CN112063021A - Preparation and use method of three-in-one oily solvent additive with antibacterial zinc ions - Google Patents
Preparation and use method of three-in-one oily solvent additive with antibacterial zinc ions Download PDFInfo
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Abstract
The invention relates to the technical field of oily environment-friendly materials, in particular to a preparation method and a use method of a three-in-one oily solvent additive with antibacterial zinc ions. The oily solvent obtained by the method can be combined with oily paint and epoxy resin materials used as an adhesive, so that the materials have health care, safety and antibacterial functions, and the new trend and the wind tide of materials used for building decoration are driven. The environment-friendly material prepared by using the oily solvent, the oily paint and the epoxy resin adhesive has the additional functions of far infrared rays, negative ions and long-acting antibacterial zinc ions, becomes a special material with the functions of health care, safety and sterility, and has great market advantage and competitiveness.
Description
Technical Field
The invention relates to the technical field of oily environment-friendly materials, in particular to a preparation method and a use method of a three-in-one oily solvent additive with antibacterial zinc ions.
Background
The existing ceramic, wood, plywood, cement paint, emulsion paint and transparent paint are in the direction of environmental building materials, the toxic adhesive is prevented from releasing formaldehyde and benzene or plasticizer, although people try to add negative ion materials to remove the peculiar smell of the products, the effects are often poor, the fading is fast, or the products cannot be completely and uniformly mixed with the materials, and the cement and the gypsum are not developed into materials capable of releasing negative ions and far infrared rays.
In the field of ceramic technology, there are cases of preparation and application methods of ceramic glaze nanoporous water solution additives, such as patent numbers: the invention patent of CN103951467B discloses a preparation method of a ceramic glaze nanoporous water solution additive, which is characterized in that water vapor passes through nanoporous material particles with pore size less than 100 nanometers, and the water solution obtained after condensation is the ceramic glaze nanoporous water solution additive. The existing nano molecular water is a water-based additive, and compared with the prior art, paint materials which use negative ions to reduce formaldehyde or benzene are generally used in green environment-friendly building materials, but an oily material can be used as a carrier, so that the oily material can simultaneously generate far infrared rays and release negative ions, and the existing nano molecular water does not exist in the market at present. For example, oil-based paint or additives requiring resin for gluing are all oil-based materials, which cannot be matched with water-based additives, so that the application range of the existing nano molecular water is limited, and therefore, the existing nano molecular water needs to be improved and widely applied to the compounding of various materials.
Disclosure of Invention
In order to solve the defects of the prior art, the invention provides a preparation method and a use method of a three-in-one oily solvent additive with antibacterial zinc ions.
In order to achieve the purpose, the invention adopts the following technical scheme that the preparation method of the three-in-one oily solvent additive with antibacterial zinc ions is characterized by comprising the following steps:
step one, taking water as a carrier, and converting the water into steam when boiling;
step two, small water molecules of water vapor are surrounded on particles generated by the 20-30 nanometer pore material, and water solution is obtained after condensation through a condenser;
adding corbicula fluminea shell powder into the aqueous solution to enable the aqueous solution with far infrared rays and negative ions to be a strong alkaline aqueous solution of Ph11, wherein the corbicula fluminea shell powder is formed by calcining and grinding corbicula fluminea shells;
step four, adding ZaO with the particle size of 10 nanometers into the strong alkali aqueous solution2Adjusting the pH of the aqueous solution to 7-8;
step five, mixing the aqueous solution with C3H8O2Mixing to obtain the three-in-one oily solvent additive which can be compounded with oily paint or Epoxy material and has far infrared rays, negative ions and antibacterial zinc ions.
Further, the water carrier of the first step is subjected to RO reverse osmosis treatment and O3After being sterilized by ultraviolet light, the mixture is heated to 100 ℃ and 130 ℃ to form water vapor.
Further, the nanoporous material in step 2 comprises: SiO 22、TiO2、Al2O3、Fe2O3、FeO、B2O3And at least one or more of rare earth and three-dimensional granular zeolite.
Further, the raw material in 2 comprises SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3The rare earth and the three-dimensional granular zeolite are prepared from the following raw materials in percentage by weight: 0.43-0.48: 0.08-0.12: 0.06-0.10: 0.04-0.08: 0.04-0.08: 0.04-0.08: 0.08-0.12: 0.06-0.10.
Further, the nanoporous material SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3The rare earth and the three-dimensional granular zeolite are prepared from the following raw materials in percentage by weight: 0.46: 0.10: 0.08: 0.06: 0.06: 0.06: 0.10: 0.08.
further, the aqueous solution and C in step 53H8O2The mixing ratio of (1): 1 or 1: 2.
further, the three-in-one oily solvent additive is blended with the oily paint, the addition amount of the three-in-one oily solvent additive accounts for 30-50% of the percentage of the oily paint, and the three-in-one oily solvent additive and the oily paint are mixed to prepare the environment-friendly paint.
Further, the three-in-one oily solvent additive and the oily paint are blended until the pH value is between 7 and 8, and then the three-in-one oily solvent additive and the oily paint are blended.
Further, the environment-friendly coating is sprayed on the surface of the base material, and is baked at 400 ℃ and 500 ℃ and then cooled.
Further, the three-in-one oily solvent additive of any one of claims 1 to 6 is blended with epoxy resin, the addition amount of the three-in-one oily solvent additive accounts for 20 to 30 percent of the percentage of the oily paint, and the three-in-one oily solvent additive is mixed with the epoxy resin to prepare the environment-friendly resin.
The preparation and application method of the three-in-one aqueous solution additive with far infrared rays, negative ions and antibacterial zinc ions of the invention prepare the oily solvent additive capable of being compounded with oily paint or Epoxy material, because C3H8O2The (namely, Propylene glycol) can be compatible with oil paint or Epoxy material, endows various materials with the antibacterial property of generating far infrared rays, negative ions and zinc ions, and can be widely applied to the compounding of various oil or resin materials.
The three-in-one oily solvent additive with antibacterial zinc ions, which is obtained by the method, can generate 12-13 micron far infrared rays at the normal temperature of 34 ℃ to generate non-thermal effect, and can improve the blood circulation of a human body, activate cells, purify blood, improve immunity, adjust autonomic nerves and improve arthralgia. The negative ions can efficiently remove PM2.5 and less more harmful ultrafine particles in the air, decompose harmful gas, pollute decoration, kill bacteria viruses and allergens, slowly release forest fragrance to create forest environment and the like, the zinc ions can effectively achieve an antibacterial target, and for the selection of modern building and decoration materials, oily paint and epoxy resin materials used as adhesives endow the materials with health care, health maintenance, safety and antibacterial functions, and drive new trends and wind tides of materials used for building decoration. The environment-friendly material prepared by using the oily solvent, the oily paint and the epoxy resin adhesive has the additional functions of far infrared rays, negative ions and long-acting antibacterial zinc ions, becomes a special material with the functions of health care, safety and sterility, and has great market advantage and competitiveness.
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FIG. 1 is a diagram illustrating the detection of far infrared radiation rate of an environmental protection steel plate according to an embodiment;
FIG. 2 is a diagram illustrating the detection of far infrared radiation rate of the environmental-friendly resin according to the second embodiment.
Detailed Description
The invention is further described below by means of specific embodiments.
The preparation method of the three-in-one oily solvent additive with antibacterial zinc ions is characterized by comprising the following steps:
step one, taking water as a carrier, and carrying out RO reverse osmosis treatment and O treatment on the water carrier3After ultraviolet sterilization, heating to 100-130 ℃ boiling to form steam;
step two, the water solution is obtained by surrounding small water molecules of water vapor on particles generated by the 20-30 nanometer pore material and condensing the particles by a condenser, wherein the nanometer pore material comprises: SiO 22、TiO2、Al2O3、Fe2O3、FeO、B2O3And rare earth and three-dimensional granular zeolite, wherein the weight ratio of the raw materials is as follows: 0.43-0.48: 0.08-0.12: 0.06-0.10: 0.04-0.08: 0.04-0.08: 0.04-0.08: 0.08-0.12: 0.06-0.10, preferably SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3The rare earth and the three-dimensional granular zeolite are prepared from the following raw materials in percentage by weight: 0.46: 0.10: 0.08: 0.06: 0.06：0.06：0.10：0.08；
Adding corbicula fluminea shell powder into the aqueous solution to enable the aqueous solution with far infrared rays and negative ions to be a strong alkaline aqueous solution of Ph11, wherein the corbicula fluminea shell powder is formed by calcining and grinding corbicula fluminea shells;
step four, adding ZaO with the particle size of 10 nanometers into the strong alkali aqueous solution2Adjusting the pH of the aqueous solution to 7-8;
step five, mixing the aqueous solution with C3H8O2Mixing to obtain three-in-one oily solvent additive with far infrared ray, negative ion and antibacterial zinc ion, aqueous solution and C3H8O2The mixing ratio of (1): 1 or 1: 2.
the invention utilizes a special formula of a pore material with the pore diameter less than 25 nanometers to generate nano particle impact at a specific temperature, then uses water molecules of water vapor as a carrier to condense and reduce the nano particles capable of generating far infrared rays and negative ions into nano particle water of water by the water carrier, and then adds clam shells which are originally waste to prepare 1500-mesh organic golden clam shell powder (namely CaO)2) And Activity ZnO of 10 nm. Adding the aqueous solution into C in a proper proportion3H8O2(i.e. Propylene glycol) to form the oily solvent additive with far infrared ray, negative ion and antibacterial zinc ion which can be compounded with oily paint or Epoxy material, endows various materials with the antibacterial property of generating far infrared ray, negative ion and zinc ion, and can be widely applied to the compounding of various materials.
The oily solvent can generate 12-13 micron far infrared rays at the normal temperature of 34 ℃ to generate non-thermal effect to improve the blood circulation of a human body, activate cells, purify blood, improve immunity, adjust autonomic nerves and improve arthralgia. The negative ions can efficiently remove PM2.5 and less more harmful ultrafine particles in the air, decompose harmful gas, pollute decoration, kill bacteria viruses and allergens, slowly release forest fragrance to create forest environment and the like, the zinc ions can effectively achieve an antibacterial target, and for the selection of modern building and decoration materials, oily paint and epoxy resin materials used as adhesives endow the materials with health care, health maintenance, safety and antibacterial functions, and drive new trends and wind tides of materials used for building decoration. The material is endowed with the additional functions of far infrared rays, negative ions and long-acting antibacterial zinc ions by using oily paint and epoxy resin adhesives, becomes a special material with the functions of body nourishing, health care, safety and sterility, and has great market advantage and competitiveness.
In a first embodiment of the present invention, a first,
the three-in-one oily solvent additive is prepared by the preparation method of the three-in-one oily solvent additive with antibacterial zinc ions, and in the fifth step, the aqueous solution and the C are mixed3H8O2The mixing ratio of (1): 1, then completing the following operations:
s1, blending the three-in-one oily solvent additive and the oily paint until the pH value is 7-8, and blending the three-in-one oily solvent additive and the oily paint to prepare the environment-friendly paint, wherein the addition amount of the three-in-one oily solvent additive accounts for 30% of the percentage of the oily paint;
s2, uniformly stirring the environment-friendly paint, and then coating paint on the color steel;
s3, baking the painted color steel at 480 ℃ and cooling;
s4, detecting the color difference and the gloss to obtain the result, comparing the color difference and the gloss with the original paint in an allowable range, and obtaining the environment-friendly color steel plate.
The obtained environment-friendly color steel plate is detected to have far infrared ray emissivity, and the result is shown in figure 1, and the result is shown in the following table after being detected to have negative ions:
the obtained environment-friendly color steel plate is subjected to antibacterial detection, and the test results are shown in the following table:
acting time: 24 hours
Remarking: 1. the antibacterial value (R) is the average Log value of the number of raw bacteria in the non-processed sample-the average Log value of the number of raw bacteria in the processed sample;
2. an antibacterial value (R) of 2.0 or more indicates an antibacterial effect.
The three-in-one oily solvent with far infrared ray, negative ion and antibacterial zinc ion can be completely compatible when used in oily paint or adhesives such as epoxy resin, etc., to replace the toxic solvent which is required to be added: the preparation method comprises the steps of blending volatile and highly dangerous solvents such as formaldehyde, toluene and the like, so that the oily coating is more environment-friendly, healthy and safe during blending, and endowing a finished product with the effects of emitting 12-13 micron far infrared light waves which can promote the blood circulation of a human body and have high catalytic and adsorption effects at 34 ℃, generating negative ions which can purify air, eliminate peculiar smell and strengthen the immune system of the human body and the like, and further releasing zinc ions to achieve the aims of long-acting bacteriostasis and sterilization.
In a second embodiment of the present invention, a second,
the preparation method of the three-in-one oily solvent additive with antibacterial zinc ions is used for preparing the three-in-one oily solvent additive, the three-in-one oily solvent additive and epoxy resin are blended, the addition amount of the three-in-one oily solvent additive accounts for 20-30% of the percentage of the oily paint, and the three-in-one oily solvent additive and the epoxy resin are mixed to prepare the environment-friendly resin.
The obtained environment-friendly resin is detected to have far infrared ray emissivity, and the result is shown in figure 2, and is detected to have negative ions, and the result is shown in the following table:
the epoxy resin material can also show the nanometer small-size effect and the quantum size effect to generate the health care and health maintenance functions, and can release zinc ions to have long-acting antibiosis or peculiar smell after the resin is glued, thereby meeting the requirements of environment-friendly and safe healthy green building materials.
The above description is only an embodiment of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by using the design concept should fall within the scope of infringing the present invention.
Claims (10)
1. The preparation method of the three-in-one oily solvent additive with antibacterial zinc ions is characterized by comprising the following steps:
step one, taking water as a carrier, and converting the water into steam when boiling;
step two, small water molecules of water vapor are surrounded on particles generated by the 20-30 nanometer pore material, and water solution is obtained after condensation through a condenser;
adding corbicula fluminea shell powder into the aqueous solution to enable the aqueous solution with far infrared rays and negative ions to be a strong alkaline aqueous solution of Ph11, wherein the corbicula fluminea shell powder is formed by calcining and grinding corbicula fluminea shells;
step four, adding ZaO with the particle size of 10 nanometers into the strong alkali aqueous solution2Adjusting the pH of the aqueous solution to 7-8;
step five, mixing the aqueous solution with C3H8O2Mixing to obtain the three-in-one oily solvent additive which can be compounded with oily paint or Epoxy material and has far infrared rays, negative ions and antibacterial zinc ions.
2. The method for preparing the three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 1, which is characterized in that: the water carrier of the step one is subjected to RO reverse osmosis treatment and O3After being sterilized by ultraviolet light, the mixture is heated to 100 ℃ and 130 ℃ to form water vapor.
3. The method for preparing a three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 1, wherein the nanoporous material in step 2 comprises: SiO 22、TiO2、Al2O3、Fe2O3、FeO、B2O3And at least one or more of rare earth and three-dimensional granular zeolite.
4. The method for preparing a three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 3, wherein the raw material in 2 comprises SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3The rare earth and the three-dimensional granular zeolite are prepared from the following raw materials in percentage by weight: 0.43-0.48: 0.08-0.12: 0.06-0.10: 0.04-0.08: 0.04-0.08: 0.04-0.08: 0.08-0.12: 0.06-0.10.
5. The method for preparing the three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 4, wherein the method comprises the following steps: the nanoporous material SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3The rare earth and the three-dimensional granular zeolite are prepared from the following raw materials in percentage by weight: 0.46: 0.10: 0.08: 0.06: 0.06: 0.06: 0.10: 0.08.
6. the method for preparing the three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 1, which is characterized in that: the aqueous solution and C in the step 53H8O2The mixing ratio of (1): 1 or 1: 2.
7. the use method of the three-in-one oily solvent additive with antibacterial zinc ions is characterized in that: blending the three-in-one oily solvent additive of any one of claims 1 to 6 with an oily paint, wherein the addition amount of the three-in-one oily solvent additive accounts for 30 to 50 percent of the percentage of the oily paint, and the three-in-one oily solvent additive is mixed with the oily paint to prepare the environment-friendly paint.
8. The use method of the three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 7, is characterized in that: and (3) blending the three-in-one oily solvent additive and the oily paint until the pH value is between 7 and 8, and then blending the three-in-one oily solvent additive and the oily paint.
9. The use method of the three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 7, is characterized in that: the environment-friendly coating is sprayed on the surface of a base material, and is baked at the temperature of 400 ℃ and 500 ℃ and then cooled.
10. The use method of the three-in-one oily solvent additive with antibacterial zinc ions as claimed in claim 1, is characterized in that: the three-in-one oily solvent additive of any one of claims 1 to 6 is blended with epoxy resin, the addition amount of the three-in-one oily solvent additive accounts for 20 to 30 percent of the percentage of the oily paint, and the three-in-one oily solvent additive is mixed with the epoxy resin to prepare the environment-friendly resin.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113845877A (en) * | 2021-09-23 | 2021-12-28 | 谢文富 | Preparation method and use method of adhesive with far infrared, antibacterial and antioxidant functions |
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