CN1241999C - Environment protecting building paint additive and its prepn process - Google Patents
Environment protecting building paint additive and its prepn process Download PDFInfo
- Publication number
- CN1241999C CN1241999C CN 01132277 CN01132277A CN1241999C CN 1241999 C CN1241999 C CN 1241999C CN 01132277 CN01132277 CN 01132277 CN 01132277 A CN01132277 A CN 01132277A CN 1241999 C CN1241999 C CN 1241999C
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- micro mist
- weight parts
- negative ion
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- paint additive
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Abstract
The present invention relates to an environment protecting building paint additive and a preparing method thereof. The building paint additive is composed of the raw material by the weight proportion: 100 portions of negative ion zeolite ore miropowder, 1 to 3 portions of far-infrared miropowder, 2.5 to 4 portions of antiseptic miropowder, 20 to 40 portions of photocatalyst miropowder, 2 to 5 portions of cocatalyst miropowder, 2 to 5 portions of dispersing agent, 2 to 3 portions of coupling agent and 100 to 300 portions of purified water which are crushed, graded, ground, refined, dispersed, activated, etc. Compared with the prior art, the present invention has the advantages of narrow particle size distribution, thin particle diameter, great concentration of released negative ions, etc.
Description
Technical field
The present invention relates to a kind of environment protecting building paint additive and manufacture method thereof.
Background technology
Existing paint additive generally is based on negative ion jewel ore deposit, fineness is generally in 1～750 μ scope, the size distribution of powder is quite wide, in a single day contain this kind additive in the water-borne coatings, then often there is coarse particles to occur on the metope, the surface quality of influence finishing back metope, and the negative ion release rate also has influence to a certain degree.
Summary of the invention
Purpose of the present invention is exactly environment protecting building paint additive that a kind of granularity is littler, more even, the negative ion burst size is better, whiteness is better and the manufacture method thereof that provides for the defective that overcomes above-mentioned prior art existence.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of environment protecting building paint additive, it is to be mixed for raw material by following prescription (weight part):
The brilliant ore deposit of negative ion zeolite micro mist 100
Far infrared micro mist 1～3
Antibiotic micro mist 2.5～4
Photocatalyst micro mist 20～40
Promotor micro mist 2～5
Dispersion agent 2～5
Coupling agent 2～3
Water purification 100～300
The brilliant ore deposit of described negative ion zeolite micro mist is selected from the silicate that Chemical Composition is Al, Si, Mn, Zn, Ti, and described far infrared micro mist is selected from ZrSiO
3, SiO
2, Al
2O
3, among the SiC one or more, described antibiotic micro mist is selected from AgNO
3, among ZnO, the CuO one or more, described dispersion agent is selected from a kind of in sodium laurylsulfonate or the Sodium hexametaphosphate 99, described coupling agent is selected from a kind of in titanic acid ester or the silane.
Also comprise high-strength sorbing material micro mist 3～4.5 in the described prescription (weight part), this high-strength sorbing material micro mist is selected from zeolite ore deposit or TiO
2In one or both.
The granularity D of the brilliant ore deposit of described negative ion zeolite micro mist
50≤ 5 μ.
The granularity of described antibiotic micro mist, photocatalyst micro mist, coupling agent micro mist is nano level.
A kind of manufacture method of above-mentioned environment protecting building paint additive, it adopts following processing step: at first the brilliant ore deposit of negative ion zeolite is added jaw crusher and carry out fragmentation, washing afterwards, airing, enter twin rollers again and grind to form the fine sand shape, magnetic separation is to remove impurity such as Fe, enter in the high-speed eddy grinding machine by the elevator conveyer mechanical feed and to pulverize, the powder that obtains enters air classifier, can get φ≤1250 orders after cyclonic separation is main powder, thicker granular powder then returns the row pulverizing again of high-speed eddy grinding machine, air-flow can advance efficient bag separator and reach effluent standard tail gas, the service temperature of above-mentioned technological process is less than or equal to 50 ℃, from bag separator bottom and the powder that comes out of cyclonic separator bottom broken through the supersonic airstream abrasive dust, obtain the micro mist that granularity is 5 μ; Get the brilliant ore deposit of the negative ion zeolite micro mist of 100 weight parts and go into strong stirring barrel, add far infrared micro mist 1～3 weight part, antibiotic micro mist 2.5～4 weight parts, photocatalyst micro mist 20～40 weight parts, promotor micro mist 2～5 weight parts simultaneously, and adding water purification, carry out the secondary grinding in the efficient wet shredder through entering again after the reinforcement stirring, reach D until mixture powder granularity ultramicronising
50≤ 0.5 μ, add at last dispersion agent 2～5 weight parts, coupling agent 2～3 weight parts and water purification 100～300 weight parts to mixture disperse, surface-active-treatment such as coating, obtain additive product.
Compared with prior art, the granularity of product of the present invention is meticulousr, and the negative ion concentration that is discharged is higher, and product of the present invention detects about metrology and measurement department and scientific and technological Cha Xin unit retrieval proof through country: its fineness reaches D
90≤ 1 μ (Britain Ma Erwen laser particle diameter instrument mensuration), negative ion continue release concentration and reach 28000 levels (per minute, every square centimeter).
Because the grain size distribution curve of product of the present invention is narrow: fineness reaches D
50≤ 0.5 μ (accurate nanometer) wherein has 15%～20% to be the level of 0.1 μ, the effect that adds accurate nanocatalyst and promotor adds the piezoelectric effect of the extraordinary zeolite micro mist of accurate nanometer, thermoelectric effect, polynary effect is with the result of effect, make it physics, chemical property has produced qualitative leap, light-electricity-heat-magnetic etc. all has exceptional function to produce, can promote water molecules to produce ionisation effect, produce hydrogen positive ion and hydroxyl negative ion, it is active oxygen, and can be continually, the special effects of so composite powder of function, can make in the coating or the free formaldehyde in the nature environment, dimethylbenzene, hazardous and noxious substances oxidations such as organic substance, and produce harmless small molecules, until being decomposed into carbonic acid gas and water or other innoxious substances.
In addition, product of the present invention also comprises some function micro mists, can produce the far infrared rays of 4～14 μ wavelength that help microcirculation in human body, and this mainly is that the thermoelectric effect of accurate nanofeature zeolite micro mist causes the vibration of nano molecular lattice and produces.
Product of the present invention has the following advantages: 1. improve human respiratory, strengthen pulmonary function; 2. reduce hypertension 3. and improve myocardial function, improve sleep quality; 4. adjusting autonomic nerve; 5. activate human body, enhance metabolism; 6. elimination foreign flavor indoors; 7. antibacterial; 8. continue to discharge negative ion.
Description of drawings
Accompanying drawing is a process flow sheet of the present invention.
Embodiment
Below in conjunction with accompanying drawing and specific embodiment thereof, the invention will be further described.
Embodiment 1
A kind of environment protecting building paint additive, it is to be mixed for raw material by following prescription (weight part):
The brilliant ore deposit of negative ion zeolite micro mist 100
Far infrared micro mist ZrSiO
32
Antibiotic micro mist AgNO
32.5
Binary photocatalyst nano-TiO
225
Promotor Y
2O
3(yttrium oxide) 2
Dispersion agent sodium laurylsulfonate 2
Coupling agent titanic acid ester 2
Water purification 100
As shown in drawings, the manufacture method of above-mentioned environment protecting building paint additive, it adopts following processing step: at first the brilliant ore deposit of negative ion zeolite is added jaw crusher and carry out fragmentation, washing afterwards, airing, enter twin rollers again and grind to form the fine sand shape, magnetic separation is to remove impurity such as Fe, enter in the high-speed eddy grinding machine by the elevator conveyer mechanical feed and to pulverize, the powder that obtains enters air classifier, can get φ≤1250 orders after cyclonic separation is main powder, thicker granular powder then returns the row pulverizing again of high-speed eddy grinding machine, air-flow can advance efficient bag separator and reach effluent standard tail gas, the service temperature of above-mentioned technological process is less than or equal to 50 ℃, from bag separator bottom and the powder that comes out of cyclonic separator bottom broken through the supersonic airstream abrasive dust, obtain the micro mist that granularity is 5 μ; Get the brilliant ore deposit of the negative ion zeolite micro mist of 100 weight parts and go into strong stirring barrel, add far infrared micro mist 1～3 weight part, antibiotic micro mist 2.5～4 weight parts, photocatalyst micro mist 20～40 weight parts, promotor micro mist 2～5 weight parts simultaneously, and adding water purification, carry out the secondary grinding in the efficient wet shredder through entering again after the reinforcement stirring, reach D until mixture powder granularity ultramicronising
50≤ 0.5 μ, add at last dispersion agent 2～5 weight parts, coupling agent 2～3 weight parts and water purification 100～300 weight parts to mixture disperse, surface-active-treatment such as coating, obtain additive product.
Result of use:
(1) get above-mentioned liquid environment-friendly building coating additive 30 grams (solid content is 50%) and promptly contain function powder 15 grams, add in 5 kilograms of Central-South board internal wall emulsion coatings, and evenly brush model (on the 10cm * 10cm), and on the metope, after measured:
1. the lasting concentration of negative ion reaches: 29000/cm
2Divide
2. far infrared transmissivity: 0.85～0.90 (4～14 μ wavelength)
3. eliminate peculiar smell residual formaldehyde concentration 0.08mg/M after the 5th day
3
(2) adopt the liquid functional paint additive (accurate nanometer) of above-mentioned prescription and prepared to be applied in the aqueous inner wall paint, prepared environment-friendly type inner wall coating has the elimination peculiar smell, the effect that continues to discharge negative ion and produce the far infrared rays of useful human body.
Embodiment 2
A kind of environment protecting building paint additive, it is to be mixed for raw material by following prescription (weight part):
The brilliant ore deposit of negative ion zeolite micro mist 100
Far infrared micro mist SiC 1
SiO
2 1
ZrSiO
3 2
Antibiotic micro mist AgNO
32
ZnO 2
The photocatalyst nano-TiO
235
Promotor Y
2O
3(yttrium oxide) 3
Dispersion agent sodium laurylsulfonate 3
Coupling agent silane 2
Water purification 200
The manufacture method of present embodiment is identical with embodiment 1.
Result of use:
(1). on get and state liquid environment protection architecture paint additive 30 grams, (solid content 50%), that is function powder 15 grams add in 5 kilograms of Central-South board internal wall emulsion coatings, fully stir evenly, and evenly brush model (on the 10cm * 10cm), and on the metope, after measured:
1. the lasting concentration of negative ion reaches: 28000/cm
2Divide
2. far infrared transmissivity: 0.9～0.91 (4～14 μ wavelength)
3. eliminate peculiar smell residual formaldehyde concentration 0.07mg/M after the 5th day
3
(2). adopt the liquid functional paint additive (accurate nanometer) of above-mentioned prescription and prepared to be applied in the aqueous inner wall paint, prepared environment-friendly type inner wall coating has the elimination peculiar smell, the effect that continues to discharge negative ion and produce the far infrared rays of useful human body.
Embodiment 3
A kind of environment protecting building paint additive, it is to be mixed for raw material by following prescription (weight part):
The brilliant ore deposit of negative ion zeolite micro mist 100
Far infrared micro mist ZrSiO
31
Antibiotic micro mist AgNO
32
CuO 2
Binary photocatalyst nano-TiO
240
Promotor Y
2O
3(yttrium oxide) 3
Sodium hexametaphosphate dispersant 2
Coupling agent titanic acid ester 2
High-strength sorbing material micro mist TiO
23
Water purification 300
The manufacture method of present embodiment is identical with embodiment 1.
Result of use:
(1). aforesaid liquid shape environment protection architecture coating intermediate is got 30 grams, (solid content 50%), that is function powder 15 grams add in 5 kilograms of Central-South board internal wall emulsion coatings, fully stir evenly, and evenly brush at model (on the 10cm * 10cm), and (10M on the metope2The room), after measured:
1. the lasting concentration of anion reaches: 28000/cm2Divide
2. far infrared transmissivity: 0.90～0.95 (4～14 μ wavelength)
3. eliminate peculiar smell residual formaldehyde concentration 0.06mg/M after the 5th day3
(2). adopt the liquid functional paint additive (accurate nanometer) of prescription 1 and technology preparation to be applied in water In the inner wall paint, prepared environment-friendly type inner wall coating has the elimination peculiar smell, and the sustained release anion reaches Produce the effect of the far infrared of useful human body.
Claims (5)
1. an environment protecting building paint additive is characterized in that, it is to be that raw material mixes by following weight part prescription:
The brilliant ore deposit of negative ion zeolite micro mist 100
Far infrared micro mist 1～3
Antibiotic micro mist 2.5～4
Photocatalyst micro mist 20～40
Promotor micro mist 2～5
Dispersion agent 2～5
Coupling agent micro mist 2～3
Water purification 100～300
The brilliant ore deposit of described negative ion zeolite micro mist is selected from the silicate that Chemical Composition is Al, Si, Mn, Zn, Ti, and described far infrared micro mist is selected from ZrSiO
3, SiO
2, Al
2O
3, among the SiC one or more, described antibiotic micro mist is selected from AgNO
3, among ZnO, the CuO one or more, described dispersion agent is selected from a kind of in sodium laurylsulfonate or the Sodium hexametaphosphate 99, described coupling agent is selected from a kind of in titanic acid ester or the silane.
2. a kind of environment protecting building paint additive according to claim 1 is characterized in that, also comprises high-strength sorbing material micro mist 3～4.5 in the described weight part prescription, and this high-strength sorbing material micro mist is selected from zeolite ore deposit or TiO
2In one or both.
3. a kind of environment protecting building paint additive according to claim 1 is characterized in that, the granularity D of the brilliant ore deposit of described negative ion zeolite micro mist
50≤ 5 μ.
4. a kind of environment protecting building paint additive according to claim 1 is characterized in that, the granularity of described antibiotic micro mist, photocatalyst micro mist, coupling agent micro mist is nano level.
5. the manufacture method of a kind of environment protecting building paint additive as claimed in claim 1, it is characterized in that, it adopts following processing step: at first the brilliant ore deposit of negative ion zeolite is added jaw crusher and carry out fragmentation, washing afterwards, airing, enter twin rollers again and grind to form the fine sand shape, magnetic separation is to remove Fe impurity, enter in the high-speed eddy grinding machine by the elevator conveyer mechanical feed and to pulverize, the powder that obtains enters air classifier, can get φ≤1250 orders after cyclonic separation is main powder, thicker granular powder then returns the row pulverizing again of high-speed eddy grinding machine, air-flow advances efficient bag separator and reaches effluent standard tail gas, the service temperature of above-mentioned technological process is less than or equal to 50 ℃, from bag separator bottom and the powder that comes out of cyclonic separator bottom broken through the supersonic airstream abrasive dust, obtain the micro mist that granularity is 5 μ; Get the brilliant ore deposit of the negative ion zeolite micro mist of 100 weight parts and go into strong stirring barrel, add far infrared micro mist 1～3 weight part, antibiotic micro mist 2.5～4 weight parts, photocatalyst micro mist 20～40 weight parts, promotor micro mist 2～5 weight parts simultaneously, and adding water purification, carry out the secondary grinding in the efficient wet shredder through entering again after the reinforcement stirring, reach D until mixture powder granularity ultramicronising
50≤ 0.5 μ, add at last dispersion agent 2～5 weight parts, coupling agent 2～3 weight parts and water purification 100～300 weight parts to mixture disperse, clad surface is active handles, and obtains additive product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01132277 CN1241999C (en) | 2001-11-23 | 2001-11-23 | Environment protecting building paint additive and its prepn process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01132277 CN1241999C (en) | 2001-11-23 | 2001-11-23 | Environment protecting building paint additive and its prepn process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1421494A CN1421494A (en) | 2003-06-04 |
| CN1241999C true CN1241999C (en) | 2006-02-15 |
Family
ID=4671314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01132277 Expired - Fee Related CN1241999C (en) | 2001-11-23 | 2001-11-23 | Environment protecting building paint additive and its prepn process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1241999C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497350A (en) * | 2016-10-10 | 2017-03-15 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | A kind of odor additive for being applied to waterborne polyester coating and preparation method thereof |
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| CN1329462C (en) * | 2003-08-04 | 2007-08-01 | 顺德鸿昌化工有限公司 | Nano internal-wall latex paint for health-care building and preparing method thereof |
| CN1328335C (en) * | 2003-08-04 | 2007-07-25 | 顺德鸿昌化工有限公司 | Negative ion type internal-wall later paint for health-care building and preparing method thereof |
| CN100372993C (en) * | 2005-03-23 | 2008-03-05 | 李上辉 | Negative ion material and synthetic leather material modified therefrom and application thereof |
| CN100358423C (en) * | 2006-06-01 | 2008-01-02 | 沈阳建筑大学 | Process for producing silicon dioxide germicide |
| CN102649095A (en) * | 2011-02-24 | 2012-08-29 | 苏州纳方工程材料有限公司 | Grinding method of titanium dioxide |
| JP6184108B2 (en) * | 2013-01-30 | 2017-08-23 | 株式会社フィルコーポレーション | Photocatalyst solution, multifunctional paint solution, base material on which photocatalyst is fixed, multifunctional base material on which powder of photocatalyst and multifunctional component is fixed |
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| CN105694572B (en) * | 2016-02-26 | 2018-07-06 | 惠州市环美盛新材料有限公司 | A kind of antibacterial increases Strong water paint additives and preparation method thereof |
| CN106967326B (en) * | 2017-02-28 | 2020-09-15 | 韦尧天 | Preparation process and use method of paint additive |
| CN109439058A (en) * | 2017-08-31 | 2019-03-08 | 福建靓隆实业有限公司 | Coating natural minerals ionic auxiliary agent, preparation method and environmental protection coating material |
| CN112063021A (en) * | 2020-09-14 | 2020-12-11 | 谢文富 | Preparation and use method of three-in-one oily solvent additive with antibacterial zinc ions |
| CN114350182A (en) * | 2021-12-17 | 2022-04-15 | 沈阳市津浩科技有限公司 | Preparation method of modified zeolite for environment-friendly high-performance interior wall coating |
-
2001
- 2001-11-23 CN CN 01132277 patent/CN1241999C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497350A (en) * | 2016-10-10 | 2017-03-15 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | A kind of odor additive for being applied to waterborne polyester coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1421494A (en) | 2003-06-04 |
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Granted publication date: 20060215 Termination date: 20101123 |