CN110205870A - A kind of composite starch and preparation method thereof for top sizing - Google Patents
A kind of composite starch and preparation method thereof for top sizing Download PDFInfo
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- CN110205870A CN110205870A CN201910258913.6A CN201910258913A CN110205870A CN 110205870 A CN110205870 A CN 110205870A CN 201910258913 A CN201910258913 A CN 201910258913A CN 110205870 A CN110205870 A CN 110205870A
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- China
- Prior art keywords
- starch
- blender
- top sizing
- storagetank
- composite
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Abstract
The composite starch and preparation method thereof that the invention discloses a kind of for top sizing, it is related to paper-making technology field, it solves the problems, such as that conventional size starch stability is poor, is characterized in that: 1) after the water, starch and molysite of the quantity set is added, blender starting;2) aluminium salt, emulsifier and dispersing agent are then added into blender, is filtered after dispersion;3) starch suspension is sent into boiling in thermophilic digestion device after dispersing;The present invention can effectively prevent age of starch, stablize starch viscosity, have good and stable filming performance, can be fully penetrated into fiber when use, fill paper pore, and the starch film formed has better intensity and smoother surface;Curing time of the invention is short, can provide paper high intensity, epipodium pressure index faster;And water-resistance of the present invention is good, and the use of Cypres can be partly or completely replaced in Process of Applying Glue.
Description
Technical field
The present invention relates to paper-making technology field more particularly to a kind of composite starch and its system for top sizing
Preparation Method.
Background technique
Wrapping paper is primarily used for the general designation of a kind of paper of packaging purpose, usually has high intensity and toughness, is resistant to
Pressure, folding, quality requirement are simpler than paper kinds such as cultural printings, need in wrapping paper manufacturing process using size-press starch pair
The coating of its surface, to increase its physical property, complies with requirement.
The surface sizing starch that factory uses at present substantially has a two major classes, one kind be conventional corn ative starch through peroxidating,
The forms such as enzymatic conversion dilute use after boiling, and cost is relatively low for this kind of sizing, but starch lot stability is poor, glue is easy always
Change, starch has been easy in Process of Applying Glue and has wadded a quilt with cotton poly- phenomenon to which sizing applicator glues rod, has caused shadow to paper machine operation and quality of finished paper
It rings, in addition a kind of oxidized starch for after traditional hypochlorite oxidation, this kind of starch causes to give birth to due to processing technology complexity
Higher cost is produced, in addition, the waste water that starch systems cleaning generates contains oxidant and can cause unfavorable shadow to later period sewage treatment
It rings, therefore, the composite starch and preparation method thereof that we have proposed a kind of for top sizing.
Summary of the invention
The technical problem to be solved by the present invention is in view of the foregoing drawbacks, provide a kind of composite starch for top sizing
And preparation method thereof, to solve the problems, such as that conventional size starch stability is poor.
To achieve the above object, the invention provides the following technical scheme:
Then a kind of composite starch for top sizing adds molysite, aluminium salt, emulsifier using cornstarch as base-material
And dispersing agent, it is prepared by way of boiling.
As a further solution of the present invention, the molysite is ferric ion salt.
As a further solution of the present invention, the aluminium salt is nanoscale aluminium salt, including alchlor, aluminum sulfate and bright
One of alum is a variety of.
As a further solution of the present invention, the ingredient of the emulsifier is stearic acid polyoxyethylene ether, the dispersing agent
For anionic polyacrylamide.
It is a kind of to prepare the above-mentioned composite starch preparation method for top sizing, which comprises the following steps:
1) feed intake: after the water, starch and molysite of the quantity set is added, blender starts, and agitator speed is
50-60rpm, in whipping process, temperature is heated to 95 DEG C in blender, keeps the temperature 30-40min;
2) aluminium salt, emulsifier and dispersing agent, agitator speed are then added into blender and are adjusted to 500rpm, until forming sediment
After powder dispersion completely, scattered starch suspension is sent by the filter of 50-80 mesh to the storagetank storage of belt stirrer
It deposits, storagetank blender keeps the revolving speed of 50rpm;
3) delivery pump in scattered starch suspension by being delivered in continuous steamer in storagetank, in boiling vessel
It is passed through the steam of high temperature and pressure, starch fluid makes the rapid water swelling of starch, division, paste by transient heating, high temperature difference and pressure
Change, storagetank storage is sent into after the heated water on-line dilution to predetermined solid content of gelatinized corn starch after boiling, gelatinization point control exists
125 DEG C, the temperature of paste liquid storagetank is controlled at 60 DEG C or more, is led to steam insulation using collet slot, is kept stirring speed 30-
40rpm。
In conclusion compared with the prior art, the invention has the following beneficial effects:
1, the present invention effectively prevents age of starch, stablizes starch viscosity, has good and stable filming performance,
Can be fully penetrated into fiber when use, paper pore is filled, and the starch film formed has better intensity and smoother
Surface.
2, the curing time of the invention is short, can provide paper high intensity, epipodium pressure index faster.
3, water-resistance of the present invention is good, and the use of Cypres can be partly or completely replaced in Process of Applying Glue.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments, based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
Embodiment 1
Then a kind of composite starch for top sizing adds molysite, aluminium salt, emulsifier using cornstarch as base-material
And dispersing agent, it is prepared by way of boiling;The molysite is ferric ion salt;The aluminium salt is nanoscale trichlorine
Change aluminium;The ingredient of the emulsifier is stearic acid polyoxyethylene ether, and the dispersing agent is anionic polyacrylamide.
A kind of preparation method preparing the above-mentioned composite starch for top sizing, comprising the following steps:
1) feed intake: after the water, starch and molysite of the quantity set is added, blender starts, and agitator speed is
60rpm, in whipping process, temperature is heated to 95 DEG C in blender, keeps the temperature 30min;
2) nanoscale alchlor, stearic acid polyoxyethylene ether and anion pp acyl are then added into blender
Amine, agitator speed are adjusted to 500rpm, until filtering scattered starch suspension by 50 mesh after starch dispersion is complete
Device is sent to the storagetank storage of belt stirrer, and storagetank blender keeps the revolving speed of 50rpm;
3) delivery pump in scattered starch suspension by being delivered in continuous steamer in storagetank, in boiling vessel
It is passed through the steam of high temperature and pressure, starch fluid makes the rapid water swelling of starch, division, paste by transient heating, high temperature difference and pressure
Change, storagetank storage is sent into after the heated water on-line dilution to predetermined solid content of gelatinized corn starch after boiling, gelatinization point control exists
125 DEG C, the temperature of paste liquid storagetank is controlled at 60 DEG C or more, is led to steam insulation using collet slot, is kept stirring speed 30rpm.
Embodiment 2
Then a kind of composite starch for top sizing adds molysite, aluminium salt, emulsifier using cornstarch as base-material
And dispersing agent, it is prepared by way of boiling;The molysite is ferric ion salt;The aluminium salt is nanoscale sulfuric acid
Aluminium;The ingredient of the emulsifier is stearic acid polyoxyethylene ether, and the dispersing agent is anionic polyacrylamide.
A kind of preparation method preparing the above-mentioned composite starch for top sizing, comprising the following steps:
1) feed intake: after the water, starch and molysite of the quantity set is added, blender starts, and agitator speed is
50rpm, in whipping process, temperature is heated to 95 DEG C in blender, keeps the temperature 40min;
2) aluminum sulfate, stearic acid polyoxyethylene ether and anionic polyacrylamide, blender are then added into blender
Revolving speed is adjusted to 500rpm, until being sent by 80 mesh filters to band and being stirred by scattered starch suspension after starch dispersion is complete
The storagetank storage of device is mixed, storagetank blender keeps the revolving speed of 50rpm;
3) delivery pump in scattered starch suspension by being delivered in continuous steamer in storagetank, in boiling vessel
It is passed through the steam of high temperature and pressure, starch fluid makes the rapid water swelling of starch, division, paste by transient heating, high temperature difference and pressure
Change, storagetank storage is sent into after the heated water on-line dilution to predetermined solid content of gelatinized corn starch after boiling, gelatinization point control exists
125 DEG C, the temperature of paste liquid storagetank is controlled at 60 DEG C or more, is led to steam insulation using collet slot, is kept stirring speed 40rpm.
Embodiment 3
Then a kind of composite starch for top sizing adds molysite, aluminium salt, emulsifier using cornstarch as base-material
And dispersing agent, it is prepared by way of boiling;The molysite is ferric ion salt;The aluminium salt is nanoscale alum;
The ingredient of the emulsifier is stearic acid polyoxyethylene ether, and the dispersing agent is anionic polyacrylamide.
A kind of preparation method preparing the above-mentioned composite starch for top sizing, comprising the following steps:
1) feed intake: after the water, starch and molysite of the quantity set is added, blender starts, and agitator speed is
55rpm, in whipping process, temperature is heated to 95 DEG C in blender, keeps the temperature 35min;
2) aluminium salt, stearic acid polyoxyethylene ether and anionic polyacrylamide are then added into blender, blender turns
Speed is adjusted to 500rpm, until being sent by 60 mesh filters to band and being stirred by scattered starch suspension after starch dispersion is complete
The storagetank of device is stored, and storagetank blender keeps the revolving speed of 50rpm;
3) delivery pump in scattered starch suspension by being delivered in continuous steamer in storagetank, in boiling vessel
It is passed through the steam of high temperature and pressure, starch fluid makes the rapid water swelling of starch, division, paste by transient heating, high temperature difference and pressure
Change, storagetank storage is sent into after the heated water on-line dilution to predetermined solid content of gelatinized corn starch after boiling, gelatinization point control exists
125 DEG C, the temperature of paste liquid storagetank is controlled at 60 DEG C or more, is led to steam insulation using collet slot, is kept stirring speed 40rpm.
Embodiment 4
Then a kind of composite starch for top sizing adds molysite, aluminium salt, emulsifier using cornstarch as base-material
And dispersing agent, it is prepared by way of boiling;The molysite is ferric ion salt;The aluminium salt is nanoscale trichlorine
Change aluminium and sulfuric acid aluminium mixture;The ingredient of the emulsifier is stearic acid polyoxyethylene ether, and the dispersing agent is anion poly- third
Acrylamide.
A kind of preparation method of the preparing above-mentioned multiplexing composite starch in top sizing, comprising the following steps:
1) feed intake: after the water, starch and molysite of the quantity set is added, blender starts, and agitator speed is
60rpm, in whipping process, temperature is heated to 95 DEG C in blender, keeps the temperature 40min;
2) alchlor and sulfuric acid aluminium mixture, stearic acid polyoxyethylene ether and anion are then added into blender
Polyacrylamide, agitator speed are adjusted to 500rpm, until passing through scattered starch suspension after starch dispersion is complete
80 mesh filters are sent to the storagetank storage of belt stirrer, and storagetank blender keeps the revolving speed of 50rpm;
3) delivery pump in scattered starch suspension by being delivered in continuous steamer in storagetank, in boiling vessel
It is passed through the steam of high temperature and pressure, starch fluid makes the rapid water swelling of starch, division, paste by transient heating, high temperature difference and pressure
Change, storagetank storage is sent into after the heated water on-line dilution to predetermined solid content of gelatinized corn starch after boiling, gelatinization point control exists
125 DEG C, the temperature of paste liquid storagetank is controlled at 60 DEG C or more, is led to steam insulation using collet slot, is kept stirring speed 35rpm.
It should be strongly noted that changing corn starch structure in the application by molysite and nanometer being added before boiling
Grade aluminium salt is the innovative point of the application, efficiently solves the problems, such as that conventional size starch stability is poor.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of composite starch for top sizing, which is characterized in that using cornstarch as base-material, then add molysite, aluminium
Salt, emulsifier and dispersing agent, are prepared by way of boiling.
2. the composite starch according to claim 1 for top sizing, which is characterized in that the molysite be ferric iron from
Alite.
3. the composite starch according to claim 2 for top sizing, which is characterized in that the aluminium salt is nanometer aluminum
One of salt, including alchlor, aluminum sulfate and alum are a variety of.
4. the composite starch according to claim 3 for top sizing, which is characterized in that the ingredient of the emulsifier is
Stearic acid polyoxyethylene ether.
5. the composite starch according to claim 4 for top sizing, which is characterized in that the dispersing agent is anion
Polyacrylamide.
6. a kind of preparation method as described in preparation claim 1-5 is any for the composite starch of top sizing, feature exist
In, comprising the following steps:
1) it feeds intake: after the water, starch and molysite of the quantity set is added, blender starting, agitator speed 50-
60rpm, in whipping process, temperature is heated to 95 DEG C in blender, keeps the temperature 30-40min;
2) aluminium salt, emulsifier and dispersing agent, agitator speed are then added into blender and are adjusted to 500rpm, until starch dispersion
After completely, scattered starch suspension is sent by filter to the storagetank storage of belt stirrer, storagetank blender is protected
Hold the revolving speed of 50rpm;
3) being delivered in continuous steamer in storagetank in scattered starch suspension is passed through height by delivery pump in boiling vessel
The steam of warm high pressure, starch fluid make the rapid water swelling of starch, division, gelatinization, boiling by transient heating, high temperature difference and pressure
Storagetank storage is sent into after the heated water on-line dilution to predetermined solid content of gelatinized corn starch afterwards, gelatinization point is controlled at 125 DEG C, paste
The temperature of liquid storagetank is controlled at 60 DEG C or more, is led to steam insulation using collet slot, is kept stirring speed 30-40rpm.
7. the preparation method of the composite starch according to claim 6 for top sizing, which is characterized in that step 2)
In, it is 50-80 mesh that filter, which filters mesh number,.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115075052A (en) * | 2022-06-28 | 2022-09-20 | 成都奥睿尔科技创新服务有限公司 | Method for preparing special glue applying powder for packaging paper |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115075052A (en) * | 2022-06-28 | 2022-09-20 | 成都奥睿尔科技创新服务有限公司 | Method for preparing special glue applying powder for packaging paper |
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Application publication date: 20190906 |