CN1176939A - Method and device for continuous and stable releasing chlorine dioxide - Google Patents
Method and device for continuous and stable releasing chlorine dioxide Download PDFInfo
- Publication number
- CN1176939A CN1176939A CN 96106896 CN96106896A CN1176939A CN 1176939 A CN1176939 A CN 1176939A CN 96106896 CN96106896 CN 96106896 CN 96106896 A CN96106896 A CN 96106896A CN 1176939 A CN1176939 A CN 1176939A
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- chlorine dioxide
- bottle
- citric acid
- interior device
- solution
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
This equipment for releasing chlorinedioxide is composed of bottle, bottle cover, jacket and inner set. The chlorine-dioxide solution in the bottle is socked by capilliary material into the solid citric acid in the inner set. Active chlorinedioxide gas is liberated through the action of chlorinedioxide solution and citric acid, the chlorine dioxide gas passes continuously through the hole on the bottle cover int othe space to make the space maintain sufficient concentration of chlorine dioxide so as to give full play of the functions of deodorization, antiseptic and antistaling.
Description
The present invention relates to the method and the device of a kind of release, stabilizing chlorine dioxide, particularly a kind of deodorizing, sterilization, fresh-keeping chlorine dioxide continuously, stopping reaction method for releasing and device.
Dioxide peroxide is just to have found in the last century as of great value compound.But because this compound boiling point low (11 ℃), its liquid and unstable gas, concentration is just may blast in 10% o'clock in air.Along with the extensively and profoundly research of domestic and international numerous scientific research personnel to dioxide peroxide, find that it is in sterilization, sterilization, anticorrosion, algae removal, mildew-resistant, food fresh keeping, aspect such as water quality and purifying air has nontoxic, noresidue, colourless, tasteless, there is not corrosion, free from environmental pollution, the good characteristic that waits safe in utilization, and scientific research does not find that as yet any microorganism can resist its oxygenizement and be not killed, and higher animal and people's cell is not had influence substantially, thereby by internationally recognized for chlorine is ideal renewal product in the sterilizing agent, by American-European countries and China praise highly be the 4th generation sterilizing agent.For the ease of accumulating and application, in recent years, many scientific research personnel have done further investigation to the technology of preparing of stabilizing chlorine dioxide, and succeed.Yet, though stabilizing chlorine dioxide has solved the accumulating problem, but it is still inconvenient in some aspects, thereby stabilizing chlorine dioxide in most of the cases must can be brought into play its due effect behind overactivation, so activated processing of palpus before general the application, it is discharged can play a role after having active dioxide peroxide molecule, and activation back concentration reduces (deposit all dioxide peroxide after the general activation and reduce about 40%) rapidly, troublesome poeration like this, also be difficult to drop into practical application in some occasion, the invention reside in and overcome weak point of the prior art, propose a kind of continuous, the method of stable releasing chlorine dioxide and device, (3 months-6 months) offer the homeostatic dioxide peroxide atmosphere of refrigerator in service life, and its effect is stable, efficiently.
The present invention is achieved by the following technical solutions.
A kind of continuously, the method for stable releasing chlorine dioxide, it is a raw material with capillary materials, solid citric acid, in solid citric acid, solid citric acid and ClO 2 solution reaction generate active chlorine dioxide to capillary materials with the stabilized chlorine dioxide solution absorbs.The special device that holds capillary materials, solid citric acid, ClO 2 solution is made of bottle, bottle cap with holes, overcoat, interior device, in installing in solid citric acid and capillary materials are contained in, stabilized chlorine dioxide is uniform-distribution with breather hole on the bottle cap in bottle.
The present invention is by above technical scheme, can provide a kind of continuously, the method and the device of stable releasing chlorine dioxide, solve family and be suitable for the defective that smelly in the refrigerator, bacterium, viral proliferation and food fresh-keeping time fall short of.Can improve simultaneously the abominable Air quality that family, room, hotel, toilet atmosphere draught-free cause, eliminate peculiar smell, and can effectively bring into play effects such as sterilization, sterilization, mildew-resistant.
Figure one is a structural map of the present invention;
Figure two is interior setting drawings of the present invention.
The present invention is the method and the device of a kind of release, stabilizing chlorine dioxide, comprise bottle 3, bottle cap with holes 1, overcoat 2, device 4 in one is arranged in the middle of bottle 3 and bottle cap 1, couple together with screw thread 8 between bottle cap and the interior device 4, couple together with screw thread 7 between interior device 4 and the bottle 3, the neck 11 of interior device 4 belows stretches in the bottle 3, and outer bulge loop 9 is set on the interior device 4, and overcoat 2 is fixed between outer bulge loop 9 and the bottle base 10.
In bottle 3, contain stabilized chlorine chlorine solution, seal package.In neck has the interior device of capillary sorbing material, fill solid citric acid, cover non-woven fabrics or other materials, seal package on the interior device.Face with before, with the removal of sealing of bottle,, and its neck had capillary filamentary material immerse in the stabilized chlorine chlorine solution simultaneously also with the removal of sealing of interior device, tighten and be placed on that refrigerator, family, room, hotel, toilet etc. are local to get final product.
The present invention proposes this device, stabilized chlorine chlorine solution in the bottle 3 (containing chlorine dioxide concentration is 3000-30000PPM) connection is drawn to the Solid Bed 4 (containing citric acid 0.5-3.0 gram) that is loaded with citric acid solid by wicking action, the stabilized chlorine chlorine solution is met the rapid reaction of citric acid and is discharged active chlorine dioxide, the generation of this gas is adjusted by the concentration and transport velocity capillaceous two aspects of contained dioxide peroxide in the control stabilization ClO 2 solution, and chlorine dioxide is discharged in the space by breather hole, makes usage space keep enough chlorine dioxide concentration continuously.
Claims (4)
- One kind continuously, the method for stable releasing chlorine dioxide, it is a main raw material with capillary materials (6), solid citric acid (5), it is characterized in that, in solid citric acid (5), solid citric acid (5) and ClO 2 solution reaction generate active chlorine dioxide to capillary materials (6) with the stabilized chlorine dioxide solution absorbs.
- 2. by the described release of claim 1, the method of stabilizing chlorine dioxide, it is characterized in that, the capillary materials that holds, solid citric acid, the device of ClO 2 solution is by bottle (3), bottle cap with holes (1), overcoat (2), interior device (4) constitutes, couple together with screw thread (8) between bottle cap (1) and the interior device (4), couple together with screw thread (7) between interior device (4) and the bottle (3), the neck (11) of interior device (4) below stretches in the bottle (3), on the interior device (4) outer bulge loop (9) is set, overcoat (2) is fixed between outer bulge loop and the bottle base (10).
- 3. by the method for the described release of claim 2, stabilizing chlorine dioxide, it is characterized in that, solid citric acid or acid material (5) are housed in the interior device (4) and have adsorbing capillary materials (6).
- 4. the method for, stable releasing chlorine dioxide described continuously by claim 2 is characterized in that bottle has stabilized chlorine dioxide solution in (3).5. press that claim 1 is described continuously, the method for stable releasing chlorine dioxide, it is characterized in that, be uniform-distribution with breather hole (12) on the bottle cap (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96106896 CN1176939A (en) | 1996-07-02 | 1996-07-02 | Method and device for continuous and stable releasing chlorine dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96106896 CN1176939A (en) | 1996-07-02 | 1996-07-02 | Method and device for continuous and stable releasing chlorine dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1176939A true CN1176939A (en) | 1998-03-25 |
Family
ID=5119419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96106896 Pending CN1176939A (en) | 1996-07-02 | 1996-07-02 | Method and device for continuous and stable releasing chlorine dioxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1176939A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100342792C (en) * | 1999-07-27 | 2007-10-17 | 松下冷机株式会社 | Antibacterial device and refrigerator provided therewith |
| CN101143225B (en) * | 2007-10-17 | 2010-07-28 | 艾雪莉 | Air purifying agent and its preparing process |
| WO2022110418A1 (en) * | 2020-11-30 | 2022-06-02 | 合肥美的电冰箱有限公司 | Volatilization device and storage device |
| CN114988370A (en) * | 2022-07-08 | 2022-09-02 | 陕西汉鼎辉能源材料科技有限公司 | Method and device for releasing chlorine dioxide from stable chlorine dioxide solution |
-
1996
- 1996-07-02 CN CN 96106896 patent/CN1176939A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100342792C (en) * | 1999-07-27 | 2007-10-17 | 松下冷机株式会社 | Antibacterial device and refrigerator provided therewith |
| CN101143225B (en) * | 2007-10-17 | 2010-07-28 | 艾雪莉 | Air purifying agent and its preparing process |
| WO2022110418A1 (en) * | 2020-11-30 | 2022-06-02 | 合肥美的电冰箱有限公司 | Volatilization device and storage device |
| CN114988370A (en) * | 2022-07-08 | 2022-09-02 | 陕西汉鼎辉能源材料科技有限公司 | Method and device for releasing chlorine dioxide from stable chlorine dioxide solution |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| AD01 | Patent right deemed abandoned | ||
| C20 | Patent right or utility model deemed to be abandoned or is abandoned |