CN101503572A - Emulsion type ceramic stain control agent - Google Patents
Emulsion type ceramic stain control agent Download PDFInfo
- Publication number
- CN101503572A CN101503572A CNA2008101726443A CN200810172644A CN101503572A CN 101503572 A CN101503572 A CN 101503572A CN A2008101726443 A CNA2008101726443 A CN A2008101726443A CN 200810172644 A CN200810172644 A CN 200810172644A CN 101503572 A CN101503572 A CN 101503572A
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- China
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- stain control
- control agent
- silicone oil
- ceramic
- emulsifying agent
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Abstract
The invention provides an emulsion type ceramic antifoulant. The antifoulant takes water as a solvent and basically comprises the following components by mass percentage: 3 to 8 of methyl silicone oil, 6 to 12 of hydrogen containing silicone oil, 2 to 6 of hydroxy silicone oil, and 1 to 3 of emulsifier. The three silicone oils are co-mixed through the emulsifier so as to reach synergistic effect withouta petroleum solvent. Therefore, the emulsion type ceramic antifoulant saves a large amount of petroleum resource, promotes the environment-friendly and obviously reduces the cost of the ceramic antifoulant.
Description
Technical field
The present invention relates to the ceramic stain control agent technical field, particularly be applied to the ceramic stain control agent on the ceramic building sheet materials such as wall floor tile, polished tile.
Background technology
At present, sell on the market and the various ceramic stain control agents that use contain a large amount of petroleum solvents.Petroleum solvent is volatilization rapidly after stain control agent is applied to the ceramic board surface, does not play real effect to antifouling.The a large amount of uses of petroleum solvent in ceramic stain control agent not only make the cost of ceramic stain control agent high, and cause the significant wastage to petroleum resources.
Summary of the invention
The purpose of this invention is to provide a kind of emulsion type ceramic stain control agent that need not to rely on petroleum solvent.
For this reason, as solvent, its essentially consist and mass fraction are ceramic stain control agent of the present invention with water:
Methyl-silicone oil 3～8
Containing hydrogen silicone oil 6～12
Hydroxy silicon oil 2～6
Emulsifying agent 1～3
Methyl-silicone oil in the combined composition has extraordinary hydrophobicity and low surface tension, and the excellent properties that containing hydrogen silicone oil and hydroxy silicon oil not only have methyl-silicone oil to be possessed, and because of its with active function groups have more chemical reactivity, can give ceramic board stronger didirtresistance in the surface-crosslinked film forming of ceramic board.The present invention with water as solvent, utilize emulsifying agent with above-mentioned three kinds of silicone oil blend, reach a synergistic effect, no longer need petroleum solvent, the content of emulsifying agent is appropriate in addition, both avoided reducing didirtresistance, and can guarantee the stability and the spreadability of emulsion again, thereby made the emulsion type ceramic stain control agent of preparing have preferable stability, good spreadability and extraordinary didirtresistance because of the wetting ability of emulsifying agent.
Advantage of the present invention is to save the bulk petroleum resource, helps environmental protection, and can significantly reduce the cost of ceramic stain control agent.On the other hand, because the pollutent that ceramic board suffers in daily life mainly is the water-based dirt, as ink, urine, tea etc., and the present invention is the emulsion-type stain control agent, compare ability with petroleum solvent type stain control agent, so the present invention more helps strengthening the antifouling property of ceramic board with stronger water-repellancy dirt infiltration.Moreover toxicological harmless of the present invention, no burn into have no irritating odor, do not fire, not quick-fried, not only be applicable to ceramic board, and can use as waterproof and oilproof emulsion at building materials fields such as stone material, glass, timber; Because its environment-protecting asepsis also can applied aspect the home-use super clean bright ceramic tile maintenance.
Embodiment
Below in conjunction with embodiment the present invention is described in further details.
Component of the present invention can also add ancillary components such as sanitas, spices, but these ancillary components not necessarily except water, methyl-silicone oil, containing hydrogen silicone oil, hydroxy silicon oil and emulsifying agent.Water as solvent preferably adopts deionized water, but also can adopt ordinary tap water, but must note water quality, because of it may influence the stability of emulsion.The content ratio of water is decided according to the required concentration of reality.The viscosity of selected methyl-silicone oil is preferably 100mm
2S
-1, perhaps 350mm
2S
-1, perhaps 500mm
2S
-1, perhaps 1000mm
2S
-1, so can make stain control agent have better didirtresistance and spreadability.Certainly,, also can adopt the methyl-silicone oil of other viscosity if having to take the second best, or the compound of the methyl-silicone oil of different viscosity.The hydrogen content of selected containing hydrogen silicone oil preferably 1.55～1.6%, the hydroxy radical content of hydroxy silicon oil preferably 6～9% can make stain control agent have better didirtresistance and spreadability so equally.Emulsifying agent can be selected nonionic emulsifying agent for use, as fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, alkylol amide, and nonionic organic fluorine tensio-active agent etc., it is composite also can to adopt several nonionic emulsifying agents to carry out; Can also add a spot of anionic emulsifier, as linear alkylbenzene sulphonic acid, sodium alkyl sulfate, fatty alcohol-ether sodium sulfate and negatively charged ion organic fluorine tensio-active agent etc., to increase the stability of emulsion.The mass ratio of nonionic emulsifying agent and anionic emulsifier should be 5～50:1.No matter emulsifying agent is one-component or composite emulsifying agent, its hydrophile-lipophile balance value, and just the HLB value is preferably allocated between 10～12, to improve the stability and the spreadability of emulsion.
Emulsion-type stain control agent of the present invention can be with the preparation of following method: with various silicone oil by certain proportioning composite after, add a certain amount of emulsifying agent, with mulser they are emulsified in the aqueous solution, form stable silicone oil emulsion.Wherein mulser adopts conventional suspension type or pipeline-type emulsifying machine etc. all can.
The using method of emulsion-type stain control agent of the present invention can be to drip the emulsion-type stain control agent on the ceramic board surface on one side, Yi Bian use the polishing of slow speed of revolution low pressure polishing machine, utilizes the mill rotation, and stain control agent is infiltrated surperficial pore better, and uniformity.After water vapored away, the silicone oil active substance rested on the ceramic board surface, infiltrated the trickle pore that is not filled up by nanometer burnishing liquid, and formed one deck waterproof and oilproof rete on the surface, brought into play antifouling effect.
Enumerate the concrete composition and the making method of several emulsion-type stain control agents of the present invention below:
Embodiment 1
Get methyl-silicone oil (350mm
2S
-1) 3 parts, 6 parts of containing hydrogen silicone oils, 2.5 parts of hydroxy silicon oils, 1.6 parts and 0.2 part Sodium dodecylbenzene sulfonate of OP-9 nonionic emulsifying agent mix, and under mulser stirs, slowly add 86.7 parts of water in batches, emulsification half hour, make.
Product was stablized with whizzer 3000r/min in centrifugal 20 minutes, placed not stratified more than six months.
Embodiment 2
Get methyl-silicone oil (500mm
2S
-1) 4 parts, 7 parts of containing hydrogen silicone oils, 3 parts of hydroxy silicon oils, 0.8 part of Tween-80 nonionic emulsifying agent, 0.7 part and 0.2 part sodium lauryl sulphate of Span-80 nonionic emulsifying agent mix, under mulser stirs, slowly add 84.3 parts of water, emulsification half hour, make in batches.Add a small amount of sanitas and spices at last again.
Product was stablized with whizzer 3000r/min in centrifugal 20 minutes, placed not stratified more than six months.
Embodiment 3
Get methyl-silicone oil (350mm
2S
-1) 3.5 parts, 9 parts of containing hydrogen silicone oils, 3.5 parts of hydroxy silicon oils, 1.2 parts and 0.2 part sodium laurylsulfonate of NP-7 nonionic emulsifying agent mix, and under mulser stirs, slowly add 82.6 parts of water in batches, emulsification half hour, make.
Product was stablized with whizzer 3000r/min in centrifugal 20 minutes, placed not stratified more than six months.
Embodiment 4
Get 350mm
2S
-11.5 parts of methyl-silicone oils, 500mm
2S
-11.5 parts of methyl-silicone oils, 1.5 parts and 0.2 part Sodium dodecylbenzene sulfonate of 8 parts of containing hydrogen silicone oils, 4 parts of hydroxy silicon oils, AEO-7 nonionic emulsifying agent mixes, and under mulser stirs, slowly adds 83.3 parts of water in batches, and emulsification half hour, make.Also can add a small amount of sanitas and spices more at last.
Product was stablized with whizzer 3000r/min in centrifugal 20 minutes, placed not stratified more than six months.
Claims (5)
1, a kind of emulsion type ceramic stain control agent is characterized in that: as solvent, its essentially consist and mass fraction are described stain control agent with water:
Methyl-silicone oil 3～8
Containing hydrogen silicone oil 6～12
Hydroxy silicon oil 2～6
Emulsifying agent 1～3.
2, ceramic stain control agent as claimed in claim 1 is characterized in that: the viscosity of described methyl-silicone oil is 100mm
2S
-1, or 350mm
2S
-1, or 500mm
2S
-1, or 1000mm
2S
-1
3, ceramic stain control agent as claimed in claim 1 is characterized in that: the hydrogen content of described containing hydrogen silicone oil is 1.55～1.6%, and the hydroxy radical content of hydroxy silicon oil is 6～9%.
4, ceramic stain control agent as claimed in claim 1 is characterized in that: described emulsifying agent is formed with anionic emulsifier is composite on a small quantity by nonionic emulsifying agent, and the mass ratio of nonionic emulsifying agent and anionic emulsifier is 5～50: 1.
5, ceramic stain control agent as claimed in claim 1 is characterized in that: the hydrophile-lipophile balance value of described emulsifying agent is between 10～12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101726443A CN101503572A (en) | 2008-11-05 | 2008-11-05 | Emulsion type ceramic stain control agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101726443A CN101503572A (en) | 2008-11-05 | 2008-11-05 | Emulsion type ceramic stain control agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101503572A true CN101503572A (en) | 2009-08-12 |
Family
ID=40975960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101726443A Pending CN101503572A (en) | 2008-11-05 | 2008-11-05 | Emulsion type ceramic stain control agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101503572A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417363A (en) * | 2011-08-02 | 2012-04-18 | 中国科学院化学研究所 | Micron-nano-sized porous composite material and preparation method thereof |
| CN102585699A (en) * | 2011-12-30 | 2012-07-18 | 蓝星化工新材料股份有限公司江西星火有机硅厂 | Hydrogen-containing silicone oil emulsion type waterproofing agent |
| CN103073995A (en) * | 2012-12-28 | 2013-05-01 | 广东一鼎科技有限公司 | Emulsion type ceramic antifoulant |
| WO2014117235A1 (en) * | 2013-01-31 | 2014-08-07 | Dalpiaz Maycon Isense | Process for producing an anti-adherent semi-paste compound for liquid steel on solid metal and an anti-adherent semi-paste compound for liquid steel on solid metal |
| CN104014466A (en) * | 2014-05-04 | 2014-09-03 | 姚燕春 | Chromatic aberration preventing technology of high-water-absorption polished tile |
| CN104497869A (en) * | 2015-01-08 | 2015-04-08 | 佛山市思特四通化工有限公司 | Quartz stone anti-fouling agent and preparation method and application thereof |
| CN111171715A (en) * | 2020-02-18 | 2020-05-19 | 清远市宏图助剂有限公司 | Emulsion type ceramic anti-fouling agent and preparation method thereof |
| CN111349398A (en) * | 2020-04-13 | 2020-06-30 | 清远市宏图助剂有限公司 | Durable polishing solution and using method thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
-
2008
- 2008-11-05 CN CNA2008101726443A patent/CN101503572A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417363A (en) * | 2011-08-02 | 2012-04-18 | 中国科学院化学研究所 | Micron-nano-sized porous composite material and preparation method thereof |
| CN102585699A (en) * | 2011-12-30 | 2012-07-18 | 蓝星化工新材料股份有限公司江西星火有机硅厂 | Hydrogen-containing silicone oil emulsion type waterproofing agent |
| CN103073995A (en) * | 2012-12-28 | 2013-05-01 | 广东一鼎科技有限公司 | Emulsion type ceramic antifoulant |
| WO2014117235A1 (en) * | 2013-01-31 | 2014-08-07 | Dalpiaz Maycon Isense | Process for producing an anti-adherent semi-paste compound for liquid steel on solid metal and an anti-adherent semi-paste compound for liquid steel on solid metal |
| CN104014466A (en) * | 2014-05-04 | 2014-09-03 | 姚燕春 | Chromatic aberration preventing technology of high-water-absorption polished tile |
| CN104497869A (en) * | 2015-01-08 | 2015-04-08 | 佛山市思特四通化工有限公司 | Quartz stone anti-fouling agent and preparation method and application thereof |
| CN111171715A (en) * | 2020-02-18 | 2020-05-19 | 清远市宏图助剂有限公司 | Emulsion type ceramic anti-fouling agent and preparation method thereof |
| CN111349398A (en) * | 2020-04-13 | 2020-06-30 | 清远市宏图助剂有限公司 | Durable polishing solution and using method thereof |
| CN111349398B (en) * | 2020-04-13 | 2021-08-10 | 清远市宏图助剂有限公司 | Durable polishing solution and using method thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
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Open date: 20090812 |