CN1226136A - Phosphate composition and its use - Google Patents
Phosphate composition and its use Download PDFInfo
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- CN1226136A CN1226136A CN 96180411 CN96180411A CN1226136A CN 1226136 A CN1226136 A CN 1226136A CN 96180411 CN96180411 CN 96180411 CN 96180411 A CN96180411 A CN 96180411A CN 1226136 A CN1226136 A CN 1226136A
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Abstract
The invention deals with phosphate water solution with cold solidification capacity. Phosphate composition containing iron oxide solution in acid, water, advantages from the following properties; it contains orthophosphorus acid and in addition metal powder. Phosphate composition is ecologically pure product, non toxic, non cancerogenic, non-allergic. It has antimicrobial, antivirus and fungicidal properties. Phosphate composition can be applied within medicine: surgery, dermatology, dentistry, oncology, pharmacology and other branches. In agriculture use: as a means of curing plant diseases, within veterinary- as a means for preventive maintenance and curing of animal diseases, within construction- as an anticorrosive, fire-resistant, hydro-electric isolating covers, ceramic tiles, concretes, which protect against radiation, as well as for producing other composite materials.
Description
The present invention relates to medicine, agricultural, penkeeping and building field.The present invention relates to have the aqueous solution of cold curing ability, this aqueous solution is known as mineral binder or astringent, and is by orthophosphoric acid, pyrophosphoric acid, triphosphoric acid, polyphosphoric acid or any other phosphoric acid synthetic oxide, phosphate or metal.They can be used in the field of medicaments: surgery, dept. of dermatology, dentistry, oncology, pharmacy and other branch.Can be used for agriculture field: the treatment plant disease; In veterinary applications: prevention and treatment Animal diseases; At building field: as the cover layer of corrosion-resistant, fire-resistant, ornamental, isolated water power, radiation-resistant ceramic tile, concrete, and make other composite.
The example of well-known phosphate binder has the phosphate binder that comprises zinc and aluminium and comprises aluminium and the phosphate binder of magnesium, by thermal treatment, they all can be used to make dental cement in dentistry, and are used to make fire-resistant cover layer (1,2) in building field.The phosphate binders of calcic can be used for making toothpaste, can be used as the composition of animal feed, can be used for making corrosion-resistant and fire-resistant cover layer (1,2) in the building field by thermal treatment.
The example that also has phosphate binders for example comprises the phosphate binders (3) of polyphosphoric acid iron, polyphosphoric acid and water.It can be by adding Fe in orthophosphoric acid
2O
3Further boil then and make.During boiling, produce steam and poly condensation product, iron and tripolyphosphate.The phosphate binders that so obtains can be used to make refractory material by thermal treatment.
The selected prototype scheme of the present invention is the phosphate composition (4) as binding agent, said composition is included in iron oxide solution, water and the other macromolecule polysaccharide or derivatives thereof in the polyphosphoric acid, and the ratio of each component is (weight portion): polyphosphoric acid 100, iron oxide 36-53, macromolecule polysaccharide or derivatives thereof 0.5-3.5, water 15-30.The defective of said composition is the manufacturing cost height, and this is because (ⅰ) can not effectively utilize polyphosphoric acid and electricity (heat) power; (ⅱ) solution is toxic since in boiling part after being dissolved in polysaccharide in the acid environment, the solvable and gaseous matter of harmfulness appears; (ⅲ) solidifying required thermal treatment is the feature of polyphosphate.
The objective of the invention is to reduce manufacturing cost, toxicity and cold curing time, it realizes by get rid of polyphosphoric acid and polysaccharide from composition, and the present invention has also removed and processes required electricity (heat) energy.
The result who replaces invalid and expensive polyphosphoric acid with orthophosphoric acid is to have reduced the composition manufacturing cost, and increased the cold curing ability.Synthesis step need not to provide electricity (heat) energy by extra power, and only is to provide energy by the exothermic reaction of carrying out in the conversion zone, and this has also reduced manufacturing cost.From composition, get rid of polysaccharide and can reduce toxic level.
Phosphate composition of the present invention is following making: add entry, croci and any metal dust such as aluminium in the orthophosphoric acid that calculates with 100% acid, the while continuous stirring, the ratio of these components is following weight portion: the ratio 2-4 of orthophosphoric acid 100 iron oxide 20-41 metal dust 0.5-2.5 water 30-70 phosphate anions and iron ion
The heat that produces in the exothermic reaction (40-50 ℃) is enough to make iron oxide and metal dust dissolving, and this need keep 2 hours.Product is transparent, brown viscous liquid, and its tight ness rating (compactness) is 1.50g/m
3, the ratio of phosphate anion and iron ion is 2.0-4.0.This solution is sustainable to be stablized 2 years.
The weight of iron oxide surpasses 41 in the present composition, will cause the dissolving and the curing of solution, and if be lower than 41, then will reduce the cold curing ability.
Replace the characteristic that aluminium powders will change composition with any other metal dust such as Fe, Ca, Mg, Zn, Co, Ni, Y, Sc etc., promptly, increase or reduction cold curing ability.
Metal dust weight surpasses 2.5 in the conversion zone, will elevate the temperature to 120-130 ℃, and cause the adhesion of dissolved particles, and make orthophosphoric acid root anion be converted into multi-phosphate.If metal dust weighs less than 0.5, the temperature in the conversion zone keeps not becoming, and course of dissolution will need several days time to carry out than jogging speed.
The weight of water surpasses or is lower than normal level in the conversion zone, will destroy required temperature.
Following table 1 and 2 has confirmed the character of liquor ferri phosphatis in the concrete composition.
Different with above-mentioned prototype and analog thereof, phosphate composition of the present invention has sterilization, kills the virus and mycocidal feature.Recorded data shows that in phosphate mixt, only cupric phosphate has microbicidal feature, and recommendedly is used to prepare fungicide.
In scope of the present invention, in the test of the scientific center that relates to concrete dangerous infectious disease that is attached to the State Medical University, theInstitute of Labour Hygiene and Professional Diseases of the HealthMinistry of Georgia, the Institute of Sanitary and Hygiene and the initial stage clinical research that the clinical science research laboratory has carried out phosphate composition of the present invention.
This studies show that the phosphate composition of the present invention in the aqueous solution can be killed plaque microorganism (microbes of plaque), pseudotuberculosis, salmonella, colibacillus, dysentery, golden staphylococcus microorganism, influenza virus, hepatitis viruse, West Nilefever virus and oncovirus (table 3,4).Handle in back 5 minutes, but sterilize instruments, clothes, house, laboratory equipment, patient's ight soil.
For the toxicity of said composition, the inorganic mixture of known 5 valency phosphorus is to one of harmless mixture of people.In addition, the phosphorus of bio-absorbable orthophosphoric acid form, and think PO
4 3-Anion is one of most important composition of the normally physiologically active of biology, regulates the HPO of blood
4 2-/ H
2PO
4 -Buffer system.
The result of the toxicology of phosphate composition of the present invention, Pathomorphology, histology, Pathological Physiology, bacteriology, physiology, biochemical, neurology, immunology research proves, this solution does not change cardiovascular and respiratory system parameter and hepatic and/or renal function, and, do not cause the change of cell to the not influence of immune state of blood index and health on every side.There is not anaphylactoid performance.This solution also has the function of removing the unhappy smell that is distributed.Phosphate composition and to make each method all be Environmental security.
Above-mentioned research proves that solution of the present invention had not both had yet non-carcinogenesis of toxicity, but and external application or drink.
The Georgia Ministry of Public Health (the Health Ministry of Georgia) application of approved phosphate composition of the present invention in field of medicaments.Manufacture method was registered in Georgia Standard June 13 nineteen ninety-five, and registration number is 15420044-001-95, and Tiflis city (theMunicipality ofTbilisi) permits its production on April 19th, 1996.
Phosphate composition of the present invention can be used for: (ⅰ) sterilization in medicine and other various fields (animal doctor, agricultural etc.); (ⅱ) and house, stock, clothes, ight soil are to carry out interim or final sterilization between infective stage; (ⅲ) handle and suspect contaminated article by the article of bacterium and virus infections; (ⅳ) purifying drinking water and liquid dung.
Table 5 has illustrated the amount and the time of the various article of sterilizing.
In Republic Hospital, sepsis and burn treatment center, urology and skin clinical research institute, carried out the clinical research of phosphate composition of the present invention.Prove that phosphate composition of the present invention has corruption and inflammatory process (comparing with furacvcline), pain relieving in the potent prevention wound healing, treatment is scratched where it itches and the feature of fungal disease, deodorizing.Therefore, said composition can be used as antibacterial agent: treatment wound, various skin injury-burn, suppurative dermatitis, trophic ulcer, bedsore, skin cracking etc.Phosphate composition of the present invention also can be used for treating tumour, ephritis, gastritis, colitis, cholecystitis, vaginitis, erosion, ulcer, conjunctivitis, keratitis, oulitis, angina, tonsillitis, pharyngitis, dermatitis, eczema, trichophytosis, hemorrhoid, burn, suppuration and gangrenous sexual trauma, erysipelas, trophic ulcer, perspiration, tumour formation, tumor disease.
The phosphate composition aqueous solution of the present invention can be used for veterinary applications, and microorganism, virus, the fungal disease of treatment animal are as brucellosis, anthrax, tularemia, plaque.
Iron can its organic mixture form be actually used in the treatment anaemia.In these mixtures, the organic mixture such as water-fast glycerine iron phosphate and the phytophero-lactolirthic organic mixture that comprise phosphorus are arranged.These two kinds of mixtures all are invalid.
When effectively using phosphate composition to be used for the treatment of purpose, can be made into various formulations: pill, pulvis, suppository, ointment and ampoule.
Because its antibiotic and Fungicidally active, phosphate composition of the present invention can be used for being used to prevent plant (vine, crops, fruit tree, oranges and tangerines, vegetables) damage by disease and insect in agricultural and the forest industry, and treatment microorganism, virus and fungal disease.
According to recorded data, the phosphate composition material can be construction material, and it is heated to composition more than 300 ℃ and makes.These materials are as follows: fire-resistant, heat insulation, corrosion-resistant and ornamental cover layer, fire resistance concrete and ceramic material, adhesive etc.
The invention still further relates to the application that has the cold curing ability and need not the phosphate composition of thermal treatment.1, fire-retardant-fire resistance cover layer, colourless, nothing is smelt, transparent aqueous solution, and tight ness rating is 1.15-1.10
The basic application of this solution is the surface that covers construction material-timber, metal, concrete and yarn fabric and paper, increases the fire resistance of these materials.This processing is carried out with spraying, coating and dip coating.1m
2The solution usage amount of material is 0.2 liter, and (perhaps 1 liter is used for 5m
2).After the processing, the surface of these materials should be at room temperature in dry environment dry 24 hours.
This solution can damaged material the surface, can not change its color and material character yet.The tight ness rating of wood materials has increased 20-30% after processing.
This solution is also non-carcinogenesis of avirulence both.It is fire-resistant, and is noninflammable.Apartment and big assembly space can be used this solution-treated.Its preparation method is environmentally friendly.
This solution can be preserved in plastics that seal or glass container.After use, wash described container with water.
The storage life of this solution is 3 years.
Fiery dangerous research department at the Ministry of Internal Affairs has carried out the research of the fire resistance of phosphate composition of the present invention.After solution-treated, on the surface of timber, yarn fabric, paper and metal material, form coating, it has withstood the test of national standard, and therefore can be described as is non-combustible material.
On the basis of above-mentioned conclusion, the work that the present invention relates to is registered in Georgia StandardNo.150044-002-96, and is permitted by the Tiflis city.2, corrosion-inhibiting compositions solution
Above-mentioned solution is used to remove the rust on the metal surface, and need not to carry out earlier mechanical treatment, is used to then prevent from further to get rusty.The said composition aqueous solution be colourless, do not have and to smell.Its tight ness rating is 1.4-1.5.By spraying or map brushing it is coated on the rust surface of metal.After the coating, remove from the metal surface and to derust, and form protective coating, this coating can be further applies with the same solution of any coating or adding pigment.
The thickness of corrosion-resistant finishes is 80-90mkm, it is characterized in that having high metal adhesion (70-90kg/cm
2), mechanical hardness (5 * 10
6M), temperature tolerance (20 ℃ to 500 ℃), and irrelevant with climatic conditions change.Its right and wrong are flammable.
This solution is avirulent, and its preparation method is an environmental sound.This solution is fire resistance, can not explode.Every 1m
2The usage amount of this solution is 0.25 liter in the surface.This solution can be kept under room temperature in the plastics or glass container of sealing, and the time is 4-5.
Used instrument and the washing of container available water.3, phosphatic coating
Above-mentioned coating can be used for applying concrete, brick building, wooden article and paper.
The feature of this coating is have height ornamental, and is irrelevant with the variation of weather or condition, and has the surface of good cohesive.By adding various pigment, the design and color that can obtain wishing.
This coating can be used on the initial surface.This coating of dilution in water can make antifouling paint in the proper ratio.Every 1m
2Coating content be 4-5kg.
This coating can be kept in glass or the plastic containers.Storage life is 2-3.Container and instrument be the available water washing after use.
This coating is avirulent.Its nothing is smelt.Its manufacture method is harmless to environment.This coating is fire-resistant and non-flammable.4, the composition solution of sclerosis porous mineral
Above-mentioned composition is the 10-20% aqueous solution, and colourless, nothing is smelt.Its tight ness rating is 1.05-1.10.It is characterized in that high adhesion characteristic being arranged with inorganic material.It is all curable under any temperature, and obtains waterproof and fire resistance (being up to 1000 ℃), and has photochemical stability, mechanical hardness.This solution is nontoxic.Its manufacture method is harmless to environment.
Apply protective coating several times on aluminosilicate by brushing or be sprayed on porous and other material (sandstone, limestone sandstone, concrete, brick etc.).The result of twice processing is that porosity reduces 20-30%, compacting hardness increase 100-200%.The temperature expansion index of treated building stones (extension index) is zero.5, on the basis of phosphate composition, to prepare ceramic material, can in this solution, add production waste and raw mineral materials processing waste material.Obtain described material by casting (pouring out) or extruding, and need not heating.
The feature of this material is to have high mechanical hardness (60), high heat endurance, the stability to erosion environment and climatic variation, dielectricity to 2000 ℃.Can change its shape, design and color as required.
Table 1
| Embodiment | 100% orthophosphoric acid | Iron oxide (kg) | Metal dust (kg) | Water (kg) | The ratio of phosphate radical and iron ion | Generated time (hr) | Synthesis temperature (℃) |
| ????1 | ???100 | ???28 | ?Al-1.0 | ????50 | ????3.0 | ????2.0 | ????40-50 |
| ????2 | ???100 | ???41 | ?Al-2.5 | ????70 | ????2.0 | ????2.5 | ????50-60 |
| ????3 | ???100 | ???20 | ?Al-0.5 | ????30 | ????4.0 | ????1.5 | ????30-40 |
| ????4 | ???100 | ???32 | ?Al-1.0 | ????60 | ????2.5 | ????2.5 | ????40-50 |
| ????5 | ???100 | ???24 | ?Al-1.0 | ????40 | ????3.5 | ????1.5 | ????30-40 |
| ????6 | ???100 | ???28 | ?Fe-1.5 | ????50 | ????3.0 | ????2.0 | ????40-50 |
| ????7 | ???100 | ???41 | ?Zn-0.5 | ????70 | ????2.0 | ????2.5 | ????40-50 |
| ????8 | ???100 | ???20 | ?Mg-0.5 | ????30 | ????4.0 | ????1.5 | ????30-50 |
Table 2
| Embodiment | Tight ness rating g/sm 3 | ????pH | Viscosity c II 3 | Stability (moon) | The sclerosis of composition material |
| Known | ????1.56-1.60 | ????1.0-2.8 | ????50-120 | ????4-12 | Thermal treatment |
| ????1 | ????1.50 | ????2.70 | ????60 | ????24 | Room temperature |
| ????2 | ????1.65 | ????3.5 | ????80 | ????5 | Room temperature |
| ????3 | ????1.45 | ????2.0 | ????50 | ????30 | Thermal treatment |
| ????4 | ????1.62 | ????2.5 | ????75 | ????24 | Room temperature |
| ????5 | ????1.48 | ????2.50 | ????50 | ????20 | Room temperature |
| ????6 | ????1.50 | ????2.70 | ????70 | ????20 | Room temperature |
| ????7 | ????1.65 | ????3.5 | ????80 | ????4 | Room temperature |
| ????8 | ????1.40 | ????2.0 | ????50 | ????24 | Thermal treatment |
Table 3
Table 4
| Microorganism | Expose 3 minutes | Expose 5 minutes | Contrast | ||||||||||
| Solution concentration | |||||||||||||
| 0.1 | 0.2 | ?0.3 | ?0.5 | ?1 | ?2 | ?0.1 | 0.2 | ?0.3 | ?0.5 | ?1 | ?2 | ||
| plaqueEV | + | - | ??- | ??- | ?- | ??- | ??- | - | ?- | ???- | ?- | ?- | + |
| pseudotuberculosis | + | + | ??+ | ??- | ?- | ??- | ??+ | + | ?- | ???- | ?- | ?- | + |
| intestineiersiniosis | + | + | ??+ | ??- | ?- | ??- | ??+ | + | ?- | ???- | ?- | ?- | + |
| sahmonella | + | + | ??+ | ??- | ?- | ??- | ??+ | + | ?- | ???- | ?- | ?- | + |
| klebsiels | + | + | ??+ | ??- | ?- | ??- | ??- | + | ?- | ???- | ?- | ?- | + |
| vibrons(cholera) | + | - | ??- | ??- | ?- | ??- | ??- | - | ?- | ???- | ?- | ?- | + |
| dysentery | + | - | ??- | ??- | ?- | ??- | ??- | - | ?- | ???- | ?- | ?- | + |
| colibacillus | + | + | ??+ | ??+ | ?- | ??- | ??+ | + | ?+ | ???- | ?- | ?- | + |
| golden?staphylococcus | + | + | ??+ | ??+ | ?- | ??- | ??+ | + | ?+ | ???+ | ?- | ?- | + |
| Anthrax | + | + | ??+ | ??- | ?- | ??- | ??+ | + | ?- | ???- | ?- | ?- | + |
| brucellosis | + | + | ??+ | ??- | ?- | ??- | ??+ | + | ?- | ???- | ?- | ?- | + |
| Virus | Expose 3 minutes | Expose 5 minutes | ||||||||||||
| Solution concentration | ||||||||||||||
| 0.01 | ?0.02 | ?0.05 | ?0.1 | ?0.2 | ?0.5 | ?1 | ?0.01 | ?0.02 | ?0.05 | ?0.1 | ?0.2 | ?0.5 | ?1 | |
| West?Nile Fever | ?+ | ???- | ??- | ??- | ??- | ??- | ?- | ???- | ????- | ???- | ?- | ??- | ??- | ?- |
| Influenza | ?+ | ???+ | ??+ | ??- | ??- | ??- | ?- | ???+ | ????+ | ???- | ?- | ??- | ??- | ?- |
| coxsacB | ?- | ???+ | ??+ | ??+ | ??- | ??- | ?- | ???+ | ????+ | ???+ | ?+ | ??- | ??- | ?- |
| hepatitis?A | ?+ | ???+ | ??+ | ??+ | ??+ | ??+ | ?+ | ???+ | ????+ | ???+ | ?+ | ??+ | ??+ | ?- |
| plaque phage | ?- | ???- | ???- | ??- | ??- | ??- | ?- | ???- | ????- | ???- | ?- | ??- | ??- | ?- |
| pseudotuber -culosis | ?- | ???- | ???- | ??- | ??- | ??- | ?- | ???- | ????- | ???- | ?- | ??- | ??- | ?- |
| oncovirus | ?+ | ???+ | ???+ | ??- | ??- | ??- | ?- | ???- | ????+ | ???- | ?- | ??- | ??- | ?- |
Table 5
Antiseptic solution " Nargosept " comprises the comparison of the antiseptic solution of chlorine, phenol and quaternary ammonium chlorine compound with other
| Article | Solution amount | Time | Handle |
| House and hard article | 500ml/m 2 | 10 | Spraying is cleaned |
| Lavatory basin, water tank, bathtub, floor sweeping device | 500ml/m 2 | 1.0 | Spraying is cleaned |
| Liquid emission: urine etc. | Many twices | 1.0 | Topple over, spray |
| Glass pane, table, furniture clothes, robe, mouth mask gloves, rubber boot | 300ml/m 2 | 1.0 | Spraying is cleaned |
| Patient's utensil | 5 liters/kg | 1.0 | Be placed in the solution |
| Labware: pottery, glass, metal | 2 liters/cover | 5 | Clean |
| Other exposure portion of hand and health | 1.0 | Be placed in the solution | |
| Utensil after the vivisection | 300ml/m 2 | 1.0 5 1.0 1.0 | Be placed on to wash to be placed in the solution in the solution and spray |
| Quality | Chlorine-containing agent | Phenol | Quaternary ammonium chlorine | Nargosept |
| 1, toxicity | Be | Be | Be | Do not have |
| 2, carcinogenicity | Be | Be | Be | Do not have |
| 3, allergy | Be | Be | Be | Do not have |
| 4, smell | By force | Special odor | Be | Nothing is smelt |
| 5, stability | Evaporation, instability | Evaporation | Evaporation | Stablize 5-6 |
| 6, to the influence of mucous membrane | Strong stimulation | Acute inflammation | Inflammation, burn | There is not influence |
| 7, to the influence of skin | Burn produces dermatitis | Acute inflammation, necrosis | Rubescent, burn | There is not influence |
| 8, to the influence of eye | Stimulate, produce conjunctivitis | Stimulate, produce conjunctivitis | Stimulate | There is not influence |
| 9, to the influence of respiratory tract | Stimulate, produce laryngitis and pharyngitis | Stimulate, produce laryngitis and pharyngitis | Stimulate | There is not influence |
| 10, to the influence of central nervous system | Dizzy, vomit and lose direction | The central nervous system numbness | Be | There is not influence |
| 11, poison | Produce acute poisoning | Produce acute poisoning | Be | There is not influence |
| 12, sterilization and killing the virus | Be 10 minutes | Be 10 minutes | Be 10 minutes | Be 5 minutes |
| 13, blood changes | Produce leukocytosis | Thrombus | Be | There is not influence |
| 14, to the influence of lung | Produce inflammation | Produce inflammation | Be inflammation | There is not influence |
| 15, to the influence of kidney | Strong renal toxicity | Renal toxicity | Renal toxicity | There is not influence |
| 16, be in, the use of hospital, school and other unit | Impossible | Impossible | Need careful | Can use safely |
Table 7
Table 8
| Character | On concrete | Asbestos cement | Slabstone | Steel-3 | ||||
| Known | Best | Known | Best | Known | Best | Known | Best | |
| The water-soluble P of resistance to water 2O 5％ | ?0.01 | ????- | ?0.05 | ????- | ????- | ???- | ?0.05 | ???- |
| Environmental stability (moon) | ????6 | ????60 | ????6 | ????60 | ????6 | ???48 | ????6 | ???36 |
| Hardness, 3% in NaCl, month | ????1 | ????4 | ????1 | ????3 | ????1 | ????3 | ????1 | ????3 |
| Impact hardness kg/cm 2 | ???40 | ???70 | ???50 | ????60 | ???30 | ???60 | ???30 | ???50 |
| Hardness on the cohesive | ????2 | ??3.6 | ||||||
| The definition of hardening time | |||||||||||
| Composition levels weight % | Compacting hardness | The pH of expressed water | |||||||||
| Postpone hour | |||||||||||
| ?24 | ??48 | ??72 | ?96 | ?120 | ?24 | ?48 | ?72 | ?96 | ?120 | ||
| Iron phosphate composition andesine-70 | Prototype | ?1.2 | ??1.8 | ??2.2 | ?2.5 | ?2.5 | ?4.5 | ?5.2 | ?5.7 | ?6.5 | ?6.5 |
| Best | ?2.5 | ??2.5 | ??3.0 | ?3.0 | ?3.0 | ?5.0 | ?5.5 | ?6.5 | ?6.5 | ?6.5 | |
| Iron phosphate composition andesine-70 kaolin-10 | Prototype | ?1.8 | ??2.5 | ??3.5 | ?4.0 | ?4.0 | ?4.0 | ?5.5 | ?6.5 | ?7.0 | ?7.0 |
| Best | ?4.0 | ??4.0 | ??5.5 | ?5.5 | ?5.5 | ?5.0 | ?5.5 | ?6.5 | ?6.5 | ?6.5 | |
| Iron phosphate composition andesine-80 | Prototype | ?0.2 | ??0.3 | ??0.5 | ?0.5 | ?0.5 | ?3.0 | ?3.0 | ?3.0 | ?3.5 | ?3.5 |
| Best | ?3.5 | ??4.0 | ??4.5 | ?4.5 | ?4.5 | ?5.5 | ?5.5 | ?6.0 | ?6.5 | ?6.5 | |
| Iron phosphate composition andesine-70 (being heated to 400 ℃) | Prototype | ?4.0 | ??- | ??- | ?- | ?- | ?7.0 | ?7.0 | ?- | ?- | ?- |
| Best | ?5.0 | ??5.0 | ??5.0 | ?5.0 | ?5.0 | ?7.0 | ?7.0 | ?7.0 | ?7.0 | ?7.0 | |
List of references
1, KopeinV.A., " The Material in regard to metalophosphate basis ", Moscow, Publishing House " Chemistry ", 1976, the 50-54 pages or leaves
2, Korbridge D., Phosphorus, Moscow, 1982, the 130-141 pages or leaves
3、USSR?Copyright?No.968005,1992
4、USSR?Copyright?No.1564281,1991
5, Sichev M.M., Inorganic Adhesives, Leningrad, Publishing House " Chemistry ", 1996, the 117-125 pages or leaves
Claims
Modification according to the 19th of treaty
1, a kind of phosphate composition, it comprises phosphoric acid, iron, metal dust such as Mn, Zn, and said composition is characterised in that the iron that is comprised is iron oxide, and described metal dust is any metal dust, and the weight part ratio of each component is for example following:
Orthophosphoric acid 100
Iron oxide 20-41
Metal dust 0.5-2.5
Water 30-70
2, phosphate composition as claimed in claim 1, its can be used for having antibiotic, kill the virus and the medicine and veterinary products of Fungicidally active in.
3, phosphate composition as claimed in claim 1, it can be used in the pharmaceutical field, is used to prepare the product of anti-inflammatory and antimycotic disease.
4, phosphate composition as claimed in claim 1, it can be used in the agriculture field, prevents fungi and microbial diseases in the plant.
5, phosphate composition as claimed in claim 1, it can be used in the building field, as the bonding astringent with cold curing ability, prepares fire-resistant, corrosion-resistant, ornamental, water proof every electricity, radiation-resistant cover layer, and need not thermal treatment.
Claims (5)
1, a kind of phosphate composition, it comprises the solution of iron oxide in acid and water, and said composition is characterised in that it comprises orthophosphoric acid and additional metals powder, and the weight part ratio of each component is for example following:
Orthophosphoric acid 100
Iron oxide 20-41
Metal dust 0.5-3.5
Water 30-70
2, phosphate composition as claimed in claim 1, its can be used for having antibiotic, kill the virus and the medicine and veterinary products of Fungicidally active in.
3, phosphate composition as claimed in claim 1, it can be used in the pharmaceutical field, is used to prepare the product of anti-inflammatory and antimycotic disease.
4, phosphate composition as claimed in claim 1, it can be used in the agriculture field, prevents fungi and microbial diseases in the plant.
5, phosphate composition as claimed in claim 1, it can be used in the building field, as the bonding astringent with cold curing ability, prepares fire-resistant, corrosion-resistant, ornamental, water proof every electricity, radiation-resistant cover layer, and need not thermal treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96180411 CN1226136A (en) | 1996-06-14 | 1996-06-14 | Phosphate composition and its use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96180411 CN1226136A (en) | 1996-06-14 | 1996-06-14 | Phosphate composition and its use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1226136A true CN1226136A (en) | 1999-08-18 |
Family
ID=5127861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96180411 Pending CN1226136A (en) | 1996-06-14 | 1996-06-14 | Phosphate composition and its use |
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| Country | Link |
|---|---|
| CN (1) | CN1226136A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457835C (en) * | 2006-05-24 | 2009-02-04 | 卞大荣 | Inorganic phosphate zinc-enriched aluminum paint and its producing method |
| CN104010963A (en) * | 2011-12-21 | 2014-08-27 | 化学制造布敦海姆两合公司 | Nutrient composition for biological systems |
| CN104115871A (en) * | 2014-07-18 | 2014-10-29 | 曹志平 | Method for inducing necrocytosis |
-
1996
- 1996-06-14 CN CN 96180411 patent/CN1226136A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100457835C (en) * | 2006-05-24 | 2009-02-04 | 卞大荣 | Inorganic phosphate zinc-enriched aluminum paint and its producing method |
| CN104010963A (en) * | 2011-12-21 | 2014-08-27 | 化学制造布敦海姆两合公司 | Nutrient composition for biological systems |
| US9375026B2 (en) | 2011-12-21 | 2016-06-28 | Chemische Fabrik Budenheim Kg | Nutrient composition for biological systems |
| CN104010963B (en) * | 2011-12-21 | 2018-01-23 | 化学制造布敦海姆两合公司 | Nutrient composition for biosystem |
| CN104115871A (en) * | 2014-07-18 | 2014-10-29 | 曹志平 | Method for inducing necrocytosis |
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