CN111808573A - Underground descaling dust suppressant and preparation method thereof - Google Patents

Underground descaling dust suppressant and preparation method thereof Download PDF

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Publication number
CN111808573A
CN111808573A CN202010536464.XA CN202010536464A CN111808573A CN 111808573 A CN111808573 A CN 111808573A CN 202010536464 A CN202010536464 A CN 202010536464A CN 111808573 A CN111808573 A CN 111808573A
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China
Prior art keywords
parts
descaling
dust suppressant
water
sodium
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Pending
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CN202010536464.XA
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Chinese (zh)
Inventor
韩林华
韩杨
韩飞
闫旭阳
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Shenmu Jinjie Anshun Coal Mine Electromechanical Repair Co ltd
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Shenmu Jinjie Anshun Coal Mine Electromechanical Repair Co ltd
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Priority to CN202010536464.XA priority Critical patent/CN111808573A/en
Publication of CN111808573A publication Critical patent/CN111808573A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/22Materials not provided for elsewhere for dust-laying or dust-absorbing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to an underground descaling dust suppressant and a preparation method thereof, wherein the underground descaling dust suppressant comprises the following components in parts by weight: 5-10 parts of sodium dodecyl benzene sulfonate; 10-30 parts of sodium silicate; 5-10 parts of sodium carboxymethyl starch; 5-9 parts of glycerol; 2-5 parts of nitrilotriacetic acid; 93.6 to 98.83 portions of water. The invention provides a descaling dust suppressant which can be used under the condition that mine backwater is high-salinity water, thereby simultaneously solving the problems of scaling and dust suppression. The components of the underground descaling dust suppressant are sequentially dissolved in water according to the mass ratio and the sequence, and the mixture is fully stirred and mixed for use. Or stirring the components except water, and dissolving in water at a certain ratio. The above processes are all operated at normal temperature.

Description

Underground descaling dust suppressant and preparation method thereof
Technical Field
The invention relates to the technical field of underground dust suppression, in particular to an underground descaling dust suppressant and a preparation method thereof.
Background
Coal mining is one of the most serious industries harming productive dust. The dust in the underground coal mine harms the health of workers, pollutes the working environment and damages the operation equipment. Currently, most industrial and mining enterprises in China mainly adopt dust suppression measures such as spraying water, adding a moisturizing dust suppressant, a solid moisture absorbent and soil fixation. Under the influence of water surface tension, when pure water is used for dust prevention, fine dust particles are difficult to wet by water, and a good effect cannot be achieved. The surface tension of water can be reduced by adding the dust suppressant, and the dust suppression efficiency is improved, so that the added dust suppressant is widely applied to the aspect of dust prevention and reduction of mine roadways.
Mine backwater in northwest areas is generally high-salt water, the content of calcium and magnesium ions is high, and the spraying pipeline can be scaled when the mine backwater is directly used for dustproof operation without treatment, so that the use of the dust suppressant is seriously influenced.
Chinese patent publication No.: CN102465711B discloses a composite dust suppressant for coal mine and a preparation method thereof, wherein the composite dust suppressant comprises 0.05-1.00% of fatty alcohol-polyoxyethylene ether (JFC), 0.05-1.00% of Sodium Dodecyl Benzene Sulfonate (SDBS), 0.01-0.50% of Polyacrylamide (PAM), 0.02-0.50% of polyaluminium chloride (PAC) and the balance of water. The components are all water-soluble substances, and can be directly sprayed by using the original water spraying system.
Chinese patent publication No.: CN105754552A discloses a quaternized chitosan mine dust suppressant and a preparation method thereof, wherein fatty alcohol-polyoxyethylene ether (JFC) 0.05-1.00%, quaternized chitosan 0.04-0.10% and water 99.80-99.91%. Low cost, natural degradation and less irritation.
However, the dust suppressant in the above patent can generate structure when the backwater in the mine is high salt water during the use process, thereby reducing the dust suppression efficiency in the mine.
Disclosure of Invention
Therefore, the invention provides an underground descaling dust suppressant and a preparation method thereof, which are used for solving the problem that scaling and dust suppression cannot be simultaneously solved in a high-salt water environment in the prior art.
On one hand, the invention provides an underground descaling dust suppressant, which comprises the following components in parts by weight: 5-10 parts of sodium dodecyl benzene sulfonate; 10-30 parts of sodium silicate; 5-10 parts of sodium carboxymethyl starch; 5-9 parts of glycerol; 2-5 parts of nitrilotriacetic acid; 93.6 to 98.83 portions of water.
Preferably, the downhole descaling dust suppressant comprises the following components in parts by weight: 10 parts of sodium dodecyl benzene sulfonate, 30 parts of sodium silicate, 10 parts of sodium carboxymethyl starch, 9 parts of glycerol, 5 parts of nitrilotriacetic acid and 98.83 parts of distilled water.
Preferably, the downhole descaling dust suppressant comprises the following components in parts by weight: 5 parts of sodium dodecyl benzene sulfonate, 10 parts of sodium silicate, 5 parts of sodium carboxymethyl starch, 5 parts of glycerol, 2 parts of nitrilotriacetic acid and 93.60 parts of distilled water.
Preferably, the downhole descaling dust suppressant comprises the following components in parts by weight: 8 parts of sodium dodecyl benzene sulfonate, 20 parts of sodium silicate, 8 parts of sodium carboxymethyl starch, 7 parts of glycerol, 4 parts of nitrilotriacetic acid and 95.30 parts of distilled water.
Further, when the underground descaling dust suppressant is stored, the components can be stored independently or prepared into a solution according to a ratio for storage.
In another aspect, the invention provides a method for preparing a downhole descaling dust suppressant, comprising the following steps:
step 1: respectively selecting specified parts by weight of sodium dodecyl benzene sulfonate, sodium silicate, sodium carboxymethyl starch, glycerol and nitrilotriacetic acid, and respectively dissolving in water;
step 2: and dissolving the materials in water, and stirring until the solution is colorless and transparent to prepare the underground descaling dust suppressant.
Further, the preparation process is carried out under normal temperature and pressure environment.
Further, the stirring time of the solution is 10-30 min.
Compared with the prior art, the descaling dust suppressant provided by the invention has the beneficial effects that the descaling dust suppressant can be used under the condition that mine backwater is high-salinity water, so that the problems of scaling and dust suppression are solved simultaneously. The components of the underground descaling dust suppressant are sequentially dissolved in water according to the mass ratio and the sequence, and the mixture is fully stirred and mixed for use. Or stirring the components except water, and dissolving in water at a certain ratio. The above processes are all operated at normal temperature.
Furthermore, the descaling dust suppressant can be prepared into a solution for storage, can be stored independently according to components and can be prepared when in use, so that the service life of the descaling dust suppressant is prolonged.
Further, the components of the invention have the following functions:
sodium dodecylbenzenesulfonate: the sodium dodecyl benzene sulfonate is neutral, is sensitive to water hardness, is not easy to oxidize, has strong foaming power and high detergency, is easy to be compounded with various auxiliaries, has lower cost, mature synthesis process and wide application field, and is an excellent anionic surfactant. The sodium dodecyl benzene sulfonate has obvious detergency effect on granular dirt, protein dirt and oily dirt, excellent detergency on granular dirt on natural fiber, raised detergency with the raised washing temperature, high protein dirt effect and rich foam. The sodium dodecyl benzene sulfonate is mainly used for preparing various liquid, powder and granular detergents, cleaning agents and the like. Meanwhile, the sodium dodecyl benzene sulfonate is used as an anionic surfactant, has good surface activity and strong hydrophilicity, and effectively reduces the tension of an oil-water interface to achieve the emulsification effect. Therefore, the sodium dodecyl benzene sulfonate is widely applied to the preparation of emulsion such as cosmetics, foods, printing and dyeing auxiliaries, pesticides and the like.
Sodium silicate: colorless orthogonal bipyramid crystals or white to off-white blocks or powder, is easily soluble in water, soluble in dilute sodium hydroxide solution, insoluble in ethanol and acid, strong in binding power, high in strength, good in acid resistance and heat resistance, and poor in alkali resistance and water resistance. The silicon compound is used for manufacturing various silicate products such as silica gel, white carbon black, zeolite molecular sieve, sodium metasilicate pentahydrate, silica sol, layered silicon, instant powdery sodium silicate, potassium sodium silicate and the like in a chemical system, and is a basic raw material of the silicon compound. Can be used as water softener, settling agent, adhesive, water softener, etc. in light industry.
Sodium carboxymethyl starch: sodium carboxymethyl starch (CMS) is a modified starch etherified with carboxymethyl, superior in performance to carboxymethyl cellulose (CMC), and is the best product for replacing CMC. The aqueous solution of CMS is stable and has excellent performance, and has the functions of adhesion, thickening, water retention, emulsification, suspension, dispersion and the like. CMS is used as a slurry stabilizer and a water-retaining agent in the oil well operation process, and plays a role in reducing water loss and improving the coalescence stability of clay particles in the drilling fluid. CMS has little influence on the plastic viscosity of the mud, has great influence on power and shearing force, is favorable for carrying drill cuttings, and can stabilize drilling fluid, reduce the loss and prevent well wall collapse particularly when drilling a salt-gypsum layer. Is particularly suitable for saline-alkali wells with high mineralization degree and high PH values.
Glycerol: can be used for preparing nitroglycerin, alkyd resin and epoxy resin; or making into various preparations, solvents, hygroscopic agents, antifreezing agents and sweeteners, and making into topical ointment or suppository etc.; meanwhile, the method can be used for preparing lubricant, moisture absorbent, anti-shrinking treatment agent for fabrics, dispersing agent and penetrating agent.
Nitrilotriacetic acid: nitrilotriacetic acid, also known as nitrilotriacetic acid, white crystalline powder. Dissolving in ammonia water and sodium hydroxide solution, and slightly dissolving in water and organic solvent; mainly used as complexing agent for extracting rare metal, polyurethane foaming catalyst, stabilizer for polystyrene production, water treatment agent, scale remover, non-phosphorus detergent, cyanide-free electroplating agent, color developer and the like.
Detailed Description
In order that the objects and advantages of the invention will be more clearly understood, the invention is further described below with reference to examples; it should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
10 parts of sodium dodecyl benzene sulfonate, 30 parts of sodium silicate, 10 parts of sodium carboxymethyl starch, 9 parts of glycerol and 5 parts of nitrilotriacetic acid are dissolved in 98.83 parts of distilled water, and stirred for 10-30min at normal temperature until the solution becomes colorless and transparent, thus obtaining the underground descaling dust suppressant.
Example 2
5 parts of sodium dodecyl benzene sulfonate, 10 parts of sodium silicate, 5 parts of sodium carboxymethyl starch, 5 parts of glycerol and 2 parts of nitrilotriacetic acid are dissolved in 93.60 parts of distilled water, and the mixture is stirred for 10-30min at normal temperature until the solution becomes colorless and transparent, thus obtaining the underground descaling dust suppressant.
Example 3
8 parts of dialkyl sodium benzenesulfonate, 20 parts of sodium silicate, 8 parts of sodium carboxymethyl starch, 7 parts of glycerol and 4 parts of nitrilotriacetic acid are dissolved in 95.30 parts of distilled water, and stirred for 10-30min at normal temperature until the solution becomes colorless and transparent, thus obtaining the underground descaling dust suppressant.
Through a field spraying experiment, the moisture-preserving dust-suppression. Effectively prevents the secondary flying of dust, has simple and convenient construction and ensures the continuous use of the fully mechanized mining unit.
It will be readily appreciated by those skilled in the art that the scope of the present invention is obviously not limited to these specific embodiments. Equivalent changes or substitutions of related technical features can be made by those skilled in the art without departing from the principle of the invention, and the technical scheme after the changes or substitutions can fall into the protection scope of the invention.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention; various modifications and alterations to this invention will become apparent to those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (8)

1. The underground descaling dust suppressant is characterized by comprising the following components in parts by weight:
5-10 parts of sodium dodecyl benzene sulfonate;
10-30 parts of sodium silicate;
5-10 parts of sodium carboxymethyl starch;
5-9 parts of glycerol;
2-5 parts of nitrilotriacetic acid;
93.6 to 98.83 portions of water.
2. The downhole descaling dust suppressant according to claim 1, comprising in parts by weight:
10 parts of sodium dodecyl benzene sulfonate, 30 parts of sodium silicate, 10 parts of sodium carboxymethyl starch, 9 parts of glycerol, 5 parts of nitrilotriacetic acid and 98.83 parts of distilled water.
3. The downhole descaling dust suppressant according to claim 1, comprising in parts by weight:
5 parts of sodium dodecyl benzene sulfonate, 10 parts of sodium silicate, 5 parts of sodium carboxymethyl starch, 5 parts of glycerol, 2 parts of nitrilotriacetic acid and 93.60 parts of distilled water.
4. The downhole descaling dust suppressant according to claim 1, comprising in parts by weight:
8 parts of sodium dodecyl benzene sulfonate, 20 parts of sodium silicate, 8 parts of sodium carboxymethyl starch, 7 parts of glycerol, 4 parts of nitrilotriacetic acid and 95.30 parts of distilled water.
5. The downhole descaling dust suppressant according to any one of claims 1-4, wherein the components are stored separately or formulated as a solution for storage.
6. A preparation method of a downhole descaling dust suppressant is characterized by comprising the following steps:
step 1: respectively selecting specified parts by weight of sodium dodecyl benzene sulfonate, sodium silicate, sodium carboxymethyl starch, glycerol and nitrilotriacetic acid, and respectively dissolving in water;
step 2: and dissolving the materials in water, and stirring until the solution is colorless and transparent to prepare the underground descaling dust suppressant.
7. The method for preparing the downhole descaling dust suppressant according to claim 6, wherein the preparation process is performed under normal temperature and pressure environment.
8. The method of claim 6, wherein the solution is stirred for 10-30 min.
CN202010536464.XA 2020-06-12 2020-06-12 Underground descaling dust suppressant and preparation method thereof Pending CN111808573A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113694827A (en) * 2021-08-27 2021-11-26 新希望六和股份有限公司 Equidistant particle cutting method of centrifugal particle forming machine for feed production

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KR20110018471A (en) * 2009-08-18 2011-02-24 황성규 Composition of asbestos scattering inhibitor for construction field
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CN102660227A (en) * 2012-05-02 2012-09-12 山西兆益矿用材料有限公司 Road dust suppressant
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CN107955583A (en) * 2017-03-27 2018-04-24 日东(青岛)研究院有限公司 A kind of efficient and environment-friendly type dust suppressant and preparation method thereof, application
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CN1468930A (en) * 2003-06-09 2004-01-21 中国铝业股份有限公司 Ecological road dust inhibitor
KR20110018471A (en) * 2009-08-18 2011-02-24 황성규 Composition of asbestos scattering inhibitor for construction field
KR20110048681A (en) * 2009-11-03 2011-05-12 폴텍주식회사 Dust restrainer
CN102660227A (en) * 2012-05-02 2012-09-12 山西兆益矿用材料有限公司 Road dust suppressant
CN105295844A (en) * 2015-11-17 2016-02-03 上海应用技术学院 Clean soil-stabilizing and dust-suppression agent and preparation method thereof
CN107955583A (en) * 2017-03-27 2018-04-24 日东(青岛)研究院有限公司 A kind of efficient and environment-friendly type dust suppressant and preparation method thereof, application
CN109370521A (en) * 2018-12-12 2019-02-22 神木市锦界安顺煤矿机电修造有限公司 Railway transportation coal oiliness antifreezing agent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113694827A (en) * 2021-08-27 2021-11-26 新希望六和股份有限公司 Equidistant particle cutting method of centrifugal particle forming machine for feed production

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Application publication date: 20201023