CN1257777A - Method for producing composite brick of nucleated glass and ceramic - Google Patents

Method for producing composite brick of nucleated glass and ceramic Download PDF

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CN1257777A
CN1257777A CN 00100030 CN00100030A CN1257777A CN 1257777 A CN1257777 A CN 1257777A CN 00100030 CN00100030 CN 00100030 CN 00100030 A CN00100030 A CN 00100030A CN 1257777 A CN1257777 A CN 1257777A
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ceramic
devitrified glass
glass
carbonate
composite brick
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CN1120078C (en
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戴长禄
孙树江
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Abstract

A composite nucleated glass-ceramic brick is made of nucleated glass and ceramic through melting nucleated glass, quenching in cold medium to become particles with different sizes, die pressing to obtain ceramic brick blank, spreading the nucleated glass particles on the surface of ceramic brick blank by the spreader while fixing them by adhesive liquid, and firing in kiln. Its advantages are low cost and gay colour. It can be used as high-grade decorative material.

Description

The production method of a kind of novel nucleated glass-Ceramic Composite brick
The present invention relates to the production method of architectural material therefor, more particularly relate to the production method of a kind of devitrified glass-Ceramic Composite brick.
As everyone knows, crystallizing glass sheet material is that aesthstic performance is good, the high-grade ornament materials that mechanical performance is strong, but because the cost height, yield poorly, and kind is single, and price is high and limit applying of it greatly.And the cost of Ceramic Tiles is low, and the output height is wide in variety, and price is low and become the traditional decoration material of extensive use, up to the present, yet the high-grade material of devitrified glass is not combined with the traditional material of pottery on the market and makes composite brick.
The object of the invention is at weak point of the prior art, and provides cost low, output height, the production method of novel high-grade glass wide in variety-Ceramic Composite brick.
Purpose of the present invention can reach by following measure: the devitrified glass shrend of fusing is become particles with different sizes; spreading fertilizer over the fields equipment with dry granular or dry powder then is sprinkling upon it on ceramic adobe of compression moulding; spread 1～3 layer; imposing fixer again fixes for 1～3 time; in kiln, burn till at last, burn till 1150 ℃～1250 ℃ of maximum temperatures, firing period 40～80 minutes; get the semi-finished product composite brick after burning till, through edging, strickling, corase grind, polishing, edging, drying.
The devitrified glass composition is SiO by weight percentage 250～65%, Al 2O 35～15%, CaO 10～25%, MgO 0～10%, Na 2O 1～6%, K 2O 1～6%, Li 2O 0～4%, BaO 0～5%, ZnO 0～10% add As 2O 30～0.5% and colouring agent 0～8%;
To meet weighing in proportion less than the various raw materials of 0.8 millimeter quartz, feldspar, calcium carbonate, brium carbonate, zinc oxide, lithium carbonate, sodium nitrate, sodium carbonate, magnesium carbonate or magnesia, arsenic trioxide and colouring agent of above-mentioned composition with fineness, mix and put into glass melter fusing, 1320 ℃～1520 ℃ of fusion temperatures;
As required, with these melting charge shrends, dry, must be less than 10 millimeters different devitrified glass particulate material.
The chemical composition of Ceramic Tiles is SiO by weight percentage 265～75%, Al 2O 315～25%, CaO 0～5%, MgO 0～5%, Na 2O 0.5～6%, K 2O 0.5～5%;
To meet mentioned component and the granularity compound less than 10 millimeters quartz, kaolinite, illite, feldspar, talcum, dolomite and diopside, and weigh by proportioning, ball milling is in small, broken bits, the adobe that spray-drying powder process, forcing press moulding, drying are made different size.This invention can make red, yellow, blue, green, black, the serial devitrified glass particulate material of Bai Liuda, colouring agent such as cupric oxide, nickel oxide, cobalt oxide, iron oxide, titanium oxide, cerium oxide, chromium oxide etc.
The present invention has following advantage compared to existing technology:
1, reduced expensive devitrified glass particulate material consumption, increased the consumption of double valency ceramic adobe, integrated and greatly reduce cost.
2, to burn till three process speed fast because pressing unfired brick, dry granular spread fertilizer over the fields the spread grain or dusting and roller kilns of machine, make output become several times even+several times increase.
3, because the high temperature firing time is short, and devitrified glass granularity broad can make devitrified glass particulate material red, yellow, blue, green, black, the serial color of Bai Liuda, making the composite brick product is diversified kind.
Technological process of the present invention is as follows:
Select materials and be crushed to 0.8 millimeter or thinner → by prescription make uniform compound → glass melter fusion, clarification → 1320 ℃～1520 ℃ → shrend of roasting temperature become particulate material different below 10 millimeters → dry the devitrified glass particulate material of different sizes.
Select materials and be crushed to below 10 millimeters → by prescription weigh → ball mill is in small, broken bits → spray tower granulation → forcing press moulding → brick bat drying.
Spread fertilizer over the fields machine with dry granular or dry powder then the devitrified glass particulate material is sprinkling upon the adobe surface; 1～3 layer → glazing machine is executed in 1～3 time → roller kilns of fixer and is burnt till; burn till 1150 ℃～1250 ℃ of maximum temperatures, semi-finished product → edging → strickling → corase grind → throwing that firing period 40～80 minutes → devitrified glass crystallization and ceramic base porcelainization are finished is simultaneously put down → edging → drying → pick → packing
With 5 embodiment, the combined process flow process elaborates to invention below.
Embodiment 1
Press chemical analysis: SiO 260.34%, Al 2O 36.75%, CaO17.60%, ZnO4.57%, BaO 2.56%, Li 2O 2.05%, Na 2O 1.6% and K 2O 4.53%, adds As 2O 30.3%, choose corresponding quartz, feldspar, calcium carbonate, brium carbonate, zinc oxide, lithium carbonate, sodium nitrate, arsenic trioxide raw material below 0.8 millimeter, weigh by proportioning, evenly mix, in glass melter, melt, 1480 ℃ of fusion temperatures, melt is shrend after clarifying, after the oven dry particulate material is sieved by 2.5 millimeters (8 mesh sieves), obtain particulate material less than 2.5 millimeters.
According to chemical composition, SiO 268.85%, Al 2O 321.90%, CaO 0.95%, MgO1.11%, K 2O 1.68%, Na 2O 5.51%, choose the various raw materials that contain kaolinite, illite, feldspar, quartz, talcum accordingly, be crushed to below 10 millimeters, weigh by proportioning, ball milling is in small, broken bits to tail over 0.8% to 10000-hole sieve, mist projection granulating becomes moisture about 7% powder, with the adobe of 660 * 660 millimeters of 3200 tons of forcing press moulding, dries to moisture it below 0.5% again.
Adopt dry granular or dry powder to spread fertilizer over the fields machine, the above-mentioned of drying evenly spread fertilizer over the fields on the adobe face less than 2.5 millimeters devitrified glass particulate material, reach 4 kilograms/meter 2Then, go into 110 meters roller kilns and burn till, its maximum temperature is 1220 ℃, firing period 53 minutes.The semi-finished product of kiln discharge are made light has the spheroidal crystal particle as the snowy white of water ornament materials through edging → strickling → corase grind → polishing → edging → drying process again.
Embodiment 2 and embodiment 3
Carry out according to embodiment 1 each step, embodiment 1 devitrified glass composition is added 0.2% cobalt oxide or 0.25% nickel oxide respectively.Like this, difference De Lanse or dark brown glittering and translucent devitrified glass-Ceramic Composite brick ornament materials.
Embodiment 4
Press chemical analysis, SiO2 58.99%, Al 2O 36.46%, CaO 16.90%, ZnO4.41%, BaO 2.44%, Li 2O 1.99%, Na 2O 1.47%%, K 2O 4.22% and MgO3.12% add CuO 0.5% and As 2O 30.3%, another chemical composition: SiO 264.96%, Al 2O 35.07%, CaO 16.62%, ZnO 4.26%, BaO 2.41%, Li 2O 1.08%, Na 2O 2.04% and K 2O 3.56%, adds As 2O 30.4%, choose accordingly various raw materials respectively less than 0.8 millimeter, weigh by proportioning, evenly mix, in glass melter, melt then, fusion temperature is respectively 1480 ℃ and 1520 ℃, melt respectively shrend after clarifying, oven dry, crosses 4 mesh sieves and 16 mesh sieves respectively, obtains less than 5 millimeters with less than two kinds of devitrified glass particulate material of 1 millimeter.
Press chemical analysis: SiO 273.58%, Al 2O 319.50%, CaO 0.88%, MgO2.18%, K 2O 3.26% and Na 2O 0.60%, chooses corresponding various raw materials less than 10 millimeters, weighs by proportioning, and ball milling is in small, broken bits to be sieved to 1.0% to 10000-hole sieve, and mist projection granulating gets the powder of moisture 6.2%, 2500 tons of forcing press moulding, dries, obtains 550 * 550 millimeters dry adobe.
Adopt two dry granulars to spread fertilizer over the fields machine, respectively with above-mentioned≤1 millimeter white micro-crystals glass particle material and≤the blue green glass-ceramic particulate material of 5mm successively is sprinkling upon on 500 * 500 millimeters the adobe face, reaches 5 kilograms/meter 2, all fix therebetween and thereafter with the fixer secondary.Then, the adobe that has two layers of devitrified glass particulate material goes in 94 meters roller kilns to burn till, and maximum sintering temperature is 1205 ℃, firing period 58 minutes.The semi-finished product that burn till obtain the devitrified glass-Ceramic Composite brick on blue green particles paripheral zone white line limit again through edging → strickling → corase grind → polishing → edging → drying process, and this ornament materials exactly likes natural marble.
Embodiment 5
Press chemical analysis: SiO 263.74%, Al 2O 35.98%, CaO 18.07%, ZnO4.32%, BaO 2.73%, Li 2O 0.60%, Na 2O 1.36% and K 2O 3.20%, adds TiO 23.86% and CeO 20.63% and As 2O 30.3%, choose corresponding various raw materials below 0.8 millimeter, weigh by proportioning, evenly mix, melt in the glass kiln, fusion temperature is 1480 ℃, melt is shrend after clarifying, and dries 8 mesh sieves (2.5 millimeters mesh), obtains the devitrified glass particulate material less than 2.5 millimeters.
Press the chemical analysis and the step of the ceramic adobe of embodiment 1,660 * 660 millimeters the ceramic adobe that preparation is dry.
Adopt dry granular (powder) to spread fertilizer over the fields machine, the compound (ratio is 4: 2: 4) of the devitrified glass particulate material of embodiment 1, embodiment 3, embodiment 5 evenly is sprinkling upon on the above-mentioned ceramic adobe face, once fix it with fixer again.Then, go into 110 meters roller kilns and burn till, 1220 ℃ of maximum temperatures, firing period 53 minutes.The semi-finished product of kiln discharge are made the graceful ornament materials of colour mixture (white, blue, tea three looks) again through edging → strickling → corase grind → polishing → edging → drying process.

Claims (3)

1, the production method of a kind of novel nucleated glass-Ceramic Composite brick; it is characterized in that: the devitrified glass shrend of fusing is become particles with different sizes; spreading fertilizer over the fields equipment with dry granular or dry powder then is sprinkling upon it on ceramic adobe of compression moulding; spread 1～3 layer, impose fixer again and fix for 1～3 time, in kiln, burn till at last; burn till 1150 ℃～1250 ℃ of maximum temperatures; firing period 40～80 minutes gets the semi-finished product composite brick, through edging, strickling, corase grind, polishing, edging, drying after burning till.
2, according to the production method of the described devitrified glass of claim 1-Ceramic Composite brick, it is characterized in that: the devitrified glass composition is SiO by weight percentage 250～65%, Al 2O 35～15%, CaO 10～25%, MgO 0～10%, Na 2O 1～6%, K 2O 1～6%, Li 2O0～4%, BaO 0～5%, ZnO 0～10%, add As 2O 30～0.5% and colouring agent 0～8%;
To meet above-mentioned composition with the various raw materials of fineness less than 0.8 millimeter quartz, feldspar, calcium carbonate, brium carbonate, zinc oxide, lithium carbonate, sodium nitrate, sodium carbonate, magnesium carbonate or magnesia, arsenic trioxide and colouring agent, weigh in proportion, mix and put into glass melter fusing, 1320 ℃～1520 ℃ of fusion temperatures;
As required, with these melting charge shrends, dry, must be less than 10 millimeters different devitrified glass particulate material.
3, according to the production method of claim 1 and 2 described devitrified glass-Ceramic Composite bricks, it is characterized in that: the chemical composition of Ceramic Tiles is SiO by weight percentage 265～75%, Al 2O 315～25%, CaO 0～5%, MgO 0～5%, Na 2O 0.5～6%, K 2O 0.5～5%;
To meet mentioned component and the granularity compound less than 10 millimeters quartz, kaolinite, illite, feldspar, talcum, dolomite and diopside, and weigh by proportioning, ball milling is in small, broken bits, the adobe that spray-drying powder process, forcing press moulding, drying are made different size.
CN 00100030 2000-01-05 2000-01-05 Method for producing composite brick of nucleated glass and ceramic Expired - Fee Related CN1120078C (en)

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CN1120078C CN1120078C (en) 2003-09-03

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100361929C (en) * 2004-11-29 2008-01-16 佛山石湾鹰牌陶瓷有限公司 Production for ceramic composite bricks
CN100364927C (en) * 2004-09-23 2008-01-30 陈继棉 Production method of ceramic polished brick and ceramic polished brick produced by it
CN100424045C (en) * 2005-04-15 2008-10-08 霍镰泉 Glaze slurry permeating coloring process for large flower lattice pattern of microcrystal glass surface
CN101337826B (en) * 2007-07-06 2010-07-28 中国地质大学（武汉） Technique of preparing microcrystalline glass-ceramic composite board by one-step firing process
CN102173818A (en) * 2011-01-28 2011-09-07 游小棠 Production device and method of fritted glaze ceramic polished tile
CN101613217B (en) * 2008-06-26 2011-12-07 广东科达机电股份有限公司 Method for one-time sintering of ceramic-microcrystalline glass composite board
CN102390931A (en) * 2011-08-02 2012-03-28 佛山石湾鹰牌陶瓷有限公司 Method for manufacturing once calcined glass ceramic brick
CN102704637A (en) * 2012-05-18 2012-10-03 佛山市三水宏源陶瓷企业有限公司 Glass ceramic-glomerocryst micro powder-ceramic composite brick and production method thereof
CN101186129B (en) * 2007-12-07 2012-10-10 广东高微晶科技有限公司 Micro-crystallizing glass-ceramic composite board and producing method thereof
CN102910827A (en) * 2012-11-16 2013-02-06 中国地质科学院 Novel wear-resisting plate produced by using waste moulding sand and preparation method of plate
CN102923958A (en) * 2012-10-31 2013-02-13 广东博德精工建材有限公司 Novel microcrystal glass ceramic composite board and preparation method thereof
CN104589486A (en) * 2014-12-26 2015-05-06 江苏苏嘉集团新材料有限公司 Method for producing firebrick
CN109160737A (en) * 2018-08-01 2019-01-08 广东博德精工建材有限公司 A kind of glass ceramics frit, microcrystallite glass-ceramic composite brick and preparation method thereof
CN112723870A (en) * 2021-03-31 2021-04-30 蒙娜丽莎集团股份有限公司 Ceramic rock plate with color jade effect and preparation method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100364927C (en) * 2004-09-23 2008-01-30 陈继棉 Production method of ceramic polished brick and ceramic polished brick produced by it
CN100361929C (en) * 2004-11-29 2008-01-16 佛山石湾鹰牌陶瓷有限公司 Production for ceramic composite bricks
CN100424045C (en) * 2005-04-15 2008-10-08 霍镰泉 Glaze slurry permeating coloring process for large flower lattice pattern of microcrystal glass surface
CN101337826B (en) * 2007-07-06 2010-07-28 中国地质大学（武汉） Technique of preparing microcrystalline glass-ceramic composite board by one-step firing process
CN101186129B (en) * 2007-12-07 2012-10-10 广东高微晶科技有限公司 Micro-crystallizing glass-ceramic composite board and producing method thereof
CN101613217B (en) * 2008-06-26 2011-12-07 广东科达机电股份有限公司 Method for one-time sintering of ceramic-microcrystalline glass composite board
CN102173818A (en) * 2011-01-28 2011-09-07 游小棠 Production device and method of fritted glaze ceramic polished tile
CN102390931A (en) * 2011-08-02 2012-03-28 佛山石湾鹰牌陶瓷有限公司 Method for manufacturing once calcined glass ceramic brick
CN102390931B (en) * 2011-08-02 2013-05-15 佛山石湾鹰牌陶瓷有限公司 Method for manufacturing once calcined glass ceramic brick
CN102704637A (en) * 2012-05-18 2012-10-03 佛山市三水宏源陶瓷企业有限公司 Glass ceramic-glomerocryst micro powder-ceramic composite brick and production method thereof
CN102704637B (en) * 2012-05-18 2015-04-22 佛山市三水宏源陶瓷企业有限公司 Glass ceramic-glomerocryst micro powder-ceramic composite brick and production method thereof
CN102923958A (en) * 2012-10-31 2013-02-13 广东博德精工建材有限公司 Novel microcrystal glass ceramic composite board and preparation method thereof
CN102910827A (en) * 2012-11-16 2013-02-06 中国地质科学院 Novel wear-resisting plate produced by using waste moulding sand and preparation method of plate
CN102910827B (en) * 2012-11-16 2014-10-22 中国地质科学院 Novel wear-resisting plate produced by using waste moulding sand and preparation method of plate
CN104589486A (en) * 2014-12-26 2015-05-06 江苏苏嘉集团新材料有限公司 Method for producing firebrick
CN109160737A (en) * 2018-08-01 2019-01-08 广东博德精工建材有限公司 A kind of glass ceramics frit, microcrystallite glass-ceramic composite brick and preparation method thereof
CN112723870A (en) * 2021-03-31 2021-04-30 蒙娜丽莎集团股份有限公司 Ceramic rock plate with color jade effect and preparation method thereof
WO2022205988A1 (en) * 2021-03-31 2022-10-06 蒙娜丽莎集团股份有限公司 Ceramic slab having colored jade effect and preparation method therefor

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