CN1227244A - Adhesive for colour glazed glass - Google Patents
Adhesive for colour glazed glass Download PDFInfo
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- CN1227244A CN1227244A CN 99114058 CN99114058A CN1227244A CN 1227244 A CN1227244 A CN 1227244A CN 99114058 CN99114058 CN 99114058 CN 99114058 A CN99114058 A CN 99114058A CN 1227244 A CN1227244 A CN 1227244A
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- glazed glass
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Abstract
The adhesive consists of two components, the component A consists of E51 epoxy resin 30-60%, epoxy propane butyl ether 5-15%, 664 epoxy resin 5-15% and filler 30-70% and the component B consists of 650 polyamide resin 20-50%, T31 curing agent 10-25%, silicon tackifier 1-10% and filler 30-70%. When the adhesive is used, two components, A and B, are compounded in the weight ratio of 1-2 to 1. The adhesive has high adhesion strength and good weather-resistance.
Description
The present invention relates to a kind of parian colored glazed glass stickup and stick with glue agent.This tackiness agent sticks with glue the agent as decorating inner and external walls except being used for colored glazed glass, still can be used for the stickup of multiple materials such as other glass material, pottery, stone material.
Along with the continuous appearance of building material, a kind of replica technique or emulation printing technology with the advanced person copy to famous and precious marble pattern and color on the surface of plate glass, handle the colored glazed glass of making through tempering again and have come out.It has surface luster good, wear-resisting, corrosion-resistant, from advantages such as heavy and lights, be the new brand of building and ornament materials.But in construction, still do not have ideal at present and paste glue.Because the glass surface state and the singularity of immanent structure wherein, bonding strength and weather resistance that stone material commonly used, ceramic tile are pasted glue do not satisfy engine request, even produce the major accident that full wafer glass comes off, brought difficulty for applying of colored glazed glass.
Purpose of the present invention will be developed a kind of tackiness agent exactly, satisfies bonding strength and the environmental resistance of construction work exterior wall finish glass bonding with glue on physicochemical property, satisfies the basic demand of building operation standard on operative weldability.
Realize that technical solution of the present invention is: a kind of adhesive for colour glazed glass, it is formed part by first, second two and forms, weighing in proportion, allotment during use, wherein:
A) first component prescription
E-51 or E-44 epoxy resin 30～60% (weight)
Epoxy propane butyl ether or propylene oxide phenyl ether or
Diglycidylether 5～15% (weight)
664 epoxy resins 5～15% (weight)
Filler 30～70 (weight)
The summation of each component is 100% (weight)
B) component B prescription
650 or 651 polyamide resins 20～50% (weight)
T31 solidifying agent 10～25% (weight)
Silane adhesion promoters 1～10% (weight)
Filler 30～70% (weight)
The each component summation is 100% (weight)
C) use proportioning first component: component B=(1～2): 1 (weight)
Compare with existing all kinds of adhesive for building, the present invention has selected the material of main part of the good epoxy resin of bonding strength height, moisture-proof heat, chemical resistance as this tackiness agent for use, improve over-all properties such as its anti-environment by various properties-correcting agent, reach the better adhesives of glass material therefore its bonding strength height, good weatherability, use the no glass obscission in back by adding tackifier.Be specially adapted to the stickup of colored glazed glass.
Fig. 1 is a first component technological process of production block diagram of the present invention.
Fig. 2 is a component B technological process of production block diagram of the present invention.
Below in conjunction with accompanying drawing the present invention is made a detailed description:
One, adhesive formulation
1, first component prescription
Epoxy resin (E-51 or E-44) 30～60% (weight)
Propylene oxide butyl ether (or propylene oxide phenyl ether or diglycidylether) 5～15% (weight)
664 epoxy resins 5～15% (weight)
Filler (lime carbonate, china clay, talcum powder, asbestos powder etc.) 30～70% (weight)
The summation of each component is 100% (weight)
2, component B prescription
650 polyamide resins (or 651 polymeric amide), 20～50% (weight)
T31 solidifying agent 10～25% (weight)
Silane adhesion promoters 1～10% (weight)
Filler (with the first component) 30～70% (weight)
The summation of each component is 100% (weight)
Two, use proportioning
First group: second group=(1～2): 1 (weight ratio) carried out weighing, allotment.Or first group: second group=(1.3～1.7): 1
Three, production technique
1, first component production technique (Fig. 1)
All the other each components that take by weighing except that filler by first component prescription place on the reaction vessel, at room temperature stir 30～60min, add the needed filler of prescription then while stirring, and it is above until the viscous fluid that is uniformity, discharging, encapsulation to stir 60min.
2, component B production technique
Take by weighing other each components except that filler by the component B prescription, place reaction vessel, at room temperature stir 30～60min, add the needed filler of prescription then while stirring, stir more than the 60min, until the viscous fluid that is uniformity, discharging, encapsulation.
Embodiment
At first prepare tackiness agent first component: take by weighing E-51 epoxy resin 20Kg, epoxy propane butyl ether 3Kg, 664 epoxy resin 1kg, place container, at room temperature stir 30～60min, progressively add lime carbonate 4.5kg, talcum powder 17.5kg then while stirring, stir about 60min, to material be evenly, discharging during no particle viscous fluid, pack for one barrel by 3kg.
Next prepares the tackiness agent component B: take by weighing 650 polyamide resin 15kg, T31 solidifying agent 1.5kg, silane adhesion promoters 2.5kg, place the cleaning drying receptacle, at room temperature stir 30～60min, add lime carbonate 7kg, talcum powder 6kg then while stirring, stir about 60min to material be evenly, discharging during no particle viscous fluid, pack for one barrel by 2kg.
The physicochemical property of this tackiness agent:
The faint yellow even paste of outward appearance
23 ℃ of working lives be not less than 1h
23 ℃ of curing periods be not more than 24h
Shrinkability is less than 0.5%
Acid resistance 5%Hcl, 24h no change
Alkali resistance 5%NaoH, 24h no change
Glued joint former intensity Mpa maintenance 14d 13.4
Water tolerance Mpa maintenance 7d, immersion 7d 15.5
Temperature tolerance Mpa maintenance 7d, 70 ℃ of 7d 16.3
Freeze-thaw resistance Mpa (25 times) maintenance 7d ,-15 ℃ of 4h, 20 ℃ of 4h, 16.7
Artificial ageing resistance Mpa 1000h 11.7
The present invention is owing to from glass molecular structure surface state, design the prescription of adhesive, therefore Physicochemical property at adhesive has remarkable advantage than existing like product. To existing several on city's field boundary Kind roughly the same adhesive has been made the stickup application test, and the result shows 1:
Several adhesive for colour glazed glass application performance comparison sheets 1
| Adhesive | Adhesive material | Sticking to environment | Bonding area | Sticking effect |
| Early spring cement gel | Colored glazed glass and cement wall surface | Workshop, our factory exterior wall | 8 of 500*500 | Less than one month, 6 sheet glass are arranged |
| Wish nation's glue | The same | Factory gate, enclosure wall | 200m 2 | After five months, there are 46 sheet glass full wafers to come off |
| The present invention | The same | The same | 300m 2 | So far (21 months) no glass came off in nearly 2 years |
Claims (3)
1, a kind of adhesive for colour glazed glass is characterized in that it forms part group by first, second two, wherein:
A) first component prescription
E-51 or E-44 epoxy resin 30～60% (weight)
Epoxy propane butyl ether or propylene oxide phenyl ether or
Diglycidylether 5～15% (weight)
664 epoxy resins 5～15% (weight)
Filler 30～70 (weight)
The summation of each component is 100% (weight)
B) component B prescription
650 or 651 polyamide resins 20～50% (weight)
T31 solidifying agent 10～25% (weight)
Silane adhesion promoters 1～10% (weight)
Filler 30～70% (weight)
The each component summation is 100% (weight)
C) use proportioning first component: component B=(1～2): 1 (weight)
2, a kind of adhesive for colour glazed glass according to claim 1 is characterized in that the filler in first, second two components is lime carbonate, china clay, talcum powder, asbestos powder etc.
3, a kind of adhesive for colour glazed glass according to claim 1 is characterized in that the use proportioning of first, second two components is (1.3～1.7): 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114058A CN1089793C (en) | 1999-02-02 | 1999-02-02 | Adhesive for colour glazed glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114058A CN1089793C (en) | 1999-02-02 | 1999-02-02 | Adhesive for colour glazed glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1227244A true CN1227244A (en) | 1999-09-01 |
| CN1089793C CN1089793C (en) | 2002-08-28 |
Family
ID=5277182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99114058A Expired - Fee Related CN1089793C (en) | 1999-02-02 | 1999-02-02 | Adhesive for colour glazed glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1089793C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962516B (en) * | 2005-11-10 | 2010-12-01 | 上海鹏业化工材料有限公司 | Environment-friendly high temperature glass wool adhesive |
| CN102634311A (en) * | 2012-03-27 | 2012-08-15 | 高玉启 | Ceramic fiber modified wear-resistance adhesive |
| CN103992623A (en) * | 2014-06-11 | 2014-08-20 | 湖北华宁防腐技术股份有限公司 | Repairing material for hard rubber anticorrosive linings and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4728384A (en) * | 1986-06-23 | 1988-03-01 | Ashland Oil, Inc. | Two component epoxy structural adhesives with improved flexibility |
| JPH0613677B2 (en) * | 1986-09-03 | 1994-02-23 | 東亞合成化学工業株式会社 | Primer |
| JPH02284982A (en) * | 1989-04-27 | 1990-11-22 | Toray Chiokoole Kk | Adhesive composition |
| CN1074469A (en) * | 1992-01-18 | 1993-07-21 | 沈阳工业学院 | 901 rapid strong glue and preparation method thereof |
-
1999
- 1999-02-02 CN CN99114058A patent/CN1089793C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962516B (en) * | 2005-11-10 | 2010-12-01 | 上海鹏业化工材料有限公司 | Environment-friendly high temperature glass wool adhesive |
| CN102634311A (en) * | 2012-03-27 | 2012-08-15 | 高玉启 | Ceramic fiber modified wear-resistance adhesive |
| CN102634311B (en) * | 2012-03-27 | 2014-05-21 | 高玉启 | Ceramic fiber modified wear-resistance adhesive |
| CN103992623A (en) * | 2014-06-11 | 2014-08-20 | 湖北华宁防腐技术股份有限公司 | Repairing material for hard rubber anticorrosive linings and preparation method thereof |
| CN103992623B (en) * | 2014-06-11 | 2016-08-17 | 湖北华宁防腐技术股份有限公司 | A kind of patching material for vulcanie corrosion protective lining and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1089793C (en) | 2002-08-28 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20020828 Termination date: 20110202 |