CN1252486A - Petroleum recovering method and equipment through microwave cracking into light hydrocarbon - Google Patents
Petroleum recovering method and equipment through microwave cracking into light hydrocarbon Download PDFInfo
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- CN1252486A CN1252486A CN 99120068 CN99120068A CN1252486A CN 1252486 A CN1252486 A CN 1252486A CN 99120068 CN99120068 CN 99120068 CN 99120068 A CN99120068 A CN 99120068A CN 1252486 A CN1252486 A CN 1252486A
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Abstract
Heated crude oil is cracked inside the microwave cracking furnace disclosed by this invention in the presence of catalyst into light hydrocarbon which is then pressed by a pressurizing pump into oil layer to dilute condensed oil and to increase petroleum recovering amount. The miniturized microwave cracking furnace of the present invention consists of microwave source, microwave guide, coupler, furnace cavity, heat insulating layer, etc. The technological equipment of the present invention is simple and can result in high recovery rate.
Description
The present invention relates to a method and equipment for extracting and processing petroleum, in particular, it relates to a method and equipment for producing light hydrocarbon by using microwave pyrolysis petroleum and recovering it.
Petroleum is one of the main energy forms in the world today, and the technological development of petroleum production is rapid because petroleum production is an important part of petroleum production. However, there are places where current mining techniques can be put to practical use. For example: the thick oil in the ground is not easy to be exploited. The data show that the underground oil recovery rate is 40-80%, and the oil is harder to recover as the oil is thicker. People think of a plurality of methods to improve the recovery rate of the thickened oil. One of them is thermal recovery method, which burns the recovered petroleum to generate steam, presses the steam into the ground, heats the thick petroleum to increase its fluidity, and is convenient for recovery. Because the action distance of the steam is short, the underground pressure is high, and the high-temperature steam is easy to be transformed into water; because of the hydrophobic property of petroleum, the water and petroleum are not well jointed, the energy waste is large, 10% of produced oil needs to be burnt, the equipment investment is large, and the effect of the thermal production method is not very ideal. The other method is to utilize light hydrocarbon matter to dissolve the thick petroleum to increase the flowability of petroleum and to press it into underground to dissolve the thick petroleum for easy exploitation. However, because of high price of light hydrocarbon, the transportation is inconvenient, and the method is not suitable for being widely applied in oil fields.
The invention aims to provide a method for producing light hydrocarbon recovery by using microwave pyrolysis petroleum and a miniaturized device thereof.
The invention is realized by the following steps: pumping part of the produced petroleum, especially thick oil, into a heater, heating to 50-200 deg.C, and microwave cracking into light hydrocarbon under the action of catalyst in the microwave cracking furnace. Then the mixture is sent into a storage tank, is pressed into the ground by an injection pump, and is well combined and dissolved with the thick petroleum in the petroleum reservoir after passing through the underground petroleum reservoir to form petroleum with good fluidity, so that the petroleum can be conveniently pumped out by an oil well pumping unit.
The reaction of cracking the thickened oil into light hydrocarbon by microwave under the action of a catalyst is as follows: +CH2＝CH2+CH3(CH2)mCH＝CH2
the flow velocity of the heated petroleum in the microwave cracking furnace is 0.5-1.5 m/min, and the conversion rate is about 30-70%.
The microwave cracking furnace can be used in series or in parallel according to the situation of an oil field site. The parallel connection can improve the treatment capacity, the series connection can improve the cracking conversion efficiency, and the furnace chambers can be shared when the series connection is carried out, so that an integral structure is formed. The use of multiple microwave pyrolysis furnaces allows the power of each microwave source to be made smaller.
The microwave cracking furnace consists of microwave source, waveguide tube, coupler, furnace cavity and heat insulating layer. The coupler is sleeved outside the furnace chamber, the input port of the coupler is connected with the microwave output port of the microwave source by a waveguide tube, one or more groups of catalyst supports are placed in the furnace chamber, each group consists of a left disc and a right disc, the middle part of the catalyst supports is provided with a mounting hole, if the catalyst supports are used by a plurality of groups, the catalyst supports can be connected by a pull rod, and the bottom of each disc is provided with a plurality of oil passing holes with the diameter of phi 3 to-8 mm. The heat insulating layer is laid outside the oven cavity and the coupler to reduce heat loss. The coupler and the furnace chamber can be made into a circular shape or a square shape.
The furnace chamber consists of a furnace end and a furnace body. The furnace end is conical, and an oil inlet, one or more flushing ports and an oil return port are arranged at the small end of the furnace end. The big end is provided with a flange which is connected with the furnace body by bolts. The furnace body is in the shape of a wine bottle, and a reaction mixed oil output port and one or more flushing ports are arranged at the small end of the furnace body. The furnace chamber, the catalyst support, the pull rod and the like are made of medium materials with small microwave absorption, such as: glass, pottery, plastic and other materials.
The invention has the advantages of simple equipment, low investment, high recovery efficiency, convenient size adjustment and capability of being completed in the oil field on site.
The invention is further illustrated by the following figures and examples.
FIG. 1 is a flow chart of the present invention.
FIG. 2 is a schematic view of the microwave cracking furnace of the apparatus of the present invention.
FIG. 3 is a schematic view of the structure of the furnace chamber of the microwave cracking furnace of the apparatus of the present invention.
FIG. 4 is a schematic diagram of the group use of the microwave cracking furnaces of the apparatus of the present invention.
Fig. 5, 6 and 7 are schematic views of the catalyst support of the present invention.
The microwave oven comprises 8-a microwave source, 9-a waveguide, 10-a coupler, 11-a furnace chamber, 12-an oil outlet, 13-a heat insulation layer, 14-an oil inlet, 15-a furnace head, 16-a furnace body, 17-a flushing port, 18-an oil return port, 19-a catalyst tray frame, 20-a support bolt, 21-a support, 22-a catalyst left disc, 23-a catalyst right disc, 24-a catalyst disc small hole and 25-a catalyst disc mounting hole.
The process flow of the present invention is shown in FIG. 1. The system and the equipment of the method for recovering the light hydrocarbon mainly comprise a heating, conveying, microwave cracking, lysate storage, pressure injection, stratum, oil pumping unit of an oil well and light hydrocarbon recovery device, and the system and the equipment of the method for recovering the light hydrocarbon comprise an oil pump, a heater, a microwave cracking furnace, a lysate storage tank, a pressure injection pump, a stratum, an oil port oil pumping unit and a light hydrocarbon recovery device, wherein the oil pump, the heater, the microwave cracking furnace, the lysate storage tank, the pressure injection pump, the stratum, the oil port oil pumping unit and the light hydrocarbon recovery device are arranged on the oil pump. Fig. 2-5 show that the microwave cracking furnace of the light hydrocarbon recovery method of the invention is composed of a microwave source, a waveguide, a coupler, a furnace chamber, an oil outlet and a heat preservation layer. Wherein the furnace chamber (11) is composed of a furnace end (15) and a furnace body (16). A catalyst tray frame is arranged in the furnace body [16]and consists of a left disc and a right disc. The small end of the furnace end (15) is provided with an oil inlet (14), one or more flushing ports (17) and an oil return port (18). The big end is provided with a flange which is connected with the furnace body by bolts, and the cone of the furnace body (16) is provided with an oil return port (12) and a flushing port (17).
The catalyst used in the present invention is a loose particulate material composed of particles capable of sensing excited discharge under microwave and a binder. Wherein the microwave sensing particles are particles of carbon substance, metal and oxide. The particles are preferably charcoal, carbon black, graphite, or the like.
If the loose particle catalyst is soaked in nickel, molybdenum, platinum and other ion solution and then dried, the cracking effect is better and the generated gas is less.
Claims (10)
1. A method for producing light hydrocarbon recovery by microwave pyrolysis of petroleum comprises the following steps: pumping part of the produced petroleum, especially the thick oil, into a heater, cracking the petroleum, sending the petroleum into a storage tank, then pumping the petroleum into the underground by using a pressure injection pump, after passing through an underground petroleum reservoir, pressing underground light hydrocarbon into the petroleum reservoir to be well combined with the thick oil and dissolved to form the petroleum with good fluidity, and the method is characterized in that the thick oil is heated to 50-300 ℃, then sent into one or more microwave cracking furnaces connected in series or in parallel, and cracked into light hydrocarbon by microwave under the action of a catalyst in the furnaces.
2. A microwave cracking furnace for recovering light hydrocarbon generated by cracking petroleum by microwave is composed of microwave source, waveguide tube, coupler, furnace cavity and insulating layer, and features that the coupler is sleeved outside the furnace cavity, the input of the coupler is connected to the microwave output of microwave source via waveguide tube, and one or more catalyst holders are arranged in the furnace cavity.
3. The method of claim 1, wherein the heated thick oil has a flow rate of 0.5 to 1.5 m/min and a temperature of 100 to 250 ℃.
4. The microwave pyrolysis furnace for recovering light hydrocarbon by using microwave pyrolysis petroleum according to claim 2, wherein the furnace chamber (11) is composed of a furnace head (15) and a furnace body (16), and the small end of the furnace head (15) is provided with an oil inlet (14), one or more flushing ports (17) and an oil return port (18). The big end is provided with a flange which is connected with the flange at one end of the furnace body by bolts, and the cone of the furnace body (16) is provided with an oil return port (12) and a flushing port (17).
5. The microwave pyrolysis furnace for recovering light hydrocarbon by using microwave pyrolysis oil according to claim 2, wherein a catalyst tray frame is installed in the furnace body [16], the catalyst tray frame consists of a left disc and a right disc, a mounting hole is arranged in the middle of the catalyst tray frame, a plurality of oil passing holes with the diameter of 3-8 mm are arranged at the bottoms of the discs, and the catalyst tray frame can be connected by using pull rods when a plurality of groups of oil passing holes are used.
6. The microwave pyrolysis furnace for producing light hydrocarbon recovery by microwave pyrolysis of petroleum according to claim 2, wherein the furnace chamber, the catalyst support, the pull rod and the like are made of medium materials with small microwave absorption, such as: glass, pottery, plastic and other materials.
7. The method of claim 1 wherein the catalyst is a loose particulate material comprising particles capable of experiencing an electrical discharge induced by microwaves and a binder.
8. The method of claim 1 wherein the microwave-sensitive particles are microparticles of carbonaceous material, metal, and oxides.
9. The method of claim 1 or 8, wherein the microwave-sensitive particles are particles of charcoal, carbon black, graphite, etc.
10. The method of claim 1 or 7, wherein the loose particle catalyst is a particle that is dried after being soaked in a plasma solution containing nickel, molybdenum, platinum, etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99120068A CN1081286C (en) | 1999-11-22 | 1999-11-22 | Petroleum recovering method and equipment through microwave cracking into light hydrocarbon |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99120068A CN1081286C (en) | 1999-11-22 | 1999-11-22 | Petroleum recovering method and equipment through microwave cracking into light hydrocarbon |
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| CN1252486A true CN1252486A (en) | 2000-05-10 |
| CN1081286C CN1081286C (en) | 2002-03-20 |
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| CN99120068A Expired - Fee Related CN1081286C (en) | 1999-11-22 | 1999-11-22 | Petroleum recovering method and equipment through microwave cracking into light hydrocarbon |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100391601C (en) * | 2006-05-11 | 2008-06-04 | 上海三瑞化学有限公司 | Catalyst for downhole catalytic reforming of viscous crude |
| GB2432368B (en) * | 2005-06-15 | 2010-03-24 | John Keith Tooley | Improvements relating to the refining of waste oil |
| US8192591B2 (en) | 2005-12-16 | 2012-06-05 | Petrobeam, Inc. | Self-sustaining cracking of hydrocarbons |
| CN103058481A (en) * | 2011-10-21 | 2013-04-24 | 中国石油化工股份有限公司 | Method for treatment of oil sludge by microwave catalytic pyrolysis |
| CN103225497A (en) * | 2013-04-16 | 2013-07-31 | 中国石油天然气股份有限公司 | Exploitation method of vaporizing formation water and displacing heavy oil by microwaves in situ |
| CN103244089A (en) * | 2013-04-16 | 2013-08-14 | 中国石油天然气股份有限公司 | Method for exploiting heavy oil by means of microwave assisted solvent extraction |
| CN103484147A (en) * | 2013-09-25 | 2014-01-01 | 西南石油大学 | Method for reducing viscocity of thick oil by synergy of plasma and catalyst |
| CN103930526A (en) * | 2011-08-29 | 2014-07-16 | 创新原油技术公司，以Ict公司名义营业 | System and method for cold cracking with steam |
| US9555345B2 (en) | 2011-07-26 | 2017-01-31 | Saudi Arabian Oil Company | Dynamic demulsification system for use in a gas-oil separation plant |
| CN108870082A (en) * | 2018-06-22 | 2018-11-23 | 昆明理工大学 | A kind of microwave heating system of viscous crude pipeline |
| CN114507535A (en) * | 2022-03-18 | 2022-05-17 | 河南海天环境科技有限公司 | Method for treating industrial organic waste by double-wave cracking |
| CN115505416A (en) * | 2022-09-27 | 2022-12-23 | 云南电网有限责任公司电力科学研究院 | Device for hydrogen oil dehydrogenation |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6186520A (en) * | 1984-10-02 | 1986-05-02 | Matsushita Electric Ind Co Ltd | High-frequency heating device |
| GB9615044D0 (en) * | 1996-07-17 | 1996-09-04 | Bp Chem Int Ltd | Oil and gas field chemicals and their use |
| ZA976292B (en) * | 1996-07-29 | 1998-02-03 | Aeci Ltd | Process for decomposing a polymer to its monomer or monomers. |
| CN1204679A (en) * | 1998-06-30 | 1999-01-13 | 丁焰 | Method and equipment for inverting biological organic matter using plasma |
| CN1208808A (en) * | 1998-09-01 | 1999-02-24 | 冯国营 | Method and equipment for prodn. of thick oil by injecting detackifier |
-
1999
- 1999-11-22 CN CN99120068A patent/CN1081286C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2432368B (en) * | 2005-06-15 | 2010-03-24 | John Keith Tooley | Improvements relating to the refining of waste oil |
| US8192591B2 (en) | 2005-12-16 | 2012-06-05 | Petrobeam, Inc. | Self-sustaining cracking of hydrocarbons |
| US8911617B2 (en) | 2005-12-16 | 2014-12-16 | Petrobeam, Inc. | Self-sustaining cracking of hydrocarbons |
| CN100391601C (en) * | 2006-05-11 | 2008-06-04 | 上海三瑞化学有限公司 | Catalyst for downhole catalytic reforming of viscous crude |
| US9555345B2 (en) | 2011-07-26 | 2017-01-31 | Saudi Arabian Oil Company | Dynamic demulsification system for use in a gas-oil separation plant |
| US10350515B2 (en) | 2011-07-26 | 2019-07-16 | Saudi Arabian Oil Company | Dynamic demulsification system for use in a gas-oil separation plant |
| CN103930526B (en) * | 2011-08-29 | 2019-11-01 | 创新原油技术公司，以Ict公司名义营业 | With the system and method for steam cold cracking solution |
| CN103930526A (en) * | 2011-08-29 | 2014-07-16 | 创新原油技术公司，以Ict公司名义营业 | System and method for cold cracking with steam |
| CN103058481A (en) * | 2011-10-21 | 2013-04-24 | 中国石油化工股份有限公司 | Method for treatment of oil sludge by microwave catalytic pyrolysis |
| CN103058481B (en) * | 2011-10-21 | 2014-04-16 | 中国石油化工股份有限公司 | Method for treatment of oil sludge by microwave catalytic pyrolysis |
| CN103225497A (en) * | 2013-04-16 | 2013-07-31 | 中国石油天然气股份有限公司 | Exploitation method of vaporizing formation water and displacing heavy oil by microwaves in situ |
| CN103244089B (en) * | 2013-04-16 | 2015-09-09 | 中国石油天然气股份有限公司 | The exploitation method of microwave radiation technology solvent extraction viscous crude |
| CN103225497B (en) * | 2013-04-16 | 2015-07-08 | 中国石油天然气股份有限公司 | Exploitation method of vaporizing formation water and displacing heavy oil by microwaves in situ |
| CN103244089A (en) * | 2013-04-16 | 2013-08-14 | 中国石油天然气股份有限公司 | Method for exploiting heavy oil by means of microwave assisted solvent extraction |
| CN103484147B (en) * | 2013-09-25 | 2015-08-05 | 西南石油大学 | A kind of plasma-catalytic is worked in coordination with viscous crude and is fallen sticking method |
| CN103484147A (en) * | 2013-09-25 | 2014-01-01 | 西南石油大学 | Method for reducing viscocity of thick oil by synergy of plasma and catalyst |
| CN108870082A (en) * | 2018-06-22 | 2018-11-23 | 昆明理工大学 | A kind of microwave heating system of viscous crude pipeline |
| CN114507535A (en) * | 2022-03-18 | 2022-05-17 | 河南海天环境科技有限公司 | Method for treating industrial organic waste by double-wave cracking |
| CN115505416A (en) * | 2022-09-27 | 2022-12-23 | 云南电网有限责任公司电力科学研究院 | Device for hydrogen oil dehydrogenation |
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| CN1081286C (en) | 2002-03-20 |
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