CN1241541C - Hair care compositions - Google Patents
Hair care compositions Download PDFInfo
- Publication number
- CN1241541C CN1241541C CNB02812622XA CN02812622A CN1241541C CN 1241541 C CN1241541 C CN 1241541C CN B02812622X A CNB02812622X A CN B02812622XA CN 02812622 A CN02812622 A CN 02812622A CN 1241541 C CN1241541 C CN 1241541C
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- China
- Prior art keywords
- weight
- composition
- compositions
- hair
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/51—Chelating agents
Abstract
Hair care compositions containing hydrogen peroxide which are to be used as hair bleachings, oxidative hair dyes, perming agents and so on. These compositions are characterized by containing hydrogen peroxide together with polyoxyethylene lanolin, an oily component, a sequestrant and water. If desired, these compositions may further contain an anionic surfactant. These compositions exhibit excellent emulsion stability without showing any separation in case of processed into emulsified compositions.
Description
Technical field
The present invention relates to the hair treatment compositions, in more detail, relate to the hair treatment compositions that contains hydrogen peroxide that is used for hair depigmenting agent, oxide hair dye, long-acting setting lotion etc.
Background technology
The hair treatment that contains hydrogen peroxide has hair depigmenting agent, oxide hair dye the 2nd dose and the 2nd dose of long-acting setting lotion etc. with compositions.But because contain hydrogen peroxide, there is the problem of damage hair, scalp irritation in these hair treatment compositionss.In order to address this problem, in order to give hair and skin moisturizing effect, people attempt adding the oiliness composition in said composition makes it become emulsification composition.
If but the hair treatment that contains hydrogen peroxide is become emulsification composition with compositions, then exist because of hydrogen peroxide decomposes or because of add the factors such as difference in specific gravity increase between oil phase/water that hydrogen peroxide causes to water, cause the balance of emulsification system to be destroyed, cause problem such as emulsification composition separation.
Isolating hair treatment compositions with well emulsify stability does not take place with regard to providing in purpose of the present invention.
Disclosure of an invention
The present invention can provide the hair treatment that contains hydrogen peroxide compositions, is characterized in containing Wool wax alcohols,ethoxylated, oiliness composition, metal ion sequestering agent and water.
The best way that carries out an invention
The present invention relates to and the relevant hair treatment compositionss that contain hydrogen peroxide such as the depigmenting agent of hair, the 2nd dose of oxide hair dye and the 2nd dose of long-acting setting lotion.Hair treatment of the present invention except hydrogen peroxide, also has Wool wax alcohols,ethoxylated, oiliness composition, metal ion sequestering agent and water with the neccessary composition of compositions.
The used Wool wax alcohols,ethoxylated of the present invention is the material that carboxyl, hydroxyl and the ethylene oxide addition polymerization in the lanoline of lanoline and purification forms, and is the non-ionic surface active agent with lanoline residue.The emulsification composition of Xing Chenging has higher emulsion stability for the separation that takes place along with the time thus, and has the advantage of all kinds of solvents such as being applicable to water, alcohol, polyhydric alcohol, is preferred solvent of the present invention.
Though there is no particular limitation to the polyoxyethylene addition molal quantity of Wool wax alcohols,ethoxylated, preferred 10～100, more preferably 20～60.Its reason is that the addition molal quantity surpasses under 100 the situation, and viscosity can obviously increase, and the usability of causing downward trend is arranged, and under the situation less than 10 molal quantitys, the inadequate trend of emulsifying is arranged.
In addition can be with commercially available Wool wax alcohols,ethoxylated, as: trade name " Solan A ", " Polychol WH400 ", " Polychol 40 " (all being that CEODA company makes) etc.
Though there is no particular limitation for the content of Wool wax alcohols,ethoxylated in the compositions of the present invention, preferred 0.01～10% weight, more preferably 0.2～5% weight.Its reason is to contain under the situation of quantity not sufficient 0.01% weight, and the inadequate trend of emulsifying is arranged, and if combined amount surpasses 10% weight, ductility variation when smearing, and then the affinity downward trend that causes with hair is arranged.
The oiliness composition that the present invention uses can adopt the general oiliness raw material that uses in the cosmetics, there is no particular limitation to these oiliness compositions, as: methyl polysiloxane, methyl phenyl silicone, methyl cyclo(poly)siloxane, octamethylcy-clotetrasiloxane, prestox D5, decamethylcyclopentaandoxane and methylhydrogenpolysi,oxane silicone oil such as (methylhydrogenpolysiloxane); Esters such as isopropyl myristate, myristic acid 2-octyl group dodecyl ester, 2 ethyl hexanoic acid spermaceti alcohol ester, hexadecylic acid 2-Octyl Nitrite, two-2 ethyl hexanoic acid DOPCP, three-2 ethyl hexanoic acid glycerine ester, oleic acid 2-octyl group dodecyl ester, glycerol three isostearates, glycerol three-2-ethylhexanoate, oleic acid 2-octyl group dodecyl ester, malic acid two isooctadecanol esters, glycerol three isostearates, diglycerol 2-ethylhexanoate; Senior alcohols such as lauryl alcohol, myristyl alcohol, hexadecanol, octadecanol, isooctadecane alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol; Senior fatty acids such as lauric acid, myristic acid, Palmic acid, stearic acid, isostearic acid, oleic acid; Hydro carbons such as liquid paraffin, paraffin, vaseline, ceresine, microcrystalline wax, Squalene, squalane; Wax classes such as Brazil wax, candelilla wax, Jojoba oil, Cera Flava, lanoline; Olive oil, Camellia oil, macadimia nut oil, American Avocado Tree wet goods oils.Senior alcohols such as this wherein preferred lauryl alcohol, myristyl alcohol, hexadecanol, octadecanol, isooctadecane alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol.
Though the content of oiliness composition is not particularly limited in the compositions of the present invention, preferred 0.01～10% weight, more preferably 0.2～5% weight.Its reason is to contain under the situation of quantity not sufficient 0.01% weight, and the inadequate trend of emulsifying is arranged, when surpassing 10% weight, and ductility variation when then smearing, and then the affinity downward trend that causes with hair is arranged.
If above-mentioned in addition two kinds of compositions are prepared burden in following ratio, then can more effective performance function of the present invention.
It is preferred 1: 0.5～1: 3 of the charge ratio (weight ratio) of oiliness composition and Wool wax alcohols,ethoxylated.Its reason is with respect to 1 weight portion oiliness composition, under the situation of mixing ratio less than 0.5 weight portion of Wool wax alcohols,ethoxylated, might can not get adequately emulsified trend, and if mixing ratio surpasses 3 weight portions, the isolating trend of emulsifying and surfactant is then arranged.
Metal ion sequestering agent among the present invention contains acidic-group with salify ability or the atomic group with coordination ability, sneaks in order to suppress hydrogen peroxide decomposes.Can be used for metal ion sequestering agent of the present invention has: alanine, ethylenediamine ethoxy triacetic acid trisodium, ethylenediaminetetraacetic acid, edetate, diethylene-triamine pentaacetic acid, diethylentriamine pentacetate, sodium citrate, gluconic acid, tartaric acid, phytic acid, polyphosphate sodium, Polymeric sodium metaphosphate., phenacetin, hydroxyl ethane di 2 ethylhexyl phosphonic acid etc.
Though the content of metal ion sequestering agent is not particularly limited in the compositions of the present invention, preferred 0.001～2% weight, more preferably 0.05～0.5% weight.Its reason is that this contains under the situation of quantity not sufficient 0.001% weight, and hydrogen peroxide has stable inadequate trend, when surpassing 0.5% weight, the trend of infringement emulsion stability is arranged then.
Among the present invention blended water can be purify waste water, ion exchange water, tap water etc.The content of water is as the criterion with the viscosity that obtains expecting in the compositions of the present invention, can carry out suitable adjustment.
For emulsion stability is improved, can add anion surfactant in compositions to hair treatment of the present invention.
Examples of anionic surfactants of the present invention has: fatty acid soaps, ether carboxylic acid, alkanesulfonic acid, higher alcohol sulfate salt, alkyl ether sulphate, alkyl allyl ether sulfuric ester, alkylphosphonic etc.This is wherein preferred: higher alcohol sulfate salt, alkyl ether sulphate and alkyl allyl ether sulfuric ester.
Though the content of anion surfactant is not particularly limited in the compositions of the present invention, preferred 0.1～10% weight, more preferably 1.0～5% weight.Its reason is to contain under the situation of quantity not sufficient 0.1% weight, has the emulsifying can not fully stable trend, and when surpassing 10% weight, the trend that can not get above desirable emulsion stability is arranged.
Hair treatment of the present invention is with containing hydrogen peroxide in the compositions.Preferred 0.001～10% weight of the content of hydrogen peroxide, more preferably 0.1～6% weight in the compositions of the present invention.Its reason is to contain under the situation of quantity not sufficient 0.001% weight, and the trend of oxidation scarce capacity is arranged, and when surpassing 10% weight, the trend that produces damage hair and chafe etc. is arranged.
The hair treatment of hydrogen peroxide that contains of the present invention in addition is with in the compositions, in the scope of not damaging purpose of the present invention, except mentioned component, can also suitably contain wetting agent, cationic surfactant, amphoteric surfactant, antioxidant, UV absorbent, antiinflammatory, vitamins, coloring agent, various spice etc. as required.
Hair treatment of the present invention can be used as depigmenting agent, oxide hair dye the 2nd dose of hair and long-acting setting lotion the 2nd dose and waits and use with compositions, its dosage form can be snowflake paste, pasty state, gel, aerosol etc.
Below describe the present invention in detail with embodiment, but the present invention is not limited by these embodiment.
Embodiment 1～6 and comparative example 1～3
According to the composition of record in table 1 and the table 2, by traditional method modulation hair treatment compositions.
Then a compositions that obtains is packed in the transparent bottle, preserved one month, whether the separation of compositions is arranged, and estimate emulsion stability according to following evaluation criterion with visual observations at 50 ℃.Its result is shown in table 1～2.
＜evaluation criterion 〉
Zero: do not separate
△: have a bit and separate
*: separate
Table 1
| Embodiment | |||||||
| 1 | 2 | 3 | 4 | 5 | 6 | ||
| The composition of composition (% weight) | POE (30) lanoline | 1.5 | 1.5 | 5.0 | - | - | - |
| POE (50) lanoline | - | - | - | 1.5 | - | 4.0 | |
| POE (70) lanoline | - | - | - | - | 1.5 | - | |
| Hexadecanol | 2.0 | 2.0 | 4.0 | 2.0 | - | 2.0 | |
| Octadecanol | - | - | - | - | 2.0 | - | |
| 35% aqueous hydrogen peroxide solution | 11.5 | 11.5 | 11.5 | 11.5 | 11.5 | 11.5 | |
| Phenacetin | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
| Purify waste water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| Emulsion stability | ○ | ○ | ○ | ○ | ○ | ○ | |
(notes)
POE: polyoxyethylated abbreviation
The polyoxyethylated addition molal quantity of numeral in the bracket.
Table 2
| Comparative example | ||||
| 1 | 2 | 3 | ||
| The composition of composition (% weight) | POE (50) lanoline | - | - | - |
| POE (40) cetyl ether | 1.5 | - | - | |
| POE (40) reduces lanoline | - | 1.5 | - | |
| POE (40) lanolin alcohol | - | - | 1.5 | |
| Hexadecanol | 2.0 | 2.0 | 2.0 | |
| 35% aqueous hydrogen peroxide solution | 11.5 | 11.5 | 11.5 | |
| Phenacetin | 0.1 | 0.1 | 0.1 | |
| Purify waste water | Surplus | Surplus | Surplus | |
| Emulsion stability | × | × | × | |
(notes)
POE: polyoxyethylated abbreviation
The polyoxyethylated addition molal quantity of numeral in the bracket.
From the result of table 1 and table 2 as can be seen, use in the compositions in the hair treatment that contains hydrogen peroxide, when modulation contained the emulsification composition of Wool wax alcohols,ethoxylated, oiliness composition, metal ion sequestering agent and water, they did not separate, and can obtain stable emulsification composition.The mixing ratio of oiliness composition and Wool wax alcohols,ethoxylated can more effective performance effect of the present invention by foregoing range operation in addition.
Embodiment 7
Hair depigmenting agent (% weight)
Aqueous hydrogen peroxide solution (35%) 10.0
Polyoxyethylene (30) lanoline 1.5
POE (2) sodium laureth sulfate 2.0
Hexadecanol 2.0
Phosphoric acid 0.05
Phenacetin 0.2
The surplus of purifying waste water
The hair depigmenting agent of above-mentioned prescription descends preservation not see respectively in one month at 50 ℃ and is separated.In addition the hair depigmenting agent after preserving is spread upon on the topknot, place after 20 minutes, clean, show good discoloration with shampoo.
Embodiment 8
The 2nd dose of oxide hair dye (% weight)
Aqueous hydrogen peroxide solution (35%) 16.5
Polyoxyethylene (30) lanoline 1.5
Hexadecanol 2.0
Phenacetin 0.2
The surplus of purifying waste water
The 1st dose of oxide hair dye (% weight)
Hexadecanol 5.0
Hexadecyltrimethylammonium chloride 1.0
Polyoxyethylene (20) cetyl ether 4.0
Disodiumedetate 0.2
Ascorbic acid 0.3
Ammonia (28%) 5.0
Sodium sulfite 0.3
P-aminophenol 0.2
P-phenylenediamine (PPD) 0.5
The amino orthoresol 0.1 of 5-
Meta-aminophenol 0.5
Resorcinol 0.2
Spice 0.2
The surplus of purifying waste water
The 2nd dose of the oxide hair dye of above-mentioned prescription preserved down at 50 ℃ and not seen respectively in one month and be separated.In addition above-mentioned the 1st dose with preserve after the 2nd dose of mixed in equal amounts, be applied in topknot and place after 30 minutes, clean with shampoo, hair is dyed brown.
Embodiment 9
The 2nd dose (% weight) of long-acting setting lotion
Aqueous hydrogen peroxide solution (35%) 16.5
Polyoxyethylene (30) lanoline 0.5
Hexadecanol 1.0
Phenacetin 0.05
Propylene glycol 2.0
Phosphoric acid is an amount of
Tetrasodium pyrophosphate is an amount of
The surplus of purifying waste water
The 1st dose (% weight) of long-acting setting lotion
Ammonium mercaptoacetate 8.0
Dimercapto acetic acid 1.0
Hexadecyltrimethylammonium chloride 1.0
Polyoxyethylene laurel ether 0.5
Disodiumedetate 0.2
Ammonia (28%) 1.5
Spice 0.1
The surplus of purifying waste water
The 2nd dose of the long-acting setting lotion of above-mentioned prescription preserved down at 50 ℃ and not seen respectively in one month and be separated.Smear hair with above-mentioned the 1st dose in addition, place water cleaning after 20 minutes, then smeared and place 20 minutes with the 2nd dose, clean with shampoo afterwards, hair presents good wave effect.
Utilizability on the industry
The hair care compositions that contains hydrogen peroxide of the present invention because it contains Wool wax alcohols,ethoxylated, oiliness composition, metal ion chelation agent and water, thereby does not separate, and presents good emulsion stability. Thereby hair care compositions of the present invention is applicable to hair decolorizer, oxide hair dye, long-acting hair-curling agent etc.
Claims (3)
1, the hair treatment emulsification composition, said composition is the hair treatment emulsification composition that contains 0.001-10 weight % hydrogen peroxide, it is characterized in that containing 0.01-10 weight % Wool wax alcohols,ethoxylated, 0.01-10 weight % oiliness composition, 0.001-2 weight % metal ion sequestering agent and water, wherein the polyoxyethylene addition molal quantity of Wool wax alcohols,ethoxylated is 10-100, the metal ion sequestering agent contains acidic-group with salify ability or the atomic group with coordination ability, and the mixed weight ratio of above-mentioned oiliness composition and above-mentioned Wool wax alcohols,ethoxylated is 1: 0.5～1: 3.
2, the hair treatment emulsification composition of claim 1, wherein above-mentioned oiliness composition is a higher alcohol.
3, claim 1 or 2 hair treatment emulsification composition, said composition also contains anion surfactant.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP256052/2001 | 2001-08-27 | ||
| JP2001256052 | 2001-08-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1520280A CN1520280A (en) | 2004-08-11 |
| CN1241541C true CN1241541C (en) | 2006-02-15 |
Family
ID=19083925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB02812622XA Expired - Fee Related CN1241541C (en) | 2001-08-27 | 2002-08-27 | Hair care compositions |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP3565838B2 (en) |
| KR (1) | KR100589452B1 (en) |
| CN (1) | CN1241541C (en) |
| WO (1) | WO2003017954A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3922573B2 (en) * | 2003-04-15 | 2007-05-30 | ホーユー株式会社 | Hydrogen peroxide-containing composition |
| JP4402614B2 (en) * | 2005-03-29 | 2010-01-20 | ホーユー株式会社 | Hair cosmetic composition |
| TWI659743B (en) * | 2013-06-28 | 2019-05-21 | 朋友股份有限公司 | Hair cosmetic composition and the composition comprising oxide, hair cosmetic material and hair cosmetic product |
| CN105686965A (en) * | 2015-12-31 | 2016-06-22 | 卢秋妤 | Hair care product and preparing method and application thereof |
| JP6705662B2 (en) * | 2016-02-29 | 2020-06-03 | ホーユー株式会社 | Oxidizing agent-containing composition, hair treatment agent, and method of using hair treatment agent |
| JP6882759B2 (en) * | 2016-12-26 | 2021-06-02 | ホーユー株式会社 | Oxidizing agent-containing composition and its usage |
| JP6814465B2 (en) * | 2016-12-26 | 2021-01-20 | ホーユー株式会社 | Multi-agent hair treatment agent composition and its usage |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5122832A (en) * | 1974-08-19 | 1976-02-23 | Tomihiko Asai | EAZOOR UKASANKAZAIYOEKINO SEIZOHO |
| JPH06157254A (en) * | 1992-04-30 | 1994-06-03 | Sasaki Kagaku Kk | Permanent waving and wave lotion agent |
| JP2848372B2 (en) * | 1997-02-07 | 1999-01-20 | ライオン株式会社 | Foam hair treatment agent |
| JP2001322916A (en) * | 2000-05-17 | 2001-11-20 | Kanebo Ltd | Second agent composition for permanent wave |
-
2002
- 2002-08-27 WO PCT/JP2002/008608 patent/WO2003017954A1/en active Application Filing
- 2002-08-27 JP JP2003522475A patent/JP3565838B2/en not_active Expired - Fee Related
- 2002-08-27 CN CNB02812622XA patent/CN1241541C/en not_active Expired - Fee Related
- 2002-08-27 KR KR1020037016189A patent/KR100589452B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2003017954A1 (en) | 2004-12-09 |
| JP3565838B2 (en) | 2004-09-15 |
| KR100589452B1 (en) | 2006-06-14 |
| CN1520280A (en) | 2004-08-11 |
| KR20040007684A (en) | 2004-01-24 |
| WO2003017954A1 (en) | 2003-03-06 |
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Granted publication date: 20060215 Termination date: 20100827 |