material of characteristic certainly.
14, a kind of fiber reinforced epoxy resin product of producing according to the method for claim 1 comprises:
A kind of hardening epoxy resin mixture, this mixture comprises epoxy resin, silica and fibrous material, and this fibrous material is selected from glass fibre, carbon fiber, aramid fibre, Kafra fiber and their mixture; With
At least one deck fibre glass roving fabric, they are placed in the hardening epoxy resin mixture in parallel with each other.
15, the fiber reinforced epoxy resin product of claim 14, this product is a plate, comprises triplex glass fiber roving fabric at least, they are placed in the hardening epoxy resin mixture in parallel with each other.
16, a kind of vehicle slider component, it comprises the body that the fiber reinforced epoxy resin product in a use such as the claim 14 is made, described body comprises hardening epoxy resin mixture and fibre glass roving fabric, described hardening epoxy resin mixture contains epoxy resin, silica and fibrous material, and this fibrous material is selected from glass fibre, carbon fiber, aramid fibre, Kafra fiber and their mixture.
17, the vehicle slider component of claim 16, this member also comprises a kind of epoxy bonded layer, so that member is fixed on desired location.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019990015219A KR100310016B1 (en) | 1999-04-28 | 1999-04-28 | Fiber-Reinforced Epoxy Panel And Process For Preparing Thereof |
| KR1999/15219 | 1999-04-28 | ||
| KR1999/38063 | 1999-09-08 | ||
| KR1019990038063A KR100314750B1 (en) | 1999-09-08 | 1999-09-08 | Fiber-Reinforced Epoxy Vehicle Block And Process For Preparing Thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1353637A CN1353637A (en) | 2002-06-12 |
| CN1264665C true CN1264665C (en) | 2006-07-19 |
Family
ID=26635022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB00808176XA Expired - Fee Related CN1264665C (en) | 1999-04-28 | 2000-04-28 | Fiber reinforced epoxy resin product and method for manufacture thereof |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2002542965A (en) |
| CN (1) | CN1264665C (en) |
| AU (1) | AU4435600A (en) |
| HK (1) | HK1047071B (en) |
| WO (1) | WO2000066338A1 (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2372706B (en) * | 2001-03-02 | 2005-08-17 | Steven Streatfield Gill | Frame |
| DE10318836A1 (en) * | 2003-04-25 | 2004-11-11 | Voith Paper Patent Gmbh | Process for coating a cylindrical body |
| CN100435210C (en) * | 2003-12-08 | 2008-11-19 | 朱富良 | Arch bar of stringed instrument made from carbon fiber and preparation technique |
| ITTO20040178A1 (en) * | 2004-03-17 | 2004-06-17 | Fiat Auto Spa | SELF-ADHESIVE STRUCTURAL STRENGTHENING ELEMENT FOR VEHICLE BODIES AND PROCEDURE FOR ITS APPLICATION |
| ITMI20060447A1 (en) * | 2006-03-14 | 2007-09-15 | Paper Technologies S R L | METHOD TO PRODUCE ONE OR MORE PRODUCTS PRODUCED MADE WITH A CALLED METHOD AND SYSTEM FOR ITS REALIZATION |
| CN100384933C (en) * | 2006-04-27 | 2008-04-30 | 上海交通大学 | process for preparing sea water resisting glass fiber reinforced epoxy resin nano composite material |
| CN102147034B (en) * | 2010-02-09 | 2013-01-09 | 李爱军 | Manufacture method of cable holder stand column |
| CN101955666B (en) * | 2010-09-30 | 2012-04-18 | 长安大学 | Preparation method of glass fiber enhanced thermosetting resin matrix composite material |
| CN102278400A (en) * | 2011-06-03 | 2011-12-14 | 贺智挺 | Glass fibre spring and manufacture method thereof |
| CN102879119A (en) * | 2011-07-13 | 2013-01-16 | 河海大学 | Composite material temperature sensor and manufacturing method of composite material temperature sensor |
| CN102490369B (en) * | 2011-12-02 | 2014-12-03 | 曹如锋 | Processing process of large-diameter anti-static fiber glass epoxy plastic pipeline |
| CN102528988A (en) * | 2011-12-20 | 2012-07-04 | 四川兴达明科机电工程有限公司 | Process for manufacturing bearing pad on surface of sensor |
| CN103224019B (en) * | 2013-04-24 | 2015-05-27 | 哈尔滨飞机工业集团有限责任公司 | Manufacture method of helicopter cabin cover windshield positioning pad |
| CN104552974A (en) * | 2013-10-09 | 2015-04-29 | 中航贵州飞机有限责任公司 | Preparation method of carbon fiber and fiberglass-combined reinforced composite |
| CN104175652A (en) * | 2014-08-26 | 2014-12-03 | 常州慧运复合材料有限公司 | Carbon fiber and glass fiber mixed type plane grating rib |
| CN104403306A (en) * | 2014-11-03 | 2015-03-11 | 安徽蓝翔电器成套设备有限公司 | Fiber adhesive-tape film composition, preparation method for fiber adhesive-tape film and fiber adhesive tape |
| CN104356416B (en) * | 2014-11-14 | 2017-09-15 | 西安超码复合材料有限公司 | A kind of preparation method of special type protection material |
| CN106808711A (en) * | 2015-12-01 | 2017-06-09 | 宁波华翔汽车纤维研发有限公司 | A kind of rapid shaping wet method mould pressing process of carbon fiber auto parts and components |
| CN106189097A (en) * | 2016-08-19 | 2016-12-07 | 常州市宏发纵横新材料科技股份有限公司 | A kind of fan blade glass fiber reinforced materials and preparation method thereof |
| CN106128746B (en) * | 2016-08-19 | 2018-11-27 | 浙江艾默可科技有限公司 | A kind of curing method reducing amorphous iron core internal stress |
| CN108530838B (en) * | 2018-04-20 | 2021-02-23 | 江苏澳盛复合材料科技有限公司 | Carbon fiber and glass fiber reinforced epoxy resin composite material and preparation method thereof |
| CN108973164B (en) * | 2018-08-21 | 2023-11-17 | 杭州友凯船艇有限公司 | Compression molding die with overflow hole, fitting and preparation scheme thereof |
| CN112063115A (en) * | 2020-09-18 | 2020-12-11 | 海南大学 | Preparation method of natural coconut shell fiber reinforced epoxy resin composite fabric |
| CN112440369B (en) * | 2020-10-30 | 2022-04-22 | 颐华建筑材料有限公司 | Concrete test block apparatus for producing |
| CN113402743B (en) * | 2021-07-15 | 2022-09-16 | 北京化工大学 | Preparation method of epoxy resin potting material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3922413A (en) * | 1974-06-03 | 1975-11-25 | Richard G Reineman | Lightweight, high strength, reinforced concrete constructions |
| JPS5621816A (en) * | 1979-07-31 | 1981-02-28 | Nissan Motor Co Ltd | Manufacture of elastic model |
| JPS56159121A (en) * | 1980-05-14 | 1981-12-08 | Mitsubishi Gas Chem Co Inc | Manufacture of multi-ply sheet |
| JPS57203511A (en) * | 1981-06-10 | 1982-12-13 | Sumitomo Electric Ind Ltd | Epoxy resin cast molding |
| JPS58205730A (en) * | 1982-05-25 | 1983-11-30 | Mitsubishi Heavy Ind Ltd | Forming method of composite product |
| JPH0925393A (en) * | 1995-05-09 | 1997-01-28 | Toray Ind Inc | Epoxy resin composition for fiber reinforced composite material, prepreg and fiber reinforced composite material |
-
2000
- 2000-04-28 CN CNB00808176XA patent/CN1264665C/en not_active Expired - Fee Related
- 2000-04-28 WO PCT/KR2000/000403 patent/WO2000066338A1/en active Application Filing
- 2000-04-28 AU AU44356/00A patent/AU4435600A/en not_active Abandoned
- 2000-04-28 JP JP2000615205A patent/JP2002542965A/en active Pending
-
2002
- 2002-12-03 HK HK02108774.3A patent/HK1047071B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| HK1047071A1 (en) | 2003-02-07 |
| HK1047071B (en) | 2007-01-12 |
| WO2000066338A1 (en) | 2000-11-09 |
| JP2002542965A (en) | 2002-12-17 |
| AU4435600A (en) | 2000-11-17 |
| CN1353637A (en) | 2002-06-12 |
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