CN104060944A - Multilayer compound eccentric-wear-preventing continuous sucker rod and manufacturing device and method thereof - Google Patents

Multilayer compound eccentric-wear-preventing continuous sucker rod and manufacturing device and method thereof Download PDF

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Publication number
CN104060944A
CN104060944A CN201410264787.2A CN201410264787A CN104060944A CN 104060944 A CN104060944 A CN 104060944A CN 201410264787 A CN201410264787 A CN 201410264787A CN 104060944 A CN104060944 A CN 104060944A
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Prior art keywords
resin
fiber
rod
thermosetting
layer
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CN201410264787.2A
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CN104060944B (en
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王瑞星
崔昌瑞
吴永太
李强
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Shengli New Big New Materials Co ltd
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Shengli Oilfield Xinda Pipes Technology Development Co Ltd
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Application filed by Shengli Oilfield Xinda Pipes Technology Development Co Ltd filed Critical Shengli Oilfield Xinda Pipes Technology Development Co Ltd
Priority to CN201710010065.8A priority Critical patent/CN106891549B/en
Priority to CN201410264787.2A priority patent/CN104060944B/en
Priority to CN201710010288.4A priority patent/CN106671453A/en
Publication of CN104060944A publication Critical patent/CN104060944A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/521Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/523Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement in the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525Component parts, details or accessories; Auxiliary operations
    • B29C70/528Heating or cooling
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • E21B17/20Flexible or articulated drilling pipes, e.g. flexible or articulated rods, pipes or cables
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C2035/0283Thermal pretreatment of the plastics material

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The invention relates to a multilayer compound eccentric-wear-preventing continuous sucker rod and a manufacturing device and a manufacturing method thereof. The sucker rod is characterized in that one section or several sections of the external surface of a fiber reinforced resin matrix composite rod body are respectively covered with a thermosetting wear layer; each thermosetting wear layer is made from one of polyurethane, a fluorocarbon coating, modified epoxide resin, vinylester resin, unsaturated polyester and phenolic resin; by adopting a manufacturing technology of multilayer composite winding and pultrusion or weaving and pultrusion, an internal layer of longitudinal fibers, an intertwining layer or a weaving layer and an external layer of longitudinal fibers are formed from interior to exterior in sequence; the manufactured rod body has a continuous length of 0-5000m. The sucker rod has the beneficial effects that the radial strength and the axial compressive strength are enhanced; the corrosion resistance and the eccentric wear resistance of the thermosetting wear layers are improved by 30%; the maximum temperature tolerance of the thermosetting wear layers is up to 190 DEG C; meanwhile, the bonding between an sucker rod body and each thermosetting wear layer is greater in length and quite high in strength, so that the slippage and the layering of an eccentric-wear-preventing layer from the surface of the sucker rod in the normal operation of an oil well are avoided.

Description

The anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE and preparation facilities and method
Technical field
The present invention relates to a kind of anti-eccentric wear coiled rod and preparation facilities thereof, particularly the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE and preparation facilities and method.
Background technology
Because the Oil Reservoir Types of developing becomes increasingly complex, the continuous increase of well depth simultaneously and the continuous deterioration of well ore deposit environment, corrosion and eccentric wear problem become oil extraction in oil field technique problem demanding prompt solution.Because possess the corrosion resistant feature of high-strength light, so composite material sucker rod has started progressively to replace traditional metal sucker rod.The composite material sucker rod adopting at present mainly comprises glass fiber reinforced plastic oil pumping rod and the large class of carbon fibre reinforced composite coiled rod two.Glass fiber reinforced plastic oil pumping rod adopts the pultrude process one-shot forming preparation of glass-fiber reinforced thermo-setting resin, extensive use, but along with the reliability requirement of modern times oil recovery improves constantly, glass fiber reinforced plastic oil pumping rod can not meet the demands, mainly there is following problem, 1, the resistance to eccentric wear of sucker rod is bad; 2, fatigue strength is inadequate; 3, the equal fixed length of glass fiber reinforced plastic oil pumping rod, respectively there is a metal joint at two ends, between root and root, adopt the metal box cupling of metal pumping rod application to be connected, and due to complex structure, difficulty of processing is large, expensive.Two metal joints for each root glass fiber reinforced plastic oil pumping rod, the cost of these two metal joints is far above the cost of a glass fiber reinforced plastic body of rod; Compare with traditional metal sucker rod in addition, except shank portion has been changed material, other parts of whole rod string there is no change, traditional metal rod string joint is many, disconnected de-probability is high, and piston effect is obvious, and the serious problem of box cupling and oil pipe eccentric wear is not resolved.Chinese patent CN1417449 discloses a kind of preparation method of Anti-wear oil pumping rod, the method is the anti-abrading block of the material such as secondary injection molding nylon in type sucker rod body, reduce the clad material using, reduce continuously coated cost and process complexity, but the anti-abrading block size of its injection moulding is less,, often there is anti-abrading block and the body of rod and depart from the relatively independent body of rod that is distributed in, occurs " sugarcoated haws " phenomenon.In addition, its body of rod fixed length, can not solve the defects such as traditional metal rod connector is many, and break-off accident rate is large, and piston effect is large; And to install anti-bias abrading block on the less body of rod of size additional be to solve eccentric wear problem between metal joint and box cupling and oil pipe, and this is only the emphasis that sucker rod, pipe eccentric wear need to solve.CN101396874 discloses a kind of preparation method and device of anti-eccentric wear composite material sucker rod, its preparation method is on the in type composite material sucker rod body of rod, the anti-eccentric wear layer of the abrasion resistant fibrous continuous-winding forming spiral bar shapes such as the aramid fiber, High molecular weight polyethylene of resin adhesive liquid was flooded in utilization, to reach anti-eccentric wear effect.The anti-eccentric wear layer of its spiral bar shape, owing to being with abrasion resistant fibrous enhancing thermosetting resin, although therefore fiber has antiwear characteristic, forms after composite material with thermosetting resin, and its wear resistance decrease is a lot, and the life-span can not extend how many.Except it possesses the anti-eccentric wear layer of spiral bar shape, its shortcoming is the same with common glass fiber reinforced plastic oil pumping rod.Chinese patent CN1461870 discloses a kind of carbon fibre reinforced composite coiled rod and preparation method, employing carbon fiber is reinforcing material, and by transversely arranged aramid fiber or superhigh molecular weight polyethylene fibers bundle and longitudinally glass fiber to form integral coating compound, mainly solve and strengthen the horizontal interlaminar shear strength of sucker rod, thereby avoid sucker rod that the problem of longitudinal splitting occurs in oil well, the while has also been improved resistance to eccentric wear and the intensity of the body of rod.But this sucker rod adopt pultrusion, coated Integratively processing method (comprise put silk-resin pickup glue-clad coated-preformed-solidify-coil operation), clad is that fabric strengthens thermosetting resin, not only strengthened material cost, and the resistance to eccentric wear of fabric clad is not ideal enough.In addition, because this carbon fibre reinforced composite coiled rod cross sectional shape is rectangle or ellipse, and its thickness only has 3~5mm, when application specific equipment removes well operations, the material of retained part almost cannot be selected, and can only adopt two-piece type clamping, left and right directions cannot be spacing, is easy to occur the phenomenon that the body of rod deflects away from retained part.Therefore its special use go into the well implement retained part structure and developing material difficulty larger, become the technical bottleneck in the application of carbon fibre reinforced composite coiled rod, limited this product large-scale promotion application.Patent of invention CN200910272324.X discloses a kind of coiled rod, use the method for unidirectional fortifying fibre pultrusion, coating thermoplastic wearing layer, its structure exists radial compressive property poor, thermoplastic wear resistant layer hardness is not high, the defects such as anti-wear performance is poor, cannot meet long-term use and job requirements.
Chinese patent literature number is 103075112A, patent name is the anti-eccentric wear coiled rod of < < fibre reinforced composites and preparation facilities and method > >, a patent of invention of declaring on November 30th, 2012 for our company, its technical scheme is that a section or several sections at the external surface of the fiber reinforced resin based composite material body of rod is covered with one deck thermoplastic wearing layer, the fiber that the body of rod adopts is glass fiber, the a kind of of carbon fiber or basalt fibre makes, resin matrix is epoxy resin, polyurethane resin or vinyl ester resin a kind of.By be provided with a plastic extruder and cooling unit between draw-gear and coiler device, utilize plastic extruder at one section or surface attachment one deck thermoplastic wearing layer of several sections of the moulding oil pumping body of rod, then through apparatus for supercooling cooling processing, form the anti-eccentric wear coiled rod of fibre reinforced composites.Beneficial effect is: given the corrosion-resistant and resistance to eccentric wear performance of sucker rod excellence, reduced greatly again joint quantity, reduced and resolve de-probability and piston effect, in addition, its production efficiency is high, easy and simple to handle.The problem of its existence is, due to the thermoplastic wearing layer adopting, its bending property and radially, axial compression resistance performance is slightly more inferior; In addition, temperature tolerance, wear resistence also than the poor performance of thermosetting wearing layer some.
Summary of the invention
Object of the present invention is exactly in view of the foregoing defects the prior art has, the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE and preparation facilities and method are provided, that at the external surface of the fiber reinforced resin based composite material body of rod one section or several sections is covered with one deck thermosetting wearing layer, use winding+pultrude process, or braiding+pultrude process, not only given the corrosion-resistant and resistance to eccentric wear performance of sucker rod excellence, and have fabulous bending property and radially, axial compression resistance performance, and wear resistence improves 30%, and temperature tolerance is up to 190 ℃.
The anti-eccentric wear coiled rod of MULTILAYER COMPOSITE, is covered with one deck thermosetting wearing layer (D) a section or several sections of the external surface of the fiber reinforced resin based composite material body of rod, and described thermosetting wearing layer (D) is polyurethane, fluororine-carbon coating, modified epoxy, vinyl ester resins, unsaturated polyester (UP), a kind of making in phenolic resins, the thickness of thermosetting wearing layer (D) is 0.5~10mm, the fiber that the described fiber reinforced resin based composite material body of rod adopts is glass fiber, one or more of carbon fiber or basalt fibre are made, the manufacturing process that adopts MULTILAYER COMPOSITE winding and pultrusion or braiding and pultrusion, is internal layer longitudinal fiber (A) from inside to outside successively, winding layer or braid (B), outer longitudinal fiber (C), all winding layers, braid and longitudinal fiber are carbon fiber, glass fiber, basalt fibre, a kind of in aramid fiber, the resin matrix of employing is epoxy resin, polyurethane resin or vinyl ester resin a kind of, the continuous length of the body of rod of making is 0~5000m.
The preparation facilities of the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE that the present invention mentions, comprise and put guide frame (1), pre-heating system (2), winding machine or braider (3), injector (5), injection molding (4), equipment for cooling die (6), pultrusion die (7), mold heating device (8), control section (9), rear solidifying heating furnice (10), draw-gear (11), coiler device (14) forms injection pultrusion equipment, in the bottom of injection molding (4), one or two adhesive pouring nozzles (4.1) are housed, one or two vacuum nozzles (4.2) are equipped with at top, the external vacuum tube of vacuum nozzle (4.2), vacuum tube is connected with vacuum tank, the adhesive pouring nozzle (4.1) of described injector (3) by bottom is to the inner resin by injection Matrix adhesive (4.3) of injection molding, the winding layer or the braid (B) that between internal layer longitudinal fiber (A) and outer longitudinal fiber (C), use braider or winding machine (2) braiding one deck to strengthen, between the draw-gear (11) of injection pultrusion equipment and coiler device (14), be provided with a thermosetting resin spraying equipment (12) and solidification equipment (13), utilize thermosetting resin spraying equipment (12) at one section or surface attachment one deck thermosetting wearing layer of several sections of the moulding oil pumping body of rod, then passing through solidification equipment (13) solidifies, form the anti-eccentric wear coiled rod of fibre reinforced composites, described thermosetting resin spraying equipment (12) comprises resin pump (12a), static blender (12b), filter (12c), resin cavity (12d), strainer (12e), nozzle (12f), heater (12g), the output of resin pump (12a) is connected to static blender (12b), the lower end of static blender (12b) is communicated with resin cavity (12d) by filter (12c), the outside of static blender (12b) is provided with heater (12g), the lower end of filter (12c) is provided with nozzle (12f), the both sides of described resin cavity (12d) are provided with strainer (12e).
Above-mentioned nozzle (12f) is comprised of resin flow channel (12h) and injection orifice plate (12i), and described resin flow channel (12h) adopts 360 degree helical structures, sprays orifice plate (12i) and adopts tapering star jet orifice structure.
Above-mentioned winding machine comprises control system (3a), servomotor (3b), reductor (3c), twin shaft exchange system (3d), be wound around fiber holding tray (3e), tensioning apparatus (3f), fiber is placed axle (3g), servomotor (3b) connects twin shaft exchange system (3d) by reductor (3c), the two ends of twin shaft exchange system (3d) connect respectively winding fiber holding tray (3e), and the outside that is wound around fiber holding tray (3e) connects fiber by tensioning apparatus (3f) and places axle (3g).
Above-mentioned braider comprises control system (3a), servomotor (3b), reductor (3c), tensioning apparatus (3f), fiber placement axle (3g), is wound around split axle drive system (3h), is wound around axle exchange system (3i), servomotor (3b) is connected and is wound around split axle drive system (3h) by reductor (3c), be wound around split axle drive system (3h) and be connected with winding axle exchange system (3i), be wound around axle exchange system (3i) outside and connect fiber placement axle (3g) by tensioning apparatus (3f).
The preparation method of the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE that the present invention mentions, comprises the following steps and makes:
(a) from putting guide frame (1), draw multiple fibre, process injection molding (5) under the traction of draw-gear (11), in injection molding (5), be full of the resin matrix glue (4.3) that injector (4) is injected, resin matrix is epoxy resin, vinyl ester resin or polyurethane resin;
(b) winding layer or the braid (B) that between internal layer longitudinal fiber (A) and outer longitudinal fiber (C), use braider or winding machine (2) braiding one deck to strengthen, wherein, by winding machine (3), be wound around one or more layers 0.1~2mm thickness, winding angle is the winding layer of 15~85 °; Or use braider (3) between internal layer longitudinal fiber (A) and outer longitudinal fiber (C), being wound around one or more layers thickness is 0.1~2mm, and intersecting angle is the braid of 15~85 °;
(b) in injection molding (4), the fiber bundle of glue dipping passes through pultrusion die (7) curing molding again, the entrance of pultrusion die (7) is provided with equipment for cooling die (6), for reducing die entrance temperature, avoid mold temperature to conduct to injection molding (5); Pultrusion die (7) around, equipment for cooling die (6) after, be distributed with mold heating device (8), 2~4 sections of heating, solidification temperature is between 95~180 ℃, heating mode in gradient, pultrusion speed is between 0.08~1.5 m/min, and pultrusion goes out the composite material body of rod; The composite material body of rod that pultrusion goes out enters rear solidifying heating furnice (9) and carries out thermal stress processing and rear solidifying, and rear curing end, by draw-gear (11);
(c) between the draw-gear (11) and coiler device (14) of injection extruding equipment, a cover thermosetting resin spraying equipment device (12) and solidification equipment (13) are set, utilize one section or the surface attachment one deck thermosetting wearing layer of several section of plastic extrusion apparatus (12) on the moulding oil pumping body of rod, then pass through solidification equipment (13); After fully solidifying, utilize coiler device (11) to be wound on the disk that diameter is 1.5m~3.5m.
The invention has the beneficial effects as follows: sucker rod of the present invention, on continous sucker rod made of fiber reinforced composition pultrude process basis, winding layer or braid have been increased, increase radial strength and axial compression strength, improved bending property, reduced bending diameter; Continuous one section or the interrupted several sections of thermosetting wearing layers of surface spraying, given the corrosion-resistant and resistance to eccentric wear performance of sucker rod excellence, compare raising 30%, and temperature tolerance is better with existing thermoplastic wearing layer, and high energy reaches 190 ℃;
In addition, adopt special-purpose spraying equipment, be different from common spraying equipment, the resin that this injection spraying equipment sprays, through measuring pump accurate measurement, guarantees the uniformity of coating thickness; The application of static blender can guarantee the abundant mixing of resin, and the uniformity of product properties is played a key effect; Thermostat guarantees that the proterties of spraying resin is consistent; Nozzle, through particular design, can guarantee the body of rod consistency of thickness of coating around; The design of two ends filter can guarantee to filter out unnecessary resin, can guarantee again the thickness of spray-on coating;
Also has preparation method provided by the invention, adopt winding pultrusion, braiding pultrusion, injection pultrusion and thermosetting resin spraying to solidify assembling process, can significantly improve the continous-stable that the continous sucker rod made of fiber reinforced composition body of rod is produced, coordinate special-purpose spray equipment, guaranteed that the position distribution of thermosetting resin wearing layer on sucker rod body of rod surface meets design requirement, the combination of wearing layer and the body of rod completes online, production efficiency is high, bond strength is large, has avoided the generation of layering, obscission.
Accompanying drawing explanation
Accompanying drawing 1 is the cross section structure figure of coiled rod of the present invention;
Accompanying drawing 2 is schematic flow sheets of preparation facilities of the present invention;
Accompanying drawing 3 is structural representations of injection molding in injection pultrude process of the present invention;
Accompanying drawing 4 is structural representations of winding machine in winding pultrude process of the present invention;
Accompanying drawing 5 is structural representations of braider in braiding pultrude process of the present invention;
Accompanying drawing 6 is structural representations of spraying equipment in thermoplastic resin spraying coating process of the present invention;
Accompanying drawing 7 is sectional views of the nozzle segment of spraying equipment of the present invention;
Accompanying drawing 8 is M-M structure charts of the nozzle segment of spraying equipment of the present invention;
In upper figure: put guide frame 1, pretreatment heating furnace 2, winding machine or braider 3, injector, 5, injection molding 4, equipment for cooling die 6, pultrusion die 7, mold heating device 8, control section 9, rear solidifying heating furnice 10, draw-gear 11, thermosetting resin spraying equipment 12, cooling unit 13, coiler device 14;
Internal layer longitudinal fiber A, winding layer or braid B, outer longitudinal fiber C, thermosetting wearing layer D;
Control system 3a, servomotor 3b, reductor 3c, twin shaft exchange system 3d, is wound around fiber holding tray 3e, tensioning apparatus 3f, fiber is placed axle 3g, is wound around split axle drive system 3h, is wound around axle exchange system 3i; Adhesive pouring nozzle 4.1, vacuum nozzle 4.2, resin matrix glue 4.3; Resin pump 12a, static blender 12b, filter 12c, resin cavity 12d, strainer 12e, nozzle 12f, heater 12g, resin flow channel 12h, injection orifice plate 12i, sucker rod body of rod 12j.
The specific embodiment
With reference to accompanying drawing 1, the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE that the present invention mentions, is covered with one deck thermosetting wearing layer D a section or several sections of the external surface of the fiber reinforced resin based composite material body of rod, and described thermosetting wearing layer D is polyurethane, fluororine-carbon coating, modified epoxy, vinyl ester resins, unsaturated polyester (UP), a kind of making in phenolic resins, the thickness of thermosetting wearing layer D is 0.5~10mm, the fiber that the described fiber reinforced resin based composite material body of rod adopts is glass fiber, one or more of carbon fiber or basalt fibre are made, and adopt the manufacturing process of MULTILAYER COMPOSITE winding and pultrusion or braiding and pultrusion, are internal layer longitudinal fiber A from inside to outside successively, winding layer or braid B, outer longitudinal fiber C, all winding layers, braid and longitudinal fiber are carbon fiber, glass fiber, basalt fibre, a kind of in aramid fiber, the resin matrix of employing is epoxy resin, polyurethane resin or vinyl ester resin a kind of, the continuous length of the body of rod of making is 0~5000m.
With reference to accompanying drawing 2, the preparation facilities of the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE that the present invention mentions, comprise guide frame 1, pre-heating system 2, winding machine or braider 3, injector 5, injection molding 4, equipment for cooling die 6, pultrusion die 7, mold heating device 8, control section 9, rear solidifying heating furnice 10, draw-gear 11, the coiler device 14 composition injection pultrusion equipment put, one or two adhesive pouring nozzles 4.1 are housed in the bottom of injection molding 4, one or two vacuum nozzles 4.2 are equipped with at top, the external vacuum tube of vacuum nozzle 4.2, vacuum tube is connected with vacuum tank; Described injector 3 is passed through the adhesive pouring nozzle 4.1 of bottom to the inner resin by injection Matrix adhesive 4.3 of injection molding; The winding layer or the braid B that between internal layer longitudinal fiber A and outer longitudinal fiber C, use braider or winding machine 2 braiding one decks to strengthen, between the draw-gear 11 of injection pultrusion equipment and coiler device 14, be provided with a thermosetting resin spraying equipment 12 and solidification equipment 13, utilize thermosetting resin spraying equipment 12 at one section or surface attachment one deck thermosetting wearing layer of several sections of the moulding oil pumping body of rod, then through solidification equipment 13, solidify, form the anti-eccentric wear coiled rod of fibre reinforced composites; Described thermosetting resin spraying equipment 12 comprises resin pump 12a, static blender 12b, filter 12c, resin cavity 12d, strainer 12e, nozzle 12f, heater 12g, the output of resin pump 12a is connected to static blender 12b, the lower end of static blender 12b is communicated with resin cavity 12d by filter 12c, the outside of static blender 12b is provided with heater 12g, the lower end of filter 12c is provided with nozzle 12f, by nozzle 12f, sucker rod body of rod 12j is sprayed, the both sides of described resin cavity 12d are provided with strainer 12e; Described nozzle 12f is comprised of resin flow channel 12h and injection orifice plate 12i, and described resin flow channel 12h adopts 360 degree helical structures, sprays orifice plate 12i and adopts tapering star jet orifice structure, specifically with reference to accompanying drawing 7 and 8.
With reference to accompanying drawing 5, above-mentioned winding machine comprises control system 3a, servomotor 3b, reductor 3c, twin shaft exchange system 3d, be wound around fiber holding tray 3e, tensioning apparatus 3f, fiber is placed axle 3g, and servomotor 3b connects twin shaft exchange system 3d by reductor 3c, the two ends of twin shaft exchange system 3d connect respectively winding fiber holding tray 3e, and the outside that is wound around fiber holding tray 3e connects fiber by tensioning apparatus 3f and places axle 3g.
With reference to accompanying drawing 6, braider comprises control system 3a, servomotor 3b, reductor 3c, tensioning apparatus 3f, fiber placement axle 3g, is wound around split axle drive system 3h, is wound around axle exchange system 3i, servomotor 3b is connected and is wound around split axle drive system 3h by reductor 3c, be wound around split axle drive system 3h and be connected with winding axle exchange system 3i, be wound around axle exchange system 3i outside and connect fiber placement axle 3g by tensioning apparatus 3f.
The preparation method of the anti-eccentric wear coiled rod of a kind of MULTILAYER COMPOSITE that the present invention mentions, comprises the following steps and makes:
A draws multiple fibre from putting guide frame 1, under the traction of draw-gear 11, through injection molding 5, is full of the resin matrix glue 4.3 that injector 4 is injected in injection molding 5, and resin matrix is epoxy resin, vinyl ester resin or polyurethane resin;
Winding layer or braid B that b is used braider or winding machine 2 braiding one decks to strengthen between internal layer longitudinal fiber A and outer longitudinal fiber C, wherein, be wound around one or more layers 0.1~2mm thickness by winding machine 3, and winding angle is the winding layer of 15~85 °; Or use braider 3 between internal layer longitudinal fiber A and outer longitudinal fiber C, being wound around one or more layers thickness is 0.1~2mm, and intersecting angle is the braid of 15~85 °;
B passes through pultrusion die 7 curing moldings again through the fiber bundle of the interior glue dipping of injection molding 4, and the entrance of pultrusion die 7 is provided with equipment for cooling die 6, for reducing die entrance temperature, avoids mold temperature to conduct to injection molding 5; Around pultrusion die 7, equipment for cooling die 6 after, be distributed with mold heating device 8,2~4 sections of heating, solidification temperature is between 95~180 ℃, heating mode in gradient, pultrusion speed is between 0.08~1.5 m/min, and pultrusion goes out the composite material body of rod; The composite material body of rod that pultrusion goes out enters rear solidifying heating furnice 9 and carries out thermal stress processing and rear solidifying, and rear curing end, by draw-gear 11;
C is between the draw-gear 11 and coiler device 14 of injection extruding equipment, a cover thermosetting resin spraying equipment device 12 and solidification equipment 13 are set, utilize one section or the surface attachment one deck thermosetting wearing layer of several section of plastic extrusion apparatus 12 on the moulding oil pumping body of rod, then pass through solidification equipment 13; After fully solidifying, utilize coiler device 11 to be wound on the disk that diameter is 1.5m~3.5m.
Below by embodiment, to the detailed description of the invention, but the invention is not restricted to these embodiment.
Embodiment 1:
The preparation method of the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE, its internal layer longitudinal fiber A is carbon fiber, and outer longitudinal fiber C is high strength glass fiber, and in the middle of ectonexine, winding layer B is high-strength glass fibre, and its preparation method comprises the steps:
Internal layer multi-beam carbon-fiber silk is entered into surfacing stove through putting row's silk hole of guide frame, furnace temperature is between 80~150 ℃, hauling speed is between 0.08~1.5 m/min, by the time be 1.0~12.5 minutes, carbon fiber after heat treatment after winding layer glass fiber is coated, enters injection molding with winding layer, outer high-strength glass fibre simultaneously, in injection molding, be full of the resin adhesive liquid that injector is injected, resin adhesive liquid proportioning is polyalcohol: isocyanates=100:121; Carbon fiber after impregnation enters pultrusion die, and pultrusion die entrance utilizes recirculated water cooling mode to be down to room temperature, but after water-cooled, utilizes mold heating device, and by three sections of heating of mould, temperature is 110 ℃, 165 ℃, 155 ℃; Composite bar after moulding continues to advance with the speed of 0.08~1.5 m/min, by length, it is 2 meters, temperature is to solidify and process after the rear solidifying heating furnice of 150 ℃, after fully cooling by air, the body of rod is through tractor, as heart yearn, enter thermosetting resin spraying equipment, thermosetting resin spraying equipment squeezes the layer of polyurethane that coating thickness is 0.5mm, after being heating and curing, be bonded in sucker rod body of rod external surface, with one section of anti-eccentric wear coiled rod of fibre reinforced composites with wearing layer, be wound on disk and complete.
Embodiment 2:
The preparation method of the anti-eccentric wear coiled rod of fibre reinforced composites, internal layer longitudinal fiber A and outer longitudinal fiber C are high-strength glass fibre, and middle winding layer B is used high-strength glass fibre, and its preparation method comprises the steps:
Hauling speed is 0.2 m/min, and change injecting resin is epoxy resin, wherein epoxy resin E-51: methyl tetrahydro phthalic anhydride: DMP-30: the parts by weight of zinc stearate are 100:85:2.0:1, two sections of heating of pultrusion die, and temperature is 120 ℃, 160 ℃; Die length 1000mm, the sucker rod after moulding is 160 ℃ by temperature, the rear curing processing stove that length is 3m is processed; Coolingly utilize fluororine-carbon coating that thermosetting resin spraying equipment continuous spray thickness is 2mm as wearing layer afterwards, after fully solidifying, with the continous sucker rod made of fiber reinforced composition of wearing layer, be wound on disk and complete.
Embodiment 3:
The preparation method of the preferred anti-eccentric wear coiled rod of fibre reinforced composites, internal layer longitudinal fiber A and outer longitudinal fiber C are basalt fibre, and middle winding layer B is also basalt fibre, and its preparation method comprises the steps:
The furnace temperature of heat treatment of fiber is 120 ℃, hauling speed is 0.38 m/min, and change injecting resin is vinyl ester resin, wherein Atlac 430:MEKP:BPO: the parts by weight of zinc stearate are 100:1.5:1.5:1, three sections of heating of mould, temperature is 95 ℃, 115 ℃, 145 ℃; Sucker rod after moulding is 140 ℃ by temperature, and the rear curing processing stove that length is 3m is processed; The cooling rear thermosetting resin spraying equipment that utilizes is extruded modified epoxy that thickness is 10mm continuously as wearing layer, after fully cooling, with the continous sucker rod made of fiber reinforced composition of wearing layer, is wound on the disk that diameter is 3.5m.
Embodiment 4:
The preparation method of the preferred anti-eccentric wear coiled rod of fibre reinforced composites, internal layer longitudinal fiber A and outer longitudinal fiber C are aramid fiber, and middle winding layer B is also aramid fiber, and its preparation method comprises the steps:
The furnace temperature of heat treatment of fiber is 120 ℃, hauling speed is 0.38 m/min, and change injecting resin is vinyl ester resin, wherein Atlac 430:MEKP:BPO: the parts by weight of zinc stearate are 100:1.5:1.5:1, three sections of heating of mould, temperature is 95 ℃, 115 ℃, 145 ℃; Sucker rod after moulding is 140 ℃ by temperature, and the rear curing processing stove that length is 3m is processed; The cooling rear thermosetting resin spraying equipment that utilizes is extruded vinyl ester resins that thickness is 10mm continuously as wearing layer, after fully cooling, with the continous sucker rod made of fiber reinforced composition of wearing layer, is wound on the disk that diameter is 3.5m.
Winding layer is replaceable is braid, and its thickness is 0.1 ~ 2mm;
Described thermosetting wearing layer is a kind of in polyurethane, fluororine-carbon coating, modified epoxy, vinyl ester resins, unsaturated polyester (UP), phenolic resins.

Claims (6)

1. the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE, is characterized in that: one section or several sections at the external surface of the fiber reinforced resin based composite material body of rod is covered with one deck thermosetting wearing layer (D), and described thermosetting wearing layer (D) is polyurethane, fluororine-carbon coating, modified epoxy, vinyl ester resins, unsaturated polyester (UP), a kind of making in phenolic resins, the thickness of thermosetting wearing layer (D) is 0.5~10mm, the fiber that the described fiber reinforced resin based composite material body of rod adopts is glass fiber, one or more of carbon fiber or basalt fibre are made, the manufacturing process that adopts MULTILAYER COMPOSITE winding and pultrusion or braiding and pultrusion, is internal layer longitudinal fiber (A) from inside to outside successively, winding layer or braid (B), outer longitudinal fiber (C), all winding layers, braid and longitudinal fiber are carbon fiber, glass fiber, basalt fibre, a kind of in aramid fiber, the resin matrix of employing is epoxy resin, polyurethane resin or vinyl ester resin a kind of, the continuous length of the body of rod of making is 0~5000m.
2. the preparation facilities of the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE, comprise and put guide frame (1), pre-heating system (2), winding machine or braider (3), injector (5), injection molding (4), equipment for cooling die (6), pultrusion die (7), mold heating device (8), control section (9), rear solidifying heating furnice (10), draw-gear (11), coiler device (14) forms injection pultrusion equipment, in the bottom of injection molding (4), one or two adhesive pouring nozzles (4.1) are housed, one or two vacuum nozzles (4.2) are equipped with at top, the external vacuum tube of vacuum nozzle (4.2), vacuum tube is connected with vacuum tank, the adhesive pouring nozzle (4.1) of described injector (3) by bottom is to the inner resin by injection Matrix adhesive (4.3) of injection molding, it is characterized in that: the winding layer or the braid (B) that between internal layer longitudinal fiber (A) and outer longitudinal fiber (C), use braider or winding machine (2) braiding one deck to strengthen, between the draw-gear (11) of injection pultrusion equipment and coiler device (14), be provided with a thermosetting resin spraying equipment (12) and solidification equipment (13), utilize thermosetting resin spraying equipment (12) at one section or surface attachment one deck thermosetting wearing layer of several sections of the moulding oil pumping body of rod, then passing through solidification equipment (13) solidifies, form the anti-eccentric wear coiled rod of fibre reinforced composites, described thermosetting resin spraying equipment (12) comprises resin pump (12a), static blender (12b), filter (12c), resin cavity (12d), strainer (12e), nozzle (12f), heater (12g), the output of resin pump (12a) is connected to static blender (12b), the lower end of static blender (12b) is communicated with resin cavity (12d) by filter (12c), the outside of static blender (12b) is provided with heater (12g), the lower end of filter (12c) is provided with nozzle (12f), the both sides of described resin cavity (12d) are provided with strainer (12e).
3. the preparation facilities of the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE according to claim 2, it is characterized in that: described nozzle (12f) is comprised of resin flow channel (12h) and injection orifice plate (12i), described resin flow channel (12h) adopts 360 degree helical structures, sprays orifice plate (12i) and adopts tapering star jet orifice structure.
4. the preparation facilities of the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE according to claim 2, it is characterized in that: described winding machine comprises control system (3a), servomotor (3b), reductor (3c), twin shaft exchange system (3d), be wound around fiber holding tray (3e), tensioning apparatus (3f), fiber is placed axle (3g), servomotor (3b) connects twin shaft exchange system (3d) by reductor (3c), the two ends of twin shaft exchange system (3d) connect respectively winding fiber holding tray (3e), the outside that is wound around fiber holding tray (3e) connects fiber by tensioning apparatus (3f) and places axle (3g).
5. the preparation facilities of the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE according to claim 2, it is characterized in that: described braider comprises control system (3a), servomotor (3b), reductor (3c), tensioning apparatus (3f), fiber is placed axle (3g), be wound around split axle drive system (3h), be wound around axle exchange system (3i), servomotor (3b) is connected and is wound around split axle drive system (3h) by reductor (3c), being wound around split axle drive system (3h) is connected with winding axle exchange system (3i), be wound around axle exchange system (3i) outside and connect fiber placement axle (3g) by tensioning apparatus (3f).
6. a preparation method for the anti-eccentric wear coiled rod of MULTILAYER COMPOSITE, is characterized in that comprising the following steps and makes:
(a) from putting guide frame (1), draw multiple fibre, process injection molding (5) under the traction of draw-gear (11), in injection molding (5), be full of the resin matrix glue (4.3) that injector (4) is injected, resin matrix is epoxy resin, vinyl ester resin or polyurethane resin;
(b) winding layer or the braid (B) that between internal layer longitudinal fiber (A) and outer longitudinal fiber (C), use braider or winding machine (2) braiding one deck to strengthen, wherein, by winding machine (3), be wound around one or more layers 0.1~2mm thickness, winding angle is the winding layer of 15~85 °; Or use braider (3) between internal layer longitudinal fiber (A) and outer longitudinal fiber (C), being wound around one or more layers thickness is 0.1~2mm, and intersecting angle is the braid of 15~85 °;
(b) in injection molding (4), the fiber bundle of glue dipping passes through pultrusion die (7) curing molding again, the entrance of pultrusion die (7) is provided with equipment for cooling die (6), for reducing die entrance temperature, avoid mold temperature to conduct to injection molding (5); Pultrusion die (7) around, equipment for cooling die (6) after, be distributed with mold heating device (8), 2~4 sections of heating, solidification temperature is between 95~180 ℃, heating mode in gradient, pultrusion speed is between 0.08~1.5 m/min, and pultrusion goes out the composite material body of rod; The composite material body of rod that pultrusion goes out enters rear solidifying heating furnice (9) and carries out thermal stress processing and rear solidifying, and rear curing end, by draw-gear (11);
(c) between the draw-gear (11) and coiler device (14) of injection extruding equipment, a cover thermosetting resin spraying equipment device (12) and solidification equipment (13) are set, utilize one section or the surface attachment one deck thermosetting wearing layer of several section of plastic extrusion apparatus (12) on the moulding oil pumping body of rod, then pass through solidification equipment (13); After fully solidifying, utilize coiler device (11) to be wound on the disk that diameter is 1.5m~3.5m.
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CN106593361A (en) * 2017-01-18 2017-04-26 大庆市华禹石油机械制造有限公司 Intelligent driving device for oil-well pump and winding type pumping unit system
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CN109723388A (en) * 2017-10-27 2019-05-07 中国石油化工股份有限公司 A kind of fibre reinforced wrapped tube and preparation method thereof
CN108104733A (en) * 2018-02-01 2018-06-01 山东中恒景新碳纤维科技发展有限公司 Pumping rod of composite carbon fiber material with autonomous repair function
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CN108678684A (en) * 2018-06-29 2018-10-19 山东大学 A kind of impact resistance composite material sucker rod
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CN109488219B (en) * 2018-11-28 2024-02-02 胜利新大新材料股份有限公司 Corrosion-resistant high-temperature-resistant composite material continuous sucker rod with multilayer structure and preparation process thereof
CN109488219A (en) * 2018-11-28 2019-03-19 胜利油田新大管业科技发展有限责任公司 Multilayered structure corrosion-resistant and high-temperature resistant composite continuous sucker rod and preparation process
CN109798075A (en) * 2019-02-10 2019-05-24 北京工商大学 A kind of endurance multilayered structure steel oil pumping polish rod and its processing technology
CN109838469A (en) * 2019-03-11 2019-06-04 江苏恒神股份有限公司 A kind of connection type of Carbon Fiber Composite Propeller Shaft
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CN112721345A (en) * 2021-01-20 2021-04-30 哈尔滨玻璃钢研究院有限公司 Composite material holding pole structure for communication antenna and preparation method thereof
CN113085225A (en) * 2021-03-31 2021-07-09 合肥工业大学 Method for continuously preparing integral composite sleeper by using controllable polyurethane composite material
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