CN115895798A - Silicon-containing fabric cleaning agent and preparation method thereof - Google Patents
Silicon-containing fabric cleaning agent and preparation method thereof Download PDFInfo
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- CN115895798A CN115895798A CN202211411180.3A CN202211411180A CN115895798A CN 115895798 A CN115895798 A CN 115895798A CN 202211411180 A CN202211411180 A CN 202211411180A CN 115895798 A CN115895798 A CN 115895798A
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- silicon
- cleaning agent
- fabric cleaning
- containing fabric
- silicone oil
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- 239000004744 fabric Substances 0.000 title claims abstract description 52
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 40
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 34
- 239000010703 silicon Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229920002545 silicone oil Polymers 0.000 claims abstract description 28
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 24
- 229920000570 polyether Polymers 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003513 alkali Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 14
- 230000000149 penetrating effect Effects 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 14
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 13
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 28
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 12
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 claims description 10
- 229920001451 polypropylene glycol Polymers 0.000 claims description 10
- NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 claims description 8
- UYLSVYARXBFEKV-UHFFFAOYSA-N cyclobutane-1,3-diamine Chemical compound NC1CC(N)C1 UYLSVYARXBFEKV-UHFFFAOYSA-N 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- -1 isotridecyl alcohol ether carboxylate Chemical class 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 claims description 4
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical group [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 4
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical group CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical group CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- VOXCUZGLPPXOHV-UHFFFAOYSA-N 6-methylheptyl hydrogen sulfate Chemical compound CC(C)CCCCCOS(O)(=O)=O VOXCUZGLPPXOHV-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 2
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses a silicon-containing fabric cleaning agent and a preparation method thereof, wherein the silicon-containing fabric cleaning agent comprises self-made polyether modified silicone oil, a nonionic surfactant, a chelating dispersant, an alkali-resistant penetrating agent, an anionic surfactant, a cationic surfactant, an alcohol ether solvent, a thickening agent and deionized water.
Description
Technical Field
The invention relates to the technical field of daily-use chemical industry, in particular to a silicon-containing fabric cleaning agent and a manufacturing method thereof.
Background
In the textile daily chemical industry and the printing and dyeing industry, the textile cleaning agent can endow the fabric with a decontamination effect, and along with the improvement of the living standard, especially high-grade clothing fabrics, the cleaning agent is required to have an excellent decontamination effect and have higher requirements on the comfort and the flexibility of the textile.
The fabric cleaning agent in the market is prepared by compounding various common surfactants as main raw materials, and the flexibility of the fabric is poorer and poorer along with the increase of the fabric washing times, and the use comfort is lower and lower, so a new fabric cleaning agent needs to be provided to solve the problem.
Disclosure of Invention
Technical problem to be solved
In order to overcome the defects of the prior art, the silicon-containing fabric cleaning agent and the manufacturing method thereof are provided, so that the surface tension performance and the wetting performance can be reduced, toxic and side effects are avoided, and the flexibility of the fabric can be improved.
(II) technical scheme
The invention is realized by the following technical scheme: the invention provides a silicon-containing fabric cleaning agent which is prepared from self-made polyether modified silicone oil, a nonionic surfactant, a chelating dispersant, an alkali-resistant penetrating agent, an anionic surfactant, a cationic surfactant, an alcohol ether solvent, a thickening agent and deionized water.
Further, the self-made polyether modified silicone oil accounts for 3% -5%, the nonionic surfactant accounts for 1% -3%, the chelating dispersant accounts for 0.2% -0.5%, the alkali-resistant penetrating agent accounts for 0.5% -1%, the anionic surfactant accounts for 0.2% -3%, the cationic surfactant accounts for 1% -5%, the alcohol ether solvent accounts for 2% -5%, the thickening agent accounts for 0.5% -2%, and the rest of the silicon-containing fabric cleaning agent accounts for deionized water.
Furthermore, the self-made polyether modified silicone oil is prepared by removing an isopropanol solvent after epoxy-terminated silicone oil, polypropylene glycol diglycidyl ether, 1, 3-cyclobutane diamine and diisobutylamine are subjected to polymerization reaction in isopropanol.
Further, the epoxy-terminated silicone oil, the polypropylene glycol diglycidyl ether, the 1, 3-cyclobutanediamine, the diisobutylamine and the isopropanol have the following mass part ratios: 300-500: 50 to 100:30 to 80:20 to 30:200 to 500 ℃, the temperature of the polymerization reaction is 30 to 85 ℃, and the time is 2 to 10 hours.
Further, the number average molecular weight selected by the epoxy-terminated silicone oil is 8000 or 10000.
Further, the number average molecular weight of the polypropylene glycol diglycidyl ether is 380 or 640.
Further, the nonionic surfactant is isomeric C12 alcohol polyoxyethylene ether 5EO or isomeric C12 alcohol polyoxyethylene ether 7EO.
Further, the chelating dispersant is tetrasodium glutamate diacetate, the alkali-resistant penetrating agent is isooctyl alcohol sulfate, the anionic surfactant is isotridecyl alcohol ether carboxylate, the cationic surfactant is coconut oil amine polyoxyethylene ether, the alcohol ether solvent is dipropylene glycol butyl ether or ethylene glycol monobutyl ether, and the thickener is sodium carboxymethylcellulose.
Further, the polyether number of the cocoamine polyoxyethylene ether is 10 and 15.
A preparation method of a silicon-containing fabric cleaning agent comprises the following steps: the method comprises the following steps:
the method comprises the following steps: epoxy-terminated silicone oil, polypropylene glycol diglycidyl ether, 1, 3-cyclobutanediamine, diisobutylamine and isopropanol are mixed according to the mass part ratio: 300-500: 50 to 100:30 to 80:20 to 30: polymerizing at the polymerization temperature of 30-85 ℃ for 2-10 hours in the proportion of 200-500, and then removing isopropanol to obtain the self-made polyether modified silicone oil.
Step two: compounding the self-made polyether modified silicone oil prepared in the step one with a nonionic surfactant, a chelating dispersant, an alkali-resistant penetrating agent, an anionic surfactant, a cationic surfactant, an alcohol ether solvent, a thickening agent and deionized water according to a certain proportion to prepare the silicon-containing fabric cleaning agent, wherein the percentage is as follows: 3-5% of self-made polyether modified silicone oil, 1-3% of nonionic surfactant, 0.2-0.5% of chelating dispersant, 0.5-1% of alkali-resistant penetrating agent, 0.2-3% of anionic surfactant, 1-5% of cationic surfactant, 2-5% of alcohol ether solvent, 0.5-2% of thickening agent and the balance of deionized water.
Step three: and (3) carrying out a dirt-removing power test and a flexibility test on the prepared silicon-containing fabric cleaning agent.
(III) advantageous effects
Compared with the prior art, the invention has the following beneficial effects:
according to the silicon-containing fabric cleaning agent and the preparation method thereof, polyether is modified by self-made polyether, polyether is introduced into the chemical structure of the silicone oil, so that the silicon-containing fabric cleaning agent has wetting and spreading properties, and then the silicon-containing fabric cleaning agent is compounded and mixed with a nonionic surfactant, a chelating dispersant, an alkali-resistant penetrating agent, an anionic surfactant, a cationic surfactant, an alcohol ether solvent, a thickening agent and deionized water according to a certain proportion.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
Adding 400 kg of epoxy terminated silicone oil (with the number average molecular weight of 8000), 60 kg of polypropylene glycol diglycidyl ether (with the number average molecular weight of 380), 40 kg of 1, 3-cyclobutane diamine, 20 kg of diisobutylamine and 300 kg of isopropanol into a 1000L reaction kettle provided with a stirrer and a thermometer, carrying out mixing polymerization at 80 ℃ for 5 hours, cooling to 40 ℃, and carrying out reduced pressure distillation to remove the isopropanol to obtain the self-made polyether modified silicone oil.
Respectively adding the following components into a 1500L reaction kettle provided with a stirrer and a thermometer: 35 kg of self-made polyether modified silicone oil, 20 kg of non-ionic surfactant isomeric C12 alcohol polyoxyethylene ether 5EO, 3 kg of chelating dispersant tetrasodium glutamate diacetate, 6 kg of alkali-resistant penetrating agent isooctanol sulfate, 10 kg of anionic surfactant isomeric tridecanol ether carboxylate, 20 kg of cationic surfactant cocoamine polyoxyethylene ether (the polyether amount is 10), 30 kg of alcohol ether solvent dipropylene glycol butyl ether, 1 kg of thickener carboxymethylcellulose sodium and 876 kg of deionized water, and uniformly stirring to prepare the silicon-containing fabric cleaning agent.
Example 2
420 kg of epoxy terminated silicone oil (with the number average molecular weight of 10000), 72 kg of polypropylene glycol diglycidyl ether (with the number average molecular weight of 640), 45 kg of 1, 3-cyclobutane diamine, 25 kg of diisobutylamine and 350 kg of isopropanol are added into a 1000L reaction kettle provided with a stirrer and a thermometer, mixed and polymerized for 5 hours at the temperature of 80 ℃, and the temperature is reduced to 40 ℃ to remove the isopropanol by reduced pressure distillation, so that the polyether modified silicone oil is obtained.
Respectively adding the following components into a 1500L reaction kettle provided with a stirrer and a thermometer: 40 kg of self-made polyether modified silicone oil, 7EO 22 kg of nonionic surfactant isomeric C12 alcohol polyoxyethylene ether, 3.2 kg of chelating dispersant tetrasodium glutamate diacetate, 6.4 kg of alkali-resistant penetrating agent isooctanol sulfate, 12 kg of anionic surfactant isomeric tridecanol ether carboxylate, 23 kg of cationic surfactant cocoamine polyoxyethylene ether (the number of polyether is 15), 32 kg of alcohol ether solvent ethylene glycol monobutyl ether, 1.2 kg of thickener carboxymethylcellulose sodium and 861.2 kg of deionized water, and the mixture is uniformly stirred to prepare the silicon-containing fabric cleaning agent.
The quality test data obtained were as follows:
appearance of the product | Colorless transparent liquid, no layering and no suspended matter |
Density (g/cm) 3 ) | 0.98 |
pH | 6~7 |
Viscosity 25 ℃ mPa s | 300~1000 |
Examples of the applications
And (3) carrying out a dirt-removing power test on the prepared silicon-containing fabric cleaning agent: reference is made to GB/T13174-2021 "determination of detergency and circulating washing performance of detergents for clothing". According to the requirements of GB/T13174-2021 annex three standard dirty cloths are mixed with self-made silicon-containing cleaning agent and hard water (using CaCO) whose hardness is 250mg/kg 3 Measured) to prepare 1L of 0.2 percent test washing solution, respectively adding the test washing solution into a vertical decontamination machine at the temperature of 30 +/-1 ℃, keeping the stirring speed at 120r/min, cleaning three kinds of standard dirty cloth for 20min, dehydrating and drying, and reading the whiteness test spectral reflectance of the standard fabric before and after cleaning by using a whiteness meter at 457 nm.
Stain removal value of certain stained cloths is as R i Equation (1) calculates:
R i =∑(F 2i -F 1i )/n…………………………(1)
in the formula:
i-i type stain cloth sample;
F 2i measuring the spectral reflectivity of the whiteness of the i-th type of dirty cloth sample after being washed by the cleaning agent,%;
F 1i -whiteness test spectral reflectance,%, of an i-th type of soiled cloth sample before cleaning;
n-the effective number of soiled swatches per group after correction.
The data is filled into the following table:
through data comparison: the fabric cleaned by the embodiment has the advantages that the stains on the surface of the fabric are removed, and the stain removal effect is good.
And (3) testing the flexibility of the prepared silicon-containing fabric cleaning agent:
after the standard dirty cloth is washed for 15 times by the silicon-containing cleaning agent in the embodiment, the cloth is dried and remoistened, more than 5 professionals evaluate the hand feeling of the fabric by touch, a grade 5 grading method is adopted, grade 1 is worst, grade 5 is best, and the test results are shown in the following table:
through data comparison in the table: the fabric cleaned by the embodiment has improved hand flexibility.
In conclusion, the fabric washed by the cleaning agent has excellent decontamination effect, can endow the fabric with soft hand feeling, and has wide market prospect.
The above-described embodiments are merely illustrative of the preferred embodiments of the present invention and do not limit the spirit and scope of the present invention. Various modifications and improvements of the technical solutions of the present invention that are made by those skilled in the art without departing from the design concept of the present invention shall fall within the protection scope of the present invention, and the technical contents of the present invention that are claimed shall be fully described in the claims.
Claims (10)
1. A silicon-containing fabric cleaning agent is characterized in that: the silicon-containing fabric cleaning agent is prepared from self-made polyether modified silicone oil, a nonionic surfactant, a chelating dispersant, an alkali-resistant penetrating agent, an anionic surfactant, a cationic surfactant, an alcohol ether solvent, a thickening agent and deionized water.
2. The silicon-containing fabric cleaning agent according to claim 1, wherein: the percentage content of the self-made polyether modified silicone oil is 3% -5%, the percentage content of the nonionic surface active agent is 1% -3%, the percentage content of the chelating dispersant is 0.2% -0.5%, the percentage content of the alkali-resistant penetrating agent is 0.5% -1%, the percentage content of the anionic surface active agent is 0.2% -3%, the percentage content of the cationic surface active agent is 1% -5%, the percentage content of the alcohol ether solvent is 2% -5%, the percentage content of the thickening agent is 0.5% -2%, and the remaining percentage content of the silicon-containing fabric cleaning agent is deionized water.
3. The silicon-containing fabric cleaning agent according to claim 1, wherein: the self-made polyether modified silicone oil is prepared by removing an isopropanol solvent after epoxy-terminated silicone oil, polypropylene glycol diglycidyl ether, 1, 3-cyclobutane diamine and diisobutylamine are subjected to polymerization reaction in isopropanol.
4. The silicon-containing fabric cleaning agent according to claim 3, wherein: the epoxy-terminated silicone oil, the polypropylene glycol diglycidyl ether, the 1, 3-cyclobutanediamine, the diisobutylamine and the isopropanol are in parts by mass as follows: 300-500: 50 to 100:30 to 80:20 to 30:200 to 500 ℃, the temperature of the polymerization reaction is 30 to 85 ℃, and the time is 2 to 10 hours.
5. The silicon-containing fabric cleaning agent according to claim 4, wherein: the number average molecular weight selected by the epoxy-terminated silicone oil is 8000 or 10000.
6. The silicon-containing fabric cleaning agent according to claim 4, wherein: the number average molecular weight of the polypropylene glycol diglycidyl ether is 380 or 640.
7. The silicon-containing fabric cleaning agent according to claim 1, wherein: the nonionic surfactant is isomeric C12 alcohol polyoxyethylene ether 5EO or isomeric C12 alcohol polyoxyethylene ether 7EO.
8. The silicon-containing fabric cleaning agent according to claim 1, wherein: the chelating dispersant is tetrasodium glutamate diacetate, the alkali-resistant penetrating agent is isooctyl alcohol sulfate, the anionic surfactant is isotridecyl alcohol ether carboxylate, the cationic surfactant is coconut oil amine polyoxyethylene ether, the alcohol ether solvent is dipropylene glycol butyl ether or ethylene glycol monobutyl ether, and the thickening agent is sodium carboxymethylcellulose.
9. The silicon-containing fabric cleaning agent according to claim 8, wherein: the polyether number of the cocoamine polyoxyethylene ether is 10 and 15.
10. A process for preparing a silicon-containing fabric cleaning agent as claimed in any one of claims 1 to 6, which comprises: the method is characterized in that: the method comprises the following steps:
the method comprises the following steps: epoxy-terminated silicone oil, polypropylene glycol diglycidyl ether, 1, 3-cyclobutanediamine, diisobutylamine and isopropanol are mixed according to the mass part ratio: 300-500: 50 to 100:30 to 80:20 to 30: polymerizing at the polymerization temperature of 30-85 ℃ for 2-10 hours in the proportion of 200-500, and then removing isopropanol to obtain the self-made polyether modified silicone oil.
Step two: compounding the self-made polyether modified silicone oil prepared in the step one with a nonionic surfactant, a chelating dispersant, an alkali-resistant penetrating agent, an anionic surfactant, a cationic surfactant, an alcohol ether solvent, a thickening agent and deionized water according to a certain proportion to prepare the silicon-containing fabric cleaning agent, wherein the percentage is as follows: 3-5% of self-made polyether modified silicone oil, 1-3% of nonionic surfactant, 0.2-0.5% of chelating dispersant, 0.5-1% of alkali-resistant penetrating agent, 0.2-3% of anionic surfactant, 1-5% of cationic surfactant, 2-5% of alcohol ether solvent, 0.5-2% of thickening agent and the balance of deionized water.
Step three: and (3) carrying out a dirt-removing capability test and a flexibility test on the prepared silicon-containing fabric cleaning agent.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1191238A (en) * | 1998-04-03 | 1998-08-26 | 洋浦斯达科工贸有限公司天津科技公司 | Non-phosphate liquid laundry detergent |
CN103214676A (en) * | 2013-04-11 | 2013-07-24 | 浙江捷发科技有限公司 | Synthesis method for terpolymer block silicone oil |
CN114214124A (en) * | 2021-12-29 | 2022-03-22 | 威莱(广州)日用品有限公司 | Smooth color-protecting laundry detergent and preparation method thereof |
CN115109256A (en) * | 2021-12-29 | 2022-09-27 | 浙江传化功能新材料有限公司 | Preparation method of block silicone oil with high flash point and low solvent content |
-
2022
- 2022-11-11 CN CN202211411180.3A patent/CN115895798A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1191238A (en) * | 1998-04-03 | 1998-08-26 | 洋浦斯达科工贸有限公司天津科技公司 | Non-phosphate liquid laundry detergent |
CN103214676A (en) * | 2013-04-11 | 2013-07-24 | 浙江捷发科技有限公司 | Synthesis method for terpolymer block silicone oil |
CN114214124A (en) * | 2021-12-29 | 2022-03-22 | 威莱(广州)日用品有限公司 | Smooth color-protecting laundry detergent and preparation method thereof |
CN115109256A (en) * | 2021-12-29 | 2022-09-27 | 浙江传化功能新材料有限公司 | Preparation method of block silicone oil with high flash point and low solvent content |
Non-Patent Citations (2)
Title |
---|
张建春 等编著: "《化纤仿毛技术原理与生产实践》", 30 September 2003, 中国纺织出版社, pages: 314 - 316 * |
罗巨涛 等编: "《纺织品有机硅及有机氟整理》", 31 January 1999, 中国纺织出版社, pages: 44 * |
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