CN1260486C - Self-bubricating lead-free bearing and manufacture method thereof - Google Patents

Self-bubricating lead-free bearing and manufacture method thereof Download PDF

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Publication number
CN1260486C
CN1260486C CNB021476187A CN02147618A CN1260486C CN 1260486 C CN1260486 C CN 1260486C CN B021476187 A CNB021476187 A CN B021476187A CN 02147618 A CN02147618 A CN 02147618A CN 1260486 C CN1260486 C CN 1260486C
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China
Prior art keywords
sintering
roll
self
lead
copper powder
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CNB021476187A
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CN1488865A (en
Inventor
孙志华
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Zhejiang Changsheng Sliding Bearings Co Ltd
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CHANGSHENG SLIDING BEARING Co Ltd JIASHAN
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    • Y02T10/865

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  • Lubricants (AREA)
  • Sliding-Contact Bearings (AREA)
  • Powder Metallurgy (AREA)

Abstract

The present invention relates to a self-lubricating lead-free bearing which comprises a metal substrate, a lead-free copper powder layer and an antifriction wear-resistant layer which are finally rolled into a shaft sleeve. The present invention discloses a method for manufacturing the self-lubricating lead-free bearing at the same time, and overcomes the disadvantage that a self-lubricating bearing can not be applied to food industry, hydraulic industry, medicine industry, etc. due to the lead containment and the suspicious carcinogenic fiber of the self-lubricating bearing. Most of all, in the method for manufacturing the self-lubricating lead-free bearing, the material of the antifriction wear-resistant layer is PTFE, EKONOL, PPS and MoS2, and toluene and aluminum nitrate are not used in technical processes.

Description

Selflubricating Pb-free bearing and method for making thereof
Affiliated technical field
The present invention relates to sliding bearing, particularly Nonlubricated bearing; Also relevant with the composition of polymeric compound.
Background technique
Three layers of composite bearing in the Nonlubricated bearing draw the initiative of West Asia company by Britain's lattice, are called for short DU.This product is a matrix with laminar steel plate, and intermediate sintering has spherical porous bronze bisque, and roll based on teflon surface shop is the plumbous mixture of being furnished with of PTFE, infiltration, topped above-mentioned copper powder layer and sintering and become anti-friction wear-resistant layer.At last above-mentioned three-layer composite board material is rolled into the bearing of the sleeve-like of different size according to the size of axle.The DU class bearing of Sheng Chaning is the SF-1 class at home all over the world, extensive use height, middle load, slow-revving occasion.But the powder of lead and gas are overflowed during owing to work, and are therefore repelled in industries such as food, medicines.
Publication number CN1234476A is by the patent that German Federal-Mogul Wiesbaden GMBH submits, and having proposed glide lamella is the scheme that anti-friction wear-resistant layer needn't be sought help from lead or its compound.In matrix material PTFE of this layer or high-melting-point fluorine thermoplastic and the PTFE mixture, contain Powdered aramid at least, its volume accounts for the 10-50% of this stratum total.But, still contain the lead more than 15% in the bronze bisque of this scheme, and handle mixture with toluene and aluminum nitrate when making, therefore still might be polluted and be ostracised.
The publication number of being submitted by U.S. Dana Corp is the patent application of CN1292852A, then disclosing backing layer is new departure of anti-friction wear-resistant layer, and by volume contains the fluoropolymer of melt-processable of the fibrillation aramide-fibre of granular ion fluoride, 2-10% of 10-30% and 2-10% and the PTFE of its surplus.Have document to show, (1) fluoride is a Toxic, as NaF; (2) sneaking into of fibrillating fibre needs outside the special equipment, and also under a cloud have a carcinogenic possibility.In addition, without exception, use toluene and aluminum nitrate in the production process indispensably; Product also uses low-viscosity (mobile) liquid lubricated, is also repelled by industries such as food.
As everyone knows, PTFE has very low friction factor, is 0.04-0.05 generally speaking, and friction factor 0.016 under high load.It is stratiform structure.Its combination force with one deck is stronger, but the interlayer combination force is very weak, very easily slide relative.During motion, can form transfer membrane on the antithesis surface, so the PTFE friction factor is very little at the utmost point in the short time.But it has relatively poor stickability on mating material, promptly is the main cause that causes heavy wear.Therefore use the chance of PTFE few separately.Is what thing the problem that technos generally is concerned about to add can make the friction factor of new bearing material still very little, and wear resistance has great raising?
EKONOL is the poly phenyl ester, is commonly called as polybenzoate.Its crystal has excellent self lubricity and excellent wear-resisting, compression croop property in the form of sheets, and its wear resistance is 500 times of PTFE.The big 3-5 of thermal conductivity ratio PTFE times, special advantage is not dissolve in nearly all organic solvent.PI is that polyimide has akin characteristic, is its substitution material therefore.
PPS is that polyphenylene sulfide is a kind of linear thermoplastic's macromolecular material.It has excellent heat resistance, chemical stability and to the high adhesive strength of metal.If it joins when forming the PTFE-PPS blend in the material that PTFE is the master, as long as reasonable mixture ratio can make the wear-resisting property of PTFE be greatly improved.But PPS will do chemical crosslinking earlier.Chemical crosslinking has been mature technology, needs to add promoter such as magnesium fluoride usually, crosslinking time 20 minutes.
M 0S 2Be molybdenum disulfide, belong to the stratiform structure of hexagonal system, very easily between layer and layer, rive, so have good self-lubricating property.M 0S 2Can be adsorbed on the metal surface strongly, even also survivable when friction, therefore can bear higher load, data shows, the thick M of 2.5 μ m 0S 2Film can bear the above pressure of 2800MPa, stands the friction velocity of 40m/s simultaneously.In addition, M 0S 2Decapacitation is by outside chloroazotic acid, dense stream acid, boiling concentrated hydrochloric acid, pure oxygen, high-temperature chlorine and the hydrogen attack, in other soda acids, medicine, solvent, water, petroleum products and synthetic lubricant, all do not dissolve, to ambiance is stable, under the general condition not with metal reaction, do not corrode rubber material.Sometimes M 0S 2Available graphite substitutes.
PPS often needs to be prior art through chemical crosslinking in use.Make the PTFE emulsion and also be regarded as prior art.It is reacted in the aqueous solution by the gas phase tetrafluoroethylene, generates PTFE and water, adds emulsifier again and makes.The PTFE emulsion can be buied in market at present.
Summary of the invention
The object of the present invention is to provide a kind of selflubricating Pb-free bearing, oil-free lubrication during its work, simultaneously not leaded, can expand to the application of food, pharmacy, water conservancy project, beverage, medical mechanical industry.Another object of the present invention is to seek out the manufacture method of above-mentioned bearing.
It is as follows to disclose new technological scheme:
A kind of selflubricating Pb-free bearing, comprise metal substrate, be sintered in the spherical porous copper powder layer of substrate one side and the friction reducing abrasion resistant material layer of infiltration and covering copper bisque, roll into sleeve-like at last, it is characterized in that compound that described copper powder is leaded and not plumbous and toluene, aluminum nitrate, fibrillation aramide-fibre; The composition of described friction reducing abrasion resistant material is by weight, teflon 30-35%, and poly phenyl ester 30-35%, molybdenum disulfide 6-10%, all the other are polyphenylene sulfide.
The method of making described bearing is:
A, on metal substrate sintered leadless free copper powder layer;
B, making anti-friction wear-resistant layer can be sprawled software
1. polyphenylene sulfide chemical crosslinking;
2. join powder, join powder respectively by aforementioned weight ratio;
3. stir, the powder except that teflon is mixed stirring three times, 5-10 minute at every turn, become mixture, stirrer rotating speed 2000-4000r/min sieves for three times, and sieve mesh is more than 100;
4. make ptfe emulsion, it is 60% ptfe emulsion that the teflon powder is made solid content;
5. system can be sprawled software, with the ptfe emulsion and the said mixture mixing of solid content 60%, stirs 5-10 minute in rotating speed is the 20-60r/min stirrer; Temperature is 15-25 ℃;
Roll C, shop, and the software shop is rolled on the copper powder layer, and thickness is not to reveal copper powder for suitable, and thickness size is 0.01-0.03mm;
D, oven dry, with 220-280 ℃ of baking 20-30 minute, volatilizing fully with moisture content in the emulsion was as the criterion;
E, in roll, the sheet material after the oven dry rerolls once, amount of rolling is 0.01-0.03mm, to increase density and combination force;
F, sintering, at nitrogen protection sintering furnace sintering, sintering temperature 370-390 ℃, time 36-45 minute, nitrogen gas purity was more than 99.9%, and the flow of different sintering furnaces is not to be oxidized to minimum discharge;
G, finish to gauge, with the sheet material behind the sintering, finish to gauge is to the requirement of finished product sheet material, minimum rolling down more than the 0.01mm;
H, blanking roll, and according to bearing size blanking, roll into sleeve-like.
The selflubricating Pb-free bearing of making according to the method described above, temporary transient called after CSB-50 under the situation of existing patented technology product-free, is contrast with present market three layers of composite bearing SF-1 product, rubs, wear test.The comparative trial table is as follows:
A, testing installation MMD-10 end wear testing machine, working condition: 1. dry friction; 2. speed V=0.2m/s; 3. pressure P=8N/mm 24. test period 180min.
Model Average friction coefficient (μ) Final temperature (℃) Final wear extent (μ m) Remarks
SF-1 0.106 94 18
CSB-50 0.109 85 15
B, testing installation are the same, working condition: 1. oil lubrication; 2. speed V=0.4m/s; 3. pressure P=8N/mm 24. test period 180min.
Model Average friction coefficient (μ) Final temperature (℃) Final wear extent (μ m) Remarks
SF-1 0.073 125 51
CSB-50 0.07 105 55
C, testing installation are the same, working condition: 1. oil lubrication; 2. speed V=1.5m/s; 3. pressure P=4.5N/mm 24. test period 180min.
Model Average friction coefficient (μ) Final temperature (℃) Final wear extent (μ m) Remarks
SF-1 0.043 96 32
CSB-50 0.038 100 26
D, testing installation MPV-20B frictional testing machine, working condition: 1. dry friction; 2. speed V=0.5m/s; 3. test period 120min.Load step by step.
Model PV value (N/mm 2.m/s) Final temperature (℃) Final wear extent (μ m) Remarks
SF-1 3.344 138 26
CSB-50 4.89 136 22
E, testing installation: YB-90 (90 ° of rolling tests), test conditions: V=1.0m/min, pressure P=24.5N/mm2, test period 50 hours.
Model Final temperature (℃) Final wear extent (μ m)
SF-1 66 43
CSB-50 52 37
The friction factor of product of the present invention is near SF-1 as can be seen from the table, but parameters such as PV value, final wear extent and final temperature obviously are better than SF-1, the not leaded and harmful fiber of copper powder layer and anti-friction wear-resistant layer particularly, simultaneously can be in order to avoid use the low viscosity Lubricants, so application industry can expand to food, beverage, water conservancy project, medicine, household electrical appliances, office machinery etc. and relates to the mechanical industry of human life's safety and health and require unleaded chemical machinery industry.
Description of drawings
Accompanying drawing is a process flow diagram of the present invention.
Embodiment
During enforcement, as described in the technological scheme of specification summary of the invention, wherein preference data is as follows:
Material prescription is by weight teflon 32-34%; Poly phenyl ester 32-34%; Molybdenum disulfide 7-8%; All the other are polyphenylene sulfide.
250-280 ℃ of oven dry humidity was dried by the fire 20-30 minute, looked the optimum that the moisture content in the emulsion is brought into play fully.
During sintering, in the nitrogen protective sintering stove, carry out, sintering temperature 375-385 ℃, sintering time 40 minutes, nitrogen gas purity is more than 99.9%.At different sintering furnaces, its nitrogen flow, pressure are also different.Be not oxidized to the best with steel substrate.
During enforcement, with PI be polyimide substitute EKONOL or/graphite replaces M 0S 2, its effect is similar.
Certainly after blanking rolls, also to carry out shaping, chamfering, at last the packing warehouse-in.

Claims (2)

1, a kind of selflubricating Pb-free bearing, comprise metal substrate, be sintered in the spherical porous copper powder layer of substrate one side and the friction reducing abrasion resistant material layer of infiltration and covering copper bisque, roll into sleeve-like at last, it is characterized in that compound that described copper powder is leaded and not plumbous and toluene, aluminum nitrate, fibrillation aramide-fibre; The composition of described friction reducing abrasion resistant material is by weight, teflon 30-35%, and poly phenyl ester 30-35%, molybdenum disulfide 6-10%, all the other are polyphenylene sulfide.
2, the manufacture method of selflubricating Pb-free bearing according to claim 1 is characterized in that:
A, on metal substrate sintered leadless free copper powder layer;
B, making anti-friction wear-resistant layer can be sprawled software
1. polyphenylene sulfide chemical crosslinking;
2. join powder, prepare burden respectively by claim 1 weight ratio;
3. stir, the powder except that teflon is mixed stirring three times, 5-10 minute at every turn, become mixture, stirrer rotating speed 2000-4000r/min sieves for three times, and sieve mesh is more than 100;
4. make ptfe emulsion, it is 60% ptfe emulsion that the teflon powder is made solid content;
5. system can be sprawled software, and the ptfe emulsion of solid content 60% is mixed with said mixture, and stirring is 5-10 minute in rotating speed is the 20-60r/min stirrer; Temperature is 15-25 ℃;
Roll C, shop, and the software shop is rolled on the copper powder layer, and thickness is not to reveal copper powder for suitable, and thickness size is 0.01-0.03mm;
D, oven dry were with 220-280 ℃ of baking 20-30 minute;
E, in roll, the sheet material after the oven dry rerolls once, amount of rolling is 0.01-0.03mm;
F, sintering, at nitrogen protection sintering furnace sintering, sintering temperature 370-390 ℃, time 36-45 minute, nitrogen gas purity was more than 99.9%, and the flow of different sintering furnaces is not to be oxidized to minimum discharge;
G, finish to gauge, with the sheet material behind the sintering, finish to gauge is to the requirement of finished product sheet material, minimum rolling down more than the 0.01mm;
H, blanking roll, and according to bearing size blanking, roll into sleeve-like.
CNB021476187A 2002-10-10 2002-10-10 Self-bubricating lead-free bearing and manufacture method thereof Expired - Lifetime CN1260486C (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101413543B (en) * 2008-12-01 2011-06-29 江苏希西维轴承有限公司 Dry friction self-lubricating slide bearing

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CN100376347C (en) * 2005-02-16 2008-03-26 龙清勇 Method for producing high efficiency movement pair surface coating
CN1319731C (en) * 2005-08-01 2007-06-06 揭朝奎 Thermo shaping method of composite material component port surface
CN1304477C (en) * 2005-09-14 2007-03-14 南京航空航天大学 Compound PTFE material with low friction and high wear resistance and its prepn process
CN100419289C (en) * 2005-12-28 2008-09-17 浙江长盛滑动轴承有限公司 Aluminium-radical three-layer composite self-lubricating bearing and manufacturing method thereof
US7754287B2 (en) * 2006-05-31 2010-07-13 E. I. Du Pont De Nemours And Company Process for forming filled bearings from fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents
CN101074702B (en) * 2007-05-24 2012-03-28 浙江长盛滑动轴承股份有限公司 Lead-free self-lubricating bearing and its production
US20110194792A1 (en) * 2010-02-11 2011-08-11 Dial Tool Industries, Inc. Bushing, piece with bushing, or method of producing
CN102235424A (en) * 2011-07-07 2011-11-09 栾清杨 Mosaic composite material bearing
DE102011087798B3 (en) * 2011-12-06 2013-04-04 Federal-Mogul Wiesbaden Gmbh Method for producing a sliding bearing with a CuNi2Si, CuFe2P or CuSnX compound
CN104249154A (en) * 2013-06-26 2014-12-31 浙江长盛滑动轴承股份有限公司 Metal matrix self-lubricating composite material and preparation method thereof
WO2014205915A1 (en) * 2013-06-26 2014-12-31 浙江长盛滑动轴承股份有限公司 Metal matrix self-lubricating composite and manufacturing method therefor
CN111101168A (en) * 2018-09-17 2020-05-05 田振奎 Self-lubricating solid soft metal silver-lead alloy coating structure
CN115418263B (en) * 2022-09-01 2023-05-02 深圳市德诚旺科技有限公司 High-sealing shaft sleeve material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101413543B (en) * 2008-12-01 2011-06-29 江苏希西维轴承有限公司 Dry friction self-lubricating slide bearing

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Address after: 314100 industrial parks in Zhejiang province Weitang Town of Jiashan County Changsheng Road No. 138

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Address before: 314100 No. 6 Fen Lake Road, Jiashan Economic Development Zone, Zhejiang, China

Patentee before: Jiashan Changsheng Sliding Bearing Co.,Ltd.

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Owner name: ZHEJIANG CHANGSHENG SLIDING BEARINGS CO., LTD.

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CP03 Change of name, title or address

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Address before: 314100 industrial parks in Zhejiang province Weitang Town of Jiashan County Changsheng Road No. 138

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Granted publication date: 20060621

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