CN1213681A - Regenerated rubber asphalt water-emulsion waterproof paint and its prepn. method - Google Patents
Regenerated rubber asphalt water-emulsion waterproof paint and its prepn. method Download PDFInfo
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- CN1213681A CN1213681A CN 98113346 CN98113346A CN1213681A CN 1213681 A CN1213681 A CN 1213681A CN 98113346 CN98113346 CN 98113346 CN 98113346 A CN98113346 A CN 98113346A CN 1213681 A CN1213681 A CN 1213681A
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- Prior art keywords
- emulsion
- waterproof paint
- rubber asphalt
- water
- regenerated rubber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000839 emulsion Substances 0.000 title claims abstract description 47
- 239000010426 asphalt Substances 0.000 title claims abstract description 37
- 239000003973 paint Substances 0.000 title claims abstract description 30
- 229920001971 elastomer Polymers 0.000 title claims description 39
- 239000005060 rubber Substances 0.000 title claims description 39
- 238000000034 method Methods 0.000 title claims description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- 239000004816 latex Substances 0.000 claims description 16
- 229920000126 latex Polymers 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 9
- 239000011301 petroleum pitch Substances 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- -1 acrylic ester Chemical class 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 239000011295 pitch Substances 0.000 claims description 5
- 230000008929 regeneration Effects 0.000 claims description 5
- 238000011069 regeneration method Methods 0.000 claims description 5
- 239000004160 Ammonium persulphate Substances 0.000 claims description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 4
- 239000012874 anionic emulsifier Substances 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 238000010074 rubber mixing Methods 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000004078 waterproofing Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Abstract
A polymer modified aqueous emulsion type of water-proof paint is prepared from styrene-acrylate copolymer emulsion and regenerated rubber-asphalt emulsion through proportional mixing, and features high tensile stretch, adhesion and strength and wide adaptability.
Description
The present invention relates to water milk type polymer modified reclaimed rubber pitch waterproof coating and preparation method.Along with the development of construction industry, the development and the application of all kinds of waterproof paints are developed rapidly, and be more and more higher to the specification of quality of building water-proof paint.In the waterproof paint that has practical value both at home and abroad at present, be to occupy bigger ratio in the prepared waterproof paint of raw material with the regenerated rubber asphalt, reclaimed rubber asphalt waterproofing paint is divided into solvent-borne type and water-latex type two classes in actual applications.The water-latex type reclaimed rubber asphalt waterproofing paint is to be mixed by anionic regeneration latex and bitumen emulsion to constitute, and is the effect of the particulate of regenerated rubber and petroleum pitch by means of aniorfic surfactant, and stable dispersion is in water and a kind of milk sap that forms.The main film forming substance of this coating is regenerated rubber and petroleum pitch, compare with the solvent-borne type like product, for having replaced organic solvent with water, thereby have nontoxic, tasteless, non-combustible advantage, and safe and reliable, can cold at normal temperatures construction operation, free from environmental pollution, simple to operate, easy to maintenance and can be moist slightly and do not have the advantages such as surface construction of ponding, thereby such waterproof paint obtains to use more widely in China in recent years.Yet there are some technical vulnerabilities in actual applications in such material, as low with the basal plane bonding force, tensile strength is low, tensile yield is not enough etc.
The objective of the invention is to solve the problem in the application of water-latex type reclaimed rubber asphalt waterproofing paint, a kind of polymer modification water-latex type reclaimed rubber waterproofing paint is provided, this coating has higher bonding strength, tensile strength and tensile yield.
The polymer modification water-latex type reclaimed rubber asphalt waterproofing paint of indication of the present invention is to adopt interpolymer latex of polystyrene and acrylic ester (hereinafter to be referred as benzene emulsion) and regenerated rubber asphalt emulsion to be composited according to 1: 1～10 ratio.Reclaimed rubber is the synthetic rubber of natural rubber or counter structure, and reclaimed rubber mixes by arbitrary proportion with pitch.Regenerated rubber asphalt emulsion, solids content are 47%.Latex of copolymer in cinnamic acrylic ester is added and is contained in the deionized water solution of ammonium persulphate, anionic emulsifier, nonionogenic tenside by vinylbenzene, butyl acrylate, vinylformic acid, makes the emulsion of solid content 48% in 2 hours 80～90 ℃ of polymerizations.Wherein styrene content is no more than 50%, can mix by arbitrary proportion between butyl acrylate, the vinylformic acid.
The method for making of the polymer modified reclaimed rubber asphalt water-emulsion waterproof paint of indication of the present invention comprises following step:
One. the preparation of regenerated rubber asphalt emulsion:
1. shoddy is plasticated on rubber mixing machine to higher plasticity number behind desulphurization reaction, mixes a certain amount of oleic acid, potassium hydroxide, ammoniacal liquor and polyvinyl alcohol, makes regeneration latex.
2. petroleum pitch and OP emulsifying agent, water, sodium hydroxide, water glass and polyvinyl alcohol are mixed and made into bitumen emulsion by a certain percentage.
Above-mentioned 1) and 2) stir, become the regenerated rubber asphalt emulsion.
Two. the preparation of vinylbenzene-acrylate copolymer emulsion:
Vinylbenzene, acrylate, vinylformic acid are added in the deionized water solution that contains ammonium persulphate, anionic emulsifier, nonionogenic tenside, are to carry out polyreaction under 80～90 ℃ 2 hours in temperature, add the ammoniacal liquor neutralization at last and make stable emulsion.Above-mentioned petroleum pitch can be No. 10 pitches and No. 60 asphalt mixtures, and acrylate can be butyl acrylate.
Three. the preparation of the polymer modified reclaimed rubber asphalt water-emulsion waterproof paint of indication of the present invention:
Above-mentioned (one) and (two) is mixed, and mixed as requested can obtain the polymer modified reclaimed rubber asphalt water-emulsion waterproof paint of indication of the present invention.
The waterproof paint result of use of indication of the present invention sees Table 1.
Table 1: polymer modified reclaimed rubber asphalt water-emulsion waterproof paint technical feature
| Regenerated rubber asphalt water-emulsion liquid (parts by weight) | Benzene emulsion (parts by weight) | Performance project | ||||||
| Solid content (%) | Bonding strength MPa | Tensile strength MPa | Tensile yield (%) | Watertightness | Acid resistance | Alkali resistance | ||
| 100 | ??0 | ????47 | ＜0.2 | ＜0.1 | ?220 | Waterproof | The surface no change | The surface no change |
| 500 | ?100 | ????47 | ?0.71 | ?0.14 | ?650 | Waterproof | The surface no change | The surface no change |
| 300 | ?100 | ????47 | ?0.98 | ?0.29 | ?995 | Waterproof | The surface no change | The surface no change |
| 100 | ?100 | ????47 | ?1.47 | ?0.71 | ?1191 | Waterproof | The surface no change | The surface no change |
Tensile strength, elongation at break are pressed the standard method test shown in the JC500-92 in the table 1.Bonding strength: 8 type matrix methods test.Watertightness: moving hydraulic pressure, 0.1MPa, 0.5h.Alkali resistance: 20 ℃ at saturated Ca (OH)
2Soak 20d in the solution.Acid resistance: 1%H
2SO
4Soak 15d in the solution.
We can see from table 1, and polymer modified reclaimed rubber pitch water emulsion waterproof paint provided by the invention is compared with unmodified regenerated rubber asphalt water-emulsion liquid waterproof paint, and bonding strength, tensile yield etc. all is significantly improved.Obviously, polymer modified reclaimed rubber asphalt water-emulsion waterproof paint provided by the present invention is compared with existing waterproof paint and is had suitable obvious effects.
Embodiment 1: with 200 parts of regenerated rubber asphalt water-emulsion liquid and 100 parts of benzene emulsion mixing and stirring, each basic mechanical design feature index of this composite water-proof coating is: solid content 47%, tensile strength 0.39MPa, bonding strength 1.14MPa, tensile yield 1100%, moving hydraulic pressure 0.1MPa, 0.5 hour are waterproof, and acid-proof alkaline is good.
Embodiment 2: with 400 parts of regenerated rubber asphalt water-emulsion liquid and 100 parts of benzene emulsion mixing and stirring, each basic mechanical design feature index of this composite water-proof coating is: solid content 47%, bonding strength 0.90MPa, tensile strength 0.22MPa, tensile yield 673%, moving hydraulic pressure 0.1MPa, 0.5 hour are waterproof, and acid-proof alkaline is good.
Wherein regenerated rubber asphalt emulsion and cinnamic acrylic ester preparation as follows respectively:
1) preparation of regenerated rubber asphalt emulsion
100 parts of 40 order desulfurization shoddies, 20 parts in No. 60 petroleum pitch, 2 parts in 420 activators, 2 parts of rosin are thrown to the reactor that whipping appts is housed, and are to carry out desulphurization reaction 2 hours under about 220 ℃ in temperature.Above-mentioned 100 parts of desulfurization material mixtures are being plasticated on the rubber mixing machine to higher plasticity number, and 6 parts of oleic acid of admixture and 1.7 parts of potassium hydroxide add 1% polyvinyl alcohol in case of necessity again, admixture distilled water, the control solid content is about 47%, and high speed dispersor emulsification disperses, and prepares stable regeneration latex.
30 parts of No. 10 petroleum pitch, 70 parts of No. 60 petroleum pitch, 2 parts of OP emulsifying agents, 100 parts of water, 0.9 part of sodium hydroxide, 1.6 parts of water glass, the mixture of 4 parts of polyvinyl alcohol is emulsification in the homogenize machine, makes the bitumen emulsion of stable solid content about 47%.
To regenerate latex and emulsified bitumen is 1: 1 mixed by weight and stirs, and promptly is prepared into regenerated rubber asphalt water-emulsion liquid, solid content about 47%.
2) preparation of interpolymer latex of polystyrene and acrylic ester
44 parts of vinylbenzene, 53 parts of butyl acrylates, 3 parts of acrylic acid mixtures are dropped in the solution reaction system that contains 0.4 part of ammonium persulphate, 0.5 part of anionic emulsifier, 2.0 portions of nonionogenic tensides and 100 parts of deionized waters, in temperature is to carry out polyreaction under 80～90 ℃ 2 hours, reaction is neutralized to PH=7～9 with ammoniacal liquor before finishing, and is prepared into solid content and is about 48% stable emulsion.
Claims (7)
1. regenerated rubber asphalt water-emulsion waterproof paint, regenerated rubber asphalt water-emulsion liquid is mixed by reclaimed rubber emulsion and bitumen emulsion, it is characterized in that adopting interpolymer latex of polystyrene and acrylic ester and regenerated rubber asphalt emulsion to be composited with the ratio of weight ratio 1: 1～10.
2. according to the waterproof paint described in the claim 1, it is characterized in that the regenerated rubber asphalt emulsion in described, its reclaimed rubber is natural rubber or synthetic rubber, and reclaimed rubber mixes by arbitrary proportion with pitch, and emulsion solids content is 47%.
3. according to the waterproof paint described in the claim 1, it is characterized in that described cinnamic acrylic ester emulsion is made up of vinylbenzene, acrylate, vinylformic acid three, wherein styrene content is no more than 50%, and emulsion solids content is 48%.
4. method of making the waterproof paint described in the claim 1 is characterized in that comprising following process for preparation:
(1) preparation of regenerated rubber asphalt emulsion:
1). after the shoddy desulfurization, on rubber mixing machine, plasticate, mix oleic acid, potassium hydroxide, ammoniacal liquor and polyvinyl alcohol and make regeneration latex;
2). petroleum pitch and OP emulsifying agent, sodium hydroxide, water glass and polyvinyl alcohol are made bitumen emulsion; Above-mentioned 1) and 2) be mixed into the regenerated rubber asphalt emulsion;
(2) preparation of vinylbenzene-acrylate copolymer emulsion: vinylbenzene, acrylate, vinylformic acid are added in the deionized water solution that contains ammonium persulphate, anionic emulsifier, nonionogenic tenside, in temperature is to carry out polyreaction under 80～90 ℃ 2 hours, add the ammoniacal liquor neutralization, make vinylbenzene-acrylate copolymer emulsion;
Above-mentioned (one) and (two) component are mixed, make waterproof paint.
5. according to the waterproof paint method for making described in the claim 4, it is characterized in that described petroleum pitch can be No. 10 and No. 60 and mixes use.
6. according to the waterproof paint method for making described in the claim 4, it is characterized in that described acrylate is a butyl acrylate.
7. according to the waterproof paint method for making described in the claim 4, it is characterized in that to contain 1% polyvinyl alcohol in the latex in the described regeneration latex method for making.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113346A CN1110526C (en) | 1998-09-14 | 1998-09-14 | Regenerated rubber asphalt water-emulsion waterproof paint and its prepn. method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113346A CN1110526C (en) | 1998-09-14 | 1998-09-14 | Regenerated rubber asphalt water-emulsion waterproof paint and its prepn. method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1213681A true CN1213681A (en) | 1999-04-14 |
| CN1110526C CN1110526C (en) | 2003-06-04 |
Family
ID=5223085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98113346A Expired - Fee Related CN1110526C (en) | 1998-09-14 | 1998-09-14 | Regenerated rubber asphalt water-emulsion waterproof paint and its prepn. method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1110526C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104776B (en) * | 2007-08-23 | 2010-05-26 | 李国树 | Macromolecule emulsion waterproofing paint |
| CN102010603A (en) * | 2010-10-27 | 2011-04-13 | 周乃承 | Rubber powder modified emulsified asphalt and preparation method thereof |
| CN101619149B (en) * | 2008-07-04 | 2011-08-17 | 天津市橡胶工业研究所 | Method for preparing cation emulsified rubber asphalt |
| CN104087168A (en) * | 2014-06-18 | 2014-10-08 | 蚌埠市光华金属制品有限公司 | Preparation method for water-emulsion-type reclaimed-rubber-modified asphalt waterproof coating |
| CN104087171A (en) * | 2014-06-18 | 2014-10-08 | 安徽先锋门业科技有限公司 | Preparation method for water-emulsion-type acrylic-acid-modified asphalt waterproof coating |
| CN106398420A (en) * | 2016-07-26 | 2017-02-15 | 苏州明轩地坪涂料有限公司 | Waterproof paint |
| CN107459934A (en) * | 2017-08-31 | 2017-12-12 | 苏州仲勉装饰有限公司 | One kind improvement quick-drying waterproof architectural coating and preparation method thereof |
| CN109233379A (en) * | 2018-10-12 | 2019-01-18 | 扬州中涂科技集团有限公司 | A kind of high-elastic waterproof asphalt emulsion |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035623C (en) * | 1992-10-16 | 1997-08-13 | 重庆建筑工程学院昆明分院 | Modified natural rubber and bitumen waterproof paint |
| CN1112591A (en) * | 1994-03-24 | 1995-11-29 | 丁铁龙 | Acrylic emulsified asphalt water-proof paint |
| CN1134445A (en) * | 1995-11-28 | 1996-10-30 | 李光祖 | Hot-molten liquid regenerated-rubber water-proofing material and its preparation method |
| CN1053687C (en) * | 1996-02-12 | 2000-06-21 | 山东省胶州市第二化工厂 | Styrene butadiene rubber bentone thick emulsified asphalt water-proof paint |
-
1998
- 1998-09-14 CN CN98113346A patent/CN1110526C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104776B (en) * | 2007-08-23 | 2010-05-26 | 李国树 | Macromolecule emulsion waterproofing paint |
| CN101619149B (en) * | 2008-07-04 | 2011-08-17 | 天津市橡胶工业研究所 | Method for preparing cation emulsified rubber asphalt |
| CN102010603A (en) * | 2010-10-27 | 2011-04-13 | 周乃承 | Rubber powder modified emulsified asphalt and preparation method thereof |
| CN102010603B (en) * | 2010-10-27 | 2012-07-04 | 周乃承 | Rubber powder modified emulsified asphalt and preparation method thereof |
| CN104087168A (en) * | 2014-06-18 | 2014-10-08 | 蚌埠市光华金属制品有限公司 | Preparation method for water-emulsion-type reclaimed-rubber-modified asphalt waterproof coating |
| CN104087171A (en) * | 2014-06-18 | 2014-10-08 | 安徽先锋门业科技有限公司 | Preparation method for water-emulsion-type acrylic-acid-modified asphalt waterproof coating |
| CN106398420A (en) * | 2016-07-26 | 2017-02-15 | 苏州明轩地坪涂料有限公司 | Waterproof paint |
| CN107459934A (en) * | 2017-08-31 | 2017-12-12 | 苏州仲勉装饰有限公司 | One kind improvement quick-drying waterproof architectural coating and preparation method thereof |
| CN109233379A (en) * | 2018-10-12 | 2019-01-18 | 扬州中涂科技集团有限公司 | A kind of high-elastic waterproof asphalt emulsion |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1110526C (en) | 2003-06-04 |
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