CN1089793C - Adhesive for colour glazed glass - Google Patents
Adhesive for colour glazed glass Download PDFInfo
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- CN1089793C CN1089793C CN99114058A CN99114058A CN1089793C CN 1089793 C CN1089793 C CN 1089793C CN 99114058 A CN99114058 A CN 99114058A CN 99114058 A CN99114058 A CN 99114058A CN 1089793 C CN1089793 C CN 1089793C
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Abstract
The present invention relates to an adhesive for bonding colored glaze glass imitating marble, which is composed of a component A and a component B. The component A and the component B are weighed and prepared in proportion when used, wherein a recipe of the component A comprises 30 to 60% of E51 epoxy resin, 5 to 15% of epoxy propane butyl ether, 5 to 15% of 664 epoxy resin and 30 to 70% of filler. A formula of the component B comprises 20 to 50% of 650 polyamide resin, 10 to 25% of T31 curing agent, 1 to 10% of silicane viscosity increaser and 30 to 70% of the filler. The component A and the component B have the use formula that the component A to the component B is equal to (1 to 2): 1. The adhesive has the advantages of high bonding strength and good weather resistance, and does not have a glass shedding phenomenon when used.
Description
The present invention relates to a kind of parian colored glazed glass stickup and stick with glue agent.This tackiness agent sticks with glue the agent as decorating inner and external walls except being used for colored glazed glass, also can be used for the stickup of multiple materials such as other glass material, pottery, stone material.
Along with the continuous appearance of building material, a kind of replica technique or emulation printing technology with the advanced person copy to famous and precious marble pattern and color on the surface of plate glass, handle the colored glazed glass of making through tempering again and have come out.It has surface luster good, wear-resisting, corrosion-resistant, from advantages such as heavy and lights, be the new brand of building decoration.But in construction, still do not have ideal at present and paste glue.Because the glass surface state and the singularity of immanent structure wherein, bonding strength and weather resistance that stone material commonly used, ceramic tile are pasted glue do not satisfy engine request, even produce the major accident that full wafer glass comes off, brought difficulty for applying of colored glazed glass.
Purpose of the present invention will be developed a kind of tackiness agent exactly, satisfies bonding strength and the environmental resistance of construction work exterior wall finish glass bonding with glue on physicochemical property, satisfies the basic demand of building operation standard on operative weldability.
Realize that technical solution of the present invention is: a kind of color axle glass cement stick, it is formed part by first, second two and forms, weighing in proportion, allotment during use, wherein:
A) first component prescription
E-51 or E-44 Resins, epoxy 30～60% (weight)
Epoxy propane butyl ether or propylene oxide phenyl ether or diglycidylether 5～15% (weight)
664 Resins, epoxy 5～15% (weight)
Filler 30～70% (weight)
The summation of each component is 100% (weight);
B) component B prescription
650 or 651 polyamide resins 20～50% (weight)
T31 solidifying agent 10～25% (weight)
Silane adhesion promoters 1～10% (weight)
Filler 30～70% (weight)
The each component summation is 100% (weight);
C) use proportioning first component: component B=1～2: 1 (weight).
Compare with existing all kinds of adhesive for building, the present invention has adopted the material of main part of the good epoxy resin of bonding strength height, moisture-proof heat, chemical resistance as this tackiness agent, improve over-all propertieies such as its anti-environment by various properties-correcting agent, reach the adhesives better glass material by adding tackifier.Therefore its bonding strength height, good weatherability are used the no glass obscission in back.Be specially adapted to the stickup of colored glazed glass.
Fig. 1 is first component technological process of production figure of the present invention.
Fig. 2 is component B technological process of production figure of the present invention.
Below in conjunction with accompanying drawing the present invention is described in further detail:
One, adhesive formulation
1, first component prescription
Epoxy resin (E-51 or E-44) 30～60% (weight)
Epoxy propane butyl ether (or expoxy propane phenyl ether or diglycidyl ether) 5～15% (weight)
664 epoxy resin 5～15% (weight)
Filler (calcium carbonate, china clay, talcum powder, flake asbestos etc.) 30～70% (weight)
The summation of each component is 100% (weight).
2, component B prescription
650 polyamides (or 651 polyamide), 20～50% (weight)
T31 curing agent 10～25% (weight)
Silane adhesion promoters 1～10% (weight)
Filler (with the first component) 30～70% (weight)
The summation of each component is 100% (weight).
Two, use proportioning
First group: second group=1～2: 1 (weight ratio) carried out weighing, allotment. Or first group: second group=1.3～1.7: 1.
Three, production technique
1, first component production technique (Fig. 1)
All the other each components that take by weighing except that filler by first component prescription place on the reaction vessel, at room temperature stir 30～60min, add the needed filler of prescription then while stirring, and it is above until the viscous fluid that is uniformity, discharging, encapsulation to stir 60min.
2, component B production technique
Take by weighing other each components except that filler by the component B prescription, place on the reaction vessel, at room temperature stir 30～60min, add the needed filler of prescription then while stirring, stir more than the 60min, until the viscous fluid that is uniformity, discharging, encapsulation.
Embodiment:
At first prepare tackiness agent first component: take by weighing E-51 Resins, epoxy 20kg, epoxy propane butyl ether 3kg, 664 Resins, epoxy 1kg, place container, at room temperature stir 30～60min, progressively add lime carbonate 4.5kg, talcum powder 17.5kg then while stirring, stir about 60min, to material be evenly, discharging during no particle viscous fluid, pack for one barrel by 3kg.
Next prepares the tackiness agent component B; Take by weighing 650 polyamide resin 15kg, T31 solidifying agent 1.5kg, silane adhesion promoters 2.5kg, place the cleaning drying receptacle, at room temperature stir 30～60min, add lime carbonate 7kg, talcum powder 6kg then while stirring, stir about 60min to material be evenly, discharging during no particle viscous fluid, pack for one barrel by 2kg.
The physicochemical property of this tackiness agent:
The faint yellow even paste of outward appearance
23 ℃ of working lives be not less than 1h
23 ℃ of curing periods be not more than 24h
Shrinkability is less than 0.5%
Acid resistance 5% Hcl, 24h no change
Alkali resistance 5% NaoH, 24h no change
Glued joint former intensity Mpa maintenance 14d 13.4
Water tolerance Mpa maintenance 7d, immersion 7d 15.5
Temperature tolerance Mpa maintenance 7d, 70 ℃ of 7d 16.3
7 ,-15 ℃ of 4h of freeze-thaw resistance Mpa (25 times) maintenance, 20 ℃ of 4h, 16.7
Artificial ageing resistance Mpa 1000h 11.7
The present invention is owing to from glass molecular structure surface state, design the prescription of adhesive, therefore Physicochemical property at adhesive has remarkable advantage than existing like product. To existing several on the market Plant roughly the same adhesive stickup application test, the results are shown in Table 1:
Several adhesive for colour glazed glass application performance comparison sheets 1
| Adhesive | Adhesive material | Sticking to environment | Bonding area | Sticking effect |
| Early spring cement gel | Colored glazed glass and cement wall surface | Workshop, our factory exterior wall | 8 of 500*500 | Less than one month, there are 6 sheet glass to come off |
| Wish nation's glue | The same | Factory gate, enclosure wall | 200m2 | After five months, there are 46 sheet glass full wafers to come off |
| The present invention | The same | The same | 300m2 | So far (21 months) no glass came off in nearly 2 years |
Claims (3)
1, a kind of color axle glass cement stick is characterized in that it forms part by first, second two and form, wherein:
A) first component prescription
E-51 or E-44 Resins, epoxy 30～60% (weight)
Epoxy propane butyl ether or propylene oxide phenyl ether or diglycidylether 5～15% (weight)
664 Resins, epoxy 5～15% (weight)
Filler 30～70% (weight)
The summation of each component is 100% (weight);
B) component B prescription
650 or 651 polyamide resins 20～50% (weight)
T31 solidifying agent 10～25% (weight)
Silane adhesion promoters 1～10% (weight)
Filler 30～70% (weight)
The each component summation is 100% (weight);
C) use proportioning first component: component B=1～2: 1 (weight).
2, a kind of adhesive for colour glazed glass according to claim 1 is characterized in that the filler in first, second two components is lime carbonate, china clay, talcum powder or asbestos powder.
3, a kind of adhesive for colour glazed glass according to claim 1, the use proportioning that it is characterized in that first, second two components is 1.3～1.7: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114058A CN1089793C (en) | 1999-02-02 | 1999-02-02 | Adhesive for colour glazed glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114058A CN1089793C (en) | 1999-02-02 | 1999-02-02 | Adhesive for colour glazed glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1227244A CN1227244A (en) | 1999-09-01 |
| CN1089793C true CN1089793C (en) | 2002-08-28 |
Family
ID=5277182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99114058A Expired - Fee Related CN1089793C (en) | 1999-02-02 | 1999-02-02 | Adhesive for colour glazed glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1089793C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962516B (en) * | 2005-11-10 | 2010-12-01 | 上海鹏业化工材料有限公司 | Environment-friendly high temperature glass wool adhesive |
| CN102634311B (en) * | 2012-03-27 | 2014-05-21 | 高玉启 | Ceramic fiber modified wear-resistance adhesive |
| CN103992623B (en) * | 2014-06-11 | 2016-08-17 | 湖北华宁防腐技术股份有限公司 | A kind of patching material for vulcanie corrosion protective lining and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4728384A (en) * | 1986-06-23 | 1988-03-01 | Ashland Oil, Inc. | Two component epoxy structural adhesives with improved flexibility |
| JPS6363758A (en) * | 1986-09-03 | 1988-03-22 | Toagosei Chem Ind Co Ltd | Primer |
| JPH02284982A (en) * | 1989-04-27 | 1990-11-22 | Toray Chiokoole Kk | Adhesive composition |
| CN1074469A (en) * | 1992-01-18 | 1993-07-21 | 沈阳工业学院 | 901 rapid strong glue and preparation method thereof |
-
1999
- 1999-02-02 CN CN99114058A patent/CN1089793C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4728384A (en) * | 1986-06-23 | 1988-03-01 | Ashland Oil, Inc. | Two component epoxy structural adhesives with improved flexibility |
| JPS6363758A (en) * | 1986-09-03 | 1988-03-22 | Toagosei Chem Ind Co Ltd | Primer |
| JPH02284982A (en) * | 1989-04-27 | 1990-11-22 | Toray Chiokoole Kk | Adhesive composition |
| CN1074469A (en) * | 1992-01-18 | 1993-07-21 | 沈阳工业学院 | 901 rapid strong glue and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1227244A (en) | 1999-09-01 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20020828 Termination date: 20110202 |