CN1215706A - Compound additive for increase of blending amount and performance of cement mixed material - Google Patents

Compound additive for increase of blending amount and performance of cement mixed material Download PDF

Info

Publication number
CN1215706A
CN1215706A CN 98110360 CN98110360A CN1215706A CN 1215706 A CN1215706 A CN 1215706A CN 98110360 CN98110360 CN 98110360 CN 98110360 A CN98110360 A CN 98110360A CN 1215706 A CN1215706 A CN 1215706A
Authority
CN
China
Prior art keywords
cement
qualified
gypsum
performance
alunite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 98110360
Other languages
Chinese (zh)
Other versions
CN1061953C (en
Inventor
赵洪义
史兆宪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Hongyi Technology Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN 98110360 priority Critical patent/CN1061953C/en
Publication of CN1215706A publication Critical patent/CN1215706A/en
Application granted granted Critical
Publication of CN1061953C publication Critical patent/CN1061953C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0042Powdery mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/023Fired or melted materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A composite additive for increasing the blending ratio and the performance of cement is prepared from calcium feldspar, alunite, lime stone, gypsum, table salt, and sodium methylene bisnaphthalene sulfonate through calcining and pulverization, and features high effect.

Description

A kind of composite additive that improves cement mixture volume and performance
The invention belongs to the cement technology field, relate to a kind of cement industry additive.
At present, in the manufacture of cement, adopting traditional activity excitation theory mostly (is NaoH-Ca (OH) 2-CaSO 4Pattern) and traditional enhancing theory coach, in order to improve cement performance and blending amount of mixture material.But the exciting agent selectivity of traditional activity excitation theory is strong, poor reliability, poor effect; It mainly is according to the fusion gypsum that tradition strengthens theory---lime expands when hydrated cementitious and makes cement stone closely knit and gain in strength, owing to replace gypsum when using, be prone to the rapid hardening problem of cement, thereby its reinforced effects and not obvious, and also be difficult to control when using.Though the kind of cement additire is a lot of in the existing cement technology, as hardening accelerator, frostproofer, accelerating chemicals, anti-fissuring agent, water reducer, activity excitant or the like, but these additives have unicity more, even when improving a certain performance of cement, other performances to cement produce detrimental action, and complex function is poor.Vertical Kiln for Cement Production enterprise ubiquity yields poorly at present simultaneously, and is of poor quality, the cost height, and benefit is low, the key issue of new height on the difficulty.
The purpose of this invention is to provide a kind of composite additive that improves cement mixture volume and performance, thereby overcome the existing above-mentioned defective of present technology.
The objective of the invention is to excite theoretical and strengthen theory with tradition is foundation, and adopting neutral salt is activity excitant and toughener, and its main points are that its raw material and weight percent consist of;
Lime feldspar 12-40%
Alunite 17-40%
Wingdale 11-15%
Gypsum 9-15%
Salt 4-12%
Methylene radical two bitter edible plant sodium sulfonate 5-15%
Preferred raw material and weight hundred scores consist of;
Lime feldspar 18-35%
Alunite 20-38%
Wingdale 11-14%
Gypsum 10-13%
Salt 5-10%
Methylene radical two bitter edible plant sodium sulfonate 8-13%
Preferred raw material and weight percent consist of:
Lime feldspar 20-25%
Alunite 30-36%
Wingdale 11-13%
Gypsum 11-13%
Salt 5-7%
Methylene radical two bitter edible plant sodium sulfonate 10-12%
The production method of additive of the present invention is first to lime feldspar, alunite, Wingdale, gypsum fragmentation, calcines through 20-50 minute down at 1150 ℃-1300 ℃, makes these raw material react withs.Secondly, after the raw material that calcination is good carries out conventional grinding with salt, add methylene radical two bitter edible plant sodium sulfonates again and mix, promptly make additive of the present invention.
Additive of the present invention and cement clinker and blended material proportioning adopt (0.5-1.0): 100, when pulverizing cement, add.
Additive result of use of the present invention mainly embodies following 4 aspects:
1, improves strength of cement, improve cement performance.Intensity can improve more than 30% in three days, seven days, and intensity can improve more than 20% in 28 days.Eliminate free lime effectively.The drying shrinkage of cement, freeze-thaw resistance, wear resistance, impervious, anti-carbonization ability, corrosion resistance, cement color etc. is improved effectively.
2, increase the blended material addition content by a relatively large margin, improve cement output, reduce cement cost.
Reach under the 52.5MPa situation at clinker strength, the slag addition content can reach 50-70%; Slag, coal gangue, zeolite, flyash mixed dosage can reach 25-40%; Can reach 30-50% during the blended material blending; Stably manufactured 425#R cement can improve cement output more than 20%.
3, accelerate the warehouse compartment turnover, guarantee that soundness of cement goes out the break-in lattice.Under the square one, can improve a label and produce cement, guarantee the super design scale of production line.Every index meets GB175-92, GB1344-92, GB12958-91 requirement.
4, utilized industrial residues such as slag, slag, flyash, coal gangue by a relatively large margin, save energy reduces environmental pollution.Make cement production enterprise can enjoy the preferential policy of country.
Further illustrate the present invention with embodiment below.
Embodiment 1:
Lime feldspar 15%
Alunite 40%
Wingdale 13%
Gypsum 13%
Salt 5%
Methylene radical two bitter edible plant sodium sulfonates 14%
Earlier lime feldspar, alunite, Wingdale, gypsum are mixed fragmentation by above-mentioned formula rate, under 1200 ℃,, make these raw material react withs through 50 minutes calcining.Secondly, after the raw material that calcining is good carries out conventional grinding with salt, add methylene radical two bitter edible plant sodium sulfonates again to stir, promptly make additive of the present invention.
Embodiment 2:
Lime feldspar 20%
Alunite 36%
Wingdale 13%
Gypsum 13%
Salt 6%
Methylene radical two bitter edible plant sodium sulfonates 12%
Different is that temperature is controlled at 1300 ℃ to production process with embodiment 1., and the time was controlled at 20 minutes.
Embodiment 3:
Lime feldspar 23%
Alunite 35%
Wingdale 12%
Gypsum 12%
Salt 6%
Methylene radical two bitter edible plant sodium sulfonates 12%
Different is that temperature is controlled at 1250 ℃ to production process with embodiment 1., and the time was controlled at 30 minutes.
Further react Application of Additives effect of the present invention with example more below, the proportioning of described additive and cement clinker and blended material adopts (0.5-1.0): 100.Example one
According to the data of enumerating in the table one, with additive and grog and the common grinding of slag that the present invention the 3rd embodiment makes, different ingredients, three kinds of raw material consumptions are different.Wherein grog is 19.5-69.2%, and slag is 20-70%, and additive is 0.5-0.8%.Data can be seen from table, with the recipe ratio of grog and gypsum, the effect highly significant.
Table one
The content sequence number Grog % Slag % Gypsum % Admixture % Fineness % Denseness % Stability SO 3 Initial set t Final set t 3 days 7 days 28 days
Anti-folding MPa Resistance to compression MPa Anti-folding MPa Resistance to compression MPa Anti-folding MPa Resistance to compression MPa
?1# 95.0 ?0.0 ?4.5 ?0.0 ?5.2 ?25.5 Qualified 2.0 ?1∶20 ?2∶25 ?4.3 ?25.3 ?5.5 ?34.6 ?7.8 ?50.8
?2# 69.2 ?20.0 ?9.0 ?0.8 ?5.7 ?26.0 Qualified 3.4 ?1∶00 ?2∶10 ?4.4 ?25.3 ?5.5 ?33.4 ?7.6 ?49.8
?3# 64.2 ?25.0 ?9.0 ?0.8 ?5.4 ?26.0 Qualified 3.3 ?1∶45 ?2∶30 ?4.2 ?24.0 ?5.4 ?32 ?7.6 ?48.3
?4# 59.2 ?30.0 ?9.0 ?0.8 ?5.8 ?26.0 Qualified 3.2 ?2∶00 ?3∶00 ?4.1 ?23.5 ?5.2 ?31 ?7.4 ?47.8
?5# 54.2 ?35.0 ?9.0 ?0.8 ?5.1 ?26.0 Qualified 3.1 ?2∶20 ?3∶30 ?4.0 ?23.0 ?5.0 ?30.5 ?7.2 ?45.2
?7# 95.0 ?0.0 ?5.0 ?0.0 ?5.0 ?25.5 Qualified 2.1 1∶40 ?2∶30 ?4.0 ?23.9 ?5.5 ?32.8 ?7.3 ?48.0
?8# 59.5 ?30.0 ?10.0 ?0.5 ?5.4 ?25.5 Qualified 3.8 ?1∶45 ?2∶55 ?4.3 ?25.5 ?6.5 ?38.1 ?8.3 ?54.8
?9# 49.5 ?40.0 ?10.0 ?0.5 ?5.6 ?26.0 Qualified 3.6 ?2∶00 ?2∶40 ?4.3 ?25.0 ?6.6 ?41.0 ?8.5 ?56.5
?10# 39.5 ?50.0 ?10.0 ?0.5 ?5.2 ?26.0 Qualified 3.5 ?2∶00 ?3∶25 ?5.0 ?25.7 ?7.5 ?37.0 ?9.3 ?53.3
?11# 29.5 ?60.0 ?10.0 ?0.5 ?5.6 ?26.0 Qualified 3.4 ?2∶40 ?3∶45 ?4.9 ?24.0 ?7.4 ?35.3 ?8.7 ?48.5
?12# 19.5 ??70.0 ?10.0 ?0.5 ?4.9 ?26.0 Qualified 3.2 ?2∶50 ?4∶10 ?5.3 ?23.2 ?6.5 ?31.0 ?8.2 ?45.4
Example two
According to the data of enumerating in the table two, with additive and the common grindings of blended material such as grog and flyash that the present invention the 3rd embodiment makes, data from table, its effect is also very obvious.
Table two
The content sequence number Grog % Gypsum % Zeolite % Slag % Slag % Flyash % Wingdale % Admixture % Stability SO 3 Initial set t Final set t 3 days 7 days 28 days
Anti-folding MPa Resistance to compression MPa Anti-folding MPa Resistance to compression MPa Anti-folding MPa Resistance to compression MPa
?1# 95.5 ?4.5 ?0.0 Qualified 1.9 ?1∶45 ?2∶30 ?5.4 ?33.4 ?6.7 ?42.1 ?8.0 ?56.4
?2# 71.0 ?9.0 ?20.0 ?1.0 Qualified 3.3 ?2∶40 ?3∶10 ?5.4 ?32.8 ?6.8 ?41.5 ?8.2 ?55.8
?3# 61.0 ?9.0 ?30.0 ?1.0 Qualified 3.2 ?2∶30 ?3∶20 ?5.2 ?29.4 ?6.2 ?38.0 ?8.0 ?53.2
?4# 51.0 ?9.0 ?40.0 ?1.0 Qualified 3.0 ?2∶50 ?4∶00 ?4.6 ?26.2 ?6.0 ?33.0 ?7.4 ?46.2
?5# 95.0 ?5.0 Qualified 2.6 ?2∶25 ?3∶30 ?5.7 ?33.0 ?6.8 ?44.2 ?8.0 ?55.4
?6# 63.5 ?6.0 ?20.0 ?4.0 ?1.0 Qualified 2.4 ?2∶31 ?3∶10 ?4.9 ?27.0 ?5.9 ?37.5 ?8.2 ?49.6
?7# 63.5 ?6.0 ?20.0 ?4.0 ?1.0 ?4.0 ?1.0 Qualified 2.4 2∶11 ?3∶10 ?5.9 ?33.5 ?7.1 ?40.9 ?8.4 ?53.6
?8# 61.5 ?6.0 ?20.0 ?2.0 ?5.0 ?4.0 ?1.0 Qualified 2.3 ?2∶10 ?2∶51 ?5.6 ?34.0 ?7.2 ?42.3 ?8.9 ?54.2
?9# 59.5 ?6.0 ?25.0 ?2.0 ?2.0 ?4.0 ?1.0 Qualified 2.2 ?2∶30 ?4∶20 ?4.7 ?21.9 ?5.7 ?35.4 ?7.8 ?44.4
?10# 53.5 ?6.0 ?33.0 ?2.0 ?4.0 ?1.0 Qualified 2.1 ?1∶55 ?3∶27 ?4.4 ?21.7 ?5.4 ?32.3 ?7.6 ?43.1
?11# 47.5 ?6.0 ?10.0 ?30.0 ?5.0 ?1.0 Qualified 2.5 ?2∶45 ?4∶15 ?5.9 ?28.5 ?7.9 ?38.0 ?8.8 ?55.1
?12# 57.5 ?6.0 ?15.0 ?15.0 ?5.0 ?1.0 Qualified 2.4 ?2∶00 ?3∶40 ?5.8 ?34.0 ?7.9 ?43.3 ?9.0 ?56.2
?13# 52.5 ?6.0 ?20.0 ?15.0 ?5.0 ?1.0 Qualified 2.5 ?2∶30 ?4∶10 ?5.3 ?27.6 ?6.8 ?38.5 ?8.4 ?49.2
?14# 57.5 ?6.0 ?20.0 ?15.0 ?1.0 Qualified 2.6 ?2∶40 ?4∶10 ?5.9 ?29.6 ?7.0 ?37.0 ?8.2 ?50.8
?15# 57.5 ?6.0 ?15.0 ?20.0 ?1.0 Qualified 2.6 ?2∶45 ?4∶10 ?5.7 ?28.4 ?6.8 ?34.2 ?8.0 ?49.9

Claims (3)

1, a kind of composite additive that improves cement mixture volume and performance is characterized in that its raw material and weight percent proportioning are;
Lime feldspar 12-40%
Alunite 17-40%
Wingdale 11-15%
Gypsum 9-15%
Salt 4-12%
Methylene radical two bitter edible plant sodium sulfonate 5-10%
2, additive according to claim 1 is characterized in that said raw material and weight percent proportioning are:
Lime feldspar 18-35%
Alunite 20-38%
Wingdale 11-14%
Gypsum 10-13%
Salt 5-10%
Methylene radical two bitter edible plant sodium sulfonate 8-13%
3, additive according to claim 1 is characterized in that said raw material and weight percent proportioning are:
Lime feldspar 20-20%
Alunite 30-36%
Wingdale 11-13%
Gypsum 11-13%
Salt 5-7%
Methylene radical two bitter edible plant sodium sulfonate 10-12%
CN 98110360 1998-07-21 1998-07-21 Compound additive for increase of blending amount and performance of cement mixed material Expired - Fee Related CN1061953C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 98110360 CN1061953C (en) 1998-07-21 1998-07-21 Compound additive for increase of blending amount and performance of cement mixed material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 98110360 CN1061953C (en) 1998-07-21 1998-07-21 Compound additive for increase of blending amount and performance of cement mixed material

Publications (2)

Publication Number Publication Date
CN1215706A true CN1215706A (en) 1999-05-05
CN1061953C CN1061953C (en) 2001-02-14

Family

ID=5220414

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 98110360 Expired - Fee Related CN1061953C (en) 1998-07-21 1998-07-21 Compound additive for increase of blending amount and performance of cement mixed material

Country Status (1)

Country Link
CN (1) CN1061953C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103864336A (en) * 2014-02-09 2014-06-18 黄小仙 Preparation method of cement composite additive
CN107902928A (en) * 2017-11-02 2018-04-13 马鞍山市宝奕金属制品工贸有限公司 A kind of method that blast furnace cinder prepares cement
CN111943559A (en) * 2020-08-25 2020-11-17 湖南加美乐素新材料股份有限公司 Cement high-compatibility water reducing agent
CN112250330A (en) * 2020-09-11 2021-01-22 邓州中联水泥有限公司 Green environment-friendly cement and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103864336A (en) * 2014-02-09 2014-06-18 黄小仙 Preparation method of cement composite additive
CN107902928A (en) * 2017-11-02 2018-04-13 马鞍山市宝奕金属制品工贸有限公司 A kind of method that blast furnace cinder prepares cement
CN111943559A (en) * 2020-08-25 2020-11-17 湖南加美乐素新材料股份有限公司 Cement high-compatibility water reducing agent
CN111943559B (en) * 2020-08-25 2022-04-22 湖南加美乐素新材料股份有限公司 Cement high-compatibility water reducing agent
CN112250330A (en) * 2020-09-11 2021-01-22 邓州中联水泥有限公司 Green environment-friendly cement and preparation method thereof

Also Published As

Publication number Publication date
CN1061953C (en) 2001-02-14

Similar Documents

Publication Publication Date Title
CN1837121A (en) Method for preparing sulphate aluminium cement by red mud
CN101037312A (en) Middle-effective pumping aid
CN110606722B (en) Building wallboard and preparation method thereof
CN1654411A (en) Fast repairing concrete material and its use method
CN106220013A (en) A kind of Desulphurization flyash complex mineral blending material and preparation method thereof
CN1278985C (en) Blast furnace titanium slag compounded micro powder used in cement, concrete and mortar
CN1028088C (en) Anti-erosion material of cement mortar or concrete and prodn. method thereof
CN1792946A (en) Grinding aiding increacing agent for cement and preparation process thereof
CN102329119A (en) High performance concrete admixture and preparation method thereof
CN113860802A (en) Environment-friendly high-performance mineral admixture and preparation method and application thereof
CN1331797C (en) Multifunctional chlorine-free alkali-free compound concrete slag admixture and its preparation process
CN1061953C (en) Compound additive for increase of blending amount and performance of cement mixed material
CN101037308A (en) Preparation method of clinker-free cement and concrete prepared with same
CN1640843A (en) Method for preparing cement using desulfurized clinker as slow coagulating agent
CN114988738B (en) Modified dolomite powder, preparation method thereof and concrete
CN100344569C (en) High efficient wide-spectrum sulfide resistant gelled material and preparation process thereof
CN1640845A (en) Concrete cementing material using desulfurized gypsum as accelerator
CN1267372C (en) Gangue active mixed material, its preparation method and high-performance cement
CN1792955A (en) High active concrete admixture
CN113831093A (en) High slump retaining recycled concrete and preparation method thereof
CN1215009C (en) White silicate cement and its production method
CN1300036C (en) Modifier for water reducing agent of calcium lignosulfonate, sodium lignosulfonate and magnesium lignosulfonate, etc.
CN1296306C (en) Process for fast baking early strength silicate cement clinker
CN1124999C (en) Additive for middle-or low-strength concrete
CN1486951A (en) Steel slag cement

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: SHANDONG HONGYI SCIENCE CO., LTD.

Free format text: FORMER OWNER: ZHAO HONGYI

Effective date: 20080829

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20080829

Address after: No. 369, Renmin Road, Hedong District, Shandong, Linyi

Patentee after: Shandong Hongyi Technology Co., Ltd.

Address before: Energy monitoring station of Shandong, Linyi (No. 215 Yimeng Road, Linyi)

Patentee before: Zhao Hongyi

C56 Change in the name or address of the patentee
CP01 Change in the name or title of a patent holder

Address after: 276034 No. 369 Renmin Road, Hedong District, Shandong, Linyi

Patentee after: Shandong Hongyi Technology Co., Ltd.

Address before: 276034 No. 369 Renmin Road, Hedong District, Shandong, Linyi

Patentee before: Shandong Hongyi Technology Co., Ltd.

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20010214

Termination date: 20130721