CN113860802A - Environment-friendly high-performance mineral admixture and preparation method and application thereof - Google Patents
Environment-friendly high-performance mineral admixture and preparation method and application thereof Download PDFInfo
- Publication number
- CN113860802A CN113860802A CN202110817251.9A CN202110817251A CN113860802A CN 113860802 A CN113860802 A CN 113860802A CN 202110817251 A CN202110817251 A CN 202110817251A CN 113860802 A CN113860802 A CN 113860802A
- Authority
- CN
- China
- Prior art keywords
- parts
- friendly high
- mineral admixture
- environment
- performance mineral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
- C04B12/005—Geopolymer cements, e.g. reaction products of aluminosilicates with alkali metal hydroxides or silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/14—Cements containing slag
- C04B7/147—Metallurgical slag
- C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
- C04B7/1535—Mixtures thereof with other inorganic cementitious materials or other activators with alkali metal containing activators, e.g. sodium hydroxide or waterglass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/26—Cements from oil shales, residues or waste other than slag from raw materials containing flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Road Paving Structures (AREA)
Abstract
The invention discloses an environment-friendly high-performance mineral admixture, a preparation method and an application thereof, wherein the environment-friendly high-performance mineral admixture is composed of the following components in parts by weight: 400 parts of slag, 400 parts of fly ash, 500 parts of red mud, 100 parts of alkali excitant and 1-3 parts of water reducing agent. The environment-friendly high-performance mineral admixture provided by the invention is prepared from the following raw materials in percentage by mass: the materials are wastes generated in industrial production, but the materials have certain activity, and the active mineral materials can excite certain strength under the action of the alkaline exciting agent, so that the active mineral materials are suitable for replacing or partially replacing cement in cement stabilized macadam, on one hand, the construction cost is reduced, on the other hand, the generation of cracks on a base course is reduced by reducing the cement consumption, and the service life of a road is prolonged.
Description
Technical Field
The invention relates to the technical field of mineral admixtures, and particularly relates to an environment-friendly high-performance mineral admixture and a preparation method and application thereof.
Background
In current traffic construction, the use of cement stabilized macadam as a semi-rigid base course is the most common pavement structure. The cement stabilized macadam base has higher compressive strength and bearing capacity, has certain bending tensile strength, and has the characteristic of continuous increase along with the increase of the age. Therefore, the asphalt pavement adopting the cement stabilized macadam base usually has smaller deformation and stronger load diffusion capacity, thereby improving the capacity of resisting the fatigue damage of the driving load of the pavement. However, a large number of engineering practices have shown that cement stabilized macadam foundations suffer from the following disadvantages:
adding 3-6% cement into the water-stable base layer. As a high-energy consumption material, the cement is mainly produced by limestone (calcium carbonate). Limestone needs to be mined during the collection process, so that the natural landscape and green vegetation of a mountain can be seriously damaged, and a large amount of greenhouse gas and dust can be discharged during the collection process, thereby causing pollution to the environment and the atmosphere. In addition, the production of cement by using limestone is a process with high energy consumption, high pollution and high emission;
secondly, the shrinkage cracking of the cement stabilized macadam base can cause the reflective cracks of the asphalt pavement. The use survey of the domestic constructed highway shows that the early pavement damage phenomena of cracking, rutting, oil flooding, loosening, pit and water damage and the like occur on a plurality of semi-rigid pavements for 1 to 3 years even if the vehicles are communicated for a long time;
thirdly, the average manufacturing cost of the cement stabilized macadam base is about 300 yuan/m3The construction cost is high.
Therefore, selecting a suitable cementitious material to replace cement, either in whole or in part, is an effective means to solve the above problems.
In view of this, the invention is particularly proposed.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide an environment-friendly high-performance mineral admixture, a preparation method and application thereof.
The invention is realized by the following steps:
the invention provides an environment-friendly high-performance mineral admixture which comprises the following components in parts by weight: 400 parts of slag, 400 parts of fly ash, 500 parts of red mud, 100 parts of alkali excitant and 1-3 parts of water reducing agent.
The invention also provides a preparation method of the environment-friendly high-performance mineral admixture, which comprises the following steps: sequentially mixing slag, fly ash, red mud, a water reducing agent and a water reducing agent according to a proportion, and grinding into fine powder to obtain the environment-friendly high-performance mineral admixture.
The invention also provides an application of the environment-friendly high-performance mineral admixture in traffic road construction.
The invention has the following beneficial effects:
the invention provides an environment-friendly high-performance mineral admixture, a preparation method and application thereof, wherein the environment-friendly high-performance mineral admixture is prepared from the following raw materials in percentage by weight: the materials are wastes generated in industrial production, but the materials have certain activity, and the active mineral materials can excite certain strength under the action of an alkaline exciting agent, are suitable for replacing or partially replacing cement in cement stabilized macadam, are used in traffic construction of a cement stabilized base course, reduce the generation of base course cracks and prolong the service life of a road.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained from the drawings without inventive effort.
FIG. 1 is an appearance diagram of an environment-friendly high-performance mineral admixture according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
In current traffic construction, the use of cement stabilized macadam as a semi-rigid base course is the most common pavement structure. However, a number of engineering practices have shown that cement stabilized macadam substrates suffer from a number of disadvantages, particularly problems associated with the use of cement and limestone. Therefore, selecting a suitable cementitious material to replace cement, either in whole or in part, is an effective means to solve the above problems.
The discharge amount of industrial solid wastes in China is 30 hundred million tons every year, wherein the discharge amount of the industrial solid wastes comprises a large amount of slag, fly ash and red mud. The discharge and the stacking of the materials cause the problems of waste of land resources and environmental pollution. However, the materials have certain activity, can excite certain strength under the action of an alkali activator, are suitable for replacing cement in cement stabilized macadam, reduce the construction cost on one hand, and reduce the generation of base cracks by reducing the using amount of the cement on the other hand, thereby prolonging the service life of roads.
In order to achieve the above object of the present invention, the following technical solutions are adopted.
In a first aspect, an embodiment of the present invention provides an environment-friendly high-performance mineral admixture, which is composed of the following components in parts by weight: 400 parts of slag, 400 parts of fly ash, 500 parts of red mud, 100 parts of alkali excitant and 1-3 parts of water reducing agent.
The embodiment of the invention provides an environment-friendly high-performance mineral admixture, which is prepared by adopting the following raw materials of a large amount of wastes which are produced in the current industry, such as byproducts in a blast furnace ironmaking process: slag, industrial waste slag discharged from a power plant using coal as a raw material: fly ash and solid waste produced in the process of preparing alumina by using bauxite: red mud. The 3 materials are used as raw materials for preparing the environment-friendly high-performance mineral admixture. The reason is that: slag itself has a good latent hydraulic activity and is easily activated by alkali, while the activity of other aluminosilicate materials is mostly difficult to be activated by alkali and to obtain good properties like alkali slag cement. Sodium oxide and potassium oxide in red mud are often combined as alkali compounds, so red mud is a raw material of alkali-binding material that can replace part of slag. The fly ash is naturally acidic, and the active ingredients of the fly ash can be excited under alkaline conditions. The 3 materials are excited to have certain strength under the action of the alkali activator, are suitable for replacing cement in cement stabilized macadam, reduce the construction cost on one hand, and reduce the generation of base cracks by reducing the cement consumption on the other hand, thereby prolonging the service life of roads.
In an alternative embodiment, the environment-friendly high-performance mineral admixture is composed of the following components in parts by weight: 350 parts of slag, 420 parts of fly ash, 480 parts of red mud, 120 parts of alkali excitant and 1-3 parts of water reducing agent.
In an alternative embodiment, the red mud should be dried, otherwise, the drying treatment at 50-60 ℃ should be carried out.
In an alternative embodiment, the alkaline activator comprises one or more of calcium hydroxide, sodium sulfate, and calcium sulfate.
In an alternative embodiment, the water-reducing agent is a polycarboxylic acid type high performance water-reducing agent.
In an optional embodiment, the specific surface area of the environment-friendly high-performance mineral admixture is 350-500m2Per kg, with a fineness of 1.0-3.5%.
In an alternative embodiment, the environmentally friendly high performance mineral admixture has a 28d mortar compressive strength of 40 to 50 MPa.
In a second aspect, an embodiment of the present invention further provides a method for preparing the environment-friendly high-performance mineral admixture, including: sequentially mixing slag, fly ash, red mud, a water reducing agent and a water reducing agent according to a proportion, and grinding into fine powder to obtain the environment-friendly high-performance mineral admixture.
In an alternative embodiment, the mixing time is from 25min to 30min and the milling time is from 60 to 100 min. In the preparation process, the mixing step is to uniformly mix the raw materials and grind the raw materials so that the properties of the obtained environment-friendly high-performance mineral admixture, such as fineness, specific surface area, setting time and the like, meet the use requirements.
In a third aspect, the embodiment of the invention provides an application of an environment-friendly high-performance mineral admixture in traffic road construction.
In an alternative embodiment, the environmentally friendly high performance mineral admixture is used in the construction of a cement stabilized base.
The features and properties of the present invention are described in further detail below with reference to examples.
In the following examples of the present invention, the raw material sources, components, preparation and experimental methods were the same as those of the comparative examples.
The water reducing agent used in the following examples and comparative examples should meet the technical requirements of table 1.
TABLE 1
Example 1
The embodiment provides an environment-friendly high-performance mineral admixture, which is prepared by the following steps:
weighing various raw materials according to the proportion of 200 parts of slag, 400 parts of fly ash, 100 parts of red mud, 1 part of alkaline activator and 1 part of water reducing agent. Wherein the alkaline activator is calcium hydroxide;
secondly, adding the measured materials into a dry mixer in sequence of slag, fly ash, red mud, an alkaline activator and a water reducing agent, and performing dry mixing for 25 min;
thirdly, the mixture is treated by a ball mill for 60 min;
and fourthly, testing the performance. Appearance properties see fig. 1. The specific surface area, fineness, setting time, safety, mortar strength and the like of the material, and the performance test results are shown in tables 2 and 3.
Example 2
The embodiment provides an environment-friendly high-performance mineral admixture, which is prepared by the following steps:
weighing various raw materials according to the proportion of 400 parts of slag, 500 parts of fly ash, 200 parts of red mud, 3 parts of an alkaline activator and 3 parts of a water reducing agent. Wherein the alkali activator is sodium hydroxide;
secondly, adding the measured materials into a dry mixer in sequence of slag, fly ash, red mud, sodium sulfate, calcium acetate and a water reducing agent, and performing dry mixing for 30 min;
thirdly, the mixture is processed by a ball mill for 100 min;
and fourthly, testing the performance. And testing the specific surface area, the fineness, the setting time, the safety, the mortar strength and the like of the material. The results of the performance tests are shown in tables 2 and 3.
Example 3
The embodiment provides an environment-friendly high-performance mineral admixture, which is prepared by the following steps:
weighing various raw materials according to the proportion of 300 parts of slag, 400 parts of fly ash, 100 parts of red mud, 2 parts of an alkaline activator and 2 parts of a water reducing agent. Wherein the alkaline activator is sodium sulfate;
secondly, adding the measured materials into a dry mixer in sequence of slag, fly ash, red mud, sodium sulfate, calcium acetate and a water reducing agent, and performing dry mixing for 25 min;
thirdly, the mixture is treated by a ball mill for 60 min;
and fourthly, testing the performance. And testing the specific surface area, the fineness, the setting time, the safety, the mortar strength and the like of the material. The results of the performance tests are shown in tables 2 and 3.
Example 4
The embodiment provides an environment-friendly high-performance mineral admixture, which is prepared by the following steps:
weighing various raw materials according to the proportion of 200 parts of slag, 400 parts of fly ash, 100 parts of red mud, 3 parts of an alkaline activator and 3 parts of a water reducing agent. Wherein the alkaline activator is calcium sulfate;
secondly, adding the measured materials into a dry mixer in sequence of slag, fly ash, red mud, sodium sulfate, calcium acetate and a water reducing agent, and performing dry mixing for 30 min;
thirdly, the mixture is processed by a ball mill for 100 min;
and fourthly, testing the performance. And testing the specific surface area, the fineness, the setting time, the safety, the mortar strength and the like of the material. The results of the performance tests are shown in tables 2 and 3.
Table 2 below shows the results of the performance tests of the environmentally friendly high performance mineral admixtures of examples 1 to 4. The test is carried out according to the test methods specified in the methods for measuring the specific surface area of the cement (GB/T8074), the method for testing the fineness of the cement (GB/T1345), the method for testing the standard consistency of the cement by using water, the setting time and the stability (GB/T1346-2011) and the method for analyzing the chemical properties of the cement (GB/T176-2017).
TABLE 2
Table 3 below shows the test results (in MPa) of the compression strength and the flexural strength of the environmentally friendly high performance mineral admixtures of examples 1 to 4, and the mortar strength was measured according to the method for testing the mortar strength of GB/T17671-1999 cement.
TABLE 3
From the test results in tables 2 and 3, the compression strength of the environmentally-friendly high-performance mineral admixture mortar provided by the embodiment of the invention is substantially equal to that of P.O 42.5.5 cement, but the flexural strength is more excellent, and the mortar meets the national standard requirements. The cement mortar can completely replace part of cement and is applied to the construction of traffic roads, so that the construction cost is reduced, the generation of cracks on a base layer is reduced by reducing the cement consumption, and the service life of the roads is prolonged.
Comparative example 1
Similar to the procedure of example 1, except that: 200 parts of slag, 400 parts of fly ash, 0 part of red mud, 3 parts of an alkaline activator and 3 parts of a water reducing agent.
Comparative example 2
Similar to the procedure of example 2, except that: 0 part of slag, 500 parts of fly ash, 200 parts of red mud, 1 part of an alkaline activator and 1 part of a water reducing agent.
Comparative example 3
Similar to the procedure of example 3, except that: 300 parts of slag, 0 part of fly ash, 100 parts of red mud, 2 parts of an alkaline activator and 2 parts of a water reducing agent.
Comparative example 4
Similar to the procedure of example 1, except that: the grinding time was 30 min. The result is: the specific surface area of the mixture is 266m2/kg, not less than 320m2Requirement of/kg.
Table 4 below shows the test results (in MPa) of the compressive strength and the flexural strength of the environmentally friendly high performance mineral admixture in comparative examples 1 to 3, and the mortar strength was measured according to the method for testing the mortar strength of GB/T17671-1999 cement mortar.
TABLE 4
According to the test results in the table 4, if the red mud is not added, only the slag and the fly ash are added, the hydration reaction of the mixed material is slow, and the strength, particularly the early attenuation, is too large; if the proportion of the red mud is increased, the strength of the admixture is obviously increased, but cracks are easily generated, the admixture is not suitable for a cement stabilized base layer, the alkali content in the red mud is high, and an alkali-aggregate reaction is easily generated. Therefore, the proportion of red mud is preferably controlled to 20% or less.
To sum up, the embodiment of the invention provides an environment-friendly high-performance mineral admixture, which comprises the following components in parts by weight: 400 parts of slag, 400 parts of fly ash, 500 parts of red mud, 100 parts of alkali excitant and 1-3 parts of water reducing agent. Wherein the alkaline activator comprises one or more of calcium hydroxide, sodium sulfate, calcium sulfate and sodium carbonate materials, the water reducing agent is a polycarboxylic acid type high-performance water reducing agent, the red mud is dried, and otherwise, the drying treatment at 50-60 ℃ is carried out. The preparation method of the environment-friendly high-performance mineral admixture comprises the following steps: firstly, weighing slag, fly ash, red mud, an alkaline activator and a water reducing agent according to the weight proportion for later use; then, adding the measured materials into a dry mixer according to the sequence of slag, fly ash, red mud, an alkaline activator and a water reducing agent, carrying out dry mixing for 25-30 min, and finally carrying out ball mill treatment on the mixture for 60-100min to obtain the environment-friendly high-performance mineral admixture. From the detection result, the compression strength of the environment-friendly high-performance mineral admixture mortar provided by the embodiment of the invention is approximately equivalent to that of P.O 42.5.5 cement, but the flexural strength is more excellent. The cement can be completely or partially replaced, and the cement-free composite material can be applied to the construction of traffic roads, so that the construction cost is reduced, the generation of cracks on a base layer is reduced by reducing the cement consumption, and the service life of the roads is prolonged.
The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention, and various modifications and changes may be made to the present invention by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (10)
1. The environment-friendly high-performance mineral admixture is characterized by comprising the following components in parts by weight: 400 parts of slag, 400 parts of fly ash, 500 parts of red mud, 100 parts of alkali excitant and 1-3 parts of water reducing agent.
2. The environment-friendly high-performance mineral admixture according to claim 1, which is characterized by comprising the following components in parts by weight: 350 parts of slag, 420 parts of fly ash, 480 parts of red mud, 120 parts of alkali excitant and 1-3 parts of water reducing agent.
3. The environment-friendly high-performance mineral admixture according to claim 1, wherein the red mud is dried red mud.
4. The environment-friendly high-performance mineral admixture according to claim 1, wherein the alkali-activator comprises one or more of calcium hydroxide, sodium sulfate and calcium sulfate, and the water-reducing agent is a polycarboxylic acid type high-performance water-reducing agent.
5. The environment-friendly high-performance mineral admixture as defined in claim 1, wherein the specific surface area of the environment-friendly high-performance mineral admixture is 350-500m2Per kg, with a fineness of 1.0-3.5%.
6. The environment-friendly high-performance mineral admixture as defined in claim 1, wherein the environment-friendly high-performance mineral admixture has a 28d mortar compressive strength of 40-50 MPa.
7. A method for preparing an environmentally friendly high performance mineral admixture as defined in any one of claims 1 to 6 comprising: sequentially mixing slag, fly ash, red mud, a water reducing agent and a water reducing agent according to a proportion, and grinding into fine powder to obtain the environment-friendly high-performance mineral admixture.
8. The method of claim 7, wherein the mixing time is 25min to 30min and the milling time is 60 to 100 min.
9. Use of the environmentally friendly high performance mineral admixture according to any one of claims 1 to 6 or the environmentally friendly high performance mineral admixture prepared by the preparation method according to any one of claims 7 to 8 in the construction of traffic roads.
10. The use according to claim 9, wherein the environmentally friendly high performance mineral admixture is used in the construction of cement stabilized substrates.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110817251.9A CN113860802A (en) | 2021-07-20 | 2021-07-20 | Environment-friendly high-performance mineral admixture and preparation method and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110817251.9A CN113860802A (en) | 2021-07-20 | 2021-07-20 | Environment-friendly high-performance mineral admixture and preparation method and application thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113860802A true CN113860802A (en) | 2021-12-31 |
Family
ID=78990173
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110817251.9A Pending CN113860802A (en) | 2021-07-20 | 2021-07-20 | Environment-friendly high-performance mineral admixture and preparation method and application thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113860802A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114685069A (en) * | 2022-04-27 | 2022-07-01 | 大唐同舟科技有限公司 | Sulfate-excited fly ash cementing material and preparation method and application thereof |
CN115355004A (en) * | 2022-09-20 | 2022-11-18 | 山东理工大学 | Method for modifying and strengthening pressure relief of red mud slurry for coal bed rock burst drilling |
CN116063019A (en) * | 2022-12-12 | 2023-05-05 | 上海百奥恒新材料有限公司 | Red mud-based composite admixture and preparation method thereof |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090188409A1 (en) * | 2006-05-25 | 2009-07-30 | Nittetsu Cement Co., Ltd. | Grouting material |
CN103193403A (en) * | 2013-03-25 | 2013-07-10 | 中国矿业大学 | Preparation method of high-activity red mud-based concrete admixture |
CN106242349A (en) * | 2016-08-05 | 2016-12-21 | 武汉理工大学 | A kind of granite stone powder complex mineral blending material and preparation method thereof |
CN108117292A (en) * | 2017-12-28 | 2018-06-05 | 江西省建筑材料工业科学研究设计院 | A kind of copper tailing slag complex mineral blending material and preparation method thereof |
CN108439831A (en) * | 2018-01-30 | 2018-08-24 | 武汉理工大学 | A kind of exciting agent and red-mud coal ash cementitious material |
CN111153621A (en) * | 2019-12-31 | 2020-05-15 | 杭州山能实业有限公司 | Concrete composite admixture and preparation method thereof |
CN111393108A (en) * | 2020-03-27 | 2020-07-10 | 江苏东交智控科技集团股份有限公司 | Environment-friendly cement-stabilized macadam and application thereof |
CN111704406A (en) * | 2020-05-28 | 2020-09-25 | 重庆三峰环境集团股份有限公司 | Application of household garbage incineration fly ash composite admixture in cement stabilized macadam mixture |
-
2021
- 2021-07-20 CN CN202110817251.9A patent/CN113860802A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090188409A1 (en) * | 2006-05-25 | 2009-07-30 | Nittetsu Cement Co., Ltd. | Grouting material |
CN103193403A (en) * | 2013-03-25 | 2013-07-10 | 中国矿业大学 | Preparation method of high-activity red mud-based concrete admixture |
CN106242349A (en) * | 2016-08-05 | 2016-12-21 | 武汉理工大学 | A kind of granite stone powder complex mineral blending material and preparation method thereof |
CN108117292A (en) * | 2017-12-28 | 2018-06-05 | 江西省建筑材料工业科学研究设计院 | A kind of copper tailing slag complex mineral blending material and preparation method thereof |
CN108439831A (en) * | 2018-01-30 | 2018-08-24 | 武汉理工大学 | A kind of exciting agent and red-mud coal ash cementitious material |
CN111153621A (en) * | 2019-12-31 | 2020-05-15 | 杭州山能实业有限公司 | Concrete composite admixture and preparation method thereof |
CN111393108A (en) * | 2020-03-27 | 2020-07-10 | 江苏东交智控科技集团股份有限公司 | Environment-friendly cement-stabilized macadam and application thereof |
CN111704406A (en) * | 2020-05-28 | 2020-09-25 | 重庆三峰环境集团股份有限公司 | Application of household garbage incineration fly ash composite admixture in cement stabilized macadam mixture |
Non-Patent Citations (3)
Title |
---|
刘龙: ""赤泥-粉煤灰-矿渣碱激发胶凝材料性质的研究"", 《洛阳理工学院学报(自然科学版)》 * |
张兰芳著: "《碱激发矿渣水泥和混凝土》", 31 August 2018, 西南交通大学出版社 * |
房永广等编著: "《赤泥资源化利用理论及技术》", 31 July 2020 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114685069A (en) * | 2022-04-27 | 2022-07-01 | 大唐同舟科技有限公司 | Sulfate-excited fly ash cementing material and preparation method and application thereof |
CN115355004A (en) * | 2022-09-20 | 2022-11-18 | 山东理工大学 | Method for modifying and strengthening pressure relief of red mud slurry for coal bed rock burst drilling |
CN115355004B (en) * | 2022-09-20 | 2024-03-19 | 山东理工大学 | Modification and reinforcement pressure relief method for red mud slurry for rock burst drilling of coal seam |
CN116063019A (en) * | 2022-12-12 | 2023-05-05 | 上海百奥恒新材料有限公司 | Red mud-based composite admixture and preparation method thereof |
CN116063019B (en) * | 2022-12-12 | 2024-01-30 | 上海百奥恒新材料有限公司 | Red mud-based composite admixture and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110041028A (en) | A kind of regeneration concrete and preparation method thereof using building waste | |
CN113860802A (en) | Environment-friendly high-performance mineral admixture and preparation method and application thereof | |
CN111205003B (en) | Preparation method of regenerated cementing material | |
CN107572841B (en) | Low-carbon cementing material and method for preparing concrete | |
CN105621907A (en) | Calcium-base geopolymer and preparation method thereof | |
CN113698164B (en) | Anti-cracking anti-settling road water-stabilizing layer material and preparation method thereof | |
CN112110705B (en) | Self-repairing semi-rigid base material for recycling construction waste | |
CN110078449B (en) | Baking-free brick prepared from sludge generated by flushing broken stone and machine-made sand and preparation method thereof | |
CN113998960B (en) | Modified micro-nano composite superfine admixture high-durability anti-crack concrete and preparation method thereof | |
CN111747666A (en) | Low-carbon cementing material prepared from waste clay brick powder and slag | |
CN105439485A (en) | Lithionite slag admixture and its preparation method and use | |
CN111847921B (en) | Low clinker cement and preparation method and application thereof | |
CN113636767A (en) | Low-carbon cement and preparation method thereof | |
CN114634318A (en) | Solid waste cementing material, full-solid waste lightweight concrete and preparation method thereof | |
CN114195443A (en) | Light recycled concrete and preparation method thereof | |
CN113149536A (en) | Regenerated micropowder concrete and preparation method thereof | |
CN110092601B (en) | Steel slag-based baking-free slow-release artificial aggregate and preparation method thereof | |
CN114656234A (en) | Red mud/coal gangue based cementing material road base layer formula and preparation process | |
NL2027168B1 (en) | Steel slag powder-ferromanganese ore slag powder composite admixture and preparation process thereof | |
CN114180914A (en) | High-strength concrete prepared by applying cobbles | |
CN114230208A (en) | High-strength cement and preparation method thereof | |
CN110981233B (en) | Ferronickel slag masonry cement and preparation method thereof | |
CN108516741B (en) | Steel slag sand-straw ash composite doping mortar and preparation method thereof | |
CN110937863A (en) | Recyclable cement concrete and preparation method thereof | |
CN110963766A (en) | High-performance concrete for inhibiting granite alkali activity and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211231 |