CN1244736C - Production technology of surface glueing starch with high reserving rate - Google Patents
Production technology of surface glueing starch with high reserving rate Download PDFInfo
- Publication number
- CN1244736C CN1244736C CN 200410016436 CN200410016436A CN1244736C CN 1244736 C CN1244736 C CN 1244736C CN 200410016436 CN200410016436 CN 200410016436 CN 200410016436 A CN200410016436 A CN 200410016436A CN 1244736 C CN1244736 C CN 1244736C
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- Prior art keywords
- starch
- reaction
- mixture
- viscosity
- carried out
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920002472 Starch Polymers 0.000 title claims abstract description 48
- 239000008107 starch Substances 0.000 title claims abstract description 48
- 235000019698 starch Nutrition 0.000 title claims abstract description 48
- 238000005516 engineering process Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000004026 adhesive bonding Methods 0.000 title abstract 4
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 150000001768 cations Chemical class 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 230000014759 maintenance of location Effects 0.000 claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 10
- 238000006266 etherification reaction Methods 0.000 claims abstract description 9
- 238000004513 sizing Methods 0.000 claims description 15
- 125000002091 cationic group Chemical group 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 5
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 238000005886 esterification reaction Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- BOMLWFWRMBFFIA-UHFFFAOYSA-M [Cl-].ClC1C=CC1[N+](C)(C)C Chemical compound [Cl-].ClC1C=CC1[N+](C)(C)C BOMLWFWRMBFFIA-UHFFFAOYSA-M 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 230000037429 base substitution Effects 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims description 2
- 229960003750 ethyl chloride Drugs 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 238000012805 post-processing Methods 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims description 2
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 229940117958 vinyl acetate Drugs 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 abstract description 7
- 150000004965 peroxy acids Chemical class 0.000 abstract description 5
- 239000002351 wastewater Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 1
- 239000000701 coagulant Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 19
- 239000000835 fiber Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000035484 reaction time Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000001254 oxidized starch Substances 0.000 description 4
- 235000013808 oxidized starch Nutrition 0.000 description 4
- 239000000945 filler Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000202567 Fatsia japonica Species 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- CSPHGSFZFWKVDL-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-trimethylazanium;chloride Chemical class [Cl-].C[N+](C)(C)CC(O)CCl CSPHGSFZFWKVDL-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical class OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003930 superacid Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Abstract
Description
Numbering | Base catalyst consumption (part) | Etherifying agent/catalyst (mol ratio) | Reaction time (h) | Reaction temperature (℃) | Substitution value (%) |
2-1 | 28 | 1∶3.0 | 3 | 75 | 0.017 |
2-2 | 20 | 1∶2.0 | 3 | 75 | 0.018 |
2-3 | 10 | 1∶1.0 | 3 | 75 | 0.015 |
Numbering | Cationic etherifying agent consumption (part) | Base catalyst consumption (part) | Reaction time (h) | Reaction temperature (℃) | Substitution value (%) |
3-1 | 10 | 20 | 3 | 75 | 0.010 |
3-2 | 22 | 20 | 3 | 75 | 0.018 |
3-3 | 28 | 20 | 3 | 75 | 0.025 |
Numbering | Peracid chemicals usage (part) | Peracid/starch (over dry ratio) | Reaction time (h) | Reaction temperature (℃) | Viscosity (Brookfield LV, 6%, 60 ℃, mPas) |
4-1 | 2 | 0.1% | 2 | 70 | 100 |
4-2 | 10 | 0.5% | 2 | 70 | 20 |
4-3 | 20 | 1.0% | 2 | 70 | 10 |
Numbering | Stabilizing agent dosage (part) | Stabilizing agent/starch (over dry ratio) | Reaction time (h) | Reaction temperature (℃) | Low temperature viscosity (Brookfield LV, 6%, 20 ℃, mPas) |
5-1 | 5 | 1% | 2 | 80 | 200 |
5-2 | 10 | 2% | 2 | 80 | 40 |
5-3 | 25 | 5% | 2 | 80 | 30 |
Sizing agent | Numbering | Surface strength (rod wax) | Surface strength raising rate (%) | Degree of sizing (g/m 2) | BOD (mg/l) | BOD rate of descent (%) | COD (mg/l) | COD rate of descent (%) |
Embodiment 1 | - | 18 | 28 | 22 | 20 | 80 | 50 | 83 |
Embodiment 2 | 2-1 | 16 | 14 | 22 | 22 | 78 | 55 | 82 |
2-2 | 18 | 28 | 22 | 21 | 79 | 53 | 81 | |
2-3 | 16 | 14 | 22 | 23 | 77 | 55 | 82 | |
Embodiment 3 | 3-1 | 14 | 0 | 22 | 23 | 77 | 55 | 82 |
3-2 | 16 | 16 | 22 | 20 | 80 | 50 | 83 | |
3-3 | 18 | 28 | 22 | 18 | 82 | 45 | 85 | |
Embodiment 4 | 4-1 | 18 | 28 | 24 | 23 | 77 | 55 | 82 |
4-2 | 16 | 14 | 24 | 23 | 77 | 55 | 82 | |
4-3 | 14 | 0 | 24 | 23 | 77 | 55 | 82 | |
Embodiment 5 | 5-1 | 16 | 14 | 23 | 22 | 78 | 53 | 81 |
5-2 | 18 | 28 | 23 | 22 | 78 | 53 | 81 | |
5-3 | 16 | 14 | 23 | 22 | 78 | 53 | 81 | |
Embodiment 6 | - | 18 | 28 | 22 | 20 | 77 | 51 | 83 |
Oxidized starch | - | 14 | / | 22 | 100 | / | 300 | / |
Sizing agent | Numbering | Surface strength (rod wax) | Surface strength raising rate (%) | IGT (cm/sec) | IGT raising rate (%) | Color density (deceiving) | Color density raising rate (%) |
Embodiment 1 | - | 18 | 28.6 | 7 | 40 | 1.5 | 25 |
Embodiment 2 | 2-1 | 18 | 28.6 | 7 | 40 | 1.6 | 33 |
2-2 | 18 | 28.6 | 7 | 40 | 1.5 | 25 | |
2-3 | 18 | 28.6 | 8 | 60 | 1.4 | 17 | |
Embodiment 3 | 3-1 | 18 | 28.6 | 7 | 40 | 1.4 | 17 |
3-2 | 18 | 28.6 | 8 | 60 | 1.5 | 25 | |
3-3 | 18 | 28.6 | 8 | 60 | 1.6 | 33 | |
Embodiment 4 | 4-1 | 18 | 28.6 | 7 | 40 | 1.5 | 25 |
4-2 | 18 | 28.6 | 7 | 40 | 1.5 | 25 | |
4-3 | 18 | 28.6 | 7 | 40 | 1.5 | 25 | |
Embodiment 5 | 5-1 | 18 | 28.6 | 7 | 40 | 1.5 | 25 |
5-2 | 16 | 14 | 7 | 40 | 1.5 | 25 | |
5-3 | 16 | 14 | 8 | 60 | 1.5 | 25 | |
Embodiment 6 | - | 18 | 28.6 | 7 | 40 | 1.4 | 17 |
Oxidized starch | - | 14 | / | 5 | / | 1.2 | / |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410016436 CN1244736C (en) | 2004-02-17 | 2004-02-17 | Production technology of surface glueing starch with high reserving rate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410016436 CN1244736C (en) | 2004-02-17 | 2004-02-17 | Production technology of surface glueing starch with high reserving rate |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1560361A CN1560361A (en) | 2005-01-05 |
CN1244736C true CN1244736C (en) | 2006-03-08 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200410016436 Expired - Fee Related CN1244736C (en) | 2004-02-17 | 2004-02-17 | Production technology of surface glueing starch with high reserving rate |
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CN (1) | CN1244736C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101195978B (en) * | 2008-01-04 | 2010-06-02 | 广西明阳生化科技股份有限公司 | Multicomponent modified starch for papermaking and producing method thereof |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4843042B2 (en) * | 2006-08-31 | 2011-12-21 | ハリマ化成株式会社 | Surface sizing agent and its use |
CN102382197B (en) * | 2011-07-28 | 2013-05-29 | 广西农垦明阳生化集团股份有限公司 | Preparation method of high viscosity cationic starch |
CN102558373A (en) * | 2011-12-15 | 2012-07-11 | 杭州纸友科技有限公司 | Efficient and clean manufacturing method of continuous-flow-state pipelined cation-oxidized starch |
CN103012605B (en) * | 2012-12-11 | 2015-01-14 | 广西民族大学 | Method for preparing high-retention environmental-friendly one-step double-modified starch |
CN103242459B (en) * | 2013-05-27 | 2015-07-15 | 江西鑫川实业有限公司 | Crosslinked amphoteric starch and preparation method thereof |
CN103696320B (en) * | 2013-12-24 | 2015-09-16 | 江西红星变性淀粉有限公司 | A kind of preparation technology of oxidative cationic size-press starch |
CN106032393A (en) * | 2015-03-20 | 2016-10-19 | 上海东升新材料有限公司 | Method for preparing cationic starch through dry method |
CN106032392A (en) * | 2015-03-20 | 2016-10-19 | 上海东升新材料有限公司 | Cationic starch and preparation method and application thereof |
CN108708215B (en) * | 2018-03-29 | 2020-07-10 | 句容市茂源织造厂 | Preparation method of starch-based papermaking surface sizing agent |
-
2004
- 2004-02-17 CN CN 200410016436 patent/CN1244736C/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101195978B (en) * | 2008-01-04 | 2010-06-02 | 广西明阳生化科技股份有限公司 | Multicomponent modified starch for papermaking and producing method thereof |
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CN1560361A (en) | 2005-01-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
ASS | Succession or assignment of patent right |
Owner name: YAO XIANPING Free format text: FORMER OWNER: ZHIYOU SCIENCE + TECHNOLOGY CO., LTD., HANGZHOU Owner name: ZHENG LIPING TIAN QINGQUAN Effective date: 20041231 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20050114 Address after: No. three, No. 50, Hangzhou economic and Technological Development Zone, Xiasha, Hangzhou, Zhejiang Applicant after: Yao Xianping Co-applicant after: Zheng Liping Co-applicant after: Tian Qingquan Address before: Xiasha Hangzhou economic and Technological Development Zone, Zhejiang City, Hangzhou province M18-0-2 Applicant before: Zhiyou Science & Technology Co., Ltd., Hangzhou |
|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Zhiyou Science & Technology Co., Ltd., Hangzhou Assignor: Yao Xianping|Zheng Liping|Tian Qingquan Contract fulfillment period: 2008.7.1 to 2018.6.30 Contract record no.: 2008330000640 Denomination of invention: Production technology of surface glueing starch with high reserving rate Granted publication date: 20060308 License type: Exclusive license Record date: 20080924 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.7.1 TO 2018.6.30 Name of requester: ZHIYOU SCIENCE & TECHNOLOGY CO., LTD., HANGZHOU Effective date: 20080924 |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060308 Termination date: 20190217 |