CN1218104A - Nano size rare earth fluoride lubricant oil additive - Google Patents
Nano size rare earth fluoride lubricant oil additive Download PDFInfo
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- CN1218104A CN1218104A CN 98123519 CN98123519A CN1218104A CN 1218104 A CN1218104 A CN 1218104A CN 98123519 CN98123519 CN 98123519 CN 98123519 A CN98123519 A CN 98123519A CN 1218104 A CN1218104 A CN 1218104A
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Abstract
A nm-class fluorinated rare-earth additive for lubricating oil is prepared from water-soluble inorganic rare-earth salt, disperser, surfactant, promoter, basic oil, and sodium fluoride, and features 10-50 nm of granularity and good dispersion in lubricating oil. It is an excellent extreme-pressure antiwear additive.
Description
The invention discloses a kind of nano size rare earth fluoride lubricant oil additive and preparation method thereof.
Rare earth fluorine has obtained widespread use in lubricating grease, U.S.4, and 507,214,4,946,607,4,946,608 disclose rare earth fluoride has good lubricity in lubricating grease.At CN 1,032549A, 1,032, among the 550A, rare earth fluorine is by being applied in the railway lubricant film forming paste of success, and obtained extraordinary lubricant effect.Because its dispersed very poor in lubricating oil, thereby limited its widespread use in lubricating oil.
The object of the present invention is to provide a kind of lubricating oil additive and preparation method thereof, it has good dispersiveness, extreme pressure and abrasion resistance in lubricating oil.
The present invention is made up of water-solubility rare-earth inorganic salt, dispersion agent, tensio-active agent, promotor, base oil, Sodium Fluoride.
Nano size rare earth fluoride lubricant oil additive by: water-solubility rare-earth inorganic salt 10-20, dispersion agent 10～30, tensio-active agent 0.1～5, promotor 10～30, base oil 40～60, Sodium Fluoride 2～5 (weight percentage) are formed.
Inorganic salt of rare earth is rare earth chloride, rare earth nitrate or perchloric acid rare earth, and rare earth is one or more in lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, the lutetium.
Dispersion agent is one or more in the two succimides of polyisobutene mono butonediimide, polyisobutene, calcium mahogany sulfonate, the petrolic magnesium sulfonate.
Tensio-active agent is one or more of Si Ben-20, Si Ben-80, Tween-40, Tween-60.
Promotor is one or more mixture of water, methyl alcohol, ethanol, propyl alcohol, butanols, amylalcohol, hexanol, octanol.
(40 ℃ of viscosity are 28.8-35.2mm to base oil for the refining base oil of mesodialyte cerul
2/ s).
Its preparation method is as follows:
10～20wt.% is soluble in water with the water-soluble inorganic rare-earth salts, and dispersion agent 10～30wt.%, tensio-active agent 0.1～5wt.%, promotor 10～30wt.%, mesodialyte cerul are made with extra care base oil, and (40 ℃ of viscosity are 28.8-35.2mm
2/ s) 40～60wt.% mixed 0.6 part of benzene (is 1 part with above-mentioned total amount) with above-mentioned solution, in stirred in water bath half an hour, slowly drip the aqueous solution of 2～5wt.% Sodium Fluoride, stirred in water bath 5～10 hours.Remove materials such as benzene, water under reduced pressure.
The nano size rare earth fluoride that institute of the present invention synthetic itrogenous organic substance is modified is the very effective lubricating oil extreme pressure of a class, wear preventive additive.Its addition as lubricating oil additive is 0.1wt%～8wt%.
In order to understand the present invention better, describe by example.
Example 1 is soluble in water with the 1.86g Lanthanum trichloride, again 2g polyisobutene mono butonediimide, 0.2g calcium mahogany sulfonate 0.3g Si Ben-80,7g base oil are mixed with above-mentioned solution, add 10ml benzene, in stirred in water bath half an hour, slowly drip the aqueous solution of 1.1g Sodium Fluoride, stirred in water bath 7 hours.Add the benzene of 50ml so that filter.Filtrate decompression is steamed volatile matter such as removing benzene, water.
Example 2 is soluble in water with the 2.22g samaric nitrate, again the two succimides of 3g polyisobutene, 0.1g calcium mahogany sulfonate, 0.3g Si Ben-80,10ml methyl alcohol, 7g base oil are mixed with above-mentioned solution, add 14ml benzene, in stirred in water bath half an hour, slowly drip the 1.1g Fluorinse, stirred in water bath 9 hours.Add the benzene of 50ml so that filter.Filtrate decompression is steamed volatile matter such as removing benzene, water.
Example 3 is soluble in water with 2.35g perchloric acid erbium, again the two succimides of 2.1g polyisobutene, 0.2g petrolic magnesium sulfonate, 0.3g Si Ben-80,6g base oil are mixed with above-mentioned solution, add 15ml benzene, in stirred in water bath half an hour, slowly drip the aqueous solution of 1.7g Sodium Fluoride, stirred in water bath 8 hours.Add the benzene of 50ml so that filter.Filtrate decompression is steamed volatile matter such as removing benzene, water.
Example 4 reaction conditionss replace with cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium with example 1 respectively with the lanthanum in the Lanthanum trichloride, can obtain corresponding nano size rare earth fluoride.
Last non seizure load and the abrasion resistance of nanometer lanthanum fluoride prepared in the example 1 in whiteruss estimated with four-ball friction and wear test machine.For the ease of contrast, last non seizure load and the resistance to abrasion of zinc dialkyl dithiophosphate (ZDDP) in whiteruss also measured.The operational condition of wear-resistant experiment is: load 392N, experimental period 30min, rotating speed 1450rpm.After experiment finishes, measure the wear scar diameter (WSD) of steel ball, the results are shown in Table 1.
By above-mentioned experimental result as can be seen, this type of nano size rare earth fluoride has good extreme pressure property and wear resistance as lubricating oil additive, is lubricating oil extreme pressure, wear preventive additive that a class has wide application prospect.
Table 1 greastest element card is stung load (P
BBe worth) and the abrasion resistance evaluation result
| Additive | Concentration (wt%) | P BValue (N) | WSD(mm) |
| Whiteruss ZDDP of the present invention | ????100 ????0.5 ????1 ????2 ????3 ????1 | ????372 ????686 ????735 ????764 ????764 ????784 | ????0.72 ????0.44 ????0.42 ????0.44 ????0.62 ????0.50 |
Claims (7)
1, a kind of nano size rare earth fluoride lubricant oil additive by: water-solubility rare-earth inorganic salt 10～20 dispersion agents 10～30 tensio-active agents 0.1～5 promotor 10～30 base oils 40～60 Sodium Fluorides 2～5 (weight percentage) are formed.
1, nano size rare earth fluoride lubricant oil additive according to claim 1, it is characterized in that the water-solubility rare-earth inorganic salt are rare earth chloride, rare earth nitrate or perchloric acid rare earth, rare earth is one or more a mixture of lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium.
2, nano size rare earth fluoride lubricant oil additive according to claim 1 is characterized in that dispersion agent is one or more a mixture of the two succimides of polyisobutene mono butonediimide, polyisobutene, calcium mahogany sulfonate, petrolic magnesium sulfonate.
3, nano size rare earth fluoride lubricant oil additive according to claim 1 is characterized in that tensio-active agent is one or more a mixture of Si Ben-20, Si Ben-80, Tween-40, Tween-60.
4, nano size rare earth fluoride lubricant oil additive according to claim 1 is characterized in that promotor is one or more mixture of water, methyl alcohol, ethanol, propyl alcohol, butanols.
5, nano size rare earth fluoride lubricant oil additive is characterized in that base oil is a mesodialyte cerul refined mineral oil according to claim 1, and 40 ℃ kinematic viscosity is 28.8-35.2mm
2/ s.
6, the preparation method of nano size rare earth fluoride lubricant oil additive comprises according to claim 1: 10～20wt.% is soluble in water with the water-soluble inorganic rare-earth salts, and dispersion agent 10～30wt.%, tensio-active agent 0.1～5wt.%, promotor 10～30wt.%, mesodialyte cerul are made with extra care base oil, and (40 ℃ of viscosity are 28.8-35.2mm
2/ s) 40～60wt.% mixes 0.6 part of benzene (is 1 part with above-mentioned total amount) with above-mentioned solution, in stirred in water bath half an hour, slowly drip the aqueous solution of 2～5wt.% Sodium Fluoride, stirred in water bath 5～10 hours, removes materials such as benzene, water under reduced pressure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98123519A CN1058985C (en) | 1998-10-08 | 1998-10-08 | Nano size rare earth fluoride lubricant oil additive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98123519A CN1058985C (en) | 1998-10-08 | 1998-10-08 | Nano size rare earth fluoride lubricant oil additive |
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| Publication Number | Publication Date |
|---|---|
| CN1218104A true CN1218104A (en) | 1999-06-02 |
| CN1058985C CN1058985C (en) | 2000-11-29 |
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|---|---|---|---|
| CN98123519A Expired - Fee Related CN1058985C (en) | 1998-10-08 | 1998-10-08 | Nano size rare earth fluoride lubricant oil additive |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001027051A3 (en) * | 1999-09-10 | 2002-01-17 | Battelle Memorial Institute | Rare earth oxide fluoride nanoparticles and hydrothermal method for forming nanoparticles |
| CN100338200C (en) * | 2004-04-14 | 2007-09-19 | 中国石油化工股份有限公司 | Process for preparing lubricating oil additive containing nano microparticles |
| CN100395320C (en) * | 2006-03-15 | 2008-06-18 | 华东理工大学 | Fluorine-containing rare earth nano lubricating oil additive and preparation process thereof |
| CN100494330C (en) * | 2007-05-16 | 2009-06-03 | 龚; | Nano bionic self-organization lubricating oil additive and preparation method thereof |
| CN103540388A (en) * | 2013-10-24 | 2014-01-29 | 大连海事大学 | FD bearing oil composition, preparation method and applications thereof |
| CN107151571A (en) * | 2017-06-05 | 2017-09-12 | 合肥嘉仕诚能源科技有限公司 | A kind of biomass fuel and preparation method |
| CN108410539A (en) * | 2018-03-01 | 2018-08-17 | 清华大学天津高端装备研究院 | A kind of oil solubility nanometer rare earth antiwear lubricating oil additive and preparation method thereof |
| CN110205185A (en) * | 2019-06-11 | 2019-09-06 | 日生能科技(厦门)有限公司 | A kind of rare earth compound lube oil additive manufacturing method |
| CN111548842A (en) * | 2020-05-21 | 2020-08-18 | 成都玉龙化工有限公司 | Lubricant and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE68901909T2 (en) * | 1988-10-10 | 1993-02-04 | Rhone Poulenc Chimie | DISPERSION OF RARE EARTH HALOGENIDES IN AQUEOUS MEDIUM. |
| CN1180079A (en) * | 1995-07-06 | 1998-04-29 | 中国科学院兰州化学物理研究所 | Fatty acid modifying metallic oxide or hydroxide nanometre powder and its preparing method |
| CN1183461A (en) * | 1995-07-06 | 1998-06-03 | 中国科学院兰州化学物理研究所 | Sulfo-organo-compound modified dichalcogenide nm micropowder and preparing method thereof |
-
1998
- 1998-10-08 CN CN98123519A patent/CN1058985C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001027051A3 (en) * | 1999-09-10 | 2002-01-17 | Battelle Memorial Institute | Rare earth oxide fluoride nanoparticles and hydrothermal method for forming nanoparticles |
| CN100338200C (en) * | 2004-04-14 | 2007-09-19 | 中国石油化工股份有限公司 | Process for preparing lubricating oil additive containing nano microparticles |
| CN100395320C (en) * | 2006-03-15 | 2008-06-18 | 华东理工大学 | Fluorine-containing rare earth nano lubricating oil additive and preparation process thereof |
| CN100494330C (en) * | 2007-05-16 | 2009-06-03 | 龚; | Nano bionic self-organization lubricating oil additive and preparation method thereof |
| CN103540388A (en) * | 2013-10-24 | 2014-01-29 | 大连海事大学 | FD bearing oil composition, preparation method and applications thereof |
| CN103540388B (en) * | 2013-10-24 | 2014-12-31 | 大连海事大学 | FD bearing oil composition, preparation method and applications thereof |
| CN107151571A (en) * | 2017-06-05 | 2017-09-12 | 合肥嘉仕诚能源科技有限公司 | A kind of biomass fuel and preparation method |
| CN108410539A (en) * | 2018-03-01 | 2018-08-17 | 清华大学天津高端装备研究院 | A kind of oil solubility nanometer rare earth antiwear lubricating oil additive and preparation method thereof |
| CN108410539B (en) * | 2018-03-01 | 2021-04-27 | 清华大学天津高端装备研究院 | Oil-soluble nano rare earth anti-wear lubricating oil additive and preparation method thereof |
| CN110205185A (en) * | 2019-06-11 | 2019-09-06 | 日生能科技(厦门)有限公司 | A kind of rare earth compound lube oil additive manufacturing method |
| CN111548842A (en) * | 2020-05-21 | 2020-08-18 | 成都玉龙化工有限公司 | Lubricant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1058985C (en) | 2000-11-29 |
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Owner name: QINGDAO MODELONG SPECIAL LUBRICATING OIL CO., LTD Free format text: FORMER OWNER: LANZHOU INST. OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES Effective date: 20030912 |
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Effective date of registration: 20030912 Address after: 266101 Qingdao South Road Industrial Park, Zhuzhou Road, Laoshan District, Shandong Patentee after: Qingdao Delong special lubricating oil Co., Ltd. Address before: 730000 No. 342, Tian Shui Road, Chengguan District, Gansu, Lanzhou Patentee before: Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
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