CN1229098C - Hair cosmetic composition - Google Patents
Hair cosmetic composition Download PDFInfo
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- CN1229098C CN1229098C CN 02128578 CN02128578A CN1229098C CN 1229098 C CN1229098 C CN 1229098C CN 02128578 CN02128578 CN 02128578 CN 02128578 A CN02128578 A CN 02128578A CN 1229098 C CN1229098 C CN 1229098C
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- hair
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- cosmetic composition
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Abstract
The invention prepares a hair cosmetic excellent in foaming property, showing foam of fine texture, creamy and soft, capable of imparting a good hair feeling even for the hair treated with a plurality of chemical treatments, suppressing rustling and stiffness in finishing and also effectively suppressing the damage to the hair such as turning over of cuticles, branched hairs, cut off hairs, and further, since a propellant is not used, not having problems in safety and environment. This hair cosmetic is obtained by filling a composition containing (a) an organic acid, (b) an organic solvent selected from benzyl alcohol, benzyloxyethanol and propylene carbonate, (c) a silicone and (d) a surfactant, in a non-aerosol type foam-ejecting container.
Description
Affiliated field
The present invention relates to cosmetic composition for hair, it can be effectively and suppresses the over-drying and sclerosis because of the hair of perming, dyeing or bleaching causing rapidly, can effectively prevent to adopt simultaneously other hair damage situation that takes place in drying device or the carding process.
Background technology
Adopted multiple aerosol type hair cosmetic foam such as hair styling foam and hair conditioning foam already,, wherein contained the concentrated solution and the propellant that is filled in the pressure vessel of cosmetic composition for hair because of its easy operating.These aerosol type hair cosmetic foams multiple propellant have been used for preparing; therefore in these product processes of design; must consider its safety, and consider and the measure of protecting the global environment for example prevent the measure that ozone layer minimizing, air pollution and environment warm.For above-mentioned viewpoint, developing the non-aerosol type hair cosmetic foam that does not contain propellant.
Up to now, the problem of following in the development of non-aerosol type hair cosmetic foam is that the foam quality that ejects from container is poor, its sense of touch adhesion, and it lacks sufficient hair fixing characteristic in addition.
In recent years, the aesthetic treatment of hair such as hair-dyeing or bleaching come into vogue rapidly.This class is handled will handle as hair-waving in conjunction with common chemical usually and is carried out.But this trend can increase the generation of the unfavorable sense of touch of hair, sends out the over-drying or sclerosis that lipid loss causes as excuse, or hair damage such as the fracture of hair top layer or come off terminal bifurcated of hair or fracture.
Therefore need a kind of new technique of exploitation, can obtain a kind of like this non-aerosol type hair cosmetic foam by it, its foam that ejects has excellent quality and quantity, and it can effectively suppress to handle the over-drying and sclerosis of the hair cause because of number of chemical, and other the hair damage situation that can effectively prevent to adopt in the drying device process or take place in the carding process.
Disclosure of the Invention
The inventor finds can be by adding the compositions that contains organic acid, specific organic solvent, polysiloxanes and surfactant in non-aerosol type foam discharger such as pumping formula foamite system, thereby make a kind of hair cosmetic foam, it has excellent foam characteristic, and can make hair have good sense of touch by exquisiteness, paste and soft and smooth foam, even handling it through number of chemical, hair also can effectively suppress the over-drying of hair or sclerosis; And it can effectively prevent hair damage such as the fracture of hair top layer or come off, terminal bifurcated of hair or fracture.This class hair cosmetic foam does not conform to propellant, does not therefore exist to relate to safety or problem of environment.
Therefore, a kind of cosmetic composition for hair is provided among the present invention, it contains (a) organic acid by adding in non-aerosol type foam discharger, (b) be selected from the organic solvent of benzylalcohol, BOE and Allyl carbonate, (c) polysiloxanes and (d) surfactant compositions and make.
Preferred forms of the present invention
The organic acid example of component (a) comprises monocarboxylic acid, dicarboxylic acids, hydroxy carboxylic acid and polycarboxylic acid.Wherein preferred dicarboxylic and hydroxy carboxylic acid (particularly alpha-hydroxy carboxylic acid compounds).Dicarboxylic acids comprises malonic acid, succinic acid, 1,3-propanedicarboxylic acid, adipic acid, maleic acid, fumaric acid and phthalic acid, wherein preferred especially maleic acid.Hydroxy carboxylic acid comprises glycolic, lactic acid, hydroxy acrylic acid, malic acid, tartaric acid and citric acid, wherein preferred alcohol acid and maleic acid, special preferably apple acid.
Can two or more these organic acid are shared.Its addition preferably accounts for the 0.05-20% (weight) of the present composition, more preferably 0.1-15% (weight), particularly 0.1-10% (weight).
The organic solvent of component (b) is selected from benzylalcohol, BOE, and Allyl carbonate.Can two or more these organic solvents are shared.Its addition preferably accounts for the 0.1-20% (weight) of the present composition, more preferably 0.2-15% (weight), particularly 0.2-10% (weight).
Remove these organic solvents, other organic solvent that is selected from polypropylene glycol and polypropylene oxide ether also is suitable for shared, to improve foam quality.Polypropylene glycol is a compound known.By the propylene oxide polymerization, can obtain the polypropylene glycol of different polymerization degree.Among the present invention, the average degree of polymerization of preferred polypropylene glycol is 7-20, more preferably 8-17, especially preferably 8-15.For polypropylene oxide ether, can adopt average degree of polymerization is 2-25, more preferably polypropylene oxide and the sugar of 5-25, particularly 8-25, methylated sugar, and sugar alcohol, the list of glycerol or polyglycereol-or two-etherification product.The example of sugar comprises erythrose, xylose, and glucose and mannose, the example of methylated sugar comprises the glucosides that methylates, and the example of sugar alcohol comprises tetramethylolmethane, and 1,2,3,4,5-pentanepentol, Sorbitol and mannitol, the example of polyglycereol comprise that the degree of polymerization is the polyglycereol of 2-3.Preferred polyoxypropylene (9-14) in the polyethenoxy ether, two glycerin ethers, polyoxypropylene (2-25) Sorbitol (sorbit), and polyoxypropylene (2-25) glucosides that methylates.
Can two or more each polypropylene glycol and polyethenoxy ether is shared.Its addition preferably accounts for the 0.05-30% (weight) of the present composition, more preferably 0.1-20% (weight), particularly 0.3-10% (weight).
The example that is used as the polysiloxanes of component (c) comprises dimethyl polysiloxane, polyether-modified polysiloxanes, amino modified polysiloxanes, carboxy-modified polysiloxanes, methyl phenyl silicone, fatty acid modified polysiloxanes, the polysiloxanes of aliphatic alcohol modification, the polysiloxanes of epoxide modification, the polysiloxanes of fluorine modification, cyclic polysiloxanes, and alkyl-modified polysiloxanes.Wherein preferred dimethyl polysiloxane, polyether-modified polysiloxanes and amino modified polysiloxanes.Adopt dimethyl polysiloxane, polyether-modified polysiloxanes and amino modified polysiloxanes can make hair have good lubricity respectively as component (c), slickness and the sense of touch of moistening.For dimethyl polysiloxane, according to its required sense of touch its can to adopt viscosity be 5mm
2/ s-10,000,000mm
2/ s.Viscosity is 10,000,000mm
2The dimethyl polysiloxane of/s provides with emulsion form usually.Wherein preferred viscosities is 5,000-10,000,000mm
2/ s, particularly 50,000-10,000,000mm
2/ s.Polyether-modified polysiloxanes is the upper title of polyoxyethylene methyl polysiloxane copolymer and poly-(oxygen ethylene oxy propylene) methyl polysiloxane.It is known that polyether-modified polysiloxanes has different HLB.Commercially available those comprise that " polysiloxanes KF351A, KF353A, KF6008, KF6016, KF6011 and KF6012 " (is trade name; The product of Shin-Etsu Chemical), and " SH3771C, 3773C and 3775C " (be trade name; The product of Dow Corning Toray Silicone).In the polyether-modified polysiloxanes, preferably through Griffin method preparation and HLB be those of 4-18, particularly 7-11.In the amino modified polysiloxanes, can adopt amino dimethyl polysiloxane (amodimethicone) oil or emulsified body.Commercially available product comprises " amino dimethyl polysiloxane emulsified body SM8704C " (trade name; And " XF-42B1989 " (trade name the product of Dow Corning Toray Silicone); The product of Toshiba Silicone).
Can two or more these class polysiloxanes are shared.Its addition preferably accounts for the 0.05-20% (weight) of the present composition, more preferably 0.1-10% (weight), particularly 0.5-5% (weight).
The surfactant of component (d) can be used for improving solubilizing power and foam characteristics.The example comprises anion surfactant such as alkylbenzenesulfonate, the alkyl or alkenyl ether sulfate, alkyl or alkenyl sulfate, alkene sulfonate, paraffin sulfonate, saturated or unsaturated fatty acid salt, the alkyl or alkenyl ether carboxylate, α-sulfone soap, N-acyl amino acids surfactant, single or two-phosphoric acid salt surfactant and sulfosuccinate; Amphoteric surfactant such as imidazoline, carbonyl betanin (carbobetaine), amido betaines, sulfobetaines, hydroxyl sulfo betaine and acylamino-sulfobetaines class amphoteric surfactant; Non-ionic surface active agent such as polyoxyalkylene alkyl, the polyoxyalkylene alkene ether, the higher fatty acids sucrose ester, polyglyceryl fatty acid ester, higher fatty acids single ethanol amide or diglycollic amide, polyoxyethylene hydrogenated Oleum Ricini, polyoxyethylene sorbitan fatty acid esters, Polyoxyethylene Sorbitol Fatty Acid Esters, alkyl sugar surfactants, alkyl amine oxide, and alkyl amido amine oxide; Cationic surfactant, as imidazoline open loop class quaternary ammonium salt, quaternary ammonium salt, single (chain alkyl) quaternary ammonium salt and two (chain alkyl) quaternary ammonium salt.
The example of the counter ion counterionsl gegenions of the anion residue of these surfactants comprises: alkali metal ion such as sodium ion and potassium ion, alkaline-earth metal ions such as calcium ion and magnesium ion, ammonium ion, alkanolamine (the monoethanolamine for example that contains 1-3 C2-3 triacontanol group, diethanolamine, triethanolamine and triisopropanolamine).The example of the counter ion counterionsl gegenions of cationic residues comprises halide ion, as chloride ion, and bromide ion and iodide ion, dimethyl sulfate ion and contain the saccharinic acid radical ion.
In these surfactants, preferred especially polyoxyethylene hydrogenated Oleum Ricini, beet alkali ampholytic surface active agent, polyoxyalkylene alkyl and single (chain alkyl) quaternary ammonium salt.
Can two or more these class surfactants are shared.Its addition preferably accounts for the 0.1-10% (weight) of the present composition, more preferably 0.5-8% (weight), particularly 1-5% (weight).
In the present composition, can add the oiliness composition as required to improve the sense of touch of dry hair.The example comprises: hydrocarbon such as Squalene, squalane, liquid alkanes, liquid isoparaffin and cycloalkane; Glyceride such as Oleum Ricini, Oleum Cocois, mink oil, American Avocado Tree oil and olive oil; Wax such as Cera Flava, whale oil, lanoline and Brazil wax; Higher alcohol such as spermol, oleyl alcohol, stearyl alcohol, isooctadecanol, and 2-octyldodecanol; Ester such as myristic acid octyldodecanol, lauric acid hexanol ester, lactic acid spermaceti alcohol ester, propylene glycolmonostearate, oleic acid oleic alcohol ester, 2 ethyl hexanoic acid hexadecane alcohol ester, isononyl isononanoate and different n-nonanoic acid tridecane alcohol ester; Higher fatty acids such as capric acid, lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid, oleic acid, coco-nut oil fatty acid, isostearic acid and different Palmic acid; And other oil is as iso stearyl glycerin ether and polyoxypropylene butyl ether.
Can two or more these oil are shared.Its addition preferably accounts for 0-50% (weight), particularly 0.5-5% (weight) of the present composition.
In the present composition, can add different typing characteristic and the sense of touch of improving hair of film forming polymer.The example comprises polyvinylpyrrolidonepolymers polymers such as polyvinyl pyrrolidone, vinyl pyrrolidone/vinyl-acetic ester copolymer, vinyl pyrrolidone/vinyl-acetic ester/vinyl propionate base ester terpolymer, vinyl pyrrolidone/alkyl amido acrylate (quaternary ammonium salt) copolymer, vinyl pyrrolidone/acrylate/(methyl) acrylate copolymer, and vinyl pyrrolidone/alkyl amido acrylate/caprolactam copolymer; Acid vinylic-ether polymer such as methyl vinyl ether/Fructus Mali pumilae anhydride alkyl half ester copolymer; Acid polyvinyl acetate base ester polymer, as vinyl-acetic ester/.beta.-methylacrylic acid copolymer, vinyl-acetic ester/.beta.-methylacrylic acid/neodecanoic acid vinyl ester copolymer, and vinyl-acetic ester/.beta.-methylacrylic acid/vinyl propionate base ester copolymer; The acid acrylic acid base polymer, as (methyl) acrylic acid/(methyl) acrylate copolymer, and acrylic acid/alkyl acrylate/alkyl acrylamide copolymer; The both sexes acrylic polymer, as N-methacryl ethyl-N, N-Dimethyl Ammonium α-N-methyl carboxybetaine/butyl methacrylate copolymer, and acrylic acid hydroxypropyl ester/butyl amino-ethyl methacrylate/octyl group amide acrylate copolymer; The alkalescence acrylic polymer is as acrylamide acrylate quaternary copolymer; Cellulose derivative such as cationic cellulose derivative, and chitin chitosan derivatives, as hydroxypropyl chitosan, carboxymethyl chitosan, and carboxymethyl chitosan.
Can two or more these film forming polymers are shared.Its addition preferably accounts for 0.1-10% (weight), particularly 0.5-5% (weight) of the present composition.
Can add ethanol, glycerol, propylene glycol or dipropylene glycol in the present composition, its content is preferably 1-40% (weight), particularly 3-20% (weight).
The pH (under 25 ℃) that is applicable to compositions of the present invention preferably is adjusted in 2.5-6.0 especially in 3.0 to 5.0 scopes.For this reason, can add above-mentioned organic acid such as citric acid or lactic acid, mineral acid or alkaline components such as sodium hydroxide.
Prepare non-aerosol type hair cosmetic foam of the present invention by in the foam discharger, adding the compositions that contains organic acid, organic solvent, polysiloxanes and surfactant.For the foam discharger, can adopt and variously can eject the foamy device of the mixture that contains scheduled volume content and predetermined air amount.The example comprises the squash type foamite system, and it can be used by finger its soft main part of extruding, pumping formula foamite system, and it can and be used by the top cover of pointing the propelling movement pumping mechanism, and the trigger-type distributor.
The example of squash type foamite system is included in Japanese Utility Model and discloses in 042785/1987,042786/1987 and 042787/1987 those that describe, and prepared therefrom those; The example of pumping formula foamite system is included in those disclosed in day disclosure special permission communique 315463/1995 and 230961/1996, and prepared therefrom those.Many these class containers add net to improve the foam quality that is ejected at its floss hole place.Wherein preferably add the container of one or two 100-300 order net.
Cosmetic composition for hair of the present invention is preferably used as hairspray or hair conditioner.
Embodiment
Embodiment 1
Each component shown in the mixture table 1, and in the compositions adding pumping formula foamite system (add two nets, is 200 order nets, and another is 250 order nets) with gained, prepare the hair cosmetic foam thus.Assess according to content as described below.Gained the results are shown in Table 1.
(appraisal procedure)
The assessment panel of being made up of 5 experts is allocated in its hand with compositions through pumping formula foamite system respectively, and observes foamy situation.
20g is added shampoo through the straight hair bundle of 2 bleachings with hands clean, the expert makes pumping formula foamite system discharge compositions once more, and applies 2g on topknot.After the drying, the sense of touch after neutralization is used is used in assessment.Then a hair in the topknot is wrapped on the tinsel that diameter is 1mm, and by electron microscope observation hair top layer.
Each assessed value is divided into 5 grades, is respectively 1 (poor), 2 (not too poor), 3 (not being easy to make commentary), 4 (good slightly) and 5 (good), and calculating mean value.Assessment to the breaking degree on hair top layer is divided into 3 grades, is respectively C (fracture), B (slight inhibitory action), and A (significant inhibitory effect).
Table 1 % (weight)
| Component | Product of the present invention | Contrast product | ||||||
| 1 | 2 | 3 | 4 | 1 | 2 | 3 | ||
| Glycolic | 1.0 | - | - | - | - | - | 1.0 | |
| Malic acid | - | 0.5 | 0.5 | 1.0 | - | - | - | |
| BOE | 1.0 | 0.5 | 0.5 | - | 0.5 | - | - | |
| Benzylalcohol | - | - | 0.5 | - | - | - | - | |
| Allyl carbonate | - | - | - | 1.0 | - | - | - | |
| Polyoxypropylene (9) two glycerin ethers (" SY-DP9 ", the product of Sakamoto Seiyaku) | 1.5 | 1.5 | 1.5 | - | 1.5 | - | 1.5 | |
| Polyoxypropylene (14) two glycerin ethers (" SY-DP14 ", the product of Sakamoto Seiyaku) | - | - | - | 1.5 | - | - | - | |
| Polyoxypropylene (9) sorbitol ester | 1.0 | 1.0 | - | - | - | - | - | |
| Polyoxypropylene methylglycoside (" Glucopolyol PP-25 ", the product of NOF company) | - | - | 1.0 | 1.0 | - | - | - | |
| Dimethyl polysiloxane (5000mm 2/s) | 2.0 | - | - | - | - | - | 2.0 | |
| Methyl phenyl silicone (100mm 2/s) | - | - | - | - | - | 2.0 | - | |
| Dimethyl polysiloxane emulsified body (" BY22-060 ", the product of Dow Corning Toray Silicone) | - | 1.5 | 2.0 | 2.0 | - | - | - | |
| Dimethyl polysiloxane polyoxyalkylene copolymers (" KF353A ", the product of Shin-Etsu Chemical) | 3.0 | - | - | - | 3.0 | - | 3.0 | |
| Amino modified polysiloxanes (" KT-1989 ", the product of GE Toshiba Silicone) | 0.5 | - | 0.5 | - | 0.5 | - | 0.5 | |
| Amino dimethyl polysiloxane emulsified body (product of " SM-8704C, Dow Corning Toray Silicone ") | - | 1.0 | 1.0 | 1.0 | - | - | - | |
| Polyoxyethylene (20) Arlacel-20 | 3.0 | 1.0 | - | - | 3.0 | 3.0 | 3.0 | |
| Polyoxyethylene (25) castor oil hydrogenated | - | 0.5 | 0.5 | 0.5 | - | - | - | |
| Polyoxyethylene (60) castor oil hydrogenated | - | 1.5 | 1.5 | 1.5 | - | - | - | |
| Polyoxyethylene (9) lauryl ether | - | - | 1.0 | 1.0 | - | - | - | |
| The stearyl trimethyl ammonium chloride | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |
| Propylene glycol | 2.0 | - | - | - | 2.0 | 2.0 | 2.0 | |
| Dipropylene glycol | - | 2.0 | 2.0 | 2.0 | - | - | - | |
| Spice | Trace | Trace | Trace | Trace | Trace | Trace | Trace | |
| 95 ° of modification alcohol | 15.0 | 10.0 | 10.0 | 10.0 | 15.0 | 10.0 | 15.0 | |
| Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| pH | 3.5 | 4.0 | 3.5 | 3.5 | 6.5 | 6.5 | 7.0 | |
| Assessed value | Foamy slickness | 4.8 | 4.6 | 4.6 | 4.6 | 2.8 | 4.0 | 4.6 |
| Foamy crush resistance | 4.6 | 4.6 | 4.6 | 4.4 | 2.2 | 2.8 | 4.4 | |
| The easily property used to hair | 4.6 | 4.8 | 4.8 | 4.6 | 2.4 | 2.2 | 4.6 | |
| Slickness when on hair, using | 4.4 | 4.6 | 4.6 | 4.4 | 2.2 | 2.2 | 4.4 | |
| The dried slickness of hair drying device | 4.2 | 4.4 | .4 | 4.6 | 2.4 | 2.4 | 4.6 | |
| Use the flexibility of back hair | 5.0 | 4.6 | 4.6 | 4.8 | 2.2 | 2.2 | 2.2 | |
| Use the non-hardenability of back hair | 4.6 | 4.6 | 4.6 | 4.6 | 2.4 | 2.4 | 4.2 | |
| The fracture on hair top layer | A | A | A | A | C | C | C | |
Claims (4)
1. cosmetic composition for hair, it contains (a) and is selected from monocarboxylic acid, dicarboxylic acids, hydroxy carboxylic acid or polycarboxylic organic acid by adding in non-aerosol type foam discharger, (b) be selected from the organic solvent of benzylalcohol, BOE and Allyl carbonate, (c) polysiloxanes, (d) compositions of surfactant and making
The content of described component (a) is, is 0.05～20 weight % in described compositions,
The content of described component (b) is, is 0.1～20 weight % in described compositions,
The content of described component (c) is, is 0.05～20 weight % in described compositions,
The content of described component (d) is, is 0.1～10 weight % in described compositions.
2. the cosmetic composition for hair of claim 1, wherein the organic acid as component (a) is dicarboxylic acids or hydroxy carboxylic acid.
3. claim 1 or 2 cosmetic composition for hair, wherein the polysiloxanes of component (c) is selected from dimethyl polysiloxane, polyether-modified polysiloxanes and amino modified polysiloxanes.
4. each cosmetic composition for hair of claim 1～3 wherein also contains polypropylene glycol or polyethenoxy ether.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001243779A JP4619581B2 (en) | 2001-08-10 | 2001-08-10 | Hair cosmetics |
| JP243779/2001 | 2001-08-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1404818A CN1404818A (en) | 2003-03-26 |
| CN1229098C true CN1229098C (en) | 2005-11-30 |
Family
ID=19073817
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02128578 Expired - Fee Related CN1229098C (en) | 2001-08-10 | 2002-08-09 | Hair cosmetic composition |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP4619581B2 (en) |
| CN (1) | CN1229098C (en) |
| TW (1) | TWI225408B (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4381165B2 (en) * | 2004-02-24 | 2009-12-09 | 花王株式会社 | Hair cosmetics |
| JP4381169B2 (en) | 2004-02-27 | 2009-12-09 | 花王株式会社 | Hair cosmetics |
| JP4422508B2 (en) * | 2004-02-27 | 2010-02-24 | 花王株式会社 | Hair cosmetics |
| JP4210614B2 (en) | 2004-03-25 | 2009-01-21 | 花王株式会社 | Hair cosmetics |
| JP4185467B2 (en) | 2004-03-25 | 2008-11-26 | 花王株式会社 | Hair cosmetics |
| JP4469688B2 (en) | 2004-08-31 | 2010-05-26 | 花王株式会社 | Hair cosmetics |
| JP4931374B2 (en) * | 2005-06-20 | 2012-05-16 | 花王株式会社 | Hair cosmetics |
| JP4756249B2 (en) * | 2006-11-07 | 2011-08-24 | 山栄化学株式会社 | Multi-agent hair cosmetic |
| EP2213277B1 (en) * | 2007-11-27 | 2017-07-19 | Kao Corporation | Hair care product |
| EP2153836A1 (en) * | 2008-08-04 | 2010-02-17 | Polichem S.A. | Film-forming liquid formulations for drug release to hair and scalp |
| JP5669485B2 (en) * | 2009-11-30 | 2015-02-12 | 花王株式会社 | Two-component hair dye |
| JP5369153B2 (en) * | 2010-08-31 | 2013-12-18 | 花王株式会社 | Two-component foam hair dye |
| WO2015005419A1 (en) * | 2013-07-11 | 2015-01-15 | 株式会社ポーラファルマ | External-use composition producing foamed state upon use |
| JP6288823B2 (en) * | 2013-11-29 | 2018-03-07 | クラシエホームプロダクツ株式会社 | Foam hair cosmetic |
| JP6396231B2 (en) * | 2014-01-27 | 2018-09-26 | 株式会社ポーラファルマ | Pharmaceutical composition for external use which exhibits foam when used |
| JP6396229B2 (en) * | 2014-01-27 | 2018-09-26 | 株式会社ポーラファルマ | Pharmaceutical composition for external use which exhibits foam when used |
| JP6396230B2 (en) * | 2014-01-27 | 2018-09-26 | 株式会社ポーラファルマ | Pharmaceutical composition for external use which exhibits foam when used |
| JP2016121145A (en) * | 2014-12-24 | 2016-07-07 | 株式会社ポーラファルマ | External composition for screen foamer |
| FR3097754B1 (en) * | 2019-06-27 | 2023-10-13 | Oreal | Process for repairing keratin fibers using a particular cyclic polycarbonate and an aminated silicone and uses |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10167938A (en) * | 1996-12-05 | 1998-06-23 | Kanebo Ltd | Foamy hair treatment agent |
-
2001
- 2001-08-10 JP JP2001243779A patent/JP4619581B2/en not_active Expired - Fee Related
-
2002
- 2002-07-31 TW TW91117145A patent/TWI225408B/en not_active IP Right Cessation
- 2002-08-09 CN CN 02128578 patent/CN1229098C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1404818A (en) | 2003-03-26 |
| JP4619581B2 (en) | 2011-01-26 |
| JP2003055160A (en) | 2003-02-26 |
| TWI225408B (en) | 2004-12-21 |
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Granted publication date: 20051130 Termination date: 20190809 |