CN1060497C - Non-asphalt emulsion water-proof coating and its preparing process - Google Patents
Non-asphalt emulsion water-proof coating and its preparing process Download PDFInfo
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- CN1060497C CN1060497C CN97108940A CN97108940A CN1060497C CN 1060497 C CN1060497 C CN 1060497C CN 97108940 A CN97108940 A CN 97108940A CN 97108940 A CN97108940 A CN 97108940A CN 1060497 C CN1060497 C CN 1060497C
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- emulsion
- water
- agent
- styrene
- waterproof paint
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- 239000000839 emulsion Substances 0.000 title claims abstract description 24
- 239000010426 asphalt Substances 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims abstract description 6
- 238000000576 coating method Methods 0.000 title claims description 17
- 239000011248 coating agent Substances 0.000 title claims description 16
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 21
- 239000003973 paint Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 9
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007762 w/o emulsion Substances 0.000 claims abstract description 6
- -1 polyethylene vinyl acetate Polymers 0.000 claims description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- 239000004816 latex Substances 0.000 claims description 10
- 229920000126 latex Polymers 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 5
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008399 tap water Substances 0.000 claims description 4
- 235000020679 tap water Nutrition 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000012874 anionic emulsifier Substances 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 238000002360 preparation method Methods 0.000 abstract description 7
- 230000032683 aging Effects 0.000 abstract description 5
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 239000004566 building material Substances 0.000 abstract 1
- 230000031700 light absorption Effects 0.000 abstract 1
- 239000007764 o/w emulsion Substances 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 10
- 238000004945 emulsification Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical class [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Abstract
The present invention belongs to the preparation of a chemical building material. An existing method for preparing emulsion styrene-butadiene-styrene waterproof paint have to take asphalt as a solubilizing agent, and the asphalt has the disadvantages of light absorption, heat absorption, no clod resistance, no hot resistance, no ageing resistance, malodor and environment pollution. The present invention provides non-asphalt emulsion styrene-butadiene-styrene waterproof paint which uses rosin and turpentine derivatives to replace the asphalt to be added with a proper amount of modifying agent, plasticizing agent and emulsifying agent; firstly water-in-oil emulsion is produced, and a large amount of water is added to reverse the water-in-oil emulsion into oil-in-water emulsion waterproof paint.
Description
The invention belongs to material of construction, in particular for waterproof, leak stopping and the sealing between the various building slabs of buildings.
Construction waterproof coating has four big classes by the formulation classification: solvent-borne type, emulsion-type, biliquid response type and hot-melting type, wherein emulsion-type is to be solvent with water, have and do not fire, the gram poison, superiority such as pollution-free and inexpensive, therefore this class waterproof paint is very welcome, but on the market emulsion-type coating such as butylbenzene, neoprene, vinylformic acid waits until that emulsion coatings all is to add some modified emulsion again with ready-made latex, filler and making, general solid content 40-50%, these coating all have visco-elasticity and water resistance preferably, price is also cheap, but, can only make thin coating and influence mechanical property and weather resistance because plasticity is not enough.And styrene-butadiene-styrene rubber is SBS rubber, has excellent elasticity and plasticity and winter hardiness, lower in the solution medium viscosity, can prepare highly filled thick coating, but SBS to be made the industrialization emulsion paint, also very difficult, " Chinese architecture water-proof material " 1994 the 1st phase P-17 and the 1st phase of nineteen ninety-five P-19 report: Chinese Suzhou is dissolved in pitch with SBS under 190-200 ℃ become the less homogeneous system of viscosity, use the emulsification of mineral emulsifying agent again, this coating is to adopt pitch as solubilizing agent, and because pitch is easily aging, also make the emulsification of SBS rubber smooth, pitch itself has water-fast, bullet is moulded, adhesiveproperties and inexpensive, therefore this coating uses very general at present, but it is well-known, pitch blackness, the extinction heat absorption, the lighter roofing of roofing temperature is raise 30 ℃, it is cold short, heat is dropped down, not ageing-resistant, in heat, light, hardening under the oxygen effect, become fragile, cracking comes off and causes waterproof effect to descend, pitch also contains harmful material, and foul smelling, increases the pollution of environment.
The purpose of this invention is to provide a kind of non-asphalt emulsion waterproof paint.This coating is white or light, nontoxic, odorless, have high elastoplasticity.
Non-asphalt emulsion water-proof coating provided by the present invention, be to adopt SBS rubber (styrene-butadiene-styrene rubber) (792 types or 802 types) to be material of main part, replace pitch as tackifier with modified rosin resin or turps derivative, use neoprene latex latex, acrylic latex, the polyethylene vinyl acetate emulsion, Vinyl Acetate Copolymer-ACRYLIC EMULSION, polypropylene, polyisobutene, isoprene-isobutylene rubber, terpolymer EP rubber is as properties-correcting agent, give coating elasticity, bonding force, ageing resistance and thermostability, used softening agent is a Dormant oils, chlorine is cured, phthalic ester, the 12-18 carbon fatty acid, Viscotrol C, plam oil, Oleum Cocois, oleum lini, epoxidised soybean oil, solvent are acetone, toluene, ethyl acetate.The used nonionic emulsifying agent of the present invention is polyoxyethylene aliphatic alcohol ether and sulfonate thereof, polyoxyethylene lipidol, polyoxyethylene alkane phenolic ether, Polyoxyethylene Sorbitol Fatty Acid Esters, and used anionic emulsifier is succinate sodium sulfonate, 12-18 alkyl (aryl) sodium sulfonate, Succinic Acid polyoxyethylene Fatty Alcohol(C12-C14 and C12-C18) (phenol) ether sulfonic acid sodium.Solvent is acetone, toluene, ethyl acetate.Waterproof paint prescription provided by the present invention contains following composition (parts by weight):
SBS rubber (styrene-butadiene-styrene rubber) 8-11
Rosin or turps derivative 12-14
Properties-correcting agent 0-5
Softening agent 2-4
Nonionic emulsifying agent 1-1.4
The sub-emulsifying agent 0.3-0.5 of cloudy note
Solvent 4-6
Filler 20-25
Pigment 0.1-1.1
Tap water adds to 100
Solid content 50-60%
Emulsion-type waterproof paint provided by the present invention is used for the waterproofing and leakage-stopping of buildings.Compare with emulsion paint of the prior art, have look shallow (or white), nontoxic odorless, high elastoplasticity, high strength and excellent low temperature flexibility and ageing-resistant performance, construction process and storage period safety, free from environmental pollution, add light reflecting material at coating surface and have also that reflective, the anti-width of cloth is penetrated, the multiple function of heat insulation, heat radiation, and cost only is the 50-60% of existing emulsion-type waterproof paint.Emulsion-type waterproof paint measurement result (comparing) with existing waterproof paint
The manufacture method of non-asphalt emulsion water-proof coating provided by the present invention is as follows: with styrene-butadiene-styrene rubber, rosin or turps derivative are miscible in solvent system A solution in 80-100 ℃, splash into then in the seed emulsion by emulsifying agent, water, a small amount of A solution composition, generate water in oil emulsion, adding a large amount of hot water makes it to reverse and is oil-in-water stable emulsion, vacuumize the recovery solvent, add filler, pigment then, the room temperature that stirs discharging.If the properties-correcting agent emulsion-type then can be behind this paint emulsification is mixed with it, add filler, pigment etc. again, promptly first emulsification post-modification, if useful properties-correcting agent is solid state then be cut into particle and SBS with miscible in A solution reemulsification, emulsification after the promptly first modification.
Embodiment 1
Parts by weight
SBS (792 type) 10
Turps derivative 14
Polychloroprene latex 4.2
Chlorine cured 3.3
0P-9 1．3
Sodium lauryl sulphate 0.3
Toluene 5
Lime carbonate 23
Pigment 0.9
Tap water 38
Solid content 57% preparation technology:
1, the preparation of A liquid: SBS rubber, turps derivative, chlorine is cured, toluene (20 parts) is in the 80-100 ℃ of miscible one-tenth clear solution of heating;
2, the preparation of B liquid: with 10 parts of water, 6 parts of A liquid, emulsifying agent stirs into emulsus in 65 ℃ and is seed emulsion B;
3, will remain A liquid under 65 ℃ and evenly splash into B liquid, drip off in about 1 hour, become water-in-oil emulsion, and add 28 parts of 65-70 ℃ of hot water again and make it to be converted into the wet emulsion of water;
4, after 60 ℃, 740 mmhg decompressions steam 18 parts of toluene, latex is changed in the correct grinding agitator, add neoprene latex, lime carbonate, pigment etc. and stir even discharging.
Embodiment 2
Parts by weight
SBS rubber (802 type) 10.3
Modified rosin resin 12.0
Ethene-vinegar VINYL ACETATE MONOMER (VAM) (EVA) 3.5
Viscotrol C 3.5
Peregal-0 1.4
12 intact basic benzene sulfonic acid sodium salts 0.4
Ethyl acetate 5.0
Lime carbonate 24.0
Pigment 0.1
Tap water 39.8
Solid content 54.8% preparation technology:
1, the preparation of A liquid: SBS, EVA, modified rosin resin, Viscotrol C is miscible in 20 parts of ethyl acetate in 70-80 ℃;
2, the preparation of B liquid: 10 parts of water, emulsifying agent, 6 parts of A liquid are stirred into seed emulsion B in 65 ℃;
3,65 ℃ evenly splash into B liquid with A liquid in following 1 hour and become water-in-oil emulsion, drip 29.8 parts of 60-70 ℃ of hot water again, make it to be converted into O/w emulsion;
4, after 50 ℃, 740 mmhg steam 15 parts of ethyl acetate parts, latex is changed in the correct grinding agitator, add lime carbonate, pigment, stir even discharging.
Claims (6)
1, a kind of non-asphalt emulsion water-proof coating, it is a host with benzene alkene-Afpol, it is characterized in that with rosin or turps derivative be tackifier, adds properties-correcting agent, softening agent and emulsifying agent, add pigment, filler again, its prescription contains following composition: (parts by weight)
Styrene-butadiene-styrene rubber (SBS) 8-11
Rosin or turps derivative 12-14
Properties-correcting agent 0-5
Softening agent 2-4
Nonionic emulsifying agent 1-1.4
Anionic emulsifier 0.3-0.5
Solvent 4-6
Filler 20-25
Pigment 0.1-1.1
Tap water adds to 100.
2, according to the waterproof paint described in the claim 1, the properties-correcting agent in it is characterized in that forming is polychloroprene latex, acrylic latex, the polyethylene vinyl acetate emulsion, Vinyl Acetate Copolymer-ACRYLIC EMULSION, polypropylene, polyisobutene, isoprene-isobutylene rubber, terpolymer EP rubber.
3, according to the waterproof paint described in the claim 1, the softening agent that it is characterized by in the composition is cured, the phthalic ester of Dormant oils, chlorine, 12-18 carbon fatty acid, or Viscotrol C, plam oil, Oleum Cocois, oleum lini, epoxidised soybean oil.
4, according to the waterproof paint described in the claim 1, the nonionic emulsifying agent that it is characterized by in the composition is polyoxyethylene aliphatic alcohol ether and sulfonate thereof, the polyoxyethylene Fatty Alcohol(C12-C14 and C12-C18), polyoxyethylene alkane phenolic ether, the polyoxyethylene sorbitol fatty acid ester, anionic emulsifier described in the composition is the succinate sodium sulfonate, 12-18 alkyl (aryl) sodium sulfonate, Succinic Acid polyoxyethylene Fatty Alcohol(C12-C14 and C12-C18) (phenol) ether sulfonic acid sodium.
5, according to the waterproof paint described in the claim 1, the solvent that it is characterized by in the composition is acetone, toluene, ethyl acetate.
6, a kind of method for preparing the waterproof paint described in the claim 1, it is characterized in that styrene-butadiene-styrene rubber, rosin or turps derivative are dissolved in solvent in 80-100 ℃ makes A solution, splash into then in the seed emulsion by emulsifying agent, water, a small amount of A solution composition, generate water in oil emulsion, then in a large amount of hot water, reverse and be oil-in-water stable emulsion, vacuumize the recovery solvent then, add filler, pigment, the room temperature that stirs discharging; Solid state properties-correcting agent should shred with SBS with miscible in A solution, and emulsion-type properties-correcting agent can directly mix with emulsive coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97108940A CN1060497C (en) | 1997-06-10 | 1997-06-10 | Non-asphalt emulsion water-proof coating and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97108940A CN1060497C (en) | 1997-06-10 | 1997-06-10 | Non-asphalt emulsion water-proof coating and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1167796A CN1167796A (en) | 1997-12-17 |
| CN1060497C true CN1060497C (en) | 2001-01-10 |
Family
ID=5170772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97108940A Expired - Fee Related CN1060497C (en) | 1997-06-10 | 1997-06-10 | Non-asphalt emulsion water-proof coating and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1060497C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1305964C (en) * | 2004-06-18 | 2007-03-21 | 张秋声 | Water-proof coiled material |
| CN103382323B (en) * | 2013-07-08 | 2016-02-24 | 苏州新奇迅网络有限公司 | Outdoor facilities Cold resistant paint and preparation method thereof |
| CN103360933B (en) * | 2013-07-22 | 2016-01-20 | 广东科顺化工实业有限公司 | Non-bituminous water-based spraying rapid hardening rubber water-proof paint and preparation method thereof |
| CN104974665A (en) * | 2014-04-04 | 2015-10-14 | 北京跨世纪洪雨防水工程有限责任公司 | Liquid butyl rubber asphalt waterproof coating and preparation method |
| CN104109479A (en) * | 2014-06-18 | 2014-10-22 | 安徽先锋门业科技有限公司 | Preparation method of thermoplastic rubber modified asphalt waterproof paint |
| CN104087074A (en) * | 2014-06-18 | 2014-10-08 | 蚌埠市光华金属制品有限公司 | Preparation method for water-emulsion-type ethylene-propylene-diene-monomer waterproof material |
| CN105038059A (en) * | 2015-07-10 | 2015-11-11 | 唐秀克 | High-viscosity waterproof material for architecture and preparation method therefor |
| CN109796875A (en) * | 2018-12-28 | 2019-05-24 | 苏州市姑苏新型建材有限公司 | Aqueous non-bituminous uncured water-repellent paint of base of one kind and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075490A (en) * | 1992-11-19 | 1993-08-25 | 江西省万载橡胶厂 | A kind of manufacture method of rubber water-proof paint using water substituted for solvent |
| CN1078732A (en) * | 1993-05-20 | 1993-11-24 | 朱西群 | Waterproof paint and production method thereof |
| CN1083506A (en) * | 1993-09-01 | 1994-03-09 | 王化岐 | Mastic neoprene water-proof paint and production technique |
-
1997
- 1997-06-10 CN CN97108940A patent/CN1060497C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075490A (en) * | 1992-11-19 | 1993-08-25 | 江西省万载橡胶厂 | A kind of manufacture method of rubber water-proof paint using water substituted for solvent |
| CN1078732A (en) * | 1993-05-20 | 1993-11-24 | 朱西群 | Waterproof paint and production method thereof |
| CN1083506A (en) * | 1993-09-01 | 1994-03-09 | 王化岐 | Mastic neoprene water-proof paint and production technique |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1167796A (en) | 1997-12-17 |
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