CN1191238A - Non-phosphate liquid laundry detergent - Google Patents
Non-phosphate liquid laundry detergent Download PDFInfo
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- CN1191238A CN1191238A CN98101502A CN98101502A CN1191238A CN 1191238 A CN1191238 A CN 1191238A CN 98101502 A CN98101502 A CN 98101502A CN 98101502 A CN98101502 A CN 98101502A CN 1191238 A CN1191238 A CN 1191238A
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- laundry detergent
- liquid laundry
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- phosphate liquid
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Abstract
A phosphorusless liquid laundry detergent is prepared from anionic surfactant, non-ionic surfactant, phosphorusless builder, enzyme, chelating agent, antisettling agent, penetrant, softening agent for fabrics, perfume and water, and features no environmental pollution, low alkality, high detergency, low cost and not decolouring fabrics.
Description
The invention belongs to articles for washing.Specifically, relate to a kind of non-phosphate liquid laundry detergent and prescription and production technique.
At present, its component of articles for washing that uses both at home and abroad mostly is made up of surfactant A, phosphorous assistant B, enzyme C, sequestrant D, anti-deposition agent E, permeate agent F, fabric softener G, spices H and water W.English Patent 2126242 discloses a kind of prescription of liquid laundry detergent, and wherein phosphorous assistant B is tripoly phosphate sodium STPP (STPP).STPP has good chelating Ca
+ 2, Mg
+ 2The ion ability reduces ionic activity, and the response capacity decline with tensio-active agent has improved soil removability; And STPP can also be much and the tensio-active agent compatibility, improves surfactivity; STPP also has good solubility, can be made into various types of washing composition, price low, easily characteristics such as purchase, so STPP becomes one of main component in the widely used prescription of domestic and international producer.Yet phosphorous prescription main drawback is: since phosphorous higher in the product, generally about 20% (as containing STPP21% in the English patent 2126242), and using in a large number and discharging of phosphorus causes the water quality eutrophication, contamination phenomenon is serious, directly the health of harm humans.Phosphorous wash water has now become human primary pollution source, and the trend that enlarges is day by day arranged.
Purpose of the present invention just provides a kind of prescription and production technique of non-phosphate liquid laundry detergent, and it is not phosphorous, and has good chelating Ca
+ 2, Mg
+ 2The ionic ability; Emulsification, dispersion, clean effect are good; Be particularly suitable for cold washing.
The object of the present invention is achieved like this, and main prescription of the present invention is: surfactant A, phosphorus-free adjuvant B, enzyme C, sequestrant D, anti-deposition agent E, permeate agent F, fabric softener G, spices H and water W.Wherein B is the compatibility of zeolite, Citrate trianion, silicate, vitriol, carbonate; A is that anion surfactant and nonionogenic tenside constitute jointly.Through experiment, find that the compatibility of the phosphorus-free adjuvant B of different ratios can replace STPP to reach good washing effect fully; When anion surfactant and nonionogenic tenside when depositing, the cold washing effect is remarkable.
Among the A of the present invention, anion surfactant can be fatty alcohol polyoxyethylene ether sulfate, alkylbenzene sulfonate, tosylate; Nonionogenic tenside can be fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene.
In the present invention, A10-30 part; B10-15 part; C0.2-1 part; D0.2-2 part; E0.2-2 part; F1-3 part; G1-3 part; H0.2-0.5 part; W40-60 part.
Owing to adopted technique scheme, major advantage of the present invention is: not phosphorous organic solvent and toxic reagent, the environmentally safe of waiting; Alkalescence is low, and strong detergency is particularly suitable for cold washing; Washing back fabric is harmless, colour-fast, and good hand touch; Equipment is simple, less investment, and production cost is low.
Below in conjunction with embodiment the present invention is done further commentary:
Embodiment 1 prescription is as follows:
8 parts of polyoxyethylenated alcohol sodium sulfate;
20 parts of Sodium dodecylbenzene sulfonatees;
10 parts of Citrate trianions;
5 parts in vitriol;
2 parts of silicate,
2 parts of sequestrants;
0.5 part of CMC;
1 part of fatty diglycollic amide;
50 parts in water.
Production technique, earlier distilled water is joined in the fatty alcohol polyoxyethylene ether sulfate, put into still after the heating for dissolving, put into Sodium dodecylbenzene sulfonate, Citrate trianion while stirring successively, sodium sulfate, water glass, fatty alkanol amide, enzyme, CMC, two octadecyl dimethyl chlorination amine and essence, stirring is dissolved evenly it fully, leaves standstill exhaust, bottling, packing.
Embodiment 2 prescriptions are as follows:
15 parts of polyoxyethylenated alcohol sodium sulfate;
6 parts of fat alcohol polyethylene ethers; 2 parts of toluenesulfonic acid sodium salts; 15 parts of water glass; 1 part of sequestrant; 2 parts of fatty alkanol amides; 5 parts in yellow soda ash; 1 part of two octadecyl diformazan ammonia chloride; 0.2 part of enzyme; 0.2 part in essence; 53 parts in water.Above making processes is identical with embodiment 1, both can get finished product.Embodiment 3 prescriptions are as follows: 10 parts of fatty alcohol-polyoxyethylene ether; 20 parts of sodium alkyl benzene sulfonates; 5 parts of Citrate trianions; 5 parts in yellow soda ash; 5 parts in sodium sulfate; 0.5 part of sequestrant; 1 part of citric acid; 2 parts of fatty alkanol amides; 0.3 part of CMC; 0.2 part of enzyme; 0.2 part in essence; 50 parts in water.Above making processes is identical with embodiment 1, both can get finished product.
Claims (6)
1. non-phosphate liquid laundry detergent, mainly be made up of surfactant A, phosphorus-free adjuvant B, enzyme C, sequestrant D, anti-deposition agent E, permeate agent F, fabric softener G, spices H and water W, it is characterized in that: auxiliary agent B is the phosphorus-free adjuvant of zeolite, Citrate trianion, vitriol, carbonate compatibility; Tensio-active agent is that anion surfactant and nonionogenic tenside are formed jointly.
2. according to the described non-phosphate liquid laundry detergent of claim 1, it is characterized in that: the anion surfactant in the tensio-active agent is fatty alcohol polyoxyethylene ether sulfate, alkylbenzene sulfonate, tosylate; Nonionogenic tenside in the surfactant A is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene.
3. according to the described non-phosphate liquid laundry detergent of claim 2, it is characterized in that component is: surfactant A 10-30 part; Phosphorus-free adjuvant B10-15 part; Enzyme C0.2-1 part; Sequestrant D0.2-2 part; Anti-deposition agent E0.2-2 part; Permeate agent F1-3 part; Fabric softener G1-3 part; Spices H0.2-0.5 part; Water W40-60 part.
4. according to the described non-phosphate liquid laundry detergent of claim 3, it is characterized in that component is:
8 parts of polyoxyethylenated alcohol sodium sulfate;
20 parts of Sodium dodecylbenzene sulfonatees;
10 parts of Citrate trianions;
2 parts of silicate;
2 parts of sequestrants;
1 part of alkylol amide;
50 parts in water.
5. according to the described non-phosphate liquid laundry detergent of claim 3, it is characterized in that component is:
15 parts of polyoxyethylenated alcohol sodium sulfate;
6 parts of fat alcohol polyethylene ethers;
15 parts of water glass;
2 parts of toluenesulfonic acid sodium salts;
1 part of sequestrant;
2 parts of alkylol amidees;
5 parts in yellow soda ash;
1 part of two octadecyl diformazan ammonia chloride;
0.2 part of enzyme;
0.2 part in essence;
53 parts in water.
6. according to the described non-phosphate liquid laundry detergent of claim 3, it is characterized in that component is:
10 parts of fatty alcohol-polyoxyethylene ether;
20 parts of sodium alkyl benzene sulfonates;
5 parts of Citrate trianions;
5 parts in yellow soda ash;
5 parts in sodium sulfate;
0.5 part of sequestrant;
1 part of citric acid;
2 parts of fatty alkanol amides;
0.3 part of CMC;
0.2 part of enzyme;
0.2 part in essence;
50 parts in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98101502A CN1191238A (en) | 1998-04-03 | 1998-04-03 | Non-phosphate liquid laundry detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98101502A CN1191238A (en) | 1998-04-03 | 1998-04-03 | Non-phosphate liquid laundry detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1191238A true CN1191238A (en) | 1998-08-26 |
Family
ID=5216741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98101502A Pending CN1191238A (en) | 1998-04-03 | 1998-04-03 | Non-phosphate liquid laundry detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1191238A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533462A (en) * | 2011-12-14 | 2012-07-04 | 中国日用化学工业研究院 | Low-temperature efficient liquid detergent composition and preparation process thereof |
| CN103215142A (en) * | 2013-01-06 | 2013-07-24 | 扬州爱丽佳家用化学品有限公司 | Washing and softness combined liquid laundry detergent |
| CN103695192A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Bactericidal disinfectant for sheet and preparation method thereof |
| CN104293504A (en) * | 2014-09-24 | 2015-01-21 | 中国海洋石油总公司 | Descaling cleaning agent for poly-containing dirt on polymer flooding produced liquid treatment equipment |
| CN105369638A (en) * | 2014-08-25 | 2016-03-02 | 江苏欣隆羽绒有限公司 | Down feather degreasing agent |
| CN106085606A (en) * | 2016-06-25 | 2016-11-09 | 李莹 | Detergent |
| CN112226289A (en) * | 2020-11-05 | 2021-01-15 | 浙江康满家日用品有限公司 | High-detergency antibacterial specific concentrated laundry detergent and preparation method thereof |
| CN115895798A (en) * | 2022-11-11 | 2023-04-04 | 射阳天源化工有限公司 | Silicon-containing fabric cleaning agent and preparation method thereof |
-
1998
- 1998-04-03 CN CN98101502A patent/CN1191238A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533462A (en) * | 2011-12-14 | 2012-07-04 | 中国日用化学工业研究院 | Low-temperature efficient liquid detergent composition and preparation process thereof |
| CN102533462B (en) * | 2011-12-14 | 2013-10-30 | 中国日用化学工业研究院 | Low-temperature efficient liquid detergent composition and preparation process thereof |
| CN103215142A (en) * | 2013-01-06 | 2013-07-24 | 扬州爱丽佳家用化学品有限公司 | Washing and softness combined liquid laundry detergent |
| CN103215142B (en) * | 2013-01-06 | 2015-10-28 | 扬州爱丽佳家用化学品有限公司 | The washing liquid that collection washing is soft two-in-one |
| CN103695192A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Bactericidal disinfectant for sheet and preparation method thereof |
| CN105369638A (en) * | 2014-08-25 | 2016-03-02 | 江苏欣隆羽绒有限公司 | Down feather degreasing agent |
| CN104293504A (en) * | 2014-09-24 | 2015-01-21 | 中国海洋石油总公司 | Descaling cleaning agent for poly-containing dirt on polymer flooding produced liquid treatment equipment |
| CN106085606A (en) * | 2016-06-25 | 2016-11-09 | 李莹 | Detergent |
| CN112226289A (en) * | 2020-11-05 | 2021-01-15 | 浙江康满家日用品有限公司 | High-detergency antibacterial specific concentrated laundry detergent and preparation method thereof |
| CN112226289B (en) * | 2020-11-05 | 2022-06-24 | 浙江康满家日用品有限公司 | Concentrated decontamination and antibacterial laundry detergent and preparation method thereof |
| CN115895798A (en) * | 2022-11-11 | 2023-04-04 | 射阳天源化工有限公司 | Silicon-containing fabric cleaning agent and preparation method thereof |
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| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |