CN1197813C - Slurry consolidation agent - Google Patents
Slurry consolidation agent Download PDFInfo
- Publication number
- CN1197813C CN1197813C CNB021048010A CN02104801A CN1197813C CN 1197813 C CN1197813 C CN 1197813C CN B021048010 A CNB021048010 A CN B021048010A CN 02104801 A CN02104801 A CN 02104801A CN 1197813 C CN1197813 C CN 1197813C
- Authority
- CN
- China
- Prior art keywords
- parts
- waste
- powder
- agent
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002002 slurry Substances 0.000 title abstract 6
- 238000007596 consolidation process Methods 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000002699 waste material Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 19
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000010881 fly ash Substances 0.000 claims abstract description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 7
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 7
- 239000004568 cement Substances 0.000 claims abstract description 7
- 239000004571 lime Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 5
- 239000005997 Calcium carbide Substances 0.000 claims abstract description 4
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 4
- 239000010436 fluorite Substances 0.000 claims abstract description 4
- 239000010440 gypsum Substances 0.000 claims abstract description 4
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 4
- 239000002893 slag Substances 0.000 claims abstract description 4
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010802 sludge Substances 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 6
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 229940056729 sodium sulfate anhydrous Drugs 0.000 claims description 3
- 238000010276 construction Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 230000005484 gravity Effects 0.000 abstract 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 2
- 239000007832 Na2SO4 Substances 0.000 abstract 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 5
- 239000002245 particle Substances 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 229910001653 ettringite Inorganic materials 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
- C04B28/065—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Treatment Of Sludge (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to a slurry consolidating agent for well sites and roadbed by using waste slurry as base material. Solves the problem of the consolidation agent which enables the waste slurry to be reused. The method is characterized in that: the components and the mixture ratio are as follows according to the parts by weight: 1-60 parts of sulphoaluminate cement clinker, 1-30 parts of gypsum powder, 1-60 parts of slag, 1-30 parts of lime powder, 1-40 parts of fly ash, 1-15 parts of calcium carbide powder and 1-15 parts of fluorite powder are mixed to form a slurry solidifying agent with the specific gravity of more than 1.65; then adding 1-20 parts of high-efficiency water reducing agent and sodium carbonate Na2CO31-20 parts of anhydrous sodium sulphate Na2SO41-20 parts of slurry solidifying agent with the specific gravity of more than 1.65. It features use of waste mud as basic material, high strength, less mixing amount and low cost. The waste mud is treated nearby the well site, the principle of treating waste by waste is realized, the construction is simple, and the operation is convenient.
Description
(1) technical field:
The present invention relates to a kind of solidifying agent that well site and roadbed use waste and old mud to use as base-material, belong to sludge consolidating agent.
(2) background technology:
At present the well site and the roadbed in oil field use materials such as cement, lime stone and soil to be used to lay ground mostly, and cement, lime stone amount ratio are bigger, also waste a large amount of land resources simultaneously.And the used drilling mud of oil drilling does not utilize mostly again, a large amount of contaminate environment.Because waste and old mud particle is tiny, viscosity is big, water ratio is high and difficult dehydration, make and utilize moisture and active substance in waste and old mud and the flyash that suitable solidifying agent and form intensity in addition is as the base mateiral of well site and road.Waste and old mud generally has water-based mud: water ratio is below 40% and do not contain polymkeric substance; Polymer mud: water ratio is below 40% and contain polymkeric substance; The high-moisture percentage mixing mud: water ratio is more than 40% and possess the character of water-based mud and polymer mud.No matter any mud uses solidifying agent commonly used at present, volume is many, intensity is low, cost height and water are stable poor, the mud that moreover this solidifying agent is big to water content, organic matter is high and the processing of waste and old mud are also very difficult, can not reach waste and old mud is utilized to realize the purpose of " turning waste into wealth " again.
(3) summary of the invention:
Technical problem to be solved by this invention is the solidifying agent problem that waste and old mud can be utilized again.
Adoptable technical scheme is: this sludge consolidating agent, comprise flyash, lime powder, and it is characterized in that: each composition and proportioning are as follows by weight:
1～60 part of sulphoaluminate cement clinker, 1～30 part of gypsum powder, 1～60 part in slag, 1～30 part of lime powder, 1～40 part in flyash, 1～15 part of calcium carbide powder, Fluorspar Powder are mixed into proportion at the sludge consolidating agent more than 1.65 for 1～15 part; 1～20 part of high efficiency water reducing agent, soda ash Na in addition again
2CO
31～20 part, Sodium sulfate anhydrous.min(99) Na
2SO
41～20 part is mixed into proportion at the sludge consolidating agent more than 1.65.
Therefore the beneficial effect of these goods is: because this solidifying agent can absorb above the free water of own wt more than 2 times, follow and discharge a large amount of heats, after waste and old mud mixes, can produce principal crystalline phase is the ettringite structure that has 32 molecular crystal water, thereby the acceleration solidifying agent combines with waste and old mud particle, and rapid coagulation in certain temperature range, sclerosis, the scene of reaching can utilize the purpose of waste and old mud.
(4) embodiment:
Below with the present invention is further illustrated:
This sludge consolidating agent comprises flyash, lime powder, is to adapt to water-based mud, it is characterized in that: each composition and proportioning are as follows by weight:
If adapt to the needs of water-based mud, polymer mud and mixing mud, can carry out as follows: 1～60 part of sulphoaluminate cement clinker, 1～30 part of gypsum powder, 1～60 part in slag, 1～30 part of lime powder, 1～40 part in flyash, 1～15 part of calcium carbide powder, Fluorspar Powder are mixed into proportion at the sludge consolidating agent more than 1.65 for 1～15 part.
If adapt to the needs of polymer mud and mixing mud, can carry out as follows: on above-mentioned sludge consolidating agent basis, in addition 1～20 part of high efficiency water reducing agent, soda ash Na again
2CO
31～20 part, Sodium sulfate anhydrous.min(99) Na
2SO
41～20 part is mixed into proportion at the sludge consolidating agent more than 1.65.Can take following three kinds of schemes to describe:
The effect parameter of each scheme is as follows:
By the proportioning of last each composition of table as seen, this solidifying agent can adapt to water-based mud, polymer mud and mixing mud, mix with waste and old mud, can produce principal crystalline phase is the ettringite structure that has 32 molecular crystal water, solidifying agent can absorb above the free water of own wt more than 2 times in addition, follow and discharge a large amount of heats, meeting acceleration solidifying agent combines with waste and old mud particle, and rapid coagulation in certain temperature range, sclerosis, intensity is big, and water stability is good, the scene of reaching can utilize the purpose of waste and old mud, make and to gather materials on the spot, utilize waste and old mud, realize the treatment of wastes with processes of wastes against one another in the well site, the principle of Chu Liing nearby, and construction is simple, easy to operate, volume is few, and price is lower than cement price.
Claims (1)
1, a kind ofly relate to the well site and sludge consolidating agent that roadbed uses waste and old mud to use as base-material, comprise flyash, lime powder, it is characterized in that: each composition and proportioning are as follows by weight:
1～60 part of sulphoaluminate cement clinker, 1～30 part of gypsum powder, 1～60 part in slag, 1～30 part of lime powder, 1～40 part in flyash, 1～15 part of calcium carbide powder, Fluorspar Powder are mixed into proportion at the sludge consolidating agent more than 1.65 for 1～15 part; 1～20 part of high efficiency water reducing agent, soda ash Na in addition again
2CO
31～20 part, Sodium sulfate anhydrous.min(99) Na
2SO
41～20 part is mixed into proportion at the sludge consolidating agent more than 1.65.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021048010A CN1197813C (en) | 2002-02-07 | 2002-02-07 | Slurry consolidation agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021048010A CN1197813C (en) | 2002-02-07 | 2002-02-07 | Slurry consolidation agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1363531A CN1363531A (en) | 2002-08-14 |
| CN1197813C true CN1197813C (en) | 2005-04-20 |
Family
ID=4740118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021048010A Expired - Fee Related CN1197813C (en) | 2002-02-07 | 2002-02-07 | Slurry consolidation agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1197813C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101863609A (en) * | 2010-06-01 | 2010-10-20 | 武汉钢铁(集团)公司 | Environment-friendly sludge modifier |
| CN107140925A (en) * | 2017-05-23 | 2017-09-08 | 上海市建筑科学研究院 | A kind of flocculation of sludge body consolidating agent and application |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100386279C (en) * | 2006-10-10 | 2008-05-07 | 武汉理工大学 | High activity mixture slurry with several mineral components and its prepn process |
| CN100457849C (en) * | 2006-10-16 | 2009-02-04 | 大庆油田有限责任公司 | Environment-friendly curing agent for waste well completion fracturing fluid |
| CN100510001C (en) * | 2007-04-20 | 2009-07-08 | 大庆油田有限责任公司 | Silt and sand curing agent |
| CN101962256B (en) * | 2010-10-25 | 2011-12-14 | 南京华廷环保科技开发有限公司 | Comprehensive treatment method for blue-green algae sludge |
| CN102320709A (en) * | 2011-05-10 | 2012-01-18 | 任丘市华北石油天华环保节能有限公司 | Slurry curing agent |
| CN102344813B (en) * | 2011-07-18 | 2014-04-02 | 徐辰楚 | Curing agent for curing marine poor subsoil |
| CN102493430B (en) * | 2011-11-30 | 2014-05-28 | 方文盛 | Method for prevention and emergency treatment of soil geological hazards |
| CN106746978A (en) * | 2016-11-28 | 2017-05-31 | 王寿光 | A kind of special cement processing method of hardening soil and silt soil |
-
2002
- 2002-02-07 CN CNB021048010A patent/CN1197813C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101863609A (en) * | 2010-06-01 | 2010-10-20 | 武汉钢铁(集团)公司 | Environment-friendly sludge modifier |
| CN107140925A (en) * | 2017-05-23 | 2017-09-08 | 上海市建筑科学研究院 | A kind of flocculation of sludge body consolidating agent and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1363531A (en) | 2002-08-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100522854C (en) | Solidifying agent for solidifying and stabilizing treatment of generated dewatered sludge in sewage plant | |
| CN109133754A (en) | A kind of muck foundation material and the method using the foundation material construction subgrade | |
| CN108203270A (en) | A kind of controllability low-intensity material | |
| CN102703086A (en) | Inorganic soil curing agent and preparation method thereof | |
| CN1197813C (en) | Slurry consolidation agent | |
| CN111943620A (en) | Slurry curing agent and application thereof | |
| JP2002348573A (en) | Greening and soil-stabilizing material having unsolubilizing property of heavy metals and engineering method for blowing seed to thick-layer substrate, method for stabilizing soil and method for treating polluted soil by each using the same material | |
| CN111138099A (en) | Curing agent for phosphogypsum waste residues and curing method thereof | |
| CN102634343B (en) | Mineral slag based soil stabilizer and preparation method and application thereof | |
| CN1442465A (en) | Soil firming agent | |
| CN113149589A (en) | Soil body curing agent doped with sludge incineration ash and preparation method thereof | |
| CN107709267A (en) | Fast hard material, its manufacture method and the fast hydraulic cement composition using the fast hard material | |
| KR101525034B1 (en) | Environment-conscious embankment material using high-volume industrial waste by hydration reaction of phosphogypsum-slag | |
| CN108275854A (en) | Added with the alkaline residue base domestic sludge curing agent of high hydroscopic resin | |
| JP2004323599A (en) | Soil-solidifying agent and method for solidifying soil | |
| JP4632865B2 (en) | Construction sludge improvement method and improvement equipment used therefor | |
| JP3803076B2 (en) | Admixture for soil stabilization and soil stabilization method using the same | |
| JP4112666B2 (en) | Solidified material | |
| CN107572987A (en) | A kind of method of modifying of mud modifying agent and engineering slurry | |
| JP2001200251A (en) | Grout for producing watertight screen | |
| CN1827549A (en) | Curing method and curing agent thereof | |
| CN107382175B (en) | Soil solidifying agent, preparation method and application thereof | |
| JP2503771B2 (en) | Solidifying material for cohesive soil of volcanic ash | |
| CN85108073A (en) | The highway composite building material that contains pulverized coal dregs | |
| KR20150099038A (en) | Reclamation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050420 Termination date: 20210207 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |