CN1259403C - Self-cleaning softener for clothing - Google Patents
Self-cleaning softener for clothing Download PDFInfo
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- CN1259403C CN1259403C CN 200410071933 CN200410071933A CN1259403C CN 1259403 C CN1259403 C CN 1259403C CN 200410071933 CN200410071933 CN 200410071933 CN 200410071933 A CN200410071933 A CN 200410071933A CN 1259403 C CN1259403 C CN 1259403C
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- clothing
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- cleaning
- softener
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Abstract
The present invention relates to a clothing self-cleaning softener. The present invention belongs to the technical field of clothing cleaning. The water solution of the clothing self-cleaning softener comprises the components by weight percentage: 5 to 20% of nanometer TiO2, 5 to 20% of nanometer SiO2, 0.1 to 10% of gamma-methylacryloyl oxo-propyl-trimethylsilicane alkane resin acceptors, 1 to 50% of lipid phosphate salt, hexadecyl trimethyl ammonium bromide, long-chain fatty acid or the mixture, 0.1 to 1% of no-ionic organic fluorine surfactant and 1 to 20% of dodecyl dimethyl benzyl chloridate amine, dialkyl dimethyl amine salt, diamide alkoxy amine salt or the mixture. The present invention can efficiently maintain clothing self-cleaning and compliance, and has the effects of oil drainage, water drainage, dirt resistance, static electricity resistance, delicate fragrance, ventilation and comfort during being worn, etc. The product has the advantages of simple preparation process, easy operation and simple and convenient use.
Description
Technical field
The invention belongs to clothing cleaning technique field, particularly relate to a kind of self-cleaning softener for clothing.
Background technology
At present, the rinse product of using on the market has clothing protective material and clean-out system.As the Chinese patent publication number is CN1042733A " clothing protective agent-" Lixijing " ", and it discloses clothing protective agent-" Lixijing " and has selected for use water-soluble organic macromolecule material polyvinyl alcohol and proper amount of surfactant and spices to process.There is no oleophobic hydrophobic effect in this product, and the some effects ventilation property, and protective material is sharp to be cleaned with cleaning dissolving, and each cleaning all need reuse, and product does not have compliance function, does not have antistatic effect.
Summary of the invention
The deficiency that the present invention exists for the solution prior art, and a kind of self-cleaning softener for clothing is provided.
The purpose of this invention is to provide a kind of using method simple, make clothing oleophobic hydrophobic (being similar to the effect of fluid drips on the He leaf), and guarantee high ventilation performance, self-cleaning, submissive, have the clothing protection product of antistatic and delicate fragrance effect simultaneously.
The technical scheme that the present invention takes is as follows:
A kind of self-cleaning softener for clothing contains following composition in its aqueous solution, each constituent mass per-cent is:
Nano-TiO
25-20%
Nanometer SiO
25-20%
γ monomethyl acryloxy propyl trimethoxy silicane coupling agent 0.1-10%
The mixture 1-5% of fat thing phosphate ester salt, cetyl trimethylammonium bromide, longer chain fatty acid or its two kinds, three kinds
Non-ionic type organic fluorine tensio-active agent 0.1-1%
The mixture 1-20% of dodecyl benzyl dimethyl ammonium chloride, two alkyl-dimethyl based quaternary ammonium salt or diamide base alkoxy quaternary ammonium salt surfactant or its two kinds, three kinds
The present invention can also take following technical measures:
Above-mentioned self-cleaning softener for clothing is characterized in that the mass percent of following composition in the self-cleaning softener for clothing aqueous solution is:
Nano-TiO
28-15%
Nanometer SiO
28-15%
γ monomethyl acryloxy propyl trimethoxy silicane coupling agent 0.5-5%
The mixture 2-4% of fat thing phosphate ester salt, cetyl trimethylammonium bromide or longer chain fatty acid or its two kinds, three kinds
Non-ionic type organic fluorine tensio-active agent 0.1-1%
The mixture 5-15% of dodecyl benzyl dimethyl ammonium chloride, two alkyl-dimethyl based quaternary ammonium salt or diamide base alkoxy quaternary ammonium salt surfactant or its two kinds, three kinds
Above-mentioned self-cleaning softener for clothing is characterized in that non-ionic type organic fluorine tensio-active agent is the non-ionic type fluorocarbon surfactant.
Above-mentioned self-cleaning softener for clothing is characterized in containing in the self-cleaning softener for clothing aqueous solution essence that mass percent is 0.1-1%.
The producing apparatus of self-cleaning softener for clothing: the production unit of this product is simple, only needs the container of a band propeller mixer.
Self-cleaning softener for clothing manufacture craft process: 50% of the adding water component in container earlier, adds titanium dioxide and silicon-dioxide more simultaneously, starts the running speed stirring of equipment with 80-200r/min.Add dispersion agent fat thing phosphoric acid salt, cetyl trimethylammonium bromide or longer chain fatty acid and make powder and water thorough mixing, generally need to stir about 30 minutes.γ-methacryloxypropyl trimethoxy silane coupling agent makes the surface of coated with silica at titanium dioxide with sol-gel processing, makes it have oil repellency and hydrophobic nature by the particulate silanization is handled.Add non-ionic type organic fluorine tensio-active agent, add fabric softening agent dodecyl benzyl dimethyl ammonium chloride, two alkyl-dimethyl based quaternary ammonium salt or diamide base alkoxy quaternary ammonium salt surfactant at last, add then essence and water component remaining 50%, fully stir after one hour again and can obtain this product.
The using method of this product: this product using method is simple, effect is obvious, at first product is sprayed on garment surface equably, then with electric iron press dried, the ironing get final product.
A common Western-style clothes is in people's live and work, because some are as oil stains such as vegetable soup, ink, the water stain permanent loss of bringing that can't remove, and a good clothing is abandoned, and just this type of thing can not take place again after using this product.Usually use this product, because its multi-efficiency can significantly reduce the stained factor of clothing, so can need only simply clean once by some months, also can be dispeled easily on a small quantity even have because of the accompanying various spots of long-term dress on the clothing surface, press then that do can relieved dress.This product uses once permanently effective, can repeatedly clean after press dried still effective.Too much cause effect to go down as wash number, can reuse this product.
Advantage of the present invention and positively effect: self-cleaning softener for clothing can effectively keep clothing self-cleaning, submissive; use the clothing of this product; can reach effects such as oleophobic, hydrophobic, anti-soil, antistatic and delicate fragrance simultaneously; and this product has improved the anti-damage ability of clothing to greatest extent; the protection clothing prolongs clothing and fades the time because of repeatedly cleaning to become; it is convenient to clean, and the high ventilation performance is arranged, and clothing is comfortable and easy to wear.The preparation technology of this product is simple, and processing ease is easy to use.
Embodiment
For further understanding technology contents of the present invention, characteristics and effect, exemplify following example now, and conjunction with figs. is described in detail as follows:
Embodiment 1
A kind of self-cleaning softener for clothing, the mass percent of following composition consists of in its aqueous solution:
Nano-TiO
28%
Nanometer SiO
28%
γ-methacryloxypropyl trimethoxy silane 3%
Cetyl trimethylammonium bromide 3%
Non-ionic type fluorocarbon surfactant 0.3%
Dodecyl benzyl dimethyl ammonium chloride 6%
Essence 0.5%
Wherein, the structural formula of γ-methacryloxypropyl trimethoxy silane is:
Fabric softener: the structural formula of dodecyl benzyl dimethyl ammonium chloride is:
Essence: the structural formula of cyclopentadecanone is:
Embodiment 2
A kind of self-cleaning softener for clothing, the mass percent of following composition consists of in its aqueous solution:
Nano-TiO
26%
Nanometer SiO
26%
γ-methacryloxypropyl trimethoxy silane 2%
Cetyl trimethylammonium bromide 2%
Non-ionic type fluorocarbon surfactant 0.5%
Dodecyl benzyl dimethyl ammonium chloride 10%
Essence 0.4%
Embodiment 3
Product 200 grams with embodiment 1 gained are sprayed at the Western-style clothes outside, press to do to press getting final product then with electric iron.
Claims (4)
1. self-cleaning softener for clothing, it is characterized in that: contain following composition in the self-cleaning softener for clothing aqueous solution, its mass percent is
Nano-TiO
25-20%
Nanometer SiO
25-20%
Y-methacryloxypropyl trimethoxy silane coupling agent 0.1-10%
Fat thing phosphate ester salt, cetyl trimethylammonium bromide, longer chain fatty acid or its mixture 1-5%
Non-ionic type organic fluorine tensio-active agent 0.1-1%
Dodecyl benzyl dimethyl ammonium chloride, two alkyl-dimethyl based quaternary ammonium salt, diamide base alkoxy quaternary ammonium salt
Tensio-active agent or its mixture 1-20%.
2. self-cleaning softener for clothing according to claim 1 is characterized in that: the mass percent of following composition is in the self-cleaning softener for clothing aqueous solution
Nano-TiO
28-15%
Nanometer SiO
28-15%
Y-methacryloxypropyl trimethoxy silane coupling agent 0.5-5%
Fat thing phosphate ester salt, cetyl trimethylammonium bromide or longer chain fatty acid or its mixture 2-4%
Non-ionic type organic fluorine tensio-active agent 0.1-1%
Dodecyl benzyl dimethyl ammonium chloride, two alkyl-dimethyl based quaternary ammonium salt or diamide base alkoxy quaternary ammonium salt
Tensio-active agent or its mixture 5-15%.
3. self-cleaning softener for clothing according to claim 1 and 2 is characterized in that: non-ionic type organic fluorine tensio-active agent is the non-ionic type fluorocarbon surfactant.
4. self-cleaning softener for clothing according to claim 1 and 2 is characterized in that: contain the essence that mass percent is 0.1-1% in the self-cleaning softener for clothing aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410071933 CN1259403C (en) | 2004-09-13 | 2004-09-13 | Self-cleaning softener for clothing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410071933 CN1259403C (en) | 2004-09-13 | 2004-09-13 | Self-cleaning softener for clothing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1613989A CN1613989A (en) | 2005-05-11 |
| CN1259403C true CN1259403C (en) | 2006-06-14 |
Family
ID=34765179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410071933 Expired - Fee Related CN1259403C (en) | 2004-09-13 | 2004-09-13 | Self-cleaning softener for clothing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1259403C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906715B (en) * | 2010-08-03 | 2012-01-18 | 上海亚孚化学有限公司 | Fluorine-containing silane coupling agent and preparation method thereof |
| CN105985870A (en) * | 2016-07-13 | 2016-10-05 | 西南大学 | Quick-drying antimicrobial mildewproof multifunctional laundry detergent and preparation method thereof |
| CN106350248A (en) * | 2016-08-26 | 2017-01-25 | 曹平 | Environment-friendly laundry detergent |
-
2004
- 2004-09-13 CN CN 200410071933 patent/CN1259403C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1613989A (en) | 2005-05-11 |
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