CN1199033A - Fine alumina ceramic preparation process using natural bauxite - Google Patents
Fine alumina ceramic preparation process using natural bauxite Download PDFInfo
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- CN1199033A CN1199033A CN 98113561 CN98113561A CN1199033A CN 1199033 A CN1199033 A CN 1199033A CN 98113561 CN98113561 CN 98113561 CN 98113561 A CN98113561 A CN 98113561A CN 1199033 A CN1199033 A CN 1199033A
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- bauxite ore
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Abstract
A process for preparing fine alumina ceramic with natural bauxite ore includes calcining buaxite ore at 1350-1650 deg.C, crushing, ball grinding to obtain powder with a size of 1-15 microns, proportioning alumina ceramic, ball grinding for 3-5 hr, spray drying, granulating, shaping, and firing at 1300-1550 deg.C for 0.5-12 hr, and features low-temp firing, low energy consumption and cost, less environmental pollution and high performance of ceramic.
Description
The invention belongs to Al
2O
3The pottery preparation.
Alumina-ceramic because of its good electric property, physical strength height, advantage such as hardness is big, thermal expansivity is little, wear-resisting and impact resistance is good, make it become a kind of most widely used pottery.Yet the sintering temperature of fine alumina ceramic is up to 1600～1700 ℃, and investment is big, energy consumption is high, adds the contradiction between its price and the performance, has limited its widespread use.
In order to address these problems, Chinese scholars had all been carried out number of research projects in recent years.The Japan scholar proposes to make raw material with superfine alumina powder, can prepare the excellent dense base substrate at 1400 ℃ of sintering, but its superfine alumina powder complicated process of preparation, cost is very high; Norton Co adopts sol-gel method to prepare so-called SG material, produces microcrystal fused alumina, and its cost is higher than 6～7 times of traditional methods.Domestic scholars is also being made number of research projects aspect the sintering temperature that reduces alumina-ceramic.But all fundamentally do not solve the price of alumina-ceramic and the contradiction between the performance, the product of using as textile industry and the mill ball in the ceramic glaze fine grinding etc., the use price is 4000～5000 yuans/ton a common raw material, its sintering temperature height, the performance of product particularly wear resisting property do not satisfy user's requirement.And use price is 80000～200000 yuans/ton high pure and ultra-fine raw material, though can reduce sintering temperature and obtain the product of excellent property, its price is that user institute is unacceptable, and external situation is also like this.
Contradiction between the cost/performance ratio that the objective of the invention is to exist at present fine alumina ceramic, utilize natural bauxite ore to be main raw material, select the technological process of optimization for use, directly prepare the fine alumina ceramic of excellent property, thereby realize the low-cost industrial preparation of high-performance fine alumina ceramic.
Below in conjunction with Fig. 1 content of the present invention is specifically described.
Fig. 1. natural bauxite ore is used to prepare the process flow sheet of the method for fine alumina ceramic.
1. the selection of natural bauxite ore and processing
The bauxite ore of China (having another name called alumine, alumina, bauxite) resource exception is abundant, and different because of its place of production, its composition difference is very large, the at present domestic production that only is used for high alumina refractories. We find to select suitable bauxite ore directly to prepare the high-performance fine alumina ceramic as raw material through for many years development test.
Select natural bauxite ore for use, its chemical constitution following (wt%):
In 1350～1650 ℃ of calcinings, through pulverizing, traditional method ball milling (material: ball: water=1: 2: 1) to median size be the powder of 1～15 μ m, for reaching best effect, at ball milling to certain fineness, add the dispersion agent (as one or more of efficient dispersion agent such as polyether base, poly-hydroxy, many carboxyls) of 0.5～1.5wt%, traditional method ball milling (material: ball: water=1: 2: 1,24 hours), control the pH value (being generally 6～8) of slip well, adjust the spray-dried raw material powder that makes in back, its median size is 1～15 μ m.2. moulding
| ????Al 2O 3 | ????SiO 2 | ????Fe 2O 3 | ????TiO 2 |
| ????＞65 | ????0.5～40 | ????0.5～2.5 | ????1～10 |
Based on above-mentioned raw material powder, add powder such as burnt aluminum oxide, diopside, quartz, magnesite, Wingdale, wollastonite, talcum in proportion, be made into 80～95 alumina ceramics raw material powder, ball milling 3～5 hours, spray-dried granulation is shaped to required shape.3. burn till
Above-mentioned base substrate was burnt till 1300～1550 ℃ of insulations in 0.5～12 hour.
Table 1 has been listed 95 porcelain of the present invention's preparation and the relevant performance and the firing temperature of GB (GB-5593-85) 95 porcelain.
Table 2 has been listed 90, the 95 porcelain balls of the present invention's preparation and the performance data of commercially available 90,95 porcelain balls.
95 porcelain and the relevant performance of GB A95 porcelain of table 1 the present invention preparation
| The present invention prepares 95 porcelain | GB A95 porcelain | |
| Volume density g/cm 3 | ????3.4～3.6 | ????＞3.60 |
| Bending strength MPa | ????250 | ????280 |
| Firing temperature ℃ | ????1500 | ????1650 |
| ??Al 2O 3Content wt% | ????95 | ????95 |
The porcelain ball of table 2 the present invention preparation and the performance index of commercially available porcelain ball
| The present invention's preparation | Commercially available | |||
| ??90 | ??95 | ??90 | ?95 | |
| Alumina content wt% | ??88.75 | ??95 | ??97～90 | ?94～96 |
| Microhardness Hm | ??＞1400 | ??＜1600 | (9.0 hardness) | (9.0 hardness) |
| Ultimate compression strength MPa | ??＞1200 | ??＞1500 | ??≥1500 | ?≥2000 |
| Density g/cm 3 | ??＞3.3 | ??＞3.4 | ??≥3.45 | ?≥3.6 |
| Wear rate g/kgh | ??＜0.2 | ??＜0.18 | ??≤0.8 | ?≤0.7 |
| Water-intake rate % | ??＜0.4 | ??＜0.2 | ??2.39 | ?-- |
As can be seen from Table 1, though the density of 95 porcelain that the present invention makes etc. a little less than GB, firing temperature of the present invention is 1500 ℃, far below 1650 ℃ of the temperature of GB regulation.
As can be seen from Table 2, the ultimate compression strength of the porcelain ball that the present invention makes and density are lower than commercially available porcelain ball, but aspect the key property of porcelain ball as wear rate and water-intake rate on, the porcelain ball that the present invention makes is better than commercially available porcelain ball, 90 porcelain mill loss rate＜0.2g/kgh that the present invention makes, 95 porcelain mill loss rate＜0.18g/kgh, 95 porcelain mill loss rate≤0.7g/kgh.Characteristics of the present invention are:
(1) selecting natural bauxite ore for use is that main raw material directly prepares fine alumina ceramic;
(2) realized easy fired, cut down the consumption of energy, reduced pollution environment;
(3) adopting cheap mineral is main raw material, greatly reduces production cost, is particularly suitable for large-scale commercial production.
(4) realize the low cost manufacturing of high-performance ceramic, solved the contradiction between the price and performance during alumina-ceramic is produced.
Embodiment 1:(1) selection of natural bauxite ore and processing
Select the bauxite ore in somewhere, Hebei for use, its chemical constitution (wt%) is:
In 1400 ℃ of calcinings 1 hour, it is salic to be 85wt%, after crushing ball was milled to 100 mesh sieves, adds compound many carboxyls high molecular polymer (PAA: NH of 1wt%
4PAA=1: 1) dispersion agent, (material: ball: water=1: 2: 1) 24 hours, the pH value of regulating slip was between 6～7 to ball milling, and spraying drying makes the powder that median size is 3 μ m then.(2) easy fired
| ??Al 2O 3 | ??SiO 2 | ??Fe 2O 3 | ??TiO 2 | Other | Alkali burns |
| ??73.1 | ??9.5 | ??0.9 | ??2.0 | ??0.5 | ??14.0 |
Ceramic formula is (wt%): wrought aluminium vanadine fine powder 93.5, calcining diopside fine powder 6.5, ball milling (material: ball: water=1: 2: 1) 3 hours mixings, the spray-dried machine drying-granulating of slip, moulding is then sent in the Si-Mo rod stove and was promptly made 80 alumina balls in 6 hours in 1350 ℃ of insulations.(3) salient features of 80 alumina balls of Huo Deing
Volume density g/cm
3: 3.1
Microhardness Hm:1200
Ultimate compression strength MPa:1000
Wear rate g/kgh:0.30
Water-intake rate %:0.60 embodiment 2:(1) selection and the processing of natural bauxite ore
Select the bauxite ore in somewhere, Henan for use, its chemical constitution (wt%) is:
In 1450 ℃ of calcinings 1 hour, it is salic to be 79.25wt%, after crushing ball was milled to 100 mesh sieves, adds compound many carboxyls high molecular polymer (PAA: NH of 1wt%
4PAA=1: 1) dispersion agent, (material: ball: water=1: 2: 1) 24 hours, the pH value of regulating slip was between 6～7 to ball milling, and spraying drying makes the powder that median size is 3 μ m then.(2) easy fired
| ??Al 2O 3 | ??SiO 2 | ??Fe 2O 3 | ???TiO 2 | Other | Alkali burns |
| ??68.0 | ??13.7 | ??1.2 | ????2.2 | ????0.7 | ????14.2 |
Ceramic formula is (wt%): wrought aluminium vanadine fine powder 40.0, aluminum oxide fine powder 58.3, calcining diopside fine powder 1.7, ball milling (material: ball: water=1: 2: 1) 3 hours mixings, the spray-dried machine drying-granulating of slip, moulding is then sent in the Si-Mo rod stove and was promptly made 90 alumina balls in 6 hours in 1400 ℃ of insulations.(3) salient features of 90 alumina balls of Huo Deing
Volume density g/cm
3: 3.38
Microhardness Hm:1410
Ultimate compression strength MPa:1250
Wear rate g/kgh:0.19
Water-intake rate %:0.36 embodiment 3:(1) selection and the processing of natural bauxite ore
Select the bauxite ore in somewhere, Guizhou for use, its chemical constitution (wt%) is:
In 1400 ℃ of calcinings 1 hour, it is salic to be 93.0wt%, after crushing ball was milled to 100 mesh sieves, adds compound many carboxyls high molecular polymer (PAA: NH of 1wt%
4PAA=1: 1) dispersion agent, (material: ball: water=1: 2: 1) 24 hours, the pH value of regulating slip was between 6～7 to ball milling, and spraying drying makes the powder that median size is 3 μ m then.(2) easy fired
| ??Al 2O 3 | ???SiO 2 | ??Fe 2O 3 | ??TiO 2 | Other | Alkali burns |
| ??80.0 | ????1.7 | ???0.8 | ??2.8 | ????0.7 | ??14.0 |
Ceramic formula is (wt%): wrought aluminium vanadine fine powder 30.0, aluminum oxide fine powder 67.1, calcining diopside fine powder 2.9, ball milling (material: ball: water=1: 2: 1) 3 hours mixings, the spray-dried machine drying-granulating of slip, moulding is then sent in the Si-Mo rod stove and was promptly made 95 alumina balls in 6 hours in 1450 ℃ of insulations.(3) salient features of 95 alumina balls of Huo Deing
Volume density g/cm
3: 3.53
Microhardness Hm:1650
Ultimate compression strength MPa:1550
Wear rate g/kgh:0.17
Water-intake rate %:0.18
Claims (1)
1. a natural bauxite ore is the method that raw material is used to prepare the high-performance fine alumina ceramic, it is characterized in that:
(1) selecting suitable natural bauxite ore for use is main raw material, its chemical constitution following (wt%):
????Al
2O
3 ????SiO
2 ????Fe
2O
3 ????TiO
2
????＞65 ????0.5～40 ????0.5～2.5 ????1～10
(2) with above-mentioned bauxite ore in 1350～1650 ℃ of calcinings, through pulverizing, traditional method ball milling (material: ball: water=1: 2: 1) to median size be the powder of 1～15 μ m, for reaching best effect, at ball milling to certain fineness, the dispersion agent that adds 0.5～1.5wt% is (as the polyether base, poly-hydroxy, one or more of efficient dispersion agent such as many carboxyls), the traditional method ball milling, control the pH value (being generally 6～8) of slip well, adjust the spray-dried raw material powder that makes in back, its median size is 1～15 μ m, and then batching, ball mill mixing, spraying drying, moulding, burn till the fine alumina ceramic that makes excellent property.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113561A CN1125791C (en) | 1998-05-18 | 1998-05-18 | Fine alumina ceramic preparation process using natural bauxite |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113561A CN1125791C (en) | 1998-05-18 | 1998-05-18 | Fine alumina ceramic preparation process using natural bauxite |
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| Publication Number | Publication Date |
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| CN1199033A true CN1199033A (en) | 1998-11-18 |
| CN1125791C CN1125791C (en) | 2003-10-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98113561A Expired - Fee Related CN1125791C (en) | 1998-05-18 | 1998-05-18 | Fine alumina ceramic preparation process using natural bauxite |
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| CN (1) | CN1125791C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101913892A (en) * | 2010-09-06 | 2010-12-15 | 山西高科耐火材料股份有限公司 | Method for producing homogenized alumina |
| CN101348366B (en) * | 2008-09-05 | 2011-05-11 | 清华大学 | Method for preparing self-toughening ceramic by mechanically activating alumina |
| CN101238068B (en) * | 2005-07-16 | 2011-10-26 | 科莱恩金融(Bvi)有限公司 | Process for producing nanocrystalline alpha-Al2O3 |
| CN108715650A (en) * | 2018-04-12 | 2018-10-30 | 雅安百图高新材料股份有限公司 | The preparation method of low specific surface area submicron alumina |
| CN111410543A (en) * | 2020-04-24 | 2020-07-14 | 朔州西廊煤炭科技有限公司 | Method for preparing functional ceramic engineering material combustion-supporting catalyst by utilizing coal solid waste or bauxite solid waste |
| CN111517769A (en) * | 2020-04-24 | 2020-08-11 | 朔州西廊煤炭科技有限公司 | Method for preparing boron carbide anti-damage ceramic engineering material by utilizing coal solid waste or bauxite solid waste |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049839A (en) * | 1989-08-26 | 1991-03-13 | 胡湧波 | High-alumina high-strength household porcelain and production method thereof |
| RU2138461C1 (en) * | 1993-07-27 | 1999-09-27 | Сумитомо Кемикал Компани, Лимитед | Aluminum oxide composition (versions) and method of manufacturing aluminum oxide ceramics |
| CN1114642A (en) * | 1994-07-08 | 1996-01-10 | 董杰 | Method for producing high-purity micro-crystal white alundum |
-
1998
- 1998-05-18 CN CN98113561A patent/CN1125791C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101238068B (en) * | 2005-07-16 | 2011-10-26 | 科莱恩金融(Bvi)有限公司 | Process for producing nanocrystalline alpha-Al2O3 |
| CN101348366B (en) * | 2008-09-05 | 2011-05-11 | 清华大学 | Method for preparing self-toughening ceramic by mechanically activating alumina |
| CN101913892A (en) * | 2010-09-06 | 2010-12-15 | 山西高科耐火材料股份有限公司 | Method for producing homogenized alumina |
| CN101913892B (en) * | 2010-09-06 | 2013-02-13 | 山西高科耐火材料股份有限公司 | Method for producing homogenized alumina |
| CN108715650A (en) * | 2018-04-12 | 2018-10-30 | 雅安百图高新材料股份有限公司 | The preparation method of low specific surface area submicron alumina |
| CN108715650B (en) * | 2018-04-12 | 2020-04-21 | 雅安百图高新材料股份有限公司 | Preparation method of submicron alumina with low specific surface area |
| CN111410543A (en) * | 2020-04-24 | 2020-07-14 | 朔州西廊煤炭科技有限公司 | Method for preparing functional ceramic engineering material combustion-supporting catalyst by utilizing coal solid waste or bauxite solid waste |
| CN111517769A (en) * | 2020-04-24 | 2020-08-11 | 朔州西廊煤炭科技有限公司 | Method for preparing boron carbide anti-damage ceramic engineering material by utilizing coal solid waste or bauxite solid waste |
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|---|---|
| CN1125791C (en) | 2003-10-29 |
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