CN106891549A - A kind of preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod - Google Patents

A kind of preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod Download PDF

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Publication number
CN106891549A
CN106891549A CN201710010065.8A CN201710010065A CN106891549A CN 106891549 A CN106891549 A CN 106891549A CN 201710010065 A CN201710010065 A CN 201710010065A CN 106891549 A CN106891549 A CN 106891549A
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China
Prior art keywords
resin
layer
fiber
rod
winding
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CN201710010065.8A
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CN106891549B (en
Inventor
王瑞星
刘洋
吴永太
李强
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Shengli new big new materials Co., Ltd
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Shengli Oilfield Xinda Pipes Technology Development Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/523Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement in the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/521Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525Component parts, details or accessories; Auxiliary operations
    • B29C70/528Heating or cooling
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • E21B17/20Flexible or articulated drilling pipes, e.g. flexible or articulated rods, pipes or cables
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C2035/0283Thermal pretreatment of the plastics material

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The present invention relates to a kind of preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod.Its technical scheme is:Adhesive pouring nozzle is housed in the bottom of injection molding, injector is by the adhesive pouring nozzle of bottom to injection molding inside resin by injection Matrix adhesive;One layer of enhanced winding layer or braiding layer are woven using braider or wrapping machine between internal layer longitudinal fiber and outer layer longitudinal fiber, a thermosetting resin spraying equipment and solidification equipment are provided between the draw-gear and coiler device of injecting pultrusion equipment.The resin that the injection spraying equipment that the present invention is used is sprayed is through measuring pump accurate measurement, it is ensured that the uniformity of coating thickness;The application of static blender can ensure being sufficiently mixed for resin, and the uniformity to product properties plays a key effect;Thermostat ensures that the proterties of spraying resin is consistent;Nozzle is specially designed, it is ensured that the consistency of thickness of coating around the body of rod;Two ends filter both can guarantee that and filtered out Excess resin, ensure that the thickness of spray-on coating.

Description

A kind of preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod
Technical field
The present invention relates to a kind of eccentric abrasion prevention coiled rod and its preparation facilities, more particularly to a kind of MULTILAYER COMPOSITE eccentric abrasion prevention The preparation facilities of coiled rod.
Background technology
Because the Oil Reservoir Types developed become increasingly complex, while the continuous deterioration being continuously increased with well ore deposit environment of well depth, Corrosion and eccentric wear problem turn into oil extraction in oil field technique problem demanding prompt solution.Because possessing the corrosion resistant feature of high-strength light, institute Have started to progressively replace traditional metal sucker rod with composite sucker rod.The composite sucker rod for using at present is mainly wrapped Include glass fiber reinforced plastic oil pumping rod and the major class of carbon fibre reinforced composite coiled rod two.Glass fiber reinforced plastic oil pumping rod is increased using glass fibre Prepared by the pultrude process one-shot forming of heat-flash thermosetting resin, have been widely used, but as the modern reliability requirement for recovering the oil is continuous Improve, glass fiber reinforced plastic oil pumping rod can not meet requirement, be primarily present problems with, 1, the resistance to eccentric wear of sucker rod it is bad;2nd, fatigue Insufficient strength;3rd, respectively there is a metal joint at the equal fixed length of glass fiber reinforced plastic oil pumping rod, two ends, should using metal sucker rod between root and root Metal box cupling is attached, and due to complex structure, difficulty of processing is big, expensive.Each glass fiber reinforced plastic oil pumping rod uses two Individual metal joint, the cost of the two metal joints is far above a cost for the fiberglass body of rod;Pumped with conventional metals in addition Bar compares, and except shank portion has changed material, the other parts of whole rod string have no change, conventional metals sucker rod Column joint is more, and the de- probability that breaks is high, and substantially, the box cupling problem serious with oil pipe eccentric wear is not resolved piston effect.It is Chinese special Sharp CN1417449 discloses a kind of preparation method of Anti-wear oil pumping rod, and the method is secondary in molded oil pumping bar body The anti-abrading block of the materials such as injection moulding nylon, the covering material that reduction is used reduces continuous cladding cost and process complexity, but Its injection abrasionproof block size is smaller, and relatively independent is distributed in the body of rod, anti-abrading block often occurs and departs from the body of rod, " sugared calabash occurs Reed " phenomenon.In addition, its body of rod fixed length, it is impossible to which it is more to solve conventional metals rod connector, break-off accident rate is big, and piston effect is big Etc. defect;And installed additional on the less body of rod of size anti-bias abrading block be can not solve it is inclined between metal joint and box cupling and oil pipe Mill problem, and this is only the emphasis that sucker rod, pipe eccentric wear need to solve.CN101396874 discloses a kind of eccentric abrasion prevention and is combined The preparation method and device of material sucker rod, its preparation method are on molded composite oil pumping club shaft, using leaching Stain crosses the eccentric abrasion prevention layer of the abrasion resistant fibrous continuous-winding forming spiral tendon shape such as the aramid fiber of resin adhesive liquid, High molecular weight polyethylene, with Reach eccentric abrasion prevention effect.The eccentric abrasion prevention layer of its spiral tendon shape, due to being with abrasion resistant fibrous enhancing thermosetting resin, thus while fine Dimension is that, with antiwear characteristic, but after forming composite with thermosetting resin, its wear resistance decrease is a lot, and the life-span can not How much is extension.In addition to its eccentric abrasion prevention for possessing spiral tendon shape layer, its shortcoming is as common glass fiber reinforced plastic oil pumping rod.China Patent CN1461870 discloses a kind of carbon fibre reinforced composite coiled rod and preparation method, uses carbon fiber to increase Strong material, and integral coating is constituted by transversely arranged aramid fiber or superhigh molecular weight polyethylene fibers beam and longitudinal glass fibre It is compound, enhancing sucker rod transverse direction interlaminar shear strength is mainly solved, there is longitudinal splitting in oil well so as to avoid sucker rod Problem, while also improving the resistance to eccentric wear and intensity of the body of rod.But the sucker rod is using pultrusion, an overall processing of cladding Method(Including putting silk-resin pickup glue-clad cladding-preforming-solidification-coiling operation), clad is fabric enhancing Thermosetting resin, not only increases material cost, and the resistance to eccentric wear of fabric clad is not ideal enough.Further, since The carbon fibre reinforced composite coiled rod cross sectional shape is rectangle or ellipse, and its thickness only has 3~5mm, is being answered When removing well operations with special equipment, the material of retained part cannot almost be selected, and can only be clamped using two-piece type, left and right Direction cannot be spacing, it is easy to which the phenomenon that the body of rod deflects away from retained part occurs.Therefore its special implement retained part of going into the well Structure and developing material difficulty are larger, as the technical bottleneck in carbon fibre reinforced composite coiled rod application, limitation The product large-scale promotion application.Patent of invention CN200910272324.X discloses a kind of coiled rod, using unidirectional Reinforcing fiber pultrusion, the method for coating thermoplastic wearing layer, it is poor to there is radial compressive property in its structure, and thermoplastic wear resistant layer is hard Degree is not high, the defect such as anti-wear performance is poor, it is impossible to meet long-term use and job requirements.
Chinese patent literature number is 103075112A, and patent name is《A kind of fibre reinforced composites eccentric abrasion prevention is continuous Sucker rod and its preparation facilities and method》, it is a patent of invention that our company declared on November 30th, 2012, its technical side Case is that to be covered with one layer of thermoplastic at one section or several sections of the outer surface of the fiber-reinforced resin matrix composite body of rod wear-resisting Layer, the fiber that the body of rod is used is made up of one kind of glass fibre, carbon fiber or basalt fibre, resin matrix be epoxy resin, One kind of polyurethane resin or vinyl ester resin.By being provided with a plastic extrusion between draw-gear and coiler device Machine and cooling device, the one layer of thermoplastic of surface attachment using plastic extruder at a section or several sections of the shaping oil pumping body of rod Wearing layer, then through apparatus for supercooling cooling treatment, forms fibre reinforced composites eccentric abrasion prevention coiled rod.Beneficial effect It is:The excellent corrosion-resistant and resistance to eccentric wear performance of sucker rod is imparted, joint quantity is greatly reduced again, de- probability is resolved in reduction And piston effect, in addition, its production efficiency is high, it is easy to operate.Its problem for existing is, because the thermoplastic for using is wear-resisting Layer, its bending property and radially, axially compressive property is slightly more inferior;In addition, temperature tolerance, wear resistence are also than thermosetting wearing layer Performance is weaker.
The content of the invention
The drawbacks described above that the purpose of the present invention exists aiming at prior art, there is provided a kind of MULTILAYER COMPOSITE eccentric abrasion prevention is continuous The preparation facilities of sucker rod, is to be covered with one layer in a section or several sections of the outer surface of the fiber-reinforced resin matrix composite body of rod Thermosetting wearing layer, using winding+pultrude process, or braiding+pultrude process, not give only excellent corrosion-resistant of sucker rod and Resistance to eccentric wear performance, and with fabulous bending property and radially, axially compressive property, and wear resistence improves 30%, temperature tolerance is most Up to 190 DEG C.
A kind of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod, in the outer surface of the fiber-reinforced resin matrix composite body of rod One section or several sections is covered with one layer of thermosetting wearing layer(D), described thermosetting wearing layer(D)For polyurethane, fluororine-carbon coating, it is modified One kind in epoxy resin, vinyl ester resinses, unsaturated polyester (UP), phenolic resin is made, thermosetting wearing layer(D)Thickness be 0.5~10mm, the fiber that the described fiber-reinforced resin matrix composite body of rod is used is glass fibre, carbon fiber or the Black Warrior One or more of rock fiber is made, using MULTILAYER COMPOSITE winding and pultrusion or braiding and the manufacturing process of pultrusion, by it is interior to Outer is successively internal layer longitudinal fiber(A), winding layer or braiding layer(B), outer layer longitudinal fiber(C), all winding layers, braiding layer and Longitudinal fiber is the one kind in carbon fiber, glass fibre, basalt fibre, aramid fiber, and the resin matrix for using is epoxy One kind of resin, polyurethane resin or vinyl ester resin, the continuous length of the body of rod being made is 0~5000m.
A kind of preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod that the present invention is mentioned, including put guide frame(1), preheating System(2), wrapping machine or braider(3), injector(5), injection molding(4), equipment for cooling die(6), pultrusion die(7)、 Mold heating device(8), control section(9), post-curing heating stove(10), draw-gear(11), coiler device(14)Composition note Pultrusion equipment is penetrated, in injection molding(4)Bottom be equipped with one or two adhesive pouring nozzles(4.1), it is true that top is equipped with one or two Empty mouth(4.2), vacuum nozzle(4.2)External vacuum tube, vacuum tube is connected with vacuum tank;Described injector(5)By bottom Adhesive pouring nozzle(4.1)To injection molding inside resin by injection Matrix adhesive(4.3);In internal layer longitudinal fiber(A)It is fine with outer layer longitudinal direction Dimension(C)Between use braider or wrapping machine(2)Braiding one layer of enhanced winding layer or braiding layer(B), inject pultrusion and set Standby draw-gear(11)And coiler device(14)Between be provided with a thermosetting resin spraying equipment(12)And solidification equipment (13), using thermosetting resin spraying equipment(12)In one section or several sections of the shaping oil pumping body of rod one layer of thermosetting of surface attachment Wearing layer, then by solidification equipment(13)Solidification, forms fibre reinforced composites eccentric abrasion prevention coiled rod;Described heat Thermosetting resin spraying equipment(12)Including resin pump(12a), static blender(12b), filter(12c), resin cavity(12d)、 Filter(12e), nozzle(12f), heater(12g), resin pump(12a)Output end be connected to static blender(12b), it is quiet State blender(12b)Lower end pass through filter(12c)With resin cavity(12d)Connection, static blender(12b)Outside be provided with Heater(12g), filter(12c)Lower end be provided with nozzle(12f), described resin cavity(12d)Both sides be provided with filter (12e).
Above-mentioned nozzle(12f)By resin flow channel(12h)With injection orifice plate(12i)Composition, described resin flow channel(12h) Using 360 degree of helical structures, orifice plate is sprayed(12i)Using taper star jet orifice structure.
Above-mentioned wrapping machine includes control system(3a), servomotor(3b), reductor(3c), twin shaft exchange system (3d), wind fiber holding tray(3e), tensioning apparatus(3f), fiber placement axle(3g), servomotor(3b)By reductor (3c)Connection twin shaft exchange system(3d), twin shaft exchange system(3d)Two ends connect respectively winding fiber holding tray(3e), twine Around fiber holding tray(3e)Outside pass through tensioning apparatus(3f)Connection fiber places axle(3g).
Above-mentioned braider includes control system(3a), servomotor(3b), reductor(3c), tensioning apparatus(3f), it is fine Dimension places axle(3g), winding split axle drive system(3h), winding axle exchange system(3i), servomotor(3b)By reductor (3c)Connection winding split axle drive system(3h), wind split axle drive system(3h)With winding axle exchange system(3i)Connection, twines Around axle exchange system(3i)Outside passes through tensioning apparatus(3f)Connection fiber places axle(3g).
A kind of preparation method of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod that the present invention is mentioned, comprises the following steps and is made:
(a)From putting guide frame(1)Multiple fibre is drawn, in draw-gear(11)Traction under by injection molding(4), injection molding (4)It is interior full of injector(5)The resin matrix glue of injection(4.3), resin matrix is epoxy resin, vinyl ester resin or poly- Urethane resin;
(b)In internal layer longitudinal fiber(A)With outer layer longitudinal fiber(C)Between use braider or wrapping machine(2)One layer of increasing of braiding Strong winding layer or braiding layer(B), wherein, by wrapping machine(3)One or more layers 0.1~2mm thickness is wound, winding angle is 15~85 ° of winding layer;Or use braider(3)In internal layer longitudinal fiber(A)With outer layer longitudinal fiber(C)Between, winding One or more layers thickness is 0.1~2mm, and intersecting angle is 15~85 ° of braiding layer;
(b)Through injection molding(4)The fibre bundle of interior glue dipping is again by pultrusion die(7)Curing molding, pultrusion die(7)'s Porch is provided with equipment for cooling die(6), for reducing die entrance temperature, it is to avoid mold temperature is conducted to injection molding(5); In pultrusion die(7)Surrounding, equipment for cooling die(6)Behind, mold heating device is distributed with(8), in 2~4 sections of heating, Gu Change temperature between 95~180 DEG C, heating mode in gradient, between 0.08~1.5 m/min, pultrusion goes out multiple pultrusion speed The condensation material body of rod;The composite body of rod that pultrusion goes out enters post-curing heating stove(9)Thermal stress treatment and solidify afterwards are carried out, it is solid afterwards Change terminates, by draw-gear(11);
(c)In the draw-gear of injection extruding equipment(11)And coiler device(14)Between, a set thermosetting resin spray is set Automatic doubler surface glouer device(12)And solidification equipment(13), using thermosetting resin spraying equipment(12)One section on the shaping oil pumping body of rod Or several sections one layer of thermosetting wearing layer of surface attachment, then by solidification equipment(13);After through fully solidification, filled using winding Put(11)By it on the disk of a diameter of 1.5m~3.5m.
The beneficial effects of the invention are as follows:Sucker rod of the invention, in continuous sucker rod made of fiber reinforced composition pultrusion work Winding layer or braiding layer are increased on the basis of skill, radial strength and axial compression strength is increased, bending property is improve, dropped Low bending diameter;Continuous one section or interrupted several sections of thermosetting wearing layers of surface spraying, impart the excellent corrosion resistant of sucker rod Erosion and resistance to eccentric wear performance, improve 30% compared with existing thermoplastic wearing layer, and temperature tolerance is more preferably, can reach 190 DEG C;
In addition, using special spraying equipment, different from common spraying equipment, the resin that this injection spraying equipment is sprayed Through measuring pump accurate measurement, it is ensured that the uniformity of coating thickness;The application of static blender can ensure being sufficiently mixed for resin, Uniformity to product properties plays a key effect;Thermostat ensures that the proterties of spraying resin is consistent;Nozzle is through special Design, it is ensured that the consistency of thickness of coating around the body of rod;The design of two ends filter both can guarantee that and filtered out Excess resin, Ensure that the thickness of spray-on coating;
The preparation method that also present invention is provided, it is solid using winding pultrusion, braiding pultrusion, injection pultrusion and thermosetting resin spraying Change assembling process, the continuous-stable of continuous sucker rod made of fiber reinforced composition body of rod production can be greatly improved, match somebody with somebody Close special spray equipment, it is ensured that position distribution of the thermosetting resin wearing layer on oil pumping club shaft surface meets design need Ask, the combination of wearing layer and the body of rod is completed online, and production efficiency is high, and bond strength is big, it is to avoid layering, the hair of obscission It is raw.
Brief description of the drawings
Accompanying drawing 1 is the cross section structure figure of coiled rod of the invention;
Accompanying drawing 2 is the schematic flow sheet of preparation facilities of the invention;
Accompanying drawing 3 is the structural representation of injection molding in injection pultrude process of the invention;
Accompanying drawing 4 is the structural representation of wrapping machine in winding pultrude process of the invention;
Accompanying drawing 5 is the structural representation of braider in braiding pultrude process of the invention;
Accompanying drawing 6 is the structural representation of spraying equipment in thermoplastic resin spraying coating process of the invention;
Accompanying drawing 7 is the sectional view of the nozzle segment of spraying equipment of the invention;
Accompanying drawing 8 is the M-M structure charts of the nozzle segment of spraying equipment of the invention;
In upper figure:Put guide frame 1, pretreatment heating furnace 2, wrapping machine or braider 3, injector, 5, injection molding 4, mould cooling Device 6, pultrusion die 7, mold heating device 8, control section 9, post-curing heating stove 10, draw-gear 11, thermosetting resin Spraying equipment 12, solidification equipment 13, coiler device 14;
Internal layer longitudinal fiber A, winding layer or braiding layer B, outer layer longitudinal fiber C, thermosetting wearing layer D;
Control system 3a, servomotor 3b, reductor 3c, twin shaft exchange system 3d wind fiber holding tray 3e, tensioning apparatus 3f, fiber places axle 3g, winds split axle drive system 3h, winding axle exchange system 3i;Adhesive pouring nozzle 4.1, vacuum nozzle 4.2, resin Matrix adhesive 4.3;Resin pump 12a, static blender 12b, filter 12c, resin cavity 12d, filter 12e, nozzle 12f, plus Hot device 12g, resin flow channel 12h, injection orifice plate 12i, oil pumping club shaft 12j.
Specific embodiment
Referring to the drawings 1, a kind of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod that the present invention is mentioned, in fiber-reinforced resin matrix One section or several sections of the outer surface of the composite body of rod is covered with one layer of thermosetting wearing layer D, and described thermosetting wearing layer D is poly- One kind in urethane, fluororine-carbon coating, modified epoxy, vinyl ester resinses, unsaturated polyester (UP), phenolic resin is made, thermosetting Property wearing layer D thickness be 0.5~10mm, the fiber that the described fiber-reinforced resin matrix composite body of rod is used is glass One or more of fiber, carbon fiber or basalt fibre is made, using MULTILAYER COMPOSITE winding and pultrusion or braiding and pultrusion Manufacturing process, be successively from inside to outside internal layer longitudinal fiber A, winding layer or braiding layer B, outer layer longitudinal fiber C, all windings Layer, braiding layer and longitudinal fiber are the one kind in carbon fiber, glass fibre, basalt fibre, aramid fiber, the resin of use Matrix is one kind of epoxy resin, polyurethane resin or vinyl ester resin, and the continuous length of the body of rod being made is 0~5000m.
Referring to the drawings 2, the preparation facilities of a kind of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod that the present invention is mentioned, including put silk Frame 1, pre-heating system 2, wrapping machine or braider 3, injector 5, injection molding 4, equipment for cooling die 6, pultrusion die 7, mould Heater 8, control section 9, post-curing heating stove 10, draw-gear 11, the composition injection pultrusion equipment of coiler device 14, One or two adhesive pouring nozzles 4.1 are housed in the bottom of injection molding 4, top is equipped with one or two vacuum nozzles 4.2, outside vacuum nozzle 4.2 Vacuum tube is connect, vacuum tube is connected with vacuum tank;Described injector 5 is noted by the adhesive pouring nozzle 4.1 of bottom to inside injection molding Enter resin matrix glue 4.3;Between internal layer longitudinal fiber A and outer layer longitudinal fiber C one is woven using braider or wrapping machine 2 The enhanced winding layer of layer or braiding layer B, one is provided between the draw-gear 11 and coiler device 14 of injecting pultrusion equipment Platform thermosetting resin spraying equipment 12 and solidification equipment 13, using thermosetting resin spraying equipment 12 the one of the shaping oil pumping body of rod Section or several sections one layer of thermosetting wearing layer of surface attachment, then solidify by solidification equipment 13, form fiber-reinforced composite material Material eccentric abrasion prevention coiled rod;Described thermosetting resin spraying equipment 12 includes resin pump 12a, static blender 12b, filtering Plate 12c, resin cavity 12d, filter 12e, nozzle 12f, heater 12g, the output end of resin pump 12a are connected to static blender The lower end of 12b, static blender 12b is connected by filter 12c with resin cavity 12d, and the outside of static blender 12b is provided with and adds The lower end of hot device 12g, filter 12c is provided with nozzle 12f, and oil pumping club shaft 12j is sprayed by nozzle 12f, described The both sides of resin cavity 12d are provided with filter 12e;Described nozzle 12f is made up of resin flow channel 12h and injection orifice plate 12i, described Resin flow channel 12h use 360 degree helical structures, injection orifice plate 12i using taper star jet orifice structure, referring in particular to accompanying drawing 7 With 8.
Referring to the drawings 5, above-mentioned wrapping machine includes control system 3a, servomotor 3b, reductor 3c, twin shaft exchange system 3d, winding fiber holding tray 3e, tensioning apparatus 3f, fiber places axle 3g, and servomotor 3b connects twin shaft and changes by reductor 3c To system 3d, the two ends of twin shaft exchange system 3d connect winding fiber holding tray 3e, the outside of winding fiber holding tray 3e respectively Fiber is connected by tensioning apparatus 3f and places axle 3g.
Referring to the drawings 6, braider includes that control system 3a, servomotor 3b, reductor 3c, tensioning apparatus 3f, fiber are put Axle 3g, winding split axle drive system 3h, winding axle exchange system 3i, servomotor 3b are put by reductor 3c connection winding split axles Drive system 3h, winding split axle drive system 3h are connected with winding axle exchange system 3i, and winding axle exchange system 3i outsides pass through Tensioning apparatus 3f connection fibers place axle 3g.
A kind of preparation method of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod that the present invention is mentioned, comprises the following steps and is made:
A draws multiple fibre from guide frame 1 is put, and by injection molding 4 under the traction of draw-gear 11, is full of in injection molding 4 The resin matrix glue 4.3 of the injection of injector 5, resin matrix is epoxy resin, vinyl ester resin or polyurethane resin;
B weaves one layer of enhanced winding between internal layer longitudinal fiber A and outer layer longitudinal fiber C using braider or wrapping machine 2 Layer or braiding layer B, wherein, one or more layers 0.1~2mm thickness is wound by wrapping machine 3, winding angle is 15~85 ° to be twined Winding layer;Or using braider 3 between internal layer longitudinal fiber A and outer layer longitudinal fiber C, winding one or more layers thickness is 0.1~2mm, intersecting angle is 15~85 ° of braiding layer;
Through the fibre bundle of glue dipping in injection molding 4 again by the curing molding of pultrusion die 7, the porch of pultrusion die 7 sets b There is equipment for cooling die 6, for reducing die entrance temperature, it is to avoid mold temperature is conducted to injection molding 4;In pultrusion die 7 Behind surrounding, equipment for cooling die 6, mold heating device 8 is distributed with, in 2~4 sections of heating, solidification temperature is at 95~180 DEG C Between, heating mode in gradient, between 0.08~1.5 m/min, pultrusion goes out the composite body of rod to pultrusion speed;Pultrusion goes out The composite body of rod carry out thermal stress treatment and solidify afterwards into post-curing heating stove 9, solidify afterwards terminate, by draw-gear 11;
C sets a set thermosetting resin spraying equipment between the draw-gear 11 and coiler device 14 of injection extruding equipment Device 12 and solidification equipment 13, using the surface attachment one of one section or several sections of plastic extrusion apparatus 12 on the shaping oil pumping body of rod Layer thermosetting wearing layer, then by solidification equipment 13;After through fully solidification, using coiler device 11 by it wound on a diameter of On the disk of 1.5m~3.5m.
Below by embodiment, to the detailed description of the invention, but the invention is not restricted to these embodiments.
Embodiment 1:
The preparation method of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod, its internal layer longitudinal fiber A is carbon fiber, outer layer longitudinal fiber C It is high strength glass fiber, ectonexine mid-wrap layer B is high-strength glass fibre, and its preparation method comprises the following steps:
By internal layer multi-beam carbon-fiber silk through putting guide frame row silk hole enter into surface treatment stove, furnace temperature between 80~150 DEG C, Hauling speed is 1.0~12.5 minutes by the time between 0.08~1.5 m/min, and the carbon fiber after heat treatment is being twined After winding layer glass fibre cladding, enter simultaneously in injection molding, injection molding full of note with winding layer, outer layer high-strength glass fibre The resin adhesive liquid of machine injection is penetrated, resin adhesive liquid proportioning is polyalcohol:Isocyanates=100:121;Carbon fiber after impregnation enters drawing Extruding mold, pultrusion die porch is down to behind room temperature, but water-cooled using recirculated water cooling mode, using mold heating device, will Three sections of heating of mould, temperature is 110 DEG C, 165 DEG C, 155 DEG C;Composite bar after shaping continues with 0.08~1.5 m/min Speed advance, by length be 2 meters, temperature be 150 DEG C post-curing heating stove solidify afterwards treatment, fully cooled down by air Afterwards, the body of rod enters thermosetting resin spraying equipment by hauling machine as heart yearn, and thermosetting resin spraying equipment squeezes coating thickness It is the layer of polyurethane of 0.5mm, after being heating and curing, oil pumping club shaft outer surface is bonded in, with one section of fiber with wearing layer Enhancing composite eccentric abrasion prevention coiled rod is wound on disk and completes.
Embodiment 2:
The preparation method of fibre reinforced composites eccentric abrasion prevention coiled rod, internal layer longitudinal fiber A and outer layer longitudinal fiber C are High-strength glass fibre, mid-wrap layer B uses high-strength glass fibre, its preparation method to comprise the following steps:
Hauling speed is 0.2 m/min, and change injecting resin is epoxy resin, its epoxy resin E-51:Methyl tetrahydrochysene benzene Acid anhydride:DMP-30:The parts by weight of zinc stearate are 100:85:2.0:1, the heating of two sections of pultrusion die, temperature is 120 DEG C, 160 ℃;Die length 1000mm, the sucker rod after shaping is 160 DEG C by temperature, and length is processed for the solidify afterwards treatment furnace of 3m;It is cold But afterwards by the use of the fluororine-carbon coating that thermosetting resin spraying equipment continuous spray thickness is 2mm as wearing layer, by fully solidification Afterwards, the continuous sucker rod made of fiber reinforced composition with wearing layer is wound on disk and completes.
Embodiment 3:
The preparation method of preferred fibre reinforced composites eccentric abrasion prevention coiled rod, internal layer longitudinal fiber A and outer layer longitudinal direction Fiber C is basalt fibre, and mid-wrap layer B is also basalt fibre, and its preparation method comprises the following steps:
The furnace temperature of heat treatment of fiber is 120 DEG C, and hauling speed is 0.38 m/min, and change injecting resin is vinyl ester resin, Wherein Atlac 430:MEKP:BPO:The parts by weight of zinc stearate are 100:1.5:1.5:1, three sections of mould is heated, and temperature is 95℃、115℃、145℃;Sucker rod after shaping is 140 DEG C by temperature, and length is processed for the solidify afterwards treatment furnace of 3m;It is cold But modified epoxy of the thickness for 10mm is continuously extruded as wearing layer by the use of thermosetting resin spraying equipment afterwards, by abundant After cooling, the continuous sucker rod made of fiber reinforced composition with wearing layer is wound on the disk of a diameter of 3.5m.
Embodiment 4:
The preparation method of preferred fibre reinforced composites eccentric abrasion prevention coiled rod, internal layer longitudinal fiber A and outer layer longitudinal direction Fiber C is aramid fiber, and mid-wrap layer B is also aramid fiber, and its preparation method comprises the following steps:
The furnace temperature of heat treatment of fiber is 120 DEG C, and hauling speed is 0.38 m/min, and change injecting resin is vinyl ester resin, Wherein Atlac 430:MEKP:BPO:The parts by weight of zinc stearate are 100:1.5:1.5:1, three sections of mould is heated, and temperature is 95℃、115℃、145℃;Sucker rod after shaping is 140 DEG C by temperature, and length is processed for the solidify afterwards treatment furnace of 3m;It is cold But vinyl ester resinses of the thickness for 10mm are continuously extruded as wearing layer by the use of thermosetting resin spraying equipment afterwards, by abundant After cooling, the continuous sucker rod made of fiber reinforced composition with wearing layer is wound on the disk of a diameter of 3.5m.
Winding layer is replaced by braiding layer, and its thickness is 0.1 ~ 2mm;
Described thermosetting wearing layer be polyurethane, fluororine-carbon coating, modified epoxy, vinyl ester resinses, unsaturated polyester (UP), One kind in phenolic resin.

Claims (2)

1. a kind of preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod, it is characterized in that including putting guide frame(1), pre-heating system (2), wrapping machine or braider(3), injector(5), injection molding(4), equipment for cooling die(6), pultrusion die(7), mould Heater(8), control section(9), post-curing heating stove(10), draw-gear(11), coiler device(14)Composition injection is drawn Extrusion forming equipment, in injection molding(4)Bottom be equipped with one or two adhesive pouring nozzles(4.1), top is equipped with one or two vacuum nozzles (4.2), vacuum nozzle(4.2)External vacuum tube, vacuum tube is connected with vacuum tank;Described injector(5)By the injecting glue of bottom Mouth(4.1)To injection molding inside resin by injection Matrix adhesive(4.3);It is characterized in that:In internal layer longitudinal fiber(A)It is vertical with outer layer To fiber(C)Between use wrapping machine or braider(3)Braiding one layer of enhanced winding layer or braiding layer(B), injection pultrusion into The draw-gear of type equipment(11)And coiler device(14)Between be provided with a thermosetting resin spraying equipment(12)And solidification Device(13), using thermosetting resin spraying equipment(12)In one section or several sections of the shaping oil pumping body of rod one layer of heat of surface attachment Solidity wearing layer, then by solidification equipment(13)Solidification, forms fibre reinforced composites eccentric abrasion prevention coiled rod;It is described Thermosetting resin spraying equipment(12)Including resin pump(12a), static blender(12b), filter(12c), resin cavity (12d), filter(12e), nozzle(12f), heater(12g), resin pump(12a)Output end be connected to static blender (12b), static blender(12b)Lower end pass through filter(12c)With resin cavity(12d)Connection, static blender(12b)'s Outside is provided with heater(12g), filter(12c)Lower end be provided with nozzle(12f), described resin cavity(12d)Both sides set There is filter(12e);
Described nozzle(12f)By resin flow channel(12h)With injection orifice plate(12i)Composition, described resin flow channel(12h)Using 360 degree of helical structures, spray orifice plate(12i)Using taper star jet orifice structure;
Described wrapping machine includes control system(3a), servomotor(3b), reductor(3c), twin shaft exchange system(3d), twine Around fiber holding tray(3e), tensioning apparatus(3f), fiber placement axle(3g), servomotor(3b)By reductor(3c)Connection is double Axle exchange system(3d), twin shaft exchange system(3d)Two ends connect respectively winding fiber holding tray(3e), winding fiber placement Disk(3e)Outside pass through tensioning apparatus(3f)Connection fiber places axle(3g).
2. the preparation facilities of MULTILAYER COMPOSITE eccentric abrasion prevention coiled rod according to claim 1, it is characterized in that:Described volume Loom includes control system(3a), servomotor(3b), reductor(3c), tensioning apparatus(3f), fiber place axle(3g), winding Split axle drive system(3h), winding axle exchange system(3i), servomotor(3b)By reductor(3c)Connection winding split axle drives Dynamic system(3h), wind split axle drive system(3h)With winding axle exchange system(3i)Connection, winds axle exchange system(3i)Outward Side passes through tensioning apparatus(3f)Connection fiber places axle(3g).
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