CN104497869A - Quartz stone anti-fouling agent and preparation method and application thereof - Google Patents
Quartz stone anti-fouling agent and preparation method and application thereof Download PDFInfo
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- CN104497869A CN104497869A CN201510009972.1A CN201510009972A CN104497869A CN 104497869 A CN104497869 A CN 104497869A CN 201510009972 A CN201510009972 A CN 201510009972A CN 104497869 A CN104497869 A CN 104497869A
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Abstract
The invention discloses a quartz stone anti-fouling agent and a preparation method and application thereof. The quartz stone anti-fouling agent comprises the following raw materials in percentage by mass: 6-16% of methyl hydrosilicone oil, 2-8% of hydroxyl-terminated polydimethylsiloxane, 0-5% of methyl silicone oil, 1-2% of cosolvent, 0.5-5% of silane coupling agent and 70-85% of solvent. The quartz stone anti-fouling agent is specially developed for coarse and porous quartz stone which is vulnerable to fouling; and by simply smearing the anti-fouling agent on the surface of the quartz stone, the quartz stone can be effectively protected from oil pens, ink, coffee, tea and other pollutants. The quartz stone anti-fouling agent disclosed by the invention is simple in preparation process, good in anti-fouling property and favorable in scrub resistance and durability, can not influence the surface gloss of the quartz stone, and is non-toxic and non-corrosive, thus not only being applicable to the quartz stone, but also being applicable to agglomerated stone, marble, matt tiles and the like.
Description
Technical field
The invention belongs to quartzite anti-soil technology field, relate to a kind of quartzite stain control agent and its preparation method and application.
Background technology
Quartzite is made up of the natural quartz (particle or micro mist etc.) of more than 90% and unsaturated polyester, colorant and other additive of about 10%.Be through that negative-pressure vacuum, high-frequency vibration are shaping, sheet material that the production method of heating cure (temperature height is kind according to solidifying agent and determines) processes.Its quality hard (Mohs' hardness 5-7), compact structure (density 2.5g/cm
3), there is the characteristic such as wear-resisting, withstand voltage, high temperature resistant, anticorrosive, impermeable that other finishing material are incomparable.
But because there are some problems in manufacturing process, the resistance to soiling of quartzite unlike a lot of producer declare so excellent, such as test uses marking pen and ink to be just easy to infiltrate quartzite and be difficult to clean up, so quartzite in use easily occurs oozing the problem such as dirt, variable color.For solving this problem, market there is a variety of quartzite stain control agent product, but their major parts are just brought the stain control agent of ceramic tile, marble etc. simply and are used on quartzite, so ubiquity antifouling power good and lasting or can affect the problems such as quartzite surface gloss after using, annoying quartzite industry always.
Summary of the invention
It is good and lasting or can affect the technological deficiencies such as quartzite surface gloss, quartzite stain control agent providing a kind of excellent performance and its preparation method and application after using that the object of the invention is not to overcome the antifouling power of existing quartzite stain control agent.
The preparation method of quartzite stain control agent of the present invention is: add in 70 ~ 85% (quality) solvent by 6 ~ 16% (quality) methyl height containing hydrogen silicone oil, 2 ~ 8% (quality) hydroxyl-terminated injecting two methyl siloxane, 0 ~ 5% (quality) methyl-silicone oil under stirring, and then add 1 ~ 2% (quality) solubility promoter, finally add 0.5 ~ 5% (quality) silane coupling agent while stirring, continue stirring 2 minutes, quartzite stain control agent of the present invention can be obtained.
Described methyl height containing hydrogen silicone oil hydrogen content is preferably 1.5% ~ 1.6%.
The hydroxy radical content of described hydroxyl-terminated injecting two methyl siloxane is preferably 0.5% ~ 10%.
Described methyl-silicone oil is preferably 100 ~ 1000mm 25 DEG C of viscosity
2s
-1.
Described solubility promoter be preferably in ethanol, ethylene glycol, glycerol or ethylene glycol ethyl ether one or more.
Described solvent be preferably in D40 solvent oil, gasoline, kerosene, diesel oil, sherwood oil, normal hexane, normal heptane one or more.
Described silane coupling agent be preferably in γ-aminopropyl triethoxysilane (KH-550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH-560), γ-(methacryloxypropyl) propyl trimethoxy silicane (KH-570), N-β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane (DL602), N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS (KH792) one or more.
Quartzite stain control agent of the present invention is under the driving of solvent, can penetrate into fast in the minute aperture of quartzite inside, solvent volatilizees fast, and the active Si-H key of methyl height containing hydrogen silicone oil, under the crosslinked action of the active group of silane coupling agent, condensation reaction can be there is rapidly with the Si-OH of hydroxyl-terminated injecting two methyl siloxane; The reactive group of three is by optimum proportioning, and synergy is final crystallisation solidification also; Crystallisate closes blocking minute aperture; and form the transparent crystalline state protective layer with hydrophobic oleophobic characteristic on quartzite surface; because crystallisate and protective layer are firmly anchored in quartzite top layer by the grafting of silane coupling agent, so scrubbing resistance and chemical stability is good, lasting anti-fouling effect can be realized.
Compared with prior art, the present invention has following outstanding advantages:
1. the quartzite stain control agent prepared by the present invention can protect multiple spot, the oil-dirt such as oil pen, machine oil is coated on the quartzite surface through quartzite stain control agent of the present invention process, still can wipes with napkin, leave no trace after more than 60 minutes; Tea, ink, coffee etc. are coated on the quartzite surface through quartzite stain control agent of the present invention process, still can wash away with clear water after more than 30 minutes, leave no trace.
2. the quartzite stain control agent prepared by the present invention has persistent feature, repeats to scrub more than 10 times and still has protection effect to multiple spot.
3. the quartzite stain control agent prepared by the present invention is applied to quartzite surface, only need minute quantity just can reach preferably antifouling power at remained on surface, and the glossiness of quartzite itself can not be affected, on the contrary because of stain control agent rete crystallisation solidification, surface gloss can be made to increase 5-10 degree.
4. quartzite stain control agent of the present invention is not only applicable to quartzite, is also applicable to marble, sub-light brick, hilllock stone etc.
5. quartzite stain control agent of the present invention adopts environmentally friendly solvent, nontoxic non-corrosiveness.
The simple using method of stain control agent is:
1. get the quartzite sample block 120mm*80mm a slice not doing antifouling process, guarantee that surface dry is clean;
2. get 2mL quartzite stain control agent, use paper handkerchief to be stained with and be uniformly coated on sample block;
After 3.5-8 second, by the new paper handkerchief wiped clean of sample block, imperceptiblely to cover;
4. the sample block back side has identified time, sample batch and experimenter's name etc.;
5. confirm sample block anti-fouling effect after at least 12 hours.
The simple test method of the antifouling quartzite sample block processed is:
1. use black oil pen to scribble on the sample block doing antifouling process;
2., after half a minute, treat that person's handwriting parches;
3. use dry paper handkerchief gently wiping oil pen's vestige can be wiped;
4. repeat above 1,2,3 steps 4 time, namely can be considered antifouling test passes without any remaining trace, namely can be considered for more than 8 times outstanding.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the scope involved by embodiment.
Embodiment 1
Be 100mm by the methyl height containing hydrogen silicone oil of the hydrogen content 1.5% of 12% (quality), the hydroxyl-terminated injecting two methyl siloxane of the hydroxy radical content 8% of 3% (quality), 25 DEG C of viscosity of 1% (quality) under stirring
2s
-1methyl-silicone oil adds in the normal heptane of 82.5% (quality), and then add the ethylene glycol of 1% (quality), the last KH-550 adding 0.5% (quality) while stirring, continues stirring 2 minutes, can obtain quartzite stain control agent of the present invention.
Embodiment 2
Under stirring the hydroxyl-terminated injecting two methyl siloxane of the methyl height containing hydrogen silicone oil of the hydrogen content 1.6% of 8% (quality), the hydroxy radical content 7% of 6% (quality) is added in the D40 solvent oil of 83% (quality), and then add the ethylene glycol ethyl ether of 2% (quality), the last DL-602 adding 1% (quality) while stirring, continue stirring 2 minutes, quartzite stain control agent of the present invention can be obtained.
Embodiment 3
Be 1000mm by the methyl height containing hydrogen silicone oil of the hydrogen content 1.55% of 16% (quality), the hydroxyl-terminated injecting two methyl siloxane of the hydroxy radical content 6% of 8% (quality), 25 DEG C of viscosity of 1% (quality) under stirring
2s
-1methyl-silicone oil adds in the normal hexane of 71% (quality), and then add the ethanol of 2% (quality), the last Kh-560 adding 2% (quality) while stirring, continues stirring 2 minutes, can obtain quartzite stain control agent of the present invention.
Claims (10)
1. a preparation method for quartzite stain control agent, is characterized in that: raw material consists of by mass percentage
The mass percent of each component adds up to 100% above
Preparation method is for add in solvent by methyl height containing hydrogen silicone oil, hydroxyl-terminated injecting two methyl siloxane, methyl-silicone oil under stirring, and then add solubility promoter, finally add silane coupling agent while stirring, continue stirring 2 minutes, described quartzite stain control agent can be obtained.
2. preparation method according to claim 1, preferably, is characterized in that described methyl height containing hydrogen silicone oil hydrogen content is 1.5% ~ 1.6%.
3. preparation method according to claim 1, is characterized in that the hydroxy radical content of described hydroxyl-terminated injecting two methyl siloxane is 0.5% ~ 10%.
4. preparation method according to claim 1, is characterized in that described methyl-silicone oil is 100 ~ 1000mm 25 DEG C of viscosity
2s
-1.
5. preparation method according to claim 1, is characterized in that described solubility promoter is one or more in ethanol, ethylene glycol, glycerol or ethylene glycol ethyl ether.
6. preparation method according to claim 1, is characterized in that described solvent is one or more in D40 solvent oil, gasoline, kerosene, diesel oil, sherwood oil, normal hexane, normal heptane.
7. preparation method according to claim 1, is characterized in that described silane coupling agent is one or more in γ-aminopropyl triethoxysilane (KH-550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH-560), γ-(methacryloxypropyl) propyl trimethoxy silicane (KH-570), N-β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane (DL602), N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS (KH792).
8. a quartzite stain control agent, is characterized in that: prepared by the preparation method described in any one of claim 1-7.
9. the application of quartzite stain control agent according to claim 8 in stone material is antifouling.
10. application according to claim 8, described stone material is any one in quartzite, hilllock stone, marble, sub-light brick.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510009972.1A CN104497869B (en) | 2015-01-08 | 2015-01-08 | Quartz stone anti-fouling agent and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510009972.1A CN104497869B (en) | 2015-01-08 | 2015-01-08 | Quartz stone anti-fouling agent and preparation method and application thereof |
Publications (2)
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|---|---|
| CN104497869A true CN104497869A (en) | 2015-04-08 |
| CN104497869B CN104497869B (en) | 2017-01-25 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860831A (en) * | 2016-04-29 | 2016-08-17 | 广东纳德新材料有限公司 | Matte brick stain-proofing agent and preparation method thereof |
| CN105907298A (en) * | 2016-05-25 | 2016-08-31 | 郑州翱翔医药科技股份有限公司 | Grafted rubber plug spraying fluid and treatment method of grafted rubber plug spraying fluid on surface of rubber plug |
| CN106147598A (en) * | 2016-06-30 | 2016-11-23 | 禹州市远大塑料电器有限责任公司 | A kind of quartz anti-fouling agent and preparation technology thereof |
| CN107778939A (en) * | 2017-10-27 | 2018-03-09 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN107858097A (en) * | 2017-11-10 | 2018-03-30 | 湖南辰砾新材料有限公司 | A kind of super-hydrophobic fluorine silicon resin ceramic stain control agent and preparation method thereof |
| CN109957327A (en) * | 2017-12-26 | 2019-07-02 | 中国科学院长春应用化学研究所 | A kind of method that long-acting hydrophobic self-cleaning surface can be constructed in multiple material substrate |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN112143276A (en) * | 2020-08-28 | 2020-12-29 | 佛山市思特四通科技有限公司 | Antifouling auxiliary agent for automobile varnish and preparation method and application thereof |
| CN112391120A (en) * | 2021-01-21 | 2021-02-23 | 佛山市纳德新材料科技有限公司 | Pure-color tile wax-seepage-proofing antifouling agent and preparation method and application thereof |
| CN115286997A (en) * | 2022-08-31 | 2022-11-04 | 佛山市晖锐新材料有限公司 | Inorganic quartz stone antifouling and waterproofing agent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005054035A (en) * | 2003-08-01 | 2005-03-03 | Ishihara Chem Co Ltd | Stain-resistant water repellant composition |
| WO2009093348A1 (en) * | 2008-01-25 | 2009-07-30 | Nitto Kasei Co., Ltd. | Antifouling coating composition, antifouling coating formed therefrom, coated matter provided at its surface with the coating, method of antifouling treatment inclusive of formation of the coating, and antifouling coating formation kit |
| CN101503572A (en) * | 2008-11-05 | 2009-08-12 | 佛山市一鼎科技有限公司 | Emulsion type ceramic stain control agent |
| CN103073995A (en) * | 2012-12-28 | 2013-05-01 | 广东一鼎科技有限公司 | Emulsion type ceramic antifoulant |
| CN104231919A (en) * | 2014-10-15 | 2014-12-24 | 大连海事大学 | Nanometer reinforced, non-transition-layer, organosilicone and low-surface-energy type antifouling paint and preparation method thereof |
-
2015
- 2015-01-08 CN CN201510009972.1A patent/CN104497869B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005054035A (en) * | 2003-08-01 | 2005-03-03 | Ishihara Chem Co Ltd | Stain-resistant water repellant composition |
| WO2009093348A1 (en) * | 2008-01-25 | 2009-07-30 | Nitto Kasei Co., Ltd. | Antifouling coating composition, antifouling coating formed therefrom, coated matter provided at its surface with the coating, method of antifouling treatment inclusive of formation of the coating, and antifouling coating formation kit |
| CN101503572A (en) * | 2008-11-05 | 2009-08-12 | 佛山市一鼎科技有限公司 | Emulsion type ceramic stain control agent |
| CN103073995A (en) * | 2012-12-28 | 2013-05-01 | 广东一鼎科技有限公司 | Emulsion type ceramic antifoulant |
| CN104231919A (en) * | 2014-10-15 | 2014-12-24 | 大连海事大学 | Nanometer reinforced, non-transition-layer, organosilicone and low-surface-energy type antifouling paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 潘继民等: "《涂料实用手册》", 30 April 2014, 机械工业出版社 * |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860831A (en) * | 2016-04-29 | 2016-08-17 | 广东纳德新材料有限公司 | Matte brick stain-proofing agent and preparation method thereof |
| CN105860831B (en) * | 2016-04-29 | 2019-05-10 | 广东纳德新材料有限公司 | A kind of dumb light brick anti-fouling agent and preparation method thereof |
| CN105907298B (en) * | 2016-05-25 | 2017-12-22 | 郑州翱翔医药科技股份有限公司 | A kind of graft type plug spray coating liquor and its processing method to plug surface |
| CN105907298A (en) * | 2016-05-25 | 2016-08-31 | 郑州翱翔医药科技股份有限公司 | Grafted rubber plug spraying fluid and treatment method of grafted rubber plug spraying fluid on surface of rubber plug |
| CN106147598A (en) * | 2016-06-30 | 2016-11-23 | 禹州市远大塑料电器有限责任公司 | A kind of quartz anti-fouling agent and preparation technology thereof |
| CN107778939A (en) * | 2017-10-27 | 2018-03-09 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN107778939B (en) * | 2017-10-27 | 2019-09-24 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN107858097A (en) * | 2017-11-10 | 2018-03-30 | 湖南辰砾新材料有限公司 | A kind of super-hydrophobic fluorine silicon resin ceramic stain control agent and preparation method thereof |
| CN109957327A (en) * | 2017-12-26 | 2019-07-02 | 中国科学院长春应用化学研究所 | A kind of method that long-acting hydrophobic self-cleaning surface can be constructed in multiple material substrate |
| CN109957327B (en) * | 2017-12-26 | 2021-08-24 | 中国科学院长春应用化学研究所 | Method for constructing long-acting hydrophobic self-cleaning surface on various material substrates |
| CN112143276A (en) * | 2020-08-28 | 2020-12-29 | 佛山市思特四通科技有限公司 | Antifouling auxiliary agent for automobile varnish and preparation method and application thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN112391120A (en) * | 2021-01-21 | 2021-02-23 | 佛山市纳德新材料科技有限公司 | Pure-color tile wax-seepage-proofing antifouling agent and preparation method and application thereof |
| CN112391120B (en) * | 2021-01-21 | 2021-05-14 | 佛山市纳德新材料科技有限公司 | Pure-color tile wax-seepage-proofing antifouling agent and preparation method and application thereof |
| CN115286997A (en) * | 2022-08-31 | 2022-11-04 | 佛山市晖锐新材料有限公司 | Inorganic quartz stone antifouling and waterproofing agent |
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Address after: 528000 first floor, building 2, No.1 Liyuan 4th Road, Chancheng District, Foshan City, Guangdong Province Patentee after: Foshan Sitong Technology Co., Ltd Address before: 528000, a room 10, 504 Bo Bo Road, Chancheng District, Guangdong, Foshan Patentee before: FOSHAN SITECH CHEMICAL TECHNOLOGY Co.,Ltd. |