CN1189520C - Emulsified paraffin wax damp-proof agent for mineral wool sound absorption board and its preparation method - Google Patents
Emulsified paraffin wax damp-proof agent for mineral wool sound absorption board and its preparation method Download PDFInfo
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Abstract
The present invention relates to emulsion paraffin damp-proof agents for a mineral cotton sound absorbing plate, which belongs to the technical field of emulsion products containing macromolecular substances. The present invention is characterized in that components of the emulsion paraffin damp-proof agents comprise the following composition by weight: 5 to 22 shares of paraffin, 5 to 20 shares of modified resin, 0.5 to 5 shares of composition of non-ionic surface active agents, 2 to 8 shares of assistant emulsifiers and water as the rest. The present invention also provides a preparation method for the emulsion paraffin damp-proof agents for a mineral cotton sound absorbing plate. The emulsion paraffin damp-proof agents have the advantages of higher stability and favorable humidity resistance, optimize the fabrication technology of the mineral cotton sound absorbing plate, reduce the dosage of the damp-proof agents and reduce cost.
Description
Technical field
The invention belongs to the latex product field of containing polymer substance, relate in particular to emulsified paraffin wax damp-proof agent for mineral wool sound absorption board.
Background technology
Mineral wool sound absorption board is the widely used a kind of high-grade functional ornamentation sound-absorbing material of present domestic construction decoration industry, and it is that main body is aided with multiple other material and auxiliary agent is made with the mineral wool.This material also must have good humidity resistance except the basic function that should have sound absorption and decorate, so that can keep its inherent form and small amount of deflection to change under changeable climate and different humidity.The auxiliary agent of giving the good moistureproofness of acoustic board is called non-blushing thinner, and this non-blushing thinner should have reliable stability, not breakdown of emulsion, never degenerate, so that the turnover of commodity and use; It should be an emulsion state also, is convenient to can mix uniformly in the making of acoustic board in the slurrying pond, forms uniform dispersion state with mineral wool and other ancillary component.Not having polar group in the molecular structure of paraffin, is a kind of apolar substance, has good moistureproofness, but paraffin is difficult to the emulsion that high stability is made in emulsification, has limited its use.Up to now, the method for making that does not have the ideal emulsified paraffin wax damp-proof agent for mineral wool sound absorption board.Present employed non-blushing thinner is with the material heat fused of paraffin and stearic acid, adds nonionic surface active agent then, as alkaline matters such as fatty alcohol-polyoxyethylene ether and aqueous sodium hydroxide solution, ammoniacal liquor, makes after stirring." oil and gas chemical industry ", the second phase the 27th in 1998 volume has been published article " preparation research of the small emulsion of paraffin ", adopt energy-saving phase emulsion process, the selection by emulsifying agent and assistant for emulsifying agent and composite has made the small emulsion of paraffin, be used for glue used in paper-making, respond well.But, the present following shortcoming of paraffin wax damp-proof agent ubiquity:
1, is difficult to make stable emulsion, demulsifying phenomenon takes place easily, separate out paraffin and go bad.
2, the mineral wool of polar group that shortage is necessary in the non-blushing thinner and acoustic board and other composition is intermolecular with the Van der Waals force combination, and non-blushing thinner is difficult to effectively and uniform absorption, and moisture effect is poor.
3, mineral wool sound absorption board complete processing difficulty, because the separating out of paraffin, when slurries online making sheet, mesh is easily blocked by paraffin, needs often to shut down cleaning or more renew net.
4, the acoustic board poor performance of Zhi Zuoing, at the baking stage of making sheet, because paraffin is failed effective combination, high volatility under the high temperature, paraffin is overflowed easily, causes disaster hidden-trouble.
Summary of the invention
The purpose of this invention is to provide a kind of emulsified paraffin wax damp-proof agent for mineral wool sound absorption board, high stability that it has and good humidity resistance have effectively solved the defective that paraffin is easily separated out in the prior art.
Another object of the present invention provides a kind of preparation method of emulsified paraffin wax damp-proof agent for mineral wool sound absorption board of the present invention.
The present invention relates to a kind of emulsified paraffin wax damp-proof agent for mineral wool sound absorption board, it is characterized in that comprising paraffin, modified resin, non-ionic surfactant composition and assistant for emulsifying agent in its component, its weight is composed as follows: paraffin: modified resin: non-ionic surfactant composition: assistant for emulsifying agent: water=5～22: 5～20: 0.5～5: 2～8: surplus.Paraffin is that the trade mark included in the GB446-93 standard is 50
#～62
#Refining and SEMI-REFINED PARAFFIN WAX.Modified resin is with resin and the preparation down of acrylic acid or the like, maleic acid class and/or methylene-succinic acid class low molecular compound mixed melting; 150～230 ℃ of melt temperatures; be more preferably 180～200 ℃; reaction times 1～4h; be more preferably 2～3h; preferably under nitrogen protection, prepare, to obtain more polar group.Its weight proportion is: portions of resin low molecular compound=1: 0.01～0.20.Wherein used resin can be: the mixture of coumarone indene resin, aromatic hydrocarbons petroleum resin, aromatic hydrocarbons and olefin-copolymerization petroleum resin, aromatic hydrocarbons petroleum resin and alkene petroleum resin.Acrylic acid or the like, maleic acid class and/or methylene-succinic acid class low molecular compound can be one or more the mixtures in following: vinylformic acid, acrylamide, methacrylic acid, Methacrylamide, maleic acid, MALEIC ANHYDRIDE, methylene-succinic acid.Non-ionic surfactant composition be A and B two class surface active agent compositions by 0.2～0.8: the complex composition of hydrophile-lipophile balance value (HLB value) between 10～13 that 0.8～0.2 weight ratio is formed.The category-A surface active agent composition is alcohols Soxylat A 25-7 type or phenols Soxylat A 25-7 type nonionogenic tenside, as oleic alcohol polyoxyethylene (10) ether (Brij-96), hexadecanol polyoxyethylene (10) ether (Brij-56), octyl phenol polyoxy ethene (10) ether (Triton X-100); The category-B surface active agent composition is anhydrous sorbitol fatty acid ester and derivative polyoxyethylene (20) sorbitan fatty acid ester, i.e. span and tween series of surfactants.Assistant for emulsifying agent comprises C and two kinds of components of D, with C
7～C
18Middle and high carbon alcohol in one or more mixture be the C component, be the D component with the esterified rosin of rosin, fortified rosin, esterified rosin and partial esterification, its weight proportion is: C: D=3～7: 7～3.
The invention provides a kind of method for preparing emulsified paraffin wax damp-proof agent for mineral wool sound absorption board, it is characterized in that paraffin, modified resin and the fusing of assistant for emulsifying agent Hybrid Heating, regulate PH8～9, add the nonionic surfactant composition, slowly add 90 ℃ of hot water while stirring, hot water is the water of soft preferably, as deionized water, pure water or softening water; Emulsion generation phase inversion becomes O/W (oil-in-water) type by W/O (water-in-oil) type, maintains the temperature at 90～99 ℃, continues to add the water stirring and emulsifying to desired concn, obtains high stability anionic emulsified olefin product.Through electron microscopic analysis, particle is trickle in the emulsion, and its particle dia is in the 0.1-0.5 mu m range, and wherein 0.15 μ m accounts for more than 80%, and the centrifugal test stability and durability is put.
Mineral wool sound absorption board provided by the invention has following significant advantage and useful effect with the ionic emulsified paraffin wax damp-proof agent:
1, have high stability, owing to added special emulsion stabilizer and dispersion agent, and adopt effective Phase inversion emulsification technology, can be interior for a long time not stratified, not breakdown of emulsion, never degenerate.
2, You Yi moistureproofness, this non-blushing thinner has excellent moisture effect because particle is trickle, and surface-area is very big, through can evenly being adsorbed on the fiber surface behind the breakdown of emulsion, can form water-repellent layer as thin as a wafer after the drying.
3, optimized the complete processing of mineral wool sound absorption board, slurrying breakdown of emulsion not when rare, paraffin can be uniformly and other raw material mix and be adsorbed on its surface, overcome the technology shortcoming that the paraffin particles precipitation is blocked mesh.
4, humidity resistance is good, because the adding of modified resin, polar group of introducing and the hydroxyl in mineral wool fibre and other auxiliary material carry out chemical bonding, nonpolarity element in the modified resin overcomes the shortcoming that paraffin is overflowed with the effect of physics " anchor closes " and " containing " when drying, paraffin is evenly distributed, and has improved humidity resistance.
5, pollution-free, this non-blushing thinner is the emulsion with water dispersion medium, and is nontoxic, tasteless.In use, there is not any hazardous solvent volatilization, harmless, environmentally safe.
In addition, the present invention also has the few advantage of consumption, presses the solid consumption and calculates, and consumption is 30% of original paraffin wax damp-proof agent, and cost has reduced by 60%.
Embodiment
Embodiment 1 adds coumarone indene resin 200Kg, MALEIC ANHYDRIDE 16Kg in 50 liters of vertical response stills of agitator, interlayer heating, temperature-control heat couple and reflux exchanger are housed, heat 180 ℃ of molten resins, the limit is slowly stirred the limit and is opened reflux condensation mode water, and reaction 3h gets modified resin.
In the reactor of 50 liters that electronic stirring, thermometer, reflux exchanger and dropping funnel are housed, add the modified resin 38.0Kg of above-mentioned preparation, 56 in addition
#SEMI-REFINED PARAFFIN WAX 14.0Kg, assistant for emulsifying agent C are synthetic C
9～14Alcohol 2.4Kg, assistant for emulsifying agent D is maleated rosin 2.6Kg, heating is all melted material, adds diethanolamine and regulates pH value 8～9, adds 1.6Kg oleic alcohol polyoxyethylene (10) ether (Brij-96) and 0.4Kg Tween-60 again.Stir, 90～99 ℃ of controlled temperature drip about 90 ℃ deionized water, speed while dripping with 1000r/min stirs, and makes the water that splashes into fully diffusing, forms W/O (water-in-oil) type milk sap, continue to add water, milk sap becomes O/W (oil-in-water) type, and continuing to drip makes phase inversion complete, and control water yield adjusting emulsion concentration is about 30%, cooling adds organic silicon defoaming agent, room temperature is reduced in stirring, and discharging gets the anionic emulsified olefin.The emulsion band blue light that is creamy white, concentration is 30%, pH value 8.6, relative density 1.022g/cm
3, viscosity (being coated with-4 glasss) 13 seconds is easily disperseed in cold water, is diluted to 0.5% concentration, 48 hours not stratified, store 6 months not stratified, never degenerate.With daily output H-600 type determination of electron microscopy, granularity is at 0.1～0.5 mu m range, and wherein 0.15 μ m accounts for 82%.
Embodiment 2 adds aromatic hydrocarbons petroleum resin 200Kg, vinylformic acid 40.0Kg in 50 liters of vertical response stills of agitator, interlayer heating, temperature-control heat couple and reflux exchanger are housed, heat 150 ℃ of molten resins, the limit is slowly stirred the limit and is opened reflux condensation mode water, and reaction 4h gets modified resin.In addition in the reactor of 50 liters that electronic stirring, thermometer, reflux exchanger and dropping funnel are housed, the modified resin 40.0Kg that adds above-mentioned preparation, 50# SEMI-REFINED PARAFFIN WAX 44.0Kg, assistant for emulsifying agent C is lauryl alcohol 2.4Kg, assistant for emulsifying agent D is fortified rosin 5.6Kg, heating is all melted material, adds 40% NaOH solution adjusting pH value 8～9, adds 8.0Kg hexadecanol polyoxyethylene (10) ether (Brij-56) and 2.0Kg Si dish-85 again.Stir, 90～99 ℃ of controlled temperature drip about 90 ℃ softening water, speed while dripping with 1000r/min stirs, and makes the water that splashes into fully diffusing, forms W/O (water-in-oil) type milk sap, continue to add water, milk sap becomes O/W (oil-in-water) type, and continuing to drip makes phase inversion complete, and control water yield adjusting emulsion concentration is about 30%, cooling adds organic silicon defoaming agent, room temperature is reduced in stirring, and discharging gets the anionic emulsified olefin.
Embodiment 3 repeats embodiment 2, but vinylformic acid is 2.0Kg, and logical nitrogen, uses pure water, and it is 11.2Kg that assistant for emulsifying agent C uses octadecanol instead, and assistant for emulsifying agent D fortified rosin is 4.8Kg.
Embodiment 4 repeats embodiment 2, but vinylformic acid 40Kg uses acrylamide 2.0Kg instead, heats 230 ℃, reaction 1h.
Embodiment 5 repeats embodiment 2, but aromatic hydrocarbons petroleum resin 200Kg and vinylformic acid 40Kg use coumarone indene resin 200Kg instead, and methacrylic acid 2.0Kg heats 150 ℃, reaction 4h.
Embodiment 6 repeats embodiment 2, but aromatic hydrocarbons petroleum resin 200Kg uses aromatic hydrocarbons and olefin-copolymerization petroleum resin 200Kg instead, and assistant for emulsifying agent C uses 16 carbon alcohol instead and is 11.2Kg, and it is 4.8Kg that assistant for emulsifying agent D uses rosin instead.
Embodiment 7 repeats embodiment 2, but aromatic hydrocarbons petroleum resin 200Kg and vinylformic acid 40Kg use aromatic hydrocarbons petroleum resin and C instead
5Olefin resin mixture 200Kg and Methacrylamide 2.0Kg, reaction 2h.
Embodiment 8 repeats embodiment 2, but aromatic hydrocarbons petroleum resin 200Kg and vinylformic acid 40Kg use coumarone indene resin 200Kg and methylene-succinic acid 2.0Kg instead.
Embodiment 9 repeats embodiment 2, but vinylformic acid 40Kg uses maleic acid 40Kg instead, and it is 8.0Kg that assistant for emulsifying agent C uses octadecanol instead, and it is 8.0Kg that assistant for emulsifying agent D uses rosin instead.
Embodiment 10 repeats embodiment 2, but the aromatic hydrocarbons petroleum resin are used aromatic hydrocarbons petroleum resin and C instead
5The mixture 200Kg of alkene petroleum resin.
Embodiment 11 repeats embodiment 2, but vinylformic acid 40Kg uses the mixture 40Kg of vinylformic acid and acrylic anhydride instead.
Embodiment 12 repeats embodiment 2, but vinylformic acid 40Kg uses the mixture 2.0Kg of maleic acid and methylene-succinic acid instead.
Embodiment 13 repeats embodiment 2, but the modified resin consumption is 25Kg, uses softening water.
Embodiment 14 repeats embodiment 2, but the modified resin consumption is 10Kg.
Embodiment 15 repeats embodiment 2, but paraffin adopts 62
#Refined Paraffin Wax, consumption are 10Kg.
Embodiment 16 repeats embodiment 2, but paraffin adopts 62
#Refined Paraffin Wax, consumption are 26Kg, and the modified resin consumption is 10.0Kg.
Embodiment 17 repeats embodiment 2, but the consumption of non-ionic surfactant composition is 1.0Kg, and wherein A component octyl phenol polyoxy ethene (10) ether (Triton X-100) is 0.5Kg, and B component this dish-20 is 0.5Kg, uses deionized water.
Embodiment 18 repeats embodiment 2, but the consumption of non-ionic surfactant composition is 5.0Kg, and wherein A component octyl phenol polyoxy ethene (10) ether (Triton X-100) is 2.5Kg, and B component this dish-20 is 2.5Kg.
Embodiment 19 repeats embodiment 2, but the consumption of assistant for emulsifying agent is 4.0Kg, and wherein C component iso-heptanol is 2.8Kg, and the esterified rosin of D component partial esterification is 1.2Kg.
Embodiment 20 repeats embodiment 2, but the consumption of assistant for emulsifying agent is 10.0Kg, and wherein C component iso-heptanol is 7.0Kg, and D component esterified rosin is 3.0Kg.
Embodiment 21 repeats embodiment 2, but modified resin is 10.0Kg, uses 52 simultaneously instead
#SEMI-REFINED PARAFFIN WAX 10.0Kg.
Embodiment 22 repeats embodiment 2, but A component oleic alcohol polyoxyethylene (20) ether (Brij-98) in the non-ionic surfactant composition is 2.0Kg, and the B component is that this dish-20 is 8.0Kg.
Embodiment 23 repeats embodiment 2, but the component octanol is 8.0Kg among the assistant for emulsifying agent C, and D component maleated rosin is 8.0Kg.
Embodiment 24 repeats embodiment 2, but vinylformic acid is 2.0Kg, and modified resin is 10.0Kg, uses 58 simultaneously instead
#Refined Paraffin Wax 10.0Kg.
Embodiment 25 repeats embodiment 2, but vinylformic acid is 25.0Kg, and modified resin is 25.0Kg, uses 58 simultaneously instead
#Refined Paraffin Wax 26.0Kg.
Embodiment 26 repeats embodiment 2, but modified resin is 10.0Kg, and non-ionic surfactant composition is 1.0Kg, and wherein A component hexadecanol polyoxyethylene (20) ether (Brij-58) is 0.5Kg, and B component this dish-40 is 0.5Kg.
Embodiment 27 repeats embodiment 2, but modified resin is 10.0Kg, and assistant for emulsifying agent is 4.0Kg, and wherein C component octadecanol is 1.2Kg, and D component nilox resin is 2.8Kg.
Embodiment 28 repeats embodiment 2, but modified resin is 25.0Kg, and assistant for emulsifying agent is 10.0Kg, and wherein C component octadecanol is 3.0Kg, and D component nilox resin is 7.0Kg.
Embodiment 29 repeats embodiment 2, but vinylformic acid is 2.0Kg, and modified resin is 10.0Kg, uses 54 simultaneously instead
#SEMI-REFINED PARAFFIN WAX 10.0Kg, nonionogenic tenside are 1.0Kg, and wherein A component fatty alcohol-polyoxyethylene ether (Ukanil-43) is 0.8Kg, and B component Tween-40 is 0.2Kg.
Embodiment 30 repeats embodiment 2, but vinylformic acid is 2.0Kg, and modified resin is 10.0Kg, uses 52 simultaneously instead
#SEMI-REFINED PARAFFIN WAX 10.0Kg, nonionogenic tenside are 1.0Kg, and wherein A component fatty alcohol-polyoxyethylene ether (Ukanil-43) is 0.8Kg, and B component tween 20 is 0.2Kg, and assistant for emulsifying agent is 4.0Kg, wherein the synthetic C of C component
10～16Alcohol is 2.8Kg, and assistant for emulsifying agent D esterified rosin is 1.2Kg.
Embodiment 31 assistant for emulsifying agent C are with 16 carbon alcohol 2.8Kg, and assistant for emulsifying agent D is with partial esterification rosin 1.2Kg.Surplus with example 2.
The 32Kg temperature that comparative examples 1 will be dissolved with 0.9Kg tensio-active agent paregal O in advance is that 70～80 ℃ hot water joins in 50 liters the wax emulsifying pot, starts agitator and slowly stirs, and slowly adds the 5.0Kg56 that contains that has melted
#The stearic molten mixture of SEMI-REFINED PARAFFIN WAX and 23.0Kg, the sodium hydroxide solution 0.81Kg of adding 40%, adjusting pH value is 7～8, speed with 1000r/min stirred 30 minutes, finish the paraffin emulsion process, add the water of 42Kg then, be diluted to the concentration about 10%.The oyster white paraffin emulsifier that obtains is placed just demixing phenomenon in 1～2 day.
Comparative examples 2 repeats embodiment 2, but the consumption of assistant for emulsifying agent is zero, and the emulsion particle that obtains is bigger, and emulsion is muddy, place a week after, demixing phenomenon is arranged.
The emulsified paraffin wax damp-proof agent that Application Example 1 makes the present invention of 0.5% is used for the making of mineral wool sound absorption board, and consumption is 0.015g/m
3(containing solid with non-blushing thinner calculates), processing performance is good in the making sheet process, the situation that paraffin was overflowed when paraffin small-particle obstruction mesh and oven dry did not take place.The condition determination of the mineral wool sound absorption board of producing is:
Sample size 500mm * 250mm * 12mm; Relative air humidity 90% ± 2%; 40 ± 2 ℃ of temperature; Storage period 48h.The amount of deflection of measuring of making moist is 4.0mm.
The emulsified paraffin wax damp-proof agent that Application Example 2 makes the present invention of 0.5% is used for the making of mineral wool sound absorption board, and consumption is 0.018g/m
3(containing amount of solid with non-blushing thinner calculates), processing performance is good in the making sheet process, the situation that paraffin was overflowed when paraffin small-particle obstruction mesh and oven dry did not take place.With thermostat container the mineral wool sound absorption board of producing is measured, condition determination is with Application Example 1, and the amount of deflection of making moist of mensuration is 3.8mm.
Contrast Application Example 1 is used for the making of mineral wool sound absorption board with about 10% the emulsified paraffin wax damp-proof agent by comparative examples 1 preparation, and consumption is 0.056g/m
3(containing amount of solid with non-blushing thinner calculates).When online, there is the paraffin of fine granularity to block mesh, there is paraffin to overflow in the drying course, can smell strong paraffin smell.With thermostat container the mineral wool sound absorption board of producing is measured, condition determination is with Application Example 1, and the amount of deflection of making moist of mensuration is 12.0mm.
Contrast Application Example 2 is used for the making of mineral wool sound absorption board with about 10% the emulsified paraffin wax damp-proof agent by comparative examples 1 preparation, and consumption is 0.084g/m
3(containing amount of solid with non-blushing thinner calculates).When online, there is the paraffin of fine granularity to block mesh, there is paraffin to separate out in the drying course, can smell strong paraffin smell.With thermostat container the mineral wool sound absorption board of producing is measured, condition determination is with Application Example 1, and the amount of deflection of making moist of mensuration is 11.6mm.
Claims (2)
1, a kind of emulsified paraffin wax damp-proof agent for mineral wool sound absorption board, it is characterized in that comprising paraffin, modified resin, non-ionic surfactant composition and assistant for emulsifying agent in its component, its weight is composed as follows: paraffin: modified resin: non-ionic surfactant composition: assistant for emulsifying agent: water=5～22: 5～20: 0.5～5: 2～8: the water yield of non-blushing thinner desired concn;
Described paraffin is that the trade mark included in the GB446-93 standard is 50
#～62
#Refining or SEMI-REFINED PARAFFIN WAX;
Described modified resin is that resin is prepared under mixed melting with low molecular compound, and its weight proportion is:
Portions of resin low molecular compound=1: 0.01～0.20;
Described resin is: the mixture of coumarone indene resin, aromatic hydrocarbons petroleum resin, aromatic hydrocarbons and olefin-copolymerization petroleum resin or aromatic hydrocarbons petroleum resin and alkene petroleum resin;
Low molecular compound wherein is one or more the mixture in following: vinylformic acid, acrylamide, methacrylic acid, Methacrylamide, maleic acid, MALEIC ANHYDRIDE, methylene-succinic acid;
Described non-ionic surfactant composition be A and B two class surface active agent compositions by 0.2～0.8: the complex composition of hydrophile-lipophile balance value between 10～13 that 0.8～0.2 weight ratio is formed;
Category-A surface active agent composition wherein is alcohols Soxylat A 25-7 type or phenols Soxylat A 25-7 type nonionogenic tenside; Category-B surface active agent composition wherein is sorbitan fatty acid ester or derivatives thereof polyoxyethylene (a 20) sorbitan fatty acid ester;
Described assistant for emulsifying agent is a lauryl alcohol, and octadecanol, 16 carbon alcohol or iso-heptanol be the C component and be that two components of D component are formed with the esterified rosin of rosin, fortified rosin, esterified rosin or partial esterification,
Its weight proportion is C: D=3～7: 7～3.
2, a kind of method for making of emulsified paraffin wax damp-proof agent for mineral wool sound absorption board according to claim 1, it is characterized in that paraffin, modified resin and the fusion of assistant for emulsifying agent Hybrid Heating, regulate pH value 8～9, add nonionic surfactant, slowly add 90 ℃ of hot water while stirring, make w/o type become O/W type emulsion, maintain the temperature at and continue to add the water stirring and emulsifying under 90～99 ℃ to desired concn.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011352272A CN1189520C (en) | 2001-12-03 | 2001-12-03 | Emulsified paraffin wax damp-proof agent for mineral wool sound absorption board and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011352272A CN1189520C (en) | 2001-12-03 | 2001-12-03 | Emulsified paraffin wax damp-proof agent for mineral wool sound absorption board and its preparation method |
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| CN1189520C true CN1189520C (en) | 2005-02-16 |
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Families Citing this family (7)
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| CN101633785B (en) * | 2009-04-20 | 2011-09-28 | 永港伟方（北京）科技股份有限公司 | Paraffin wax emulsion as well as preparation method and application thereof |
| CN102250474A (en) * | 2011-05-19 | 2011-11-23 | 江苏力宝建材工业有限公司 | Marble wax and preparation method thereof |
| CN103172873A (en) * | 2011-12-23 | 2013-06-26 | 北京石油化工学院 | Method for preparing waterproof agent for acoustic mineral wool board by using modified petroleum resin emulsion |
| CN105155345A (en) * | 2015-09-11 | 2015-12-16 | 句容市兴武包装有限公司 | Moisture-proof paper and preparation method thereof |
| CN105256649A (en) * | 2015-09-11 | 2016-01-20 | 句容市兴武包装有限公司 | Moistureproof agent for paper products and preparation method therefor |
| WO2020061137A1 (en) | 2018-09-19 | 2020-03-26 | Owens Corning Intellectual Capital, Llc | Mineral wool insulation |
| CN113548822A (en) * | 2021-06-28 | 2021-10-26 | 江苏绿利新材料科技有限公司 | Water-retention thickening high-performance mortar additive |
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Address after: Lu Town, Linzi District, Zibo, Shandong Patentee after: Zibo Huanlukang New Material Sci. & Tech. Co., Ltd. Address before: Lu Town, Linzi District, Zibo, Shandong Patentee before: Linzi Ludi Fine Chemical Plant, Zibo City |
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Owner name: SHANDONG HUANLUKANG NEW MATERIALS TECHNOLOGY CO., Free format text: FORMER NAME OR ADDRESS: ZIBO CENTRAL GREEN TECHNOLOGY AND CULTURE NEW MATERIALS CO., LTD. |
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Address after: 255400, Shandong Province, Linzi District, Zibo City, Phoenix Town, Hao Village West first Patentee after: Shandong Huanlu Kangxin Materials Technology Co., Ltd. Address before: Lu Town, Linzi District, Zibo, Shandong Patentee before: Zibo Huanlukang New Material Sci. & Tech. Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050216 Termination date: 20181203 |