CN1216117C - Ecological road dust inhibitor - Google Patents

Ecological road dust inhibitor Download PDF

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Publication number
CN1216117C
CN1216117C CN 03128148 CN03128148A CN1216117C CN 1216117 C CN1216117 C CN 1216117C CN 03128148 CN03128148 CN 03128148 CN 03128148 A CN03128148 A CN 03128148A CN 1216117 C CN1216117 C CN 1216117C
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China
Prior art keywords
dust
inhibitor
water
road surface
solution
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Expired - Lifetime
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CN 03128148
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CN1468930A (en
Inventor
谭卓英
程运材
刘文静
罗桂民
闭历平
王太海
梁祖荣
何蔚
邱海涛
吴缨
王振敏
林益民
柴红保
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Aluminum Corp of China Ltd
Guangxi University
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Aluminum Corp of China Ltd
Guangxi University
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Priority to CN 03128148 priority Critical patent/CN1216117C/en
Publication of CN1468930A publication Critical patent/CN1468930A/en
Application granted granted Critical
Publication of CN1216117C publication Critical patent/CN1216117C/en
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Abstract

The present invention discloses an ecological road dust inhibitor for controlling dust. The dust inhibitor solution is prepared from 0.10 to 3.00% of carboxymethyl starch, 0.01 to 2.50% of sodium silicate and 0.01 to 2.00% of glycerol, and the three materials are immersed in water or dissolved in water by directly stirring before being applied. The dust inhibitor of the present invention has the advantages of effective coalescence, moisture absorption and water retention combination, long dust inhibiting time, high performance-price ratio, simple technical process and operation, no toxic or side effect of independent components and the solution, no corrosive action, quick biochemical degradation in nature after a dust inhibiting period, no secondary pollution and proper water and soil environment improvement. The dust inhibitor can be used for inhibiting thick dust in mine roads as well as urban roads, squares, construction sites, station quays, etc., almost has no site limit, and has a wide application range.

Description

Environmental road surface dust-inhibitor
Technical field:
The present invention relates to a kind of dust-inhibitor that is mainly used in the road surface dust Control, can be used for the dust Control on road surface, mine, production site and urban road square etc.
Background technology:
At present, common both at home and abroad dust suppression technological method is except that watering dust suppression (containing watering, spraying, the ultrasonic static water that involves), and it is several to spray wetting agent, solid/liquid moisture adsorbent, dust adhering agent, high power water-absorbing resin and compound dust-inhibitor in addition.In, state such as U.S., day, moral, Russia, Australia all carried out the research to dust-inhibitor.In recent years, along with the development of polymer fine chemical technology, aspect super strength water absorbent, make progress.But it is high or have drawbacks such as toxicological characteristics, corrodibility, difficult degradation and secondary pollution to go back ubiquity function singleness or price.Though have stronger agglutinating value(of coal) as the dust-inhibitor of making base-material with crude oil, pitch and residual oil etc., can not moisture-absorption water-retention, the variation of temperature that can not conform, and have toxicity, bio-refractory; With CaCl 2, MgCl 2Though add tensio-active agent such as lipid acid, sodium laurylsulfonate etc. and make wetting agent and adopt dust-inhibitors such as super strength water absorbent such as sodium polyacrylate to have stronger water-absorbent in halogenide and ammonium sulfate, sodium bicarbonate etc. inorganic salt, but agglutinating value(of coal) is poor, and has problems such as toxicity, corrodibility, volatility and bio-refractory.
Summary of the invention:
In order to overcome existing dust-inhibitor function singleness, cost performance is low, or has secondary pollution environmental problems such as toxicity, corrodibility, bio-refractory, the invention provides a kind of dust-inhibitor prescription, this dust-inhibitor not only has dust suppression over-all propertieies such as the coalescence of cohering, moisture absorption and water conservation, and can suitably improve the water and soil environment, the fixed road surface of safeguarding, strengthen the anti-spreading performance on road surface, prevent the soil erosion on soil property road surface and damage cost performance height, nontoxic nothing corrosion, easy biochemical degradation, non-secondary pollution; Preparation and spray processing are simple.
The technical solution adopted in the present invention is: this dust-inhibitor is formed by cohering coalescence, moisture absorption and three major portions of full water.One is the coalescence factor.This factor can become tiny dust granules coalescence bigger particle and have good consolidation strength, thereby, reduce the rate of kicking up of dust and the anti-spreading of ground (soil property or cementaceous), reduce reentrainment of dust.Its two, be the moisture absorption factor.This factor has stronger water absorbability, can absorb airborne moisture content, keeps the moistening of dust suppression road surface, thereby the substance of increase dust granules reduces airborne dust.Particularly when night temperature reduce, the moisture content that the is evaporated face of land of coming in the daytime, the road surface is under the effect of moisture absorption factor hydrophilic group, fully moisture absorption makes the moisture content of evaporation obtain in time replenishing, thereby strengthens the ageing of dust suppression.Its three, be the water conservation factor.The effect of this factor is to form one deck molecular film on the dust granules surface that is surrounded by water, and to reduce the velocity of evaporation of moisture content, the moisture content that reduces ground dust suppression layer runs off.The solution of its configuration has the over-all properties of cohering coalescence, moisture absorption and water conservation, can reduce the surface tension of water.
The coalescence factor is carboxymethyl starch (Carboxyl Methyl Starch is called for short CMS) in the dust-inhibitor, it is a kind of white powder, stirring in natural water at normal temperatures is solubilized, immersion process will help shortening the required churning time of dissolving, in dust-inhibitor, this components contents is 0.1-3.0%.The moisture absorption factor is water glass (Sodium Silicate) crystal, white, and soluble in water, this components contents is 0.01-2.50% in dust-inhibitor.The water conservation factor is glycerol (Glycerine also claims glycerine), is colourless liquid, and its content is 0.01-2.00%.
Be that the present invention is made up of carboxymethyl starch, water glass and glycerol, its proportioning is respectively 0.1-3.00%, 0.01-2.50% and 0.01-2.00%, and surplus is supplied by water.Before enforcement, dust-inhibitor is three kinds of independently components; When preparing dust-inhibitor during enforcement,, be prepared into the solution of above proportioning with water as solvent.Promptly calculate the weight of three components, again the water yield is filled up to 100%, three components are soaked the back or directly stir in water and make it fully that dissolving gets final product by total solution weight and proportioning.
The performance index of preparation back dust-inhibitor are: (1) pH value: 〉=6.5; (2) viscosity: 〉=300mpas; (3) high temperature resistant: 〉=45 ℃; (4) improve saturated water absorption: the saturated water absorption 20% that improves roof and floor soil and dust; (5) reduce rate of permeation: dust infiltration rate average out to 2.81 mm/min under field conditions (factors) are 0.05 mm/min under dust-inhibitor, have improved the surface adsorption effect of dust, and the moisture-absorption water-retention time is long; The anti-evaporating time under (6) 45 ℃ of constant high temperatures: 65 hours (till water content 4%), vaporator rate is 4.8 Grams Per Hours, unit surface vaporator rate 0.678 gram per centimeter 2(7) improve anti-abrasive property: adopt the XMQ-240X90 conical bell mill, rotating speed 96RPM, milling time 30 seconds, (percentage composition of D<0.08mm) is 6.43% to be lower than 200 orders; (8) fine dusts is had strong cohesive action, fixed road surface, the flushing that the shale road surface is caused that can prevent to sprinkle water destroys; (9) surface tension reduces, basically eliminate the reentrainment of dust when spraying.
Each component of dust-inhibitor can independently store by component before enforcement, also can be prepared into solution by proportioning and store.
Can replace water glass with bibulous weak acid strong alkali salt.Described bibulous weak acid strong alkali salt is meant yellow soda ash, sodium bicarbonate, salt of wormwood.
Present embodiment adopts the spray liquid mode to use, and except that increasing dust-inhibitor preparation facility and process for preparation, its use is suitable with watering dust prevention.
The invention has the beneficial effects as follows, with the effective combination of coalescence, moisture absorption and water conservation, the dust suppression time is long, the cost performance height, technical matters and simple to operate, the without any side effects and corrosive nature of independent component and solution thereof, dust suppression action period later can be at the very fast biochemical degradation of nature, do not have any secondary pollution, and can suitably improve the water and soil environment.This dust-inhibitor also can be used for urban road, square except that the inhibition that is used for the thick big dust of mine road, building field, and the inhibition of dust such as station terminal is limited by hardly in the place, and is with a wide range of applications.This invention is carried out industrial application in the soil property place of middle aluminium Guangxi branch office mine transportation highway and the thick big dust of ore drawing platform, and application shows, sprays once (0.2-1.0L/M 2) after, dust suppression working lipe is more than 5 days, Air quality all reaches secondary or grade III Standard, and significantly reduce the human and material resources and the financial resources consumption of sprinkling, reduce the unit cost (0.77 yuan/ton) of ore, year saving water resources 11 ten thousand steres are obtained tangible economic benefit.This technology in January, 2003 by evaluation at the provincial and ministerial level.
Description of drawings:
Fig. 1 is dust-inhibitor preparation technology figure of the present invention.
Embodiment:
Embodiment 1: be used for shale road and place.
Get in carboxymethyl starch 1.0kg, water glass 0.5kg, the glycerol 0.5kg adding 98kg water, normal temperature fully stirs down and promptly was prepared into the 100kg dust-inhibitor in 15-20 minute.In dust-inhibitor, the content of carboxymethyl starch is 1%, and water glass is 0.5%, and glycerol is 0.5%, and water is 98%.The same with most of solvends, suitably heat and can accelerate dissolving.Simultaneously, soak in advance will help shortening and dissolve required churning time, and can not influence its performance.For reducing churning time, also it can be stirred into the solution of high density earlier, and then be diluted with water to the proportioning of requirement.Dissolving back dust-inhibitor promptly prepares and finishes fully.At this moment, the dust-inhibitor for preparing can be filled into the water barrow or other spray appliances are realized spraying.
Embodiment 2: be used for street and cement highway.
Get in carboxymethyl starch 0.2kg, water glass 0.5kg, the glycerol 0.1kg adding 99.2kg water, normal temperature fully stirs down and promptly was prepared into the 100kg dust-inhibitor in 15-20 minute.In dust-inhibitor, the content of carboxymethyl starch is 0.2%, and water glass is 0.5%, and glycerol is 0.1%, and water is 99.2%.Other are with embodiment 1.
Embodiment 3: be used for indoor cement flooring and face.
Get in carboxymethyl starch 0.1kg, sodium bicarbonate 0.2kg, the glycerol 0.1kg adding 99.6kg water, normal temperature fully stirs down and promptly was prepared into the 100kg dust-inhibitor in 15-20 minute.In dust-inhibitor, the content of carboxymethyl starch is 0.1%, and sodium bicarbonate is 0.2%, and glycerol is 0.1%, and water is 99.6%.Other are with embodiment 1.
Application example:
Once fixedly highway, nine, ten districts contact highway and nine, ten districts contained mud bauxite and unload the ore deposit platform and implement this dust-inhibitor at No. 1, No. 3, No. 5 stopes of Guangxi branch office of Chinese Aluminium Co., Ltd.Fortune ore deposit and personnel that above-mentioned highway was born the exploiting field at that time carry; Unload the ore deposit platform and then bear whole mud bauxite that contain in mining area and unload the ore deposit task, the mining area adopts, shell, unload and be 3 classes and worked continuously in 24 hours, and transporting and unload the ore deposit ability is 8000 ton per days.When at a time when dry season, temperature is up to 40 degrees centigrade.During enforcement, it is 8000 kilograms that single uses dust-inhibitor.Every sprinkling 1 time, but dust suppression all reached secondary or tertiary circulation border quality standard more than 5 days.In above-mentioned location or the place totally spray 120000 kilograms.

Claims (4)

1. road surface dust-inhibitor, it is characterized in that: be made up of carboxymethyl starch, water glass and glycerol, its proportioning is respectively 0.1-3.00%, 0.01-2.50% and 0.01-2.00%, and surplus is supplied by water; Before enforcement, dust-inhibitor is three kinds of independently components; During enforcement, use water as solvent, be prepared into the solution of above proportioning.
2. road surface according to claim 1 dust-inhibitor is characterized in that: each component of dust-inhibitor can independently store by component before enforcement, also can be prepared into solution by proportioning and store.
3. road surface according to claim 1 dust-inhibitor is characterized in that: can replace water glass with bibulous weak acid strong alkali salt.
4. road surface according to claim 3 dust-inhibitor is characterized in that: described bibulous weak acid strong alkali salt is meant yellow soda ash, sodium bicarbonate, salt of wormwood.
CN 03128148 2003-06-09 2003-06-09 Ecological road dust inhibitor Expired - Lifetime CN1216117C (en)

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Application Number Priority Date Filing Date Title
CN 03128148 CN1216117C (en) 2003-06-09 2003-06-09 Ecological road dust inhibitor

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Application Number Priority Date Filing Date Title
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CN1468930A CN1468930A (en) 2004-01-21
CN1216117C true CN1216117C (en) 2005-08-24

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899283A (en) * 2009-05-26 2010-12-01 世纪汉元(北京)科技有限公司 Method for preparing dust suppressant for coal dust transportation, loading and unloading
CN101619205B (en) * 2009-08-13 2012-06-27 沈阳建筑大学 Modified gelatin dust suppressant and preparation method thereof
CN102585770B (en) * 2012-01-05 2016-07-06 沈阳铁道工业集团有限公司 Railway breeze, Coal Transport dust suppressant and preparation method thereof
CN102643630A (en) * 2012-04-23 2012-08-22 天津理工大学 Method for preparing covering agent special for coal truck
CN102660227B (en) * 2012-05-02 2013-12-11 山西兆益矿用材料有限公司 Road dust suppressant
CN105018032A (en) * 2015-07-01 2015-11-04 宁夏浤森环保科技有限公司 Road dust depressor and preparation method thereof
CN105295844A (en) * 2015-11-17 2016-02-03 上海应用技术学院 Clean soil-stabilizing and dust-suppression agent and preparation method thereof
CN106350014A (en) * 2016-08-29 2017-01-25 辽宁点石技术开发有限公司 Ecological dust reducing agent and preparing method thereof
CN109944628B (en) * 2019-03-26 2020-05-26 山东科技大学 Mine high-molecular spray dust-settling agent, preparation method and application thereof
CN111892912A (en) * 2020-03-12 2020-11-06 南通乐尔环保科技有限公司 Formula of anti-freezing dust suppressant
CN111808573A (en) * 2020-06-12 2020-10-23 神木市锦界安顺煤矿机电修造有限公司 Underground descaling dust suppressant and preparation method thereof
CN115975600B (en) * 2023-01-30 2023-10-27 中交园林(山东)有限公司 Ecological efficient dust suppressant for garden construction and preparation method thereof

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