CN1242936A - Water-contained pesticide for heated-fumigation method - Google Patents
Water-contained pesticide for heated-fumigation method Download PDFInfo
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- CN1242936A CN1242936A CN99110551A CN99110551A CN1242936A CN 1242936 A CN1242936 A CN 1242936A CN 99110551 A CN99110551 A CN 99110551A CN 99110551 A CN99110551 A CN 99110551A CN 1242936 A CN1242936 A CN 1242936A
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- Prior art keywords
- insecticidal
- water
- aqueous
- aqueous insecticidal
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- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000003958 fumigation Methods 0.000 title description 4
- 239000000575 pesticide Substances 0.000 title description 4
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
- 238000010438 heat treatment Methods 0.000 claims description 29
- 239000002917 insecticide Substances 0.000 claims description 21
- 230000002745 absorbent Effects 0.000 claims description 19
- 239000002250 absorbent Substances 0.000 claims description 19
- 241000238631 Hexapoda Species 0.000 claims description 14
- 235000015165 citric acid Nutrition 0.000 claims description 10
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 5
- 235000002906 tartaric acid Nutrition 0.000 claims description 5
- 239000011975 tartaric acid Substances 0.000 claims description 5
- 239000001361 adipic acid Substances 0.000 claims description 4
- 235000011037 adipic acid Nutrition 0.000 claims description 4
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 239000002728 pyrethroid Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 7
- 230000005068 transpiration Effects 0.000 abstract 1
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 26
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000011259 mixed solution Substances 0.000 description 14
- 229940051250 hexylene glycol Drugs 0.000 description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- 239000004695 Polyether sulfone Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229920006393 polyether sulfone Polymers 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 3
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229940024113 allethrin Drugs 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- ZCVAOQKBXKSDMS-PVAVHDDUSA-N (+)-trans-(S)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-PVAVHDDUSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229960001901 bioallethrin Drugs 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- -1 silafluofene Chemical compound 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 239000001384 succinic acid Substances 0.000 description 2
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 2
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- MIZYPRIEDMSCAC-UHFFFAOYSA-N (2-methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl) 2,2,3,3-tetramethylcyclopropane-1-carboxylate Chemical compound CC1=C(CC=C)C(=O)CC1OC(=O)C1C(C)(C)C1(C)C MIZYPRIEDMSCAC-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- XFTRTWQBIOMVPK-YFKPBYRVSA-N Citramalic acid Natural products OC(=O)[C@](O)(C)CC(O)=O XFTRTWQBIOMVPK-YFKPBYRVSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XFTRTWQBIOMVPK-UHFFFAOYSA-N citramalic acid Chemical compound OC(=O)C(O)(C)CC(O)=O XFTRTWQBIOMVPK-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001550 time effect Effects 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
- B65D5/42—Details of containers or of foldable or erectable container blanks
- B65D5/44—Integral, inserted or attached portions forming internal or external fittings
- B65D5/50—Internal supporting or protecting elements for contents
- B65D5/5028—Elements formed separately from the container body
- B65D5/5035—Paper elements
- B65D5/5038—Tray-like elements formed by folding a blank and presenting openings or recesses
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
- B65D5/42—Details of containers or of foldable or erectable container blanks
- B65D5/44—Integral, inserted or attached portions forming internal or external fittings
- B65D5/52—External stands or display elements for contents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/20—Containers, packaging elements or packages, specially adapted for particular articles or materials for incompressible or rigid rod-shaped or tubular articles
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
This insecticidal liquid contains (A) a compound having >=1% solubility in water at 25 deg.C and further having two or more carboxyl groups. To obtain the subject insecticidal liquid capable of enabling the insecticidal liquid to be stably transpired extremely for a long period in the insecticidal method of a transpiration method by using the aqueous insecticidal liquid, and capable of stably keeping the insecticidal activities for a long period by adding a specific compound.
Description
The present invention relates to a kind of aqueous insecticidal of heated-fumigation method and this insecticide of use is prevented and treated insect by heating fumigating method of being used for.
Method by heating fumigating control insect, comprise that the part with the porous absorbent cores immerses in the liquid pesticide, thereby insecticide is absorbed in the absorbent cores upper end of heating absorbent cores, the stifling thus insecticide that is absorbed, this method is widely used now.Because have advantages such as noninflammability, thus present so-called aqueous insecticidal (comprise aqueous solvent and be dissolved in insecticide component in this solvent) in fact the liquid pesticide as this method use.
Method by heating fumigating control insect is compared with the method for using mosquito-dispelling tablet or mosquito-repellent incense volume, and its advantage is that simple to operate, safety, action effect are lasting or the like.Yet, especially need now a kind of insecticidal effect more lasting many methods.
After the use aqueous insecticidal has carried out extensive studies by the method for heating fumigating control insect under passing through these situations, the inventor finds, in the method for using aqueous insecticidal by heating fumigating control insect, the aqueous insecticidal that contains specific compound is longer than the stable stifling time of common aqueous insecticidal, promptly keep the time of stable insecticidal effect more lasting, finished the present invention thus.
A target of the present invention provides a kind of aqueous insecticidal that is used for heated-fumigation method, this insecticide comprise insecticide component and contain two carboxyls at least and 25 ℃ under solvability in water be 1wt% or bigger compound by weight.
Another target of the present invention provides a kind of method of using aqueous insecticidal by heating fumigating control insect.
In aqueous insecticidal of the present invention, containing of using, the solvability in water was that 1wt% or bigger compound (hereinafter being known as The compounds of this invention) comprise by weight under at least two carboxyls and 25 ℃, for example dicarboxylic acids such as succinic acid, adipic acid, tartaric acid, malonic acid, malic acid, citramalic acid or the like and tricarboxylic acids such as citric acid or the like.Optimization citric acid, tartaric acid and adipic acid, more preferably citric acid.
In aqueous insecticidal of the present invention, the concentration of The compounds of this invention is 0.001-10wt% normally by weight, preferred 0.01-5wt%, more preferably 0.05-2wt%.
In aqueous insecticidal of the present invention, the insecticide component that uses comprises, for example pyrethroid compound such as allethrin, bioallethrin, esbiothrin, prallethrin, PH, empenthrin, resmethrin, phenothrin, permethrin, transfluthrin, terallethrin, silafluofene, ether chrysanthemum ester or the like.
In aqueous insecticidal of the present invention, the concentration of said insecticide component is 0.1-15wt% normally by weight, preferred 0.2-5wt%, more preferably 0.5-2wt%.
Aqueous insecticidal of the present invention comprises water and water-soluble secondary solvent.The water-soluble secondary solvent of Shi Yonging comprises in the present invention, hydrophilic solvent etc. for example, as alcohols, for example ethanol, isopropyl alcohol etc., dihydroxylic alcohols such as hexylene glycol, DEGMBE etc. with and analog.
Contain by weight water and the water-soluble secondary solvent of 75-99.899wt% altogether in the aqueous insecticidal of the present invention.Based on the total amount of water and water-soluble secondary solvent, the content of water is 15-80wt% normally by weight, preferred 30-80wt%, more preferably 40-60wt%.
Can contain spices, surfactant, colouring agent, stabilizing agent etc. in the aqueous insecticidal of the present invention.
Aqueous insecticidal of the present invention can be used for preventing and treating in the method for insect by heating fumigating, place it in the heating fumigating device and use, these devices for example are disclosed among JP-B-52-12106, JP-U-58-45670, JP-B-7-74130, the JP-A-7-3 16002 etc.
The present invention does not have special restriction to the absorbent cores of using in the heating fumigating device, as long as it can absorb liquid pesticide of the present invention, and the heating that can stand heater etc. gets final product, for example can be by fiber such as mineral wool, felt etc., porous mineral binding (porous mineralbound) or sinter, the mechanograph of toner such as polyether sulfone (polyether sulfone) etc. are made.
Use aqueous insecticidal of the present invention to comprise by the method for heating fumigating control insect, for example, an a kind of part (normally lower part) of absorbent cores is immersed in the aqueous insecticidal, thereby insecticide is absorbed in the absorbent cores, usually 80-180 ℃, preferably approximately at 120-140 ℃ with the not dipping of indirect absorbent cores such as (for example) heater part (for example normally the part above it), the stifling thus insecticide that is absorbed.
Fig. 1 represents to can be used for the example of the device of the aqueous insecticidal that is used for heating fumigating of the present invention or the inventive method by heating fumigating control insect.
In Fig. 1, numeral 1 is an aqueous insecticidal, the 2nd, and heater, the 3rd, absorbent cores, the 4th, the vessel of insecticide 1 immerses the bottom of absorbent cores 3 in the insecticide 1, and insecticide 1 is absorbed 3 li of absorbent cores, with the top of heater 2 heating absorbent cores 3.
The following examples are more detailed description of the present invention.Embodiment 1
The prallethrin of 0.8 weight portion and the citric acid of 0.05 weight portion are dissolved in the solvent mixture of hexylene glycol and water (50/50 (w/w)), obtain the aqueous insecticidal of 100 weight portions.Embodiment 2
The aqueous citric acid solution of the 0.1wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 3
The aqueous citric acid solution of the 0.4wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 4
The aqueous citric acid solution of the 0.5wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 5
The adipic acid aqueous solution of the 2wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 6
The aqueous tartaric acid solution of the 2wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 7
The aqueous citric acid solution of the 2wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 8
The aqueous tartaric acid solution of the 10.0wt% of 59.8 weight portions and the isopropyl alcohol of 39.9 weight portions are mixed, then the allethrin of 0.3 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 9
The succinic acid aqueous solution of the 4.0wt% of 17.4 weight portions and the DEGMBE of 69.6 weight portions are mixed, then the empenthrin of 13 weight portions is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 10
The succinic acid aqueous solution of the 4.0wt% of 19.9 weight portions and the DEGMBE of 79.8 weight portions are mixed, then the transfluthrin of 0.3 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Embodiment 11
The aqueous citric acid solution of the 15.0wt% of 59.5 weight portions and the isopropyl alcohol of 39.7 weight portions are mixed, then the allethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Comparative Examples 1
The prallethrin of 0.8 weight portion is dissolved in the solvent mixture of hexylene glycol and water (50/50 (w/w)), obtains the aqueous insecticidal of 100 weight portions.Comparative Examples 2
The aqueous ascorbic acid of the 0.4wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Comparative Examples 3
The aqueous ascorbic acid of the 2wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Comparative Examples 4
The benzoic acid aqueous solution of the 0.4wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Comparative Examples 5
The aqueous solution of salicylic acid of the 0.2wt% of 49.6 weight portions and the hexylene glycol of 49.6 weight portions are mixed, then the prallethrin of 0.8 weight portion is dissolved in the mixed solution of gained, obtain the aqueous insecticidal of 100 weight portions.Experimental example 1
At embodiment 2,3 or 4, perhaps the aqueous insecticidal that obtains in the Comparative Examples 1 joins in the container that volume is 45ml, loads onto the absorbent cores of porous polyether sulfone then in container with 45ml.Then, put container into as shown in Figure 1 the heating fumigating type device that is used for preventing and treating insect, and the upper end indirect of absorbent cores to 120-135 ℃, by heating the insecticide component in the aqueous insecticidal (prallethrin) is fumigated test.The rate of volatilization of insecticide component is to come by the following method to determine: promptly collect the steam of volatilization, with silicagel column suction 1 hour, with acetone the silica gel in the silicagel column is extracted then, concentrate afterwards and carry out quantitative analysis with gas-chromatography.When beginning to heat every day heating fumigating 10 hours and continue 20 days, determine respectively the 1st day, the 10th day and the 20th day insecticide component (prallethrin) rate of volatilization (mg/hr).The result is as shown in table 1.
Table 1
Experimental example 2
| Aqueous insecticidal | The 1st day | The 10th day | The |
| Embodiment | |||
| 2 | ????0.8 | ????0.9 | ????0.8 |
| | ????0.6 | ????0.5 | ????0.7 |
| | ????0.6 | ????0.5 | ????0.6 |
| Comparative Examples 1 | ????0.7 | ????1.3 | ????0 |
At embodiment 2,5,6 or 7, it is in the container of 45ml that the aqueous insecticidal that perhaps obtains in the Comparative Examples 2 or 3 adds volume with 45ml, loads onto the absorbent cores of porous polyether sulfone for then this container.Then, put container into heating fumigating type device that shown in Figure 1 being used for prevents and treats insect, and the upper end indirect of absorbent cores to 120-135 ℃, observe the outward appearance of preparation after 50 hours.The result is as shown in table 2.
Table 2
Experimental example 3
| Aqueous insecticidal | |
| Embodiment | |
| 2 | Do not change |
| Embodiment 5 | Do not change |
| Embodiment 6 | Do not change |
| Embodiment 7 | Do not change |
| Comparative Examples 2 | Become brown |
| Comparative Examples 3 | Become brown |
At embodiment 2,5,6 or 7, it is in the container of 45ml that the aqueous insecticidal that perhaps obtains in the Comparative Examples 1,4 or 5 adds volume with 45ml, loads onto the absorbent cores of porous polyether sulfone for then this container.Then, put container into heating fumigating type device that shown in Figure 1 being used for prevents and treats insect, and the upper end indirect of absorbent cores to 120-135 ℃, by the heating aqueous insecticidal is fumigated test.After 150 hours or 200 hours, determine the volatilization percentage (%) of heating aqueous insecticidal.The result is as shown in table 3.
Table 3
| Aqueous insecticidal | After 150 hours | After 200 |
| Embodiment | ||
| 2 | ????43.4％ | ????51.2％ |
| Embodiment 5 | ????54.4％ | ????64.8％ |
| Embodiment 6 | ????38.3％ | ????41.5％ |
| Embodiment 7 | ????41.9％ | ????47.0％ |
| Comparative Examples 1 | ????100％ | ??????- |
| Comparative Examples 4 | ????100％ | ??????- |
| Comparative Examples 5 | ????100％ | ??????- |
According to the present invention, in the method for using aqueous insecticidal by heating fumigating control insect, aqueous insecticidal of the present invention can stably be fumigated very long a period of time, and insecticidal effect also can stably keep very long a period of time simultaneously.
Claims (8)
1. aqueous insecticidal that is used for heating fumigating, it contain insecticide component and have at least two carboxyls and 25 ℃ under solvability in water be 1wt% or bigger compound by weight.
2. aqueous insecticidal that is used for heating fumigating, it comprises:
(1) contain that the solvability in water is 1wt% or bigger compound by weight under at least two carboxyls and 25 ℃,
(2) insecticide component,
(3) water, and
(4) water-soluble secondary solvent,
Wherein and by weight based on the total amount of said insecticide, the amount of component (1) is 0.001-10wt%, the amount of component (2) is 0.1-15wt%, the total amount of component (3) and (4) is 75-99.899wt%, and the amount of component (3) is the 15-80wt% of the total amount of component (3) and (4) by weight.
3. according to the aqueous insecticidal of claim 1 or 2, wherein said insecticide component is a pyrethroid coumpound.
4. according to claim 1,2 or 3 aqueous insecticidal, wherein said have that the solvability in water is that 1wt% or bigger compound are citric acid, succinic acid, adipic acid or tartaric acid under at least two carboxyls and 25 ℃.
5. method by heating fumigating control insect, this method comprises and immerses the part of porous absorbent cores in the aqueous insecticidal and heat the not impregnated part of absorbent cores, said aqueous insecticidal comprise insecticide component and have at least two carboxyls and 25 ℃ under solvability in water be 1wt% or bigger compound by weight.
6. according to the method for claim 5, wherein said heating is to carry out in 80-180 ℃ temperature range.
According to each described aqueous insecticidal of claim 1-4 in the purposes aspect the heating fumigating.
8. has the solvability in water under at least two carboxyls and 25 ℃ and is by weight 1wt% or bigger compound purposes as the stifling stabilizing agent of the aqueous insecticidal of heating fumigating.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21394898 | 1998-07-29 | ||
| JP213948/1998 | 1998-07-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1242936A true CN1242936A (en) | 2000-02-02 |
| CN1147230C CN1147230C (en) | 2004-04-28 |
Family
ID=16647709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991105516A Expired - Lifetime CN1147230C (en) | 1998-07-29 | 1999-07-29 | Water-contained pesticide for heated-fumigation method |
Country Status (7)
| Country | Link |
|---|---|
| KR (1) | KR100771384B1 (en) |
| CN (1) | CN1147230C (en) |
| AR (1) | AR021169A1 (en) |
| BR (1) | BR9903016B1 (en) |
| ES (1) | ES2157811B1 (en) |
| IT (1) | IT1306174B1 (en) |
| NL (1) | NL1012690C2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102626082A (en) * | 2011-02-04 | 2012-08-08 | 住友化学株式会社 | Pesticidal material for heat transpiration and a method for controlling pests by heat transpiration |
| CN102754644A (en) * | 2011-04-28 | 2012-10-31 | 狮王株式会社 | Smoke insecticide, smoke insect-killing apparatus, and insect-killing method |
| CN103766333A (en) * | 2012-10-25 | 2014-05-07 | 狮王株式会社 | Fumigating insecticide and fumigating insecticidal device |
| CN104247707A (en) * | 2013-06-26 | 2014-12-31 | 住友化学株式会社 | Aqueous pest control composition |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080027143A1 (en) * | 2006-07-14 | 2008-01-31 | Munagavalasa Murthy S | Chemical formulation for an insecticide |
| US7455245B2 (en) | 2006-07-14 | 2008-11-25 | S.C. Johnson & Son, Inc. | Diffusion device |
| CN103766391B (en) * | 2012-10-25 | 2017-01-18 | 狮王株式会社 | Fumigating insecticide and fumigating insecticidal device |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5428818A (en) * | 1977-08-05 | 1979-03-03 | Fumakilla Ltd | Method of enhancing effect of pesticide smoked in short time |
| AU1611383A (en) | 1982-07-02 | 1984-01-05 | Robert Young & Company Limited | Pesticidal formulation with cypermethrin |
| DE9012996U1 (en) * | 1990-09-12 | 1991-10-10 | Perycut Chemie Ag | |
| JPH08310907A (en) * | 1995-05-18 | 1996-11-26 | Dainippon Jochugiku Co Ltd | Aqueous insecticide for thermal transpiration and killing of insect |
| AU708907B2 (en) * | 1995-09-14 | 1999-08-12 | Sumitomo Chemical Company, Limited | Liquid insecticidal preparation for heat fumigation and method for killing insects by heat fumigation |
-
1999
- 1999-07-22 ES ES009901659A patent/ES2157811B1/en not_active Expired - Fee Related
- 1999-07-23 IT IT1999RM000469A patent/IT1306174B1/en active
- 1999-07-23 NL NL1012690A patent/NL1012690C2/en not_active IP Right Cessation
- 1999-07-26 KR KR1019990030362A patent/KR100771384B1/en not_active IP Right Cessation
- 1999-07-28 BR BRPI9903016-0A patent/BR9903016B1/en not_active IP Right Cessation
- 1999-07-28 AR ARP990103713A patent/AR021169A1/en active IP Right Grant
- 1999-07-29 CN CNB991105516A patent/CN1147230C/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102626082A (en) * | 2011-02-04 | 2012-08-08 | 住友化学株式会社 | Pesticidal material for heat transpiration and a method for controlling pests by heat transpiration |
| CN102626082B (en) * | 2011-02-04 | 2016-02-10 | 住友化学株式会社 | Hot flashing insecticidal materials and the method for passing through hot flashing Control pests |
| CN102754644A (en) * | 2011-04-28 | 2012-10-31 | 狮王株式会社 | Smoke insecticide, smoke insect-killing apparatus, and insect-killing method |
| CN102754644B (en) * | 2011-04-28 | 2015-05-06 | 狮王株式会社 | Smoke insecticide, smoke insect-killing apparatus, and insect-killing method |
| CN103766333A (en) * | 2012-10-25 | 2014-05-07 | 狮王株式会社 | Fumigating insecticide and fumigating insecticidal device |
| CN103766333B (en) * | 2012-10-25 | 2017-10-27 | 狮王株式会社 | Sootiness type insecticide and sootiness type insect-killing device |
| CN104247707A (en) * | 2013-06-26 | 2014-12-31 | 住友化学株式会社 | Aqueous pest control composition |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1306174B1 (en) | 2001-05-30 |
| ES2157811A1 (en) | 2001-08-16 |
| ITRM990469A1 (en) | 2001-01-23 |
| KR100771384B1 (en) | 2007-10-31 |
| BR9903016A (en) | 2000-05-02 |
| NL1012690C2 (en) | 2000-04-26 |
| NL1012690A1 (en) | 2000-02-01 |
| KR20000011977A (en) | 2000-02-25 |
| CN1147230C (en) | 2004-04-28 |
| ITRM990469A0 (en) | 1999-07-23 |
| AR021169A1 (en) | 2002-07-03 |
| BR9903016B1 (en) | 2009-05-05 |
| ES2157811B1 (en) | 2002-03-16 |
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