CN109456734A - A kind of soil-rock mixture structure road dust solidification dust suppressant and preparation method thereof - Google Patents

A kind of soil-rock mixture structure road dust solidification dust suppressant and preparation method thereof Download PDF

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Publication number
CN109456734A
CN109456734A CN201811487369.4A CN201811487369A CN109456734A CN 109456734 A CN109456734 A CN 109456734A CN 201811487369 A CN201811487369 A CN 201811487369A CN 109456734 A CN109456734 A CN 109456734A
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China
Prior art keywords
dust
pulvis
soil
liquor
rock mixture
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Pending
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CN201811487369.4A
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Chinese (zh)
Inventor
姬永生
刘本琳
郭煜诚
时方鸣
徐之山
张领雷
张莉
吴守荣
石博文
徐圣楠
严久鑫
陈鑫冰
陈豪
周样梅
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China University of Mining and Technology CUMT
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China University of Mining and Technology CUMT
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Priority to CN201811487369.4A priority Critical patent/CN109456734A/en
Publication of CN109456734A publication Critical patent/CN109456734A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/22Materials not provided for elsewhere for dust-laying or dust-absorbing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Structures (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The present invention relates to dust on the roads pollutant abatement technology fields, and in particular to a kind of soil-rock mixture structure road dust solidification dust suppressant and preparation method thereof.The dust suppressant (based on mass fraction) is made of the pulvis of 10%-30% and liquor two parts of 70%-90%, and pulvis is made of 10%-20% curing agent, 20%-60% slag micropowder, 10%-30% pozzolanic materials, 1%-5% surfactant;Liquor is by 20%-80% sodium silicate exciting agent, 1%-5% polymer emulsion, 10%-70% water composition.When use by pulvis be added liquor be uniformly mixed.There is good permeability can penetrate into road table certain depth, solidified by reacting with fine solid particle, anti-dust effect is prominent based on liquor for road dust solidification dust suppressant of the present invention.It is convenient to use, it is only necessary at the scene by pulvis, two component of liquor be uniformly mixed can carry out sprinkling use.

Description

A kind of soil-rock mixture structure road dust solidification dust suppressant and preparation method thereof
Technical field
The invention belongs to dust on the roads pollutant abatement technology fields, are related to a kind of dust on the roads prevention and treatment material, and in particular to A kind of soil-rock mixture structure road dust solidification dust suppressant and preparation method thereof.
Background technique
Coal plays huge effect as one of China's main energy sources, to Chinese national economy, and as society passes through The development of Ji, demand will be huger.However a large amount of powder is inevitably generated in the exploitation of coal mine, transportational process Dirt, particularly with the exploitation of open coal mine, due to its open operation and earth's surface is exposed constantly by weathering Erosion, dust Contamination phenomenon is serious, and wherein carriage way dust pollution phenomenon is severe and processing is difficult.
Carriage way is mainly soil-rock mixture structure, and road surface is made of crushed stone body and subtle powder, medium stone body Road surface skeleton structure is constituted, fine dust particles then pile up between these crushed stone body gaps by heap.Pass through in vehicle or strong wind passes through Out-of-date, the fine solid particle in rubble body gap is easily raised with vehicle with the wind, is generated serious fugitive dust harm, is caused live visibility It reduces, influences the normally travel of coaler, cause serious security risk, while also seriously threatening field personnel's Physically and mentally healthy and acceleration equipment abrasion.
Currently used dust suppression measure mainly has the treatment measures such as watering dust suppression, dust suppressant dust suppression and surface cure.But Since the effect of the combined factors such as carriage way soil-rock mixture structure and mining area special climate causes these dust-suppression methods herein Application effect is bad on kind road.
Watering dust suppression, since the general earth's surface in Open pit Area is relatively exposed, temperature is higher (highest temperature is up to 50 degree or more), Wind speed is very fast, and under high temperature and wind effect, moisture evaporation is very fast, and subsequent dust is still with the wind with Che Yangqi.Due to row Lane road surfaces water evaporation rate is too fast, for sufficiently parent profit road surface need sprinkling truck back and forth constantly to sprinkle water, spend cost compared with Height, and continuously sprinkle water and easily corrode the destruction that roadbed causes carriage way, increase roadbed maintenance cost.
Dust suppressant dust suppression is a kind of by the way that water conservation, hydrophilic component are added into water, is moistened to increase water body to the parent of powder Degree, reduces the treatment measures of the evaporation rate of moisture in soil or wet powder, and the essence of dust suppression is identical as watering dust suppression. The watering frequency of carriage way can be extended to a certain extent by the incorporation of dust suppressant, and reduces watering amount, but its Total workload and watering amount is still very huge, simultaneously because dust suppressant cost itself is just higher, therefore cannot still bring Preferable economic benefit not can effectively solve carriage way fugitive dust problem still.
Smear thick slurry (cement slurry, pitch, resin etc.) although surface peening or solidification measure can be by link table The solidification of flour body, temporarily plays good anti-dust effect, but be difficult to penetrate into road table since these hardening slurries are more sticky, only Form one layer of solidification hard shell on road surface layer, internal powder is not solidified sufficiently.And this layer solidifies hard shell in vehicle loading Under easily remove, be crushed, uncured powder still can be with the wind with Che Yangqi inside road surface.Therefore these surface cure measures according to Carriage way fugitive dust problem is not can effectively solve so.
Summary of the invention
Road of the present invention solidifies the liquid slurry that dust suppressant is a kind of low viscosity, has preferable hydrophily and permeability Can, the powder granule between rubble body can be preferably infiltrated after spilling lower road surface and penetrates into road table certain depth.It simultaneously can be with powder Body, which reacts, solidifies powder sufficiently, since product of the present invention consolidates carriage way surface layer certain depth soil-rock mixture Change, improve carriage way bearing capacity to a certain extent, improves road surface and resist the effect of vehicle-mounted and weathering Erosion, dust suppression period It is longer to come with preferable economic benefit.
Of the existing technology in order to overcome the problems, such as, present invention is primarily aimed at provide a kind of soil-rock mixture structure road Road dust solidifies dust suppressant and preparation method thereof, to bring good economic benefit and ecological benefits.
Technical solution of the present invention includes: a kind of soil-rock mixture structure road dust solidification dust suppressant, in the dust suppressant Each component mass fraction: it is made of the pulvis of 10%-30% and liquor two parts of 70%-90%;
Each component mass fraction in pulvis: by 10%-20% curing agent, 20%-60% slag micropowder, 10%-30% pozzolanic materials, 1%-5% surfactant composition;
Each component mass fraction in liquor: by 20%-80% sodium silicate exciting agent, 1%-5% polymer emulsion, 10%-70% water group At;When use by pulvis be added liquor be uniformly mixed.
Solidify a kind of prioritization scheme of dust suppressant: the powder as soil-rock mixture structure road dust of the present invention Curing agent in agent is made of hydrated lime in powder and anhydrous sodium metasilicate powder, and the mass ratio of hydrated lime in powder and anhydrous sodium metasilicate powder is 1:0.5 ~ 1.
Solidify a kind of prioritization scheme of dust suppressant: the powder as soil-rock mixture structure road dust of the present invention Slag micropowder is to meet S95 grades of graining blast-furnace cinder micro-powders as defined in GB/T 18046-2008 standard in agent, is granulated blast-furnace mine Slag is handled through iron removal by magnetic separation and grinding reaches specific surface area >=400 m2/kg and is made, and wherein partial size is ultra-fine less than 30 ì m Graining blast-furnace cinder micro-powder accounts for 90% of gross mass or more.
Solidify a kind of prioritization scheme of dust suppressant: the powder as soil-rock mixture structure road dust of the present invention Pozzolanic materials is the higher silicon ash of pozzolanic activity, metakaolin or high-quality fly ash in agent.
Solidify a kind of prioritization scheme of dust suppressant: the powder as soil-rock mixture structure road dust of the present invention Surfactant is one kind of naphthalene system, aliphatic or high-efficiency water-reducing agent of poly-carboxylic acid in agent.
Solidify a kind of prioritization scheme of dust suppressant: the liquid as soil-rock mixture structure road dust of the present invention Sodium silicate exciting agent is so that its modulus is existed by the way that suitable sodium hydroxide conciliation is added in the waterglass to high mode in agent 1.0-2.0, sodium silicate of the Baume degrees at 37 ° -48 °.
Solidify a kind of prioritization scheme of dust suppressant: the liquid as soil-rock mixture structure road dust of the present invention Polymer emulsion in agent is that non-reactive styrene-butadiene latex, acrylic acid ester emulsion, acetate emulsion or ethene-vinyl acetate are total Copolymer emulsion.
The present invention, which is achieved by the steps of, inhibits soil-rock mixture dust on the roads function:
1, pulvis and liquor are prepared by said ratio respectively;
2, pulvis is added in liquor and stirs into homogeneous slurry;
3, slurries are sprayed on road surface.
Road dust solidification dust suppressant of the present invention has following beneficial features:
Permeability is strong, and anti-dust effect is prominent
Hardening slurry of the present invention have good hydrophily and permeability can along rubble body gap infiltration road table certain depth, and A series of physical chemical action can occur with subtle powder sufficiently to solidify it, solidification effect is good, and anti-dust effect is obvious.
The dust suppression period is long, high financial profit
Hardening slurry of the present invention penetrates into road table certain depth, rubble body and subtle powder is cured as an entirety, to a certain degree On improve the bearing capacity on road surface, enhance it and resist vehicle-mounted and wind erosion ability, the dust suppression period is longer, can bring good Good economic benefit.
It is environmental-friendly, it is pollution-free
This product constituent is nontoxic, will not be to environmental effects, safety non-pollution.
It is convenient to use
The present invention only needs for two groups of effective components to be uniformly mixed, and does not need additional special installation and configuration condition requirement, It is of less demanding to construction personnel, it is ready-to-use to facilitate site operation.
Detailed description of the invention
Fig. 1 is soil-rock mixture structure road dust solidification dust suppressant using effect schematic diagram of the present invention.
Specific embodiment
Below by embodiment, the present invention will be further described.
Embodiment 1
Soil-rock mixture structure road dust solidifies dust suppressant, is made of pulvis and liquor two parts, and wherein liquor is as main Ingredient proportion is larger.
The pulvis is made of curing agent, slag micropowder, pozzolanic materials, surfactant;The quality hundred of each component Divide ratio:
The curing agent 20%, is made of hydrated lime in powder and anhydrous sodium metasilicate powder, the two mass ratio 1:0.5.
The slag micropowder, 60%, it is micro- to meet S95 grades of granulated blast-furnace slags as defined in GB/T 18046-2008 standard Powder, is handled for granulated blast-furnace slag through iron removal by magnetic separation and grinding reaches specific surface area >=400 m2/kg and is made, wherein partial size Superfine graining blast-furnace cinder micro-powder less than 30 μm accounts for 90% or more of gross mass.
The pozzolanic materials, 15%, select silicon ash.
The surfactant, 5%, select naphthalene system.
The liquor is made of sodium silicate exciting agent, polymer emulsion and water;Each component mass percent:
Sodium silicate exciting agent, 50%, to make its modulus by the way that suitable sodium hydroxide conciliation is added in the waterglass to high mode Between 1.0-2.0, Baume degrees is at 37 ° -- the sodium silicate between 48 °.
Polymer emulsion, 5%, it is non-reactive styrene-butadiene latex.
Remaining is water.
Proportion mixing, pulvis are carried out according to the pulvis of mass percent 10%-30% and the liquor of mass percent 70%-90% Optimum ratio with liquor is (mass ratio): 2:8.
It is as follows that the road dust solidifies dust suppressant preparation step:
(1) pulvis and liquor are prepared by said ratio respectively;
(2) pulvis is added in liquor and stirs into homogeneous slurry;
(3) slurries are sprayed on road surface.
Embodiment 2
It is substantially the same manner as Example 1, except that:
The mass percent of each component in the pulvis: curing agent, 10%;Slag micropowder, 60%;Pozzolanic materials, 29%, choosing Use metakaolin;Surfactant, 1%, it is aliphatic.
Each component mass percent in the liquor: sodium silicate exciting agent, 80%;Polymer emulsion, 1%, it is acrylic acid Ester lotion;Remaining is water.
Embodiment 3
It is substantially the same manner as Example 1, except that:
The mass percent of the pulvis each component: curing agent, 30%;Slag micropowder, 25%;Pozzolanic materials, 40%, it selects Flyash;Surfactant, 5%, it is high-efficiency water-reducing agent of poly-carboxylic acid.
The liquor each component mass percent: sodium silicate exciting agent, 20%;Polymer emulsion, 4%, it is vinyl acetate Lotion or ethylene-vinyl acetate copolymer emulsion;Remaining is water.
Embodiment 4
It is substantially the same manner as Example 1, except that:
The mass percent of the pulvis each component: curing agent, 30%;Slag micropowder, 30%;Pozzolanic materials, 35%, it selects Flyash;Surfactant, 5%, it is high-efficiency water-reducing agent of poly-carboxylic acid.
The liquor each component mass percent: sodium silicate exciting agent, 20%;Polymer emulsion, 4%, it is vinyl acetate Lotion or ethylene-vinyl acetate copolymer emulsion;Remaining is water.
Scope of protection of the present invention is not limited thereto, is original of the invention described in description above and embodiment Reason and the specific example designed according to the principle of the invention, the variation in office why not being detached under the premise of spirit and scope of the invention And modification, all it should belong in protection scope of the present invention.

Claims (7)

1. a kind of soil-rock mixture structure road dust solidifies dust suppressant, it is characterised in that: the dust suppressant by 10%-30% pulvis (based on mass fraction) is formed with the liquor of 70%-90%;
Wherein, pulvis is living by 10%-20% curing agent, 20%-60% slag micropowder, 10%-30% pozzolanic materials and the surface 1%-5% Property agent composition (based on mass fraction);
Liquor forms (based on mass fraction) by 20%-80% sodium silicate exciting agent, 1%-5% polymer emulsion, 10%-70% water;
Being uniformly mixed pulvis and liquor according to said ratio can be used.
2. soil-rock mixture structure road dust according to claim 1 solidifies dust suppressant, it is characterised in that: the pulvis In curing agent be made of hydrated lime in powder and anhydrous sodium metasilicate powder, the mass ratio of hydrated lime in powder and anhydrous sodium metasilicate powder is 1: 0.5~1。
3. soil-rock mixture structure road dust according to claim 1 solidifies dust suppressant, it is characterised in that: the pulvis Middle slag micropowder is to meet S95 grades of graining blast-furnace cinder micro-powders as defined in GB/T 18046-2008 standard, is granulated blast-furnace slag It is handled through iron removal by magnetic separation and grinding reaches specific surface area >=400 m2/kg and is made, wherein superfine granule of the partial size less than 30 ì m Change blast-furnace cinder micro-powder and accounts for 90% of gross mass or more.
4. soil-rock mixture structure road dust according to claim 1 solidifies dust suppressant, it is characterised in that: the pulvis Middle pozzolanic materials is the higher silicon ash of pozzolanic activity, metakaolin or high-quality fly ash.
5. soil-rock mixture structure road dust according to claim 1 solidifies dust suppressant, it is characterised in that: the pulvis Middle surfactant is one kind of naphthalene system, aliphatic or high-efficiency water-reducing agent of poly-carboxylic acid.
6. soil-rock mixture structure road dust according to claim 1 solidifies dust suppressant, it is characterised in that: the liquor Middle sodium silicate exciting agent is to make its modulus in 1.0- by the way that suitable sodium hydroxide conciliation is added in the waterglass to high mode 2.0, sodium silicate of the Baume degrees at 37 ° -48 °.
7. soil-rock mixture structure road dust according to claim 1 solidifies dust suppressant, it is characterised in that: the liquor In polymer emulsion be non-reactive styrene-butadiene latex, acrylic acid ester emulsion, acetate emulsion or ethene-vinyl acetate copolymerization It is a variety of or a kind of in object lotion.
CN201811487369.4A 2018-12-06 2018-12-06 A kind of soil-rock mixture structure road dust solidification dust suppressant and preparation method thereof Pending CN109456734A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112900409A (en) * 2021-01-27 2021-06-04 中国铝业股份有限公司 Dust suppression method for soil road for transportation
CN115353861A (en) * 2022-08-18 2022-11-18 北京中岩大地环境科技有限公司 Foam dust suppressant suitable for urban raise dust
CN115362886A (en) * 2022-08-25 2022-11-22 国家电投集团江西中业兴达电力实业有限公司 Fly ash stacking and dust raising prevention method

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CN106587784A (en) * 2016-12-28 2017-04-26 西安长大公路养护技术有限公司 Geopolymer double fluid grouting material for road base reinforcement and preparation method thereof
CN106747004A (en) * 2016-12-28 2017-05-31 西安长大公路养护技术有限公司 Geopolymer single fluid grouting material reinforced for roadbase and preparation method thereof
CN107117916A (en) * 2017-03-23 2017-09-01 广东省建筑科学研究院集团股份有限公司 A kind of powder soil solidification additive for roadbase
CN108409243A (en) * 2018-04-03 2018-08-17 中国矿业大学 Constraint pipe perfusion pile and preparation method thereof for underground sulfate corrosion environment

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Publication number Priority date Publication date Assignee Title
CN102060480A (en) * 2010-11-05 2011-05-18 中国科学院广州地球化学研究所 Composite curing agent for dredged silt in watercourse
KR101603757B1 (en) * 2015-09-23 2016-03-28 주식회사 삼표산업 Inorganic lightweight heat insulating composition and a manufacturing method of inorganic lightweight heat insulating material containing the same
CN105272091A (en) * 2015-09-25 2016-01-27 山东科技大学 Geopolymer composite grouting material, and preparation method and use method thereof
CN106587784A (en) * 2016-12-28 2017-04-26 西安长大公路养护技术有限公司 Geopolymer double fluid grouting material for road base reinforcement and preparation method thereof
CN106747004A (en) * 2016-12-28 2017-05-31 西安长大公路养护技术有限公司 Geopolymer single fluid grouting material reinforced for roadbase and preparation method thereof
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112900409A (en) * 2021-01-27 2021-06-04 中国铝业股份有限公司 Dust suppression method for soil road for transportation
CN115353861A (en) * 2022-08-18 2022-11-18 北京中岩大地环境科技有限公司 Foam dust suppressant suitable for urban raise dust
CN115362886A (en) * 2022-08-25 2022-11-22 国家电投集团江西中业兴达电力实业有限公司 Fly ash stacking and dust raising prevention method
CN115362886B (en) * 2022-08-25 2024-06-04 国家电投集团江西中业兴达电力实业有限公司 Fly ash stacking dust-raising prevention method

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