CN117759940B - Method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel - Google Patents

Method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel Download PDF

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CN117759940B
CN117759940B CN202311824834.XA CN202311824834A CN117759940B CN 117759940 B CN117759940 B CN 117759940B CN 202311824834 A CN202311824834 A CN 202311824834A CN 117759940 B CN117759940 B CN 117759940B
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waste liquid
industrial waste
temperature
flue gas
biomass fuel
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CN117759940A (en
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陈建骅
董志刚
王婷婷
张辉
杨建明
田雨
李勇
张勇坚
朱江
樊灿铝
张哲宇
李建成
熊志远
江秋悦
李玉锦
王振宇
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Yunnan Energy Saving Technology Development Operation Co ltd
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Yunnan Energy Saving Technology Development Operation Co ltd
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Abstract

The invention discloses a method for heating by cooperatively utilizing industrial waste liquid by biomass fuel, which comprises the following steps: (1) Biomass fuel is used as combustion-supporting fuel to be added into a hearth and burned stably; (2) Spraying high-concentration wastewater into a basic combustion chamber in an atomized manner, attaching the basic combustion chamber to biomass fuel for pyrolysis and incineration to fix alkali salt substances in the basic combustion chamber, and keeping the temperature above the basic combustion chamber above 1100 ℃; (3) The method comprises the steps of respectively adopting an injection atomization premix combustion technology for oil and solvent industrial waste liquid, performing atomization premix combustion through a burner, and continuously combusting atomized liquid drops carried out by sprayed flames in a high-temperature incineration chamber; (4) Mixing the high-temperature flue gas with low-temperature flue gas at the rear section of an induced draft fan before the high-temperature flue gas exits the high-temperature incineration chamber to reduce the temperature of the flue gas to about 925 ℃, premixing with urea solution to reduce NOx, and allowing the flue gas to enter a waste heat recovery device after the temperature of the flue gas is lower than the ash melting point temperature; (5) And cooling the flue gas by a waste heat recovery device, and discharging the flue gas after meeting the discharge index by dedusting and denitration again.

Description

Method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel
Technical Field
The invention relates to the technical field of waste liquid treatment, in particular to a method for supplying heat by cooperatively utilizing industrial waste liquid with biomass fuel.
Background
Combustion treatment of industrial waste liquid is a common treatment method, but there are many problems in practical use. Enterprises such as pharmacy, food processing and the like process industrial waste liquid, namely organic liquid waste with a certain heat value, including oils, solvents and high BOD and COD waste water. The incineration temperature of the waste is not lower than 1100 ℃ in the treatment process, the heat value fluctuation of oils and solvents serving as industrial waste liquid is large, the incineration temperature of the high COD waste water after being brought into treatment cannot meet the temperature requirement of 1100 ℃, and meanwhile, alkaline substances of the high COD waste water after being incinerated are converted into low-melting inorganic salts to be directly adhered to an evaporation tube bundle of a boiler, so that system faults are easy to cause, and the high COD waste water is difficult to popularize and use effectively.
Disclosure of Invention
The invention aims to provide a method for supplying heat by cooperatively utilizing industrial waste liquid with biomass fuel.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a method for utilizing biomass fuel to supply heat by utilizing industrial waste liquid cooperatively uses an industrial waste liquid incinerator to burn the industrial waste liquid; the industrial waste liquid incinerator sequentially forms a basic combustion chamber and a high-temperature incineration chamber above the hearth; the method is characterized in that: the method comprises the following steps:
(1) Biomass fuel is used as combustion-supporting fuel to be added into a hearth and burned stably;
(2) Spraying high-concentration wastewater into a basic combustion chamber in an atomized manner, attaching the basic combustion chamber to biomass fuel for pyrolysis and incineration to fix alkali salt substances in the basic combustion chamber, and keeping the temperature above the basic combustion chamber above 1100 ℃;
(3) The method comprises the steps of respectively adopting an injection atomization premix combustion technology for oil and solvent industrial waste liquid, performing atomization premix combustion through a burner, and continuously combusting atomized liquid drops carried out by sprayed flames in a high-temperature incineration chamber;
(4) Introducing low-temperature flue gas to mix before the high-temperature flue gas exits the high-temperature incineration chamber to reduce the temperature of the flue gas, premixing with urea solution to reduce NOx, and allowing the flue gas to enter a waste heat recovery device after the temperature of the flue gas is lower than the ash melting point temperature;
(5) And cooling the flue gas by a waste heat recovery device, and discharging the flue gas after meeting the discharge index by dedusting and denitration again.
Preferably, the biomass fuel feeding amount in the step (1) is 0.2-0.5 t/h.m 2 (the biomass fuel amount per hour/the cross-sectional area of the combustion chamber hearth of the industrial waste liquid incinerator).
Preferably, in the step (3), the time for the oil and solvent industrial waste liquid to enter the high-temperature incineration chamber is more than 2s, so that the oil and solvent industrial waste liquid is completely combusted and decomposed.
Preferably, in the step (2), the feeding amount of the high-concentration wastewater is 0.01-0.03 t/h.m 2 (the amount of biomass fuel per hour/the cross-sectional area of the combustion chamber hearth of the industrial waste liquid incinerator).
Preferably, in the step (3), the feeding amount of the oil industrial waste liquid is 0.02-0.06 t/h.m 2 (the amount of biomass fuel per hour/the cross-sectional area of a combustion chamber hearth of the industrial waste liquid incinerator); the feeding amount of the solvent industrial waste liquid is 0.01-0.05 t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber hearth of the industrial waste liquid incinerator).
Preferably, in the step (4), the amount of the low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target, and the low-temperature flue gas adopts the flue gas discharged after the induced draft fan.
Preferably, in the step (4), the concentration of the urea solution is 15% to 20%.
Preferably, the high concentration wastewater in the step (2) is wastewater with COD (chemical oxygen demand) of more than 1000 mg/L.
By adopting the technical scheme, the method has the following advantages:
(1) According to the invention, biomass fuel particles are used as basic fuel to increase and maintain the incineration temperature, meanwhile, ash residues after biomass fuel combustion can be used as an adhesion solidification product of alkaline substances in waste liquid, the incineration temperature of industrial waste liquid is maintained above 1100 ℃ through biomass fuel combustion supporting, and the alkaline substances after waste water incineration are fixed in the ash residues, so that the stability and reliability of a system are improved, and the popularization and the use are facilitated.
(2) The invention respectively utilizes the biomass fuel layer combustion and the pyrolysis combustion to form a high-temperature environment, and sequentially pyrolyzes and incinerates the industrial waste liquid such as concentrated waste water, waste oil, waste solvent and the like, thereby eliminating the hidden trouble of environmental pollution on site. The heat released by the combustion of the industrial waste liquid can be used for supplying heat to the production departments of enterprises.
(3) The invention uses low-temperature flue gas to regulate and control the temperature of high-temperature flue gas entering the waste heat boiler, thereby avoiding slag from adhering to a boiler tube bundle and reducing the boiler efficiency.
Drawings
Fig. 1 is a simplified illustration of the present invention.
Detailed Description
The following describes the embodiments of the present invention further with reference to the drawings. The description of these embodiments is provided to assist understanding of the present invention, but is not intended to limit the present invention. In addition, the technical features of the embodiments of the present invention described below may be combined with each other as long as they do not collide with each other. The parts of the examples below, in which specific parameters are not described, are performed according to the prior art parameters.
Example 1
A method for utilizing biomass fuel to supply heat by utilizing industrial waste liquid cooperatively uses an industrial waste liquid incinerator to burn the industrial waste liquid; the industrial waste liquid incinerator sequentially forms a basic combustion chamber and a high-temperature incineration chamber above the hearth; the method comprises the following steps:
(1) Biomass fuel is used as basic fuel to be added into a hearth and burned stably, and the feeding amount of the biomass fuel is 0.2t/h.m 2 (the amount of the biomass fuel per hour/the cross section area of a combustion chamber hearth of the industrial waste liquid incinerator);
(2) Spraying high-concentration (COD is more than 1000 mg/L) wastewater in an atomized manner into a basic combustion chamber, wherein the feeding amount of the high-concentration wastewater is 0.01t/h.m 2 (the amount of biomass fuel per hour/the cross section area of a combustion chamber hearth of an industrial waste liquid incinerator); the low-temperature flue gas is introduced when the waste liquid is combusted, the introduced amount of the low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target, and the control of the peroxy coefficient of the heated high-temperature flue gas is realized when the waste liquid is combusted; attaching to biomass fuel for pyrolysis and incineration to fix alkali salt matter in the biomass fuel, so that the temperature above the basic combustion chamber is kept above 1100 ℃;
(3) The method comprises the steps of respectively adopting an injection atomization premix combustion technology for oil and solvent industrial waste liquid, performing atomization premix combustion through a burner, and continuously combusting atomized liquid drops carried out by sprayed flames in a high-temperature incineration chamber; the residence time of the oil and solvent industrial waste liquid in the high-temperature incineration chamber is more than 2s, so that the oil and solvent industrial waste liquid is completely combusted and decomposed; the feeding amount of the oil industrial waste liquid is 0.02t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber of the industrial waste liquid incinerator); the feeding amount of the solvent industrial waste liquid is 0.01t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber hearth of the industrial waste liquid incinerator)
(4) Introducing low-temperature flue gas before the high-temperature flue gas exits the high-temperature incineration chamber, mixing to control the temperature of the flue gas, premixing with urea solution (the concentration is 15 percent, the units are the same) to reduce NOx, and enabling the temperature of the flue gas to be lower than the ash melting point temperature and then entering a waste heat recovery device; the amount of low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target; the feeding amount of the urea solution is determined according to the operation requirement of the actual preparation and the out-of-stock device;
(5) And cooling the flue gas by a waste heat recovery device, and discharging the flue gas after meeting the discharge index by dedusting and denitration again.
Example 2
A method for utilizing biomass fuel to supply heat by utilizing industrial waste liquid cooperatively uses an industrial waste liquid incinerator to burn the industrial waste liquid; the industrial waste liquid incinerator sequentially forms a basic combustion chamber and a high-temperature incineration chamber above the hearth; the method comprises the following steps:
(1) Biomass fuel is used as basic fuel to be added into a hearth and burned stably, and the feeding amount of the biomass fuel is 0.5t/h.m 2 (the amount of the biomass fuel per hour/the cross section area of a combustion chamber hearth of the industrial waste liquid incinerator);
(2) Spraying high-concentration (COD is more than 1000 mg/L) wastewater in an atomized manner into a basic combustion chamber, wherein the feeding amount of the high-concentration wastewater is 0.03t/h.m 2 (the amount of biomass fuel per hour/the cross section area of a combustion chamber hearth of an industrial waste liquid incinerator); the low-temperature flue gas is introduced when the waste liquid is combusted, the introduced amount of the low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target, and the control of the peroxy coefficient of the heated high-temperature flue gas is realized when the waste liquid is combusted; attaching to biomass fuel for pyrolysis and incineration to fix alkali salt matter in the biomass fuel, so that the temperature above the basic combustion chamber is kept above 1100 ℃;
(3) The method comprises the steps of respectively adopting an injection atomization premix combustion technology for oil and solvent industrial waste liquid, performing atomization premix combustion through a burner, and continuously combusting atomized liquid drops carried out by sprayed flames in a high-temperature incineration chamber; the residence time of the oil and solvent industrial waste liquid in the high-temperature incineration chamber is more than 2s, so that the oil and solvent industrial waste liquid is completely combusted and decomposed; the feeding amount of the oil industrial waste liquid is 0.06t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber of the industrial waste liquid incinerator); the feeding amount of the solvent industrial waste liquid is 0.05t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber hearth of the industrial waste liquid incinerator)
(4) Introducing low-temperature flue gas to mix before the high-temperature flue gas exits the high-temperature incineration chamber to control the temperature of the flue gas, premixing with urea solution (concentration 20%) to reduce NOx, and allowing the flue gas temperature to be lower than the ash melting point temperature and then to enter a waste heat recovery device; the amount of low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target; the feeding amount of the urea solution is determined according to the operation requirement of the actual preparation and the out-of-stock device;
(5) And cooling the flue gas by a waste heat recovery device, and discharging the flue gas after meeting the discharge index by dedusting and denitration again.
Example 3
A method for utilizing biomass fuel to supply heat by utilizing industrial waste liquid cooperatively uses an industrial waste liquid incinerator to burn the industrial waste liquid; the industrial waste liquid incinerator sequentially forms a basic combustion chamber and a high-temperature incineration chamber above the hearth; the method comprises the following steps:
(1) Biomass fuel is used as basic fuel to be added into a hearth and burned stably, and the feeding amount of the biomass fuel is 0.35t/h.m 2 (the amount of the biomass fuel per hour/the cross section area of a combustion chamber hearth of the industrial waste liquid incinerator);
(2) Spraying high-concentration (COD is more than 1000 mg/L) wastewater in an atomized manner into a basic combustion chamber, wherein the feeding amount of the high-concentration wastewater is 0.02t/h.m 2 (the amount of biomass fuel per hour/the cross section area of a combustion chamber hearth of an industrial waste liquid incinerator); the low-temperature flue gas is introduced when the waste liquid is combusted, the introduced amount of the low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target, and the control of the peroxy coefficient of the heated high-temperature flue gas is realized when the waste liquid is combusted; attaching to biomass fuel for pyrolysis and incineration to fix alkali salt matter in the biomass fuel, so that the temperature above the basic combustion chamber is kept above 1100 ℃;
(3) The method comprises the steps of respectively adopting an injection atomization premix combustion technology for oil and solvent industrial waste liquid, performing atomization premix combustion through a burner, and continuously combusting atomized liquid drops carried out by sprayed flames in a high-temperature incineration chamber; the residence time of the oil and solvent industrial waste liquid in the high-temperature incineration chamber is more than 2s, so that the oil and solvent industrial waste liquid is completely combusted and decomposed; the feeding amount of the oil industrial waste liquid is 0.04t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber of the industrial waste liquid incinerator); the feeding amount of the solvent industrial waste liquid is 0.03t/h.m 2 (the amount of biomass fuel per hour/the cross section area of the combustion chamber hearth of the industrial waste liquid incinerator)
(4) Introducing low-temperature flue gas to mix before the high-temperature flue gas exits the high-temperature incineration chamber to control the temperature of the flue gas, premixing with urea solution (concentration 18%) to reduce NOx, and allowing the flue gas temperature to be lower than the ash melting point temperature and then to enter a waste heat recovery device; the amount of low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target; the feeding amount of the urea solution is determined according to the operation requirement of the actual preparation and the out-of-stock device;
(5) And cooling the flue gas by a waste heat recovery device, and discharging the flue gas after meeting the discharge index by dedusting and denitration again.
According to the invention, biomass fuel particles are used as basic fuel to increase and maintain the incineration temperature, meanwhile, ash residues after biomass fuel combustion can be used as an adhesion solidified substance of alkaline substances in waste liquid, the incineration temperature of industrial waste liquid is maintained above 1100 ℃ through biomass fuel combustion supporting, and the alkaline substances after waste water incineration are fixed in the ash residues, so that the stability and reliability of a system are improved.
The embodiments of the present invention have been described in detail above with reference to the accompanying drawings, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made to these embodiments without departing from the principles and spirit of the invention, and yet fall within the scope of the invention.

Claims (8)

1. A method for utilizing biomass fuel to supply heat by utilizing industrial waste liquid cooperatively uses an industrial waste liquid incinerator to burn the industrial waste liquid; the industrial waste liquid incinerator sequentially forms a basic combustion chamber and a high-temperature incineration chamber above the hearth; the method is characterized in that: the method comprises the following steps:
(1) Biomass fuel is used as combustion-supporting fuel to be added into a hearth and burned stably;
(2) Spraying high-concentration wastewater into a basic combustion chamber in an atomized manner, attaching the basic combustion chamber to biomass fuel for pyrolysis and incineration to fix alkali salt substances in the basic combustion chamber, and keeping the temperature above the basic combustion chamber above 1100 ℃;
(3) The method comprises the steps of respectively adopting an injection atomization premix combustion technology for oil and solvent industrial waste liquid, performing atomization premix combustion through a burner, and continuously combusting atomized liquid drops carried out by sprayed flames in a high-temperature incineration chamber;
(4) Introducing low-temperature flue gas to mix before the high-temperature flue gas exits the high-temperature incineration chamber to reduce the temperature of the flue gas, premixing with urea solution to reduce NOx, and allowing the flue gas to enter a waste heat recovery device after the temperature of the flue gas is lower than the ash melting point temperature;
(5) And cooling the flue gas by a waste heat recovery device, and discharging the flue gas after meeting the discharge index by dedusting and denitration again.
2. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1, wherein the method comprises the following steps: the biomass fuel feeding amount in the step (1) is 0.2-0.5 t/h.m 2, wherein t/h.m 2 represents the biomass fuel amount per hour/the cross section area of a combustion chamber hearth of the industrial waste liquid incinerator.
3. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1 or 2, wherein the method comprises the following steps: in the step (3), the residence time of the oil and solvent industrial waste liquid in the high-temperature incineration chamber is more than 2s, so that the oil and solvent industrial waste liquid is completely combusted and decomposed.
4. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1 or 2, wherein the method comprises the following steps: in the step (2), the feeding amount of the high-concentration wastewater is 0.01-0.03 t/h.m 2, wherein t/h.m 2 represents the amount of biomass fuel per hour/the cross-sectional area of a combustion chamber hearth of the industrial waste liquid incinerator.
5. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1 or 2, wherein the method comprises the following steps: in the step (3), the feeding amount of the oil industrial waste liquid is 0.02-0.06 t/h.m 2, wherein t/h.m 2 represents the amount of biomass fuel per hour/the cross section area of a combustion chamber hearth of the industrial waste liquid incinerator; the feeding amount of the solvent industrial waste liquid is 0.01-0.05 t/h.m 2, wherein t/h.m 2 represents the amount of biomass fuel per hour/the cross section area of a combustion chamber hearth of the industrial waste liquid incinerator.
6. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1 or 2, wherein the method comprises the following steps: in the step (4), the amount of the low-temperature flue gas is controlled by taking the reduction of the flue gas temperature in the out-of-stock area to 925+/-25 ℃ as a target, and the low-temperature flue gas adopts the flue gas discharged after the induced draft fan.
7. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1 or 2, wherein the method comprises the following steps: in the step (4), the concentration of the urea solution is 15% -20%.
8. The method for heat supply by cooperatively utilizing industrial waste liquid with biomass fuel according to claim 1 or 2, wherein the method comprises the following steps: the high-concentration wastewater in the step (2) is wastewater with COD (chemical oxygen demand) of more than 1000 mg/L.
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