CN1188268C - Process for preparing composite fibre-metal (or non-metal) liner material - Google Patents
Process for preparing composite fibre-metal (or non-metal) liner material Download PDFInfo
- Publication number
- CN1188268C CN1188268C CNB011388293A CN01138829A CN1188268C CN 1188268 C CN1188268 C CN 1188268C CN B011388293 A CNB011388293 A CN B011388293A CN 01138829 A CN01138829 A CN 01138829A CN 1188268 C CN1188268 C CN 1188268C
- Authority
- CN
- China
- Prior art keywords
- metal
- fiber
- inner liner
- metallic inner
- manufacture method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Landscapes
- Moulding By Coating Moulds (AREA)
Abstract
The present invention relates to a method for manufacturing a metal or non-metal inner lining composite material which has the advantages of low material cost, low resin content, high labor efficiency, high elastic modulus, high bending modulus and large tensile strength and bending strength. A metal or non-metal inner lining is taken and is placed on a correction guiding frame; fiber or fabric is immersed in a resin slurry tank and is formed, and the fiber or the fabric is coated on the inner lining to enter a mold; traction is carried out, and the traction speed is 100 to 1500 mm/minute; then, shaping and heating are carried out; the mold is divided into from 2 to 4 sections, the temperature of each section from the back section to the front section is controlled to be from 120 to 190 DEG C, from 100 to 120 DEG C, from 60 to 100 DEG C and from 50 to 90 DEG C, and the temperature of the later section is higher than that of the former section; after the mold is drawn out, cutting is carried out, and a finished product is manufactured.
Description
Technical field
The present invention relates to the manufacture method of a kind of fiber-metal or non-metallic inner liner composite.
Background technology
Traditional fiber reinforcement thermosetting plastics, bending modulus is low, production cost is high.The fiber reinforcement thermosetting plastics of liner has appearred having in recent years, its intensity, elastic modelling quantity, hot strength, bending strength all are eager to excel many than traditional fiber gain of heat solidity plastics, but because its manufacture method adopts hand to stick with paste or the winding method, make that the slurry consumption is big, manufacturing cost height and efficiency are low.
Summary of the invention
The present invention will solve the problem that prior art intensity is low, elastic modelling quantity is low, bending modulus is low, resin content is high, cost is high, efficiency is low, provide that a kind of the cost of material is low, resin content is low, efficiency height and elastic modelling quantity height, bending modulus height, the manufacture method of fiber-metal that hot strength and bending strength are big or non-metallic inner liner composite.
The present invention is achieved in that and gets metal or non-metallic inner liner is placed on the correcting frame, fiber or fabric are flooded integer in resin slurry oar groove, cladding is on liner, enter mould, draw, hauling speed is 100～1500mm/ branch, integer, heating again, mould is divided into two～four sections, and every section temperature control extremely before is respectively 120～190 ℃, 100～120 ℃, 60～100 ℃, 50～90 ℃ by the back, and the back segment temperature is higher than front-end temperature, cut off again, make finished product.
According to the manufacture method of above-mentioned fiber-metal or non-metallic inner liner composite, scribble adhesive at metal or non-metallic inner liner surface, to strengthen the adhesive force between liner and the fiber.
According to the manufacture method of above-mentioned fiber-metal or non-metallic inner liner composite, said resin slurry is the thermosetting resin slurry.
According to the manufacture method of above-mentioned fiber-metal or non-metallic inner liner composite, said thermosetting resin is unsaturated polyester resin or epoxy resin or phenolic resins or vinylite.
According to the manufacture method of above-mentioned fiber-metal or non-metallic inner liner composite, said thermosetting resin slurry is made up of 100 parts of unsaturated-resins, 1～100 part of filler, 0.1～5 part of promoter, 0.1～5 part in curing agent, releasing agent 1～5 part (weight ratio).
Owing to adopt pultrusion manufactured fiber-metal or non-metallic inner liner composite, the fiber content of the formed product of pultrude process is 55～75%, so resin content reduces greatly in the goods behind the pultrusion, make production cost low, and because the pultrusion method is to produce continuously, make efficiency improve greatly, in addition, fiber-the metal or the non-metallic inner liner composite that adopt the pultrusion method to make, it is good to have density, the elastic modelling quantity height, the bending modulus height, hot strength, the characteristics that bending strength is big, this method is widely used in hollow material, tubing, profile shapes, the manufacturing of sheet material.
Description of drawings
Fig. 1 is a process chart of the present invention.
The specific embodiment
Embodiment 1:
As shown in the figure, getting metal or non-metallic inner liner is placed on the correcting frame, glass fibre (other fiber) or fabric (cloth or felt) are flooded in resin slurry oar groove, said resin slurry is thermosetting resin-unsaturated polyester resin (or epoxy resin or phenolic resins), specifically consists of 100 parts of unsaturated-resins, 100 parts of fillers, 1 part of promoter, 5 parts in curing agent, 1 part of releasing agent (weight ratio).Integer clads on liner again, enters mould, draw and draw, hauling speed is 100～150mm/ branch, integer, heating again, and mould 4 is divided into two sections, (be lower than two sections, the section bar that makes is difficult to moulding), the front and rear sections temperature is controlled to be 100～110 ℃, 120～130 ℃, after involving, cut off, make finished product.
Embodiment 2:
As shown in the figure, getting metal or non-metallic inner liner is placed on the correcting frame, fiber or fabric (cloth or felt) are flooded in resin slurry oar groove, said resin slurry is thermosetting resin-unsaturated polyester resin (or epoxy resin or phenolic resins), specifically consists of 100 parts of unsaturated-resins, 1 part of filler, promoter～5 part, 0.1 part in curing agent, 5 parts of releasing agents (weight ratio).Integer clads on liner again, enters mould, draws, and hauling speed is 1000～1500mm/ branch, integer, heating again, and mould 4 is divided into two sections, and the front and rear sections temperature is controlled to be 110～120 ℃, 170～190 ℃, after involving, cuts off, and makes finished product.
Embodiment 3:
As shown in the figure, the metal or the non-metallic inner liner of getting the shape that adheres to specification are placed on the correcting frame, fiber or fabric (cloth or felt) are flooded in resin slurry oar groove, said resin slurry is thermosetting resin-unsaturated polyester resin (or epoxy resin or phenolic resins), specifically consists of 100 parts of unsaturated-resins, 50 parts of fillers, 2 parts of promoter, 3 parts in curing agent, 3 parts of releasing agents (weight ratio).Integer clads on liner again, enters mould, carries out index, hauling speed is 800～900mm/ branch, integer, heating again, and mould 4 is divided into two sections, after every section temperature is controlled to be 105～115 ℃, 150～170 ℃, involves from front to back, cut off, make finished product.
Embodiment 4:
As shown in the figure, get metal or non-metallic inner liner and be placed on the correcting frame, fiber or fabric (cloth or felt) are flooded back (the resin slurry component is with embodiment 1) in resin slurry oar groove, integer, cladding enters mould on liner, draw, hauling speed is 100～150mm/ branch, integer, heating again, and mould 4 is divided into three sections, every section temperature is controlled to be 60～80,100～110 ℃, 120～140 ℃ from front to back, after involving, cut off, make finished product.
Embodiment 5:
As shown in the figure, get metal or non-metallic inner liner and be placed on the correcting frame, fiber or fabric (cloth or felt) are flooded back (the resin slurry component is with embodiment 2) in resin slurry oar groove, integer, cladding enters mould on liner, draw, hauling speed is 1000～1500mm/ branch, integer, heating again, and mould is divided into three sections, every section temperature is controlled to be 80～100 ℃, 110～120 ℃, 170～190 ℃ from front to back, after involving, cut off, make finished product.
Embodiment 6:
As shown in the figure, get the metal or the non-metallic inner liner that adhere to specification and be placed on the correcting frame, fiber or fabric (cloth or felt) are flooded back (the resin slurry component is with embodiment 3) in resin slurry oar groove, integer, cladding enters mould on liner, draw, hauling speed is 800～900mm/ branch, integer, heating again, and mould is divided into three sections, every section temperature is controlled to be 75～85 ℃, 105～115 ℃, 150～170 ℃, after involving, cut off, make finished product.
Embodiment 7:
As shown in the figure, get metal or non-metallic inner liner and be placed on the correcting frame, fiber or fabric (cloth or felt) are flooded back (the resin slurry component is with embodiment 2) in resin slurry oar groove, integer, cladding enters mould on liner, draw, hauling speed is 100～150mm/ branch, integer, heating again, and mould 4 is divided into four sections, every section temperature is controlled to be 50～60 ℃, 60～80 ℃, 100～110 ℃, 120～140 ℃ from front to back, after involving, cut off, make finished product.
Embodiment 8:
As shown in the figure, get metal or non-metallic inner liner and be placed on the correcting frame, fiber or fabric (cloth or felt) are flooded back (the resin slurry component is with embodiment 1) in resin slurry oar groove, integer, cladding enters mould on liner, draw, hauling speed is 1000～1500mm/ branch, integer, heating again, mould are divided into four sections, from front to back every section temperature be controlled to be 80～90 ℃, 90～100 ℃, 110～120 ℃, 170～190 ℃ involve after, cut off, make finished product.
Embodiment 9:
As shown in the figure, getting the metal or the non-metallic inner liner that adhere to specification is placed on the correcting frame, fiber or fabric (cloth or felt) are flooded back (the resin slurry component is with embodiment 3) in resin slurry oar groove, integer, cladding is on liner, enter mould, carry out index, hauling speed is 800～900mm/ branch, integer, heating again, and mould 4 is divided into two sections, every section temperature is controlled to be 65～75 ℃, 75～85 ℃, 105～115 ℃, 150～160 ℃ from front to back, after involving, cut off, make finished product.
Mould in the foregoing description 7～9 also can be divided into five sections, and every section temperature is controlled to be 50～90 ℃, 60～100 ℃, 100～120 ℃, 120～190 ℃, 120～190 ℃ from front to back.
Embodiment 10:
Get metal or non-metallic inner liner, the surface is coating adhesive evenly, is placed on the correcting frame, and other operation and technological parameter are with embodiment 1～embodiment 9.
Claims (5)
1, the manufacture method of a kind of fiber-metal or non-metallic inner liner composite, it is characterized in that getting metal or non-metallic inner liner is placed on the correcting frame, fiber or fabric are flooded in resin slurry oar groove, integer, cladding is on liner, enter mould, draw, hauling speed is 100～1500mm/ branch, again integer, heating, mould is divided into two sections at least, be controlled to be 120～190 ℃, 100～120 ℃, 60～100 ℃, 50～90 ℃ by the back to preceding every section temperature, and the back segment temperature is higher than front-end temperature, after involving, cut off, make finished product.
2, the manufacture method of fiber-metal according to claim 1 or non-metallic inner liner composite is characterized in that scribbling adhesive at metal or non-metallic inner liner surface, to strengthen the adhesive force between liner and the fiber.
3, the manufacture method of fiber-metal according to claim 1 or non-metallic inner liner composite is characterized in that said resin slurry is the thermosetting resin slurry.
4, the manufacture method of fiber-metal according to claim 3 or non-metallic inner liner composite is characterized in that said thermosetting resin is unsaturated polyester resin or epoxy resin or phenolic resins or vinylite.
5, the manufacture method of fiber-metal according to claim 3 or non-metallic inner liner composite is characterized in that said thermosetting resin slurry is made up of 100 parts of unsaturated-resins, 1～100 part of filler, 0.1～5 part of promoter, 0.1～5 part in curing agent, releasing agent 1～5 part (weight ratio).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011388293A CN1188268C (en) | 2001-12-12 | 2001-12-12 | Process for preparing composite fibre-metal (or non-metal) liner material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011388293A CN1188268C (en) | 2001-12-12 | 2001-12-12 | Process for preparing composite fibre-metal (or non-metal) liner material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1363456A CN1363456A (en) | 2002-08-14 |
| CN1188268C true CN1188268C (en) | 2005-02-09 |
Family
ID=4674790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011388293A Expired - Fee Related CN1188268C (en) | 2001-12-12 | 2001-12-12 | Process for preparing composite fibre-metal (or non-metal) liner material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1188268C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106938509B (en) * | 2017-05-18 | 2023-04-18 | 大连日瑞铸模有限公司 | Composite resin metal mold and manufacturing method thereof |
| CN108044963B (en) * | 2017-12-05 | 2020-02-07 | 山东柏远复合材料科技有限公司 | Production process of prestressed plastic steel PE composite pipe |
| CN111434483A (en) * | 2019-01-14 | 2020-07-21 | 中国科学院宁波材料技术与工程研究所 | Metal lining braided composite material for vehicle and preparation method and application thereof |
-
2001
- 2001-12-12 CN CNB011388293A patent/CN1188268C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1363456A (en) | 2002-08-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1919587A (en) | Method for increasing transverse strength of fiber reinforced resin pultrusion section bar and product thereof | |
| CN102700153B (en) | Continuous pultrusion manufacturing method and production device for fibrous composite drive shaft | |
| EP2437926B1 (en) | Fiber reinforced plastic bolt and method for producing the same | |
| CN205000906U (en) | Fibre reinforced composite continuous sucker rod's preparation facilities | |
| CN106243631A (en) | The basalt fibre of a kind of pultrusion strengthens composite of thermosetting resin and preparation method thereof | |
| CN104060944A (en) | Multilayer compound eccentric-wear-preventing continuous sucker rod and manufacturing device and method thereof | |
| CN103225369B (en) | A kind of surface fibre composite reinforcement with helicitic texture and preparation method thereof | |
| CN1916327A (en) | Fiber wall with strong rib material of plastic | |
| CN107672194A (en) | A kind of FRP stirrups with ribbing and preparation method | |
| CN1324257C (en) | Bamboo-plastic composite pipe shaping method | |
| CN108892396A (en) | It is a kind of for producing the size of great surface quality SMC glass fibre | |
| CN1580101A (en) | Thermoplastic resin base carbon fiber composite material, and its manufacturing method and apparatus | |
| CN110126304A (en) | A method of reducing carbon fibre composite machining cost | |
| CN105140639B (en) | Fiberglass radome and preparation method thereof | |
| CN1188268C (en) | Process for preparing composite fibre-metal (or non-metal) liner material | |
| CN105082571A (en) | Blank forming method for manufacturing composite material bolt | |
| CN203008798U (en) | Fiber reinforced composite material anti-eccentric continuous sucker rod | |
| CN106832722A (en) | A kind of preparation method of thermoplastic composite | |
| CN202965218U (en) | Preparation device for fiber reinforced composite material anti-eccentric wearing continuous sucker rod | |
| CN107964228A (en) | A kind of preparation process of transparent SMC moulding materials | |
| CN103991227A (en) | Production method for constant-section composite-material section material | |
| CN102733214B (en) | Integrated high-flexibility reinforced core for cables and preparation method thereof | |
| CN214528796U (en) | Basha wood-like light high-strength composite section | |
| CN1631656A (en) | Fibre reinforced pultrusion rod and its preparation method and application | |
| CN108102302A (en) | A kind of structural strengthening basalt fibre composite sheet and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |