CN1260688A - 吸烟制品及其吸烟材料 - Google Patents
吸烟制品及其吸烟材料 Download PDFInfo
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- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
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Abstract
本发明涉及一种再制吸烟材料,包括非多元醇烟雾发生剂、烟草(选择性)、粘合剂(选择性)和无机填料。该吸烟材料中还可进一步含有多元醇烟雾发生剂。还提供一种含有这种材料的吸烟制品,该材料按常规排列或在环形物中有轴向配置的芯。本发明的另一方面是,多元醇或非多元醇烟雾发生剂置于包含本发明吸烟材料的吸烟制品的过滤元件中。在吸烟制品燃烧时,过滤嘴中的烟雾材料洗脱成烟雾。
Description
本发明涉及吸烟制品,例如香烟,及其吸烟材料。
在专利文献中,有许多有关用来替代传统的切割烟草香烟填料的吸烟材料的提议。
本发明的目的是提供新的提供主流烟的吸烟材料。尽管它含有少量源自烟草的成分,但对消费者来说它是完全可以接受的。
本发明提供一种吸烟材料,它包括一种非多元醇烟雾发生剂,最多20wt%的烟草,不多于20wt%的粘合剂和不少于30wt%的无机填料。
举例来说,三甘醇二乙酸酯(“TEGDA”)、甘油三乙酸酯(“三醋精”)或甘油二乙酸酯(“二醋精”)可以单独或混合用作非多元醇烟雾发生剂。吸烟制品科学和技术领域的技术人员熟知的是,TEGDA和三醋精的确定用途是用作醋酸纤维素香烟过滤嘴丝束的塑性剂(粘合剂)。因此令人惊异的发现是,当在本发明吸烟材料中用作烟雾发生物质时,这些物质和类似的物质在主流烟中提供被吸烟者评价为非常可接受的烟雾。
非多元醇烟雾发生剂在本发明吸烟材料中的量通常为约2wt%-约30wt%。更通常的范围是约5wt%-约20wt%,更为通常的是5-15%。
整个烟雾发生剂可包括多元醇烟雾发生剂,如甘油、丙二醇和三甘醇中的一种或多种。
本发明的吸烟材料可以这样制备,将各成分加水打成颗粒微细的浆,将所得的浆在带式或线式成片机(wire sheet-forming machine)或加热转鼓上浇铸成薄片状,这对本领域技术人员来说容易理解。或者,将各成分的混合物和水一起装填进挤出机。浇铸或挤出的产品适当切割和粉碎成颗粒状的吸烟材料。
如果用来制备吸烟材料的成分中不包括烟草,则最好将颗粒状的吸烟材料与颗粒状的烟草掺混。这种情况下,吸烟材料适宜地占混合物的至少约30wt%。吸烟材料适当地占混合物重量的大部分,即大于掺混物的50wt%。掺混物中的烟草可以是膨胀(expanded)的烟草。
可以从中选出本发明吸烟材料中的粘合剂的一类物质是藻酸盐。已经发现藻酸钠是很好的。其它适宜的粘合剂物质是,例如纤维素或改性纤维素、羟丙基纤维素或羧甲基纤维素、淀粉或改性淀粉及天然胶类物质。
适宜用作无机填料的材料是碳酸钙、珍珠岩、蛭石、硅藻土、胶体二氧化硅、氧化镁、硫酸镁、碳酸镁或本领域技术人员知道的其它低密度无机填料。
在本发明吸烟材料中,无机填料的优选量为至少约35wt%,优选至少约40wt%,更优选至少约45wt%。
在本发明吸烟材料中,烟草的量可以少于15%,优选少于10%,更优选少于5%。本发明吸烟材料的粘合剂的量可以少于15wt%,更优选少于10wt%。
本发明吸烟材料可以包括一种或多种机械稳定剂或增强材料,如可可、糖和纤维如纸纤维。还可以适当包括例如膨胀介质,如淀粉、支链淀粉或其它多糖或发泡剂,及高脂或高油物质如可可脂或橄榄油、玉米油。
本发明吸烟材料可以用于传统的吸烟制品中,例如,与可以是烟草材料的其它吸烟材料掺混,或不掺混或与其同轴排列。
本发明的第二方面是一种包括可抽吸烟条和过滤嘴的吸烟制品,所述烟条包括芯和外围部分,所述芯部分包括第一颗粒状吸烟材料和包着所述第一吸烟材料的第一卷烟纸包裹物(cigarette paper wrapper),所述外围部分包括围着所述芯成环形配置的第二颗粒状吸烟材料和包着所述第二吸烟材料的第二卷烟纸包裹物,其中所述的第一或第二吸烟材料任一包括非多元醇烟雾发生剂、最多20wt%的烟草、不多于20wt%的粘合剂和不少于30wt%的无机填料。
注意到,本发明第二方面吸烟制品中的所述吸烟材料之一是上述本发明第一方面的吸烟材料。在上述吸烟制品的第一吸烟材料和第二吸烟材料中都可以有本发明上述第一方面的吸烟材料。
优选吸烟制品的所述第二吸烟材料是本发明上述第一方面的吸烟材料。
第一吸烟材料适宜是切割的烟草填料,最好是切割的薄片状填料。
很优选的是,在本发明吸烟制品中可抽吸烟条的芯和外围部分延伸至烟条的整个长度。还很优选芯与烟条同轴配置。
本发明的第三方面提供一种包括可抽吸烟条和过滤嘴的吸烟制品,可抽吸烟条包括吸烟材料,过滤嘴包括有可洗脱的烟雾发生剂的过滤材料,所述烟雾发生剂是多元醇和/或非多元醇烟雾发生剂,在该吸烟制品被吸时,烟雾发生剂从过滤嘴上洗脱从而增强吸烟材料所提供的烟雾。
该吸烟制品是同轴排列或不非同轴排列。
吸烟材料优选包括烟雾发生剂、粘合剂和无机填料,更优选包括非多元醇烟雾发生剂、最多20wt%的烟草、不多于20wt%的粘合剂和不少于30wt%的无机填料。或者,吸烟材料可包括一种或多种我们于1995年9月6日申请、国际专利申请号为PCT/GB 95/02110的共同未决申请中的烟雾发生剂或烟雾发生燃料源。作为另一个可替代品,吸烟材料可以包括通常的切割烟叶材料。
烟雾发生剂可以是一种多元醇、一种酯、一种高沸点烃、甘油、丙二醇、三甘醇、亚甲基二醇、柠檬酸甲酯、三醋精或二醋精,单独或混合使用。
在具有常规香烟外圆周即25mm的吸烟制品中,所述芯的外圆周适宜地为约17mm。
实施例1
本发明的吸烟制品,如香烟,包括圆周约17mm的芯,该芯由通常用于超细香烟,如British American Tobacco(德国)生产的商标名称为CAPRICE的超细香烟的切割薄片填料和传统卷烟纸包裹物组成。围着芯成环形配置的香烟外围部分由50wt%的膨胀薄片烟草和50wt%的本发明吸烟材料的掺合物组成,所述吸烟材料包在由Glatz Inc.制造的实验名(experimental designation)为GNS40MV的低侧流卷烟纸的外包裹物中。膨胀烟草是用已知的“干冰膨胀烟草”(DIET)烟草膨胀法膨胀而得。本发明的吸烟材料浇铸成带后经切割和粉碎,具有重量百分数如下的成分:
TEGDA 2.6
甘油 6.5
普通烟草掺混物(磨碎) 19.8
藻酸钠 9.9
白垩 48.3
可可 6.4
含6-9%蔗糖浆的蔗糖(Demerera Sugar) 3.0
纸纤维 3.5
芯和外围部分长度相同。
本发明香烟还包括普通的通气的纤维性醋酸纤维素过滤嘴。
实施例2
本发明吸烟材料第二个例子的各成分重量百分数如下:
TEGDA 6
甘油 6
普通烟草掺混物(磨碎) 20
藻酸钠 10
白垩 51
可可 4
含6-9%蔗糖浆的蔗糖 3
切割和粉碎形式的该第二吸烟材料可以,例如,与常规的切割烟草香烟填料掺混。吸烟材料与填料的掺混比例可以为,例如7∶3。可将掺混物装填入制造香烟的机器中制得包括有掺混物和普通卷烟纸或低侧流纸的外包裹物的卷烟条。
实施例3
本发明吸烟材料的第三个例子的各成分重量百分数如下:
TEGDA 10
甘油 4
藻酸钠 8
白垩 78
切割和粉碎形式的该第三吸烟材料可以,例如,与常规的切割烟草填料掺混,掺混比例可以为,例如4∶6,并用于制造卷烟条。
实施例4
制备下面三种吸烟材料制剂以便比较。每个成分的百分数为重量百分数。
表1
试样号
1 2 3
三醋精 0 9.6 4
甘油 8.6 0 4
普通烟草掺混物(磨碎) 20.3 20.1 20
藻酸钠 8.1 8 8
纤维 1 1 1
珍珠岩 62 61.3 63
烟排出
喷烟数目 3.4 5.3 4.0
TPM(毫克/支香烟) 7.5 5.3 7.6
水(毫克/支香烟) 2.7 0.8 2.1
烟碱(毫克/支香烟) 0.19 0.1 0.2
甘油(毫克/支香烟) 1.11 n/m n/m
三醋精 n/m 2.03 n/m
NFDPM(毫克/支香烟) 4.59 4.36 5.35
NAFDPM(毫克/支香烟) 3.48 2.33 n/m
NAFDM=烟碱,无烟雾干颗粒物质(烟雾为甘油或三醋精)。
NFDPM=无烟碱干颗粒物质。
n/m=未测出
在35cm3喷烟的标准机器吸烟条件下抽吸香烟2秒,其过程中每分钟(燃掉)烟头长度为35mm。
实施例5
为了观察过滤元件中的烟雾发生剂对带有标准纤维性醋酸纤维素过滤嘴的吸烟制品的影响,将混合的甘油和三醋精片(上述实施例4的试样3)用在过滤嘴中含有不同含量烟雾发生剂的吸烟制品中。香烟长84mm,直径约8mm,过滤元件27mm,在35mm烟头长度的标准机器吸烟条件下抽吸香烟。过滤嘴上的烟雾发生剂为丙二醇(PG)。
表2
试样号
4 5 6 7 8
过滤嘴上的PG(mg) 0 5 10 20 30
烟排出
喷烟数目 4 4 4 3.75 4
TPM(毫克/支香烟) 7.6 5.7 7.56 8.4 11.6
水(毫克/支香烟) 2.05 1.35 1.33 1.58 2.23
烟碱(毫克/支香烟) 0.20 0.17 0.17 0.13 0.15
NFDPM(毫克/支香烟) 5.35 4.18 6.06 6.69 9.22
%烟组成
水(%) 27.0 23.7 17.6 18.8 19.2
烟碱(%) 2.6 3.0 2.2 1.5 1.3
可以看到附加的烟雾发生剂稀释了烟成分,有效地降低各种烟成分的烟排放量。
实施例6
表3列出了本发明吸烟材料的其它配方。附加的材料包括淀粉、油和碱水。在试样58a中,制备0.1M的碳酸钠溶液并用它代替通常的水加入到干混合物中,直至达到需要的pH值。每个成分的百分数为重量百分数。
表3试样号 烟草 藻酸钠 糖 可可 白垩 甘油 Tcgda 三醋精 其他成分2a 20 10 15 4 39 6 63a 20 10 3 20 35 6 65a 20 10 3 4 37 6 207a 20 10 3 4 51 6 - 68a 20 10 3 4 37 6 - 2010a 20 10 3 4 51 - 12 -11a 18 9 3 4 56 - 10 -12a 20 10 3 4 41 6 6 - 10(纸纤维)16a 20 10 3 - 45 6 6 - 10(淀粉)17a 20 10 3 - 45 6 6 - 10(可可脂)26a 20 25 3 4 36 6 6 -34a 20 10 3 - 45 6 6 - 10(玉米油)39a 20 10 - - 55 - 1541a 20 10 3 4 - 6 6 - 51(珍珠岩)42a 20 10 3 4 26 6 6 25(珍珠岩)51a 20 10 3 - 30 6 6 - 15(熟制淀粉)52a 20 10 - - 55 - - - 15(橄榄油)58a 20 10 3 4 51 6 6 - pH=9.3
Claims (30)
1.一种吸烟材料,包括非多元醇烟雾发生剂,最多20wt%的烟草,不多于20wt%的粘合剂和不少于30wt%的无机填料。
2.根据权利要求1的吸烟材料,其中所述的非多元醇烟雾发生剂是三甘醇二乙酸酯、甘油三乙酸酯和甘油二乙酸酯中的一种或多种。
3.根据权利要求1或2的吸烟制品,其中所述的非多元醇烟雾发生剂在所述的吸烟材料中的含量为约2wt%-约30wt%。
4.根据权利要求3的吸烟材料,其中所述的非多元醇烟雾发生剂的含量为约5wt%-约20wt%。
5.根据权利要求4的吸烟材料,其中所述的非多元醇烟雾发生剂的含量为约5wt%-约15wt%。
6.根据权利要求1-5任一项的吸烟材料,其中所述的无机填料在所述吸烟材料中的含量为至少35wt%。
7.根据权利要求6的吸烟材料,其中所述的无机填料的量为至少40wt%。
8.根据权利要求7的吸烟材料,其中所述的无机填料的量为至少45wt%。
9.根据前面权利要求中任一项的吸烟材料,其中所述的烟草在所述吸烟材料中的量为低于15wt%。
10.根据权利要求9的吸烟材料,其中所述的烟草的量为低于10wt%。
11.根据权利要求10的吸烟材料,其中所述的烟草的量为低于5wt%。
12.根据前面权利要求中任一项的吸烟材料,其中所述的粘合剂在所述吸烟材料中的量为低于15wt%。
13.根据权利要求12的吸烟材料,其中所述的粘合剂的量为低于10wt%。
14.根据前面权利要求中任一项的吸烟材料,其中所述的无机填料是碳酸钙、珍珠岩、蛭石、硅藻土、胶体二氧化硅、氧化镁、硫酸镁、碳酸镁或其它低密度无机填料中的一种或多种。
15.根据前面权利要求中任一项的吸烟制品,其中所述的粘合剂是藻酸盐、纤维素或改性纤维素、淀粉或改性淀粉及天然胶类物质的一种或多种。
16.根据前面权利要求中任一项的吸烟材料,其中所述的吸烟材料还包括机械稳定剂或增强材料、膨胀介质或含有高脂肪或高油的材料。
17.根据权利要求16的吸烟材料,其中所述的材料还包括可可、糖、纤维、淀粉、支链淀粉、其它多糖膨胀剂、发泡剂、可可脂、橄榄油和玉米油中的一种或多种。
18.一种吸烟制品,包括可抽吸烟条和过滤嘴,所述烟条包括芯和外围部分,所述芯包括第一颗粒状吸烟材料和包着所述第一吸烟材料的第一卷烟纸包裹物,所述外围部分包括围着所述芯成环形配置的第二颗粒状吸烟材料和包着所述第二吸烟材料的第二卷烟纸包裹物,其中所述的第一或第二吸烟材料的任一个包括非多元醇烟雾发生剂、最多20wt%的烟草、不多于20wt%的粘合剂和不少于30wt%的无机填料。
19.根据权利要求18的吸烟制品,其中所述第一或第二吸烟材料之一的所述吸烟材料包括根据权利要求2-17任一项的吸烟材料。
20.根据权利要求18或19的吸烟制品,其中所述的第二吸烟材料是所述的根据权利要求1-17任一项的吸烟材料。
21.根据权利要求18或19的吸烟制品,其中所述的第一和第二吸烟材料都包括一部分包含非多元醇烟雾发生剂、最多20wt%的烟草、不多于20wt%的粘合剂和不少于30wt%的无机填料的吸烟材料。
22.根据权利要求18-21任一项的吸烟制品,其中所述的第一或第二吸烟材料的其它部分是切割烟草填料。
23.根据权利要求18-22任一项的吸烟制品,其中所述可抽吸烟条的所述芯和所述外围部分均延伸至所述烟条的整个长度。
24.根据权利要求18-23任一项的吸烟制品,其中所述的芯与所述烟条同轴配置。
25.一种吸烟制品,包括可抽吸烟条和过滤嘴,可抽吸烟条包括吸烟材料,过滤嘴包括有可洗脱的烟雾发生剂的过滤材料,所述烟雾发生剂是多元醇和/或非多元醇烟雾发生剂,在该吸烟制品被吸时,烟雾发生剂从过滤嘴上洗脱从而增强吸烟材料所提供的烟雾。
26.根据权利要求25的吸烟制品,其中所述的烟条包括置于环形物中的轴向排列的芯。
27.根据权利要求25或26的吸烟制品,其中所述的吸烟材料包括烟雾发生剂、粘合剂和无机填料。
28.根据权利要求27的吸烟制品,其中所述的吸烟材料是权利要求1-17任一项所描述的吸烟材料。
29.基本如实施例1-6中任一个所描述的吸烟材料。
30.基本如实施例1-6中任一个所描述的吸烟制品。
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GBGB9712815.1A GB9712815D0 (en) | 1997-06-19 | 1997-06-19 | Smoking article and smoking material therefor |
GB9712815.1 | 1997-06-19 |
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- 1998-05-29 ES ES98924487T patent/ES2244062T3/es not_active Expired - Lifetime
- 1998-05-29 EP EP03001102A patent/EP1304049A3/en not_active Withdrawn
- 1998-05-29 EP EP98924487A patent/EP0991330B1/en not_active Expired - Lifetime
- 1998-05-29 BR BR9810045-9A patent/BR9810045A/pt not_active IP Right Cessation
- 1998-05-29 AU AU76680/98A patent/AU756450B2/en not_active Ceased
- 1998-05-29 NZ NZ514210A patent/NZ514210A/xx not_active IP Right Cessation
- 1998-05-29 US US09/446,232 patent/US6779531B1/en not_active Expired - Lifetime
- 1998-05-29 CA CA002425096A patent/CA2425096A1/en not_active Abandoned
- 1998-05-29 CA CA002291017A patent/CA2291017C/en not_active Expired - Fee Related
- 1998-05-29 DE DE69830793T patent/DE69830793T2/de not_active Expired - Lifetime
- 1998-05-29 PT PT98924487T patent/PT991330E/pt unknown
- 1998-05-29 CN CN988062631A patent/CN1131674C/zh not_active Expired - Lifetime
- 1998-05-29 KR KR10-1999-7011911A patent/KR100478844B1/ko not_active IP Right Cessation
- 1998-05-29 WO PCT/GB1998/001586 patent/WO1998057556A1/en active IP Right Grant
- 1998-05-29 DK DK98924487T patent/DK0991330T3/da active
- 1998-05-29 JP JP50392899A patent/JP4016067B2/ja not_active Expired - Lifetime
- 1998-05-29 NZ NZ501477A patent/NZ501477A/en not_active IP Right Cessation
- 1998-05-29 AT AT98924487T patent/ATE298983T1/de active
- 1998-05-29 EP EP02011586A patent/EP1250856A3/en not_active Withdrawn
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2000
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Cited By (10)
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CN110326819A (zh) * | 2005-07-19 | 2019-10-15 | 尤尔实验室有限公司 | 用于与装置一起使用的料盒 |
US11647783B2 (en) | 2005-07-19 | 2023-05-16 | Juul Labs, Inc. | Devices for vaporization of a substance |
US11904089B2 (en) | 2011-08-16 | 2024-02-20 | Juul Labs, Inc. | Devices for vaporization of a substance |
CN104350204A (zh) * | 2012-06-01 | 2015-02-11 | 德尔福特集团有限公司 | 包括薄片填料的卷烟纸 |
CN104350204B (zh) * | 2012-06-01 | 2017-03-08 | 德尔福特集团有限公司 | 包括薄片填料的卷烟纸 |
CN104223354A (zh) * | 2014-09-03 | 2014-12-24 | 湖南中烟工业有限责任公司 | 一种受热不塌陷的低温卷烟 |
CN104223354B (zh) * | 2014-09-03 | 2016-08-24 | 湖南中烟工业有限责任公司 | 一种受热不塌陷的低温卷烟 |
CN109938398A (zh) * | 2019-03-29 | 2019-06-28 | 红云红河烟草(集团)有限责任公司 | 一种加热不燃烧卷烟烟弹及其制作方法 |
CN114667070A (zh) * | 2020-05-19 | 2022-06-24 | 韩国烟草人参公社 | 发出声音的吸烟制品 |
CN114667070B (zh) * | 2020-05-19 | 2024-03-22 | 韩国烟草人参公社 | 发出声音的吸烟制品 |
Also Published As
Publication number | Publication date |
---|---|
EP0991330B1 (en) | 2005-07-06 |
EP1250856A3 (en) | 2003-05-28 |
WO1998057556A1 (en) | 1998-12-23 |
CA2491914A1 (en) | 1998-12-23 |
CA2425096A1 (en) | 1998-12-23 |
GB9712815D0 (en) | 1997-08-20 |
CN1131674C (zh) | 2003-12-24 |
JP4016067B2 (ja) | 2007-12-05 |
EP1304049A3 (en) | 2003-12-17 |
EP1250856A2 (en) | 2002-10-23 |
ES2244062T3 (es) | 2005-12-01 |
PT991330E (pt) | 2005-09-30 |
CA2291017C (en) | 2007-05-15 |
BR9810045A (pt) | 2000-08-29 |
CA2491914C (en) | 2008-07-22 |
US6779531B1 (en) | 2004-08-24 |
AU756450B2 (en) | 2003-01-16 |
NZ514210A (en) | 2003-01-31 |
AU7668098A (en) | 1999-01-04 |
DE69830793D1 (de) | 2005-08-11 |
KR20010013889A (ko) | 2001-02-26 |
EP0991330A1 (en) | 2000-04-12 |
CA2291017A1 (en) | 1998-12-23 |
WO1998057556A8 (en) | 1999-12-23 |
EP1304049A2 (en) | 2003-04-23 |
ATE298983T1 (de) | 2005-07-15 |
JP2002504830A (ja) | 2002-02-12 |
DK0991330T3 (da) | 2005-10-17 |
US20050081869A1 (en) | 2005-04-21 |
NZ501477A (en) | 2002-02-01 |
DE69830793T2 (de) | 2006-04-27 |
KR100478844B1 (ko) | 2005-03-24 |
HK1025725A1 (en) | 2000-11-24 |
US7398783B2 (en) | 2008-07-15 |
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