CN117559025B - Battery material aging mechanism and waste battery recycling device - Google Patents

Battery material aging mechanism and waste battery recycling device Download PDF

Info

Publication number
CN117559025B
CN117559025B CN202410040783.XA CN202410040783A CN117559025B CN 117559025 B CN117559025 B CN 117559025B CN 202410040783 A CN202410040783 A CN 202410040783A CN 117559025 B CN117559025 B CN 117559025B
Authority
CN
China
Prior art keywords
assembly
ultraviolet light
material conveying
battery
aging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202410040783.XA
Other languages
Chinese (zh)
Other versions
CN117559025A (en
Inventor
郑伟鹏
丁柏栋
林晓杰
施荣锐
韦秀溪
陈发燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Jiecheng New Energy Material Technology Co ltd
Original Assignee
Guangdong Jiecheng New Energy Material Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Jiecheng New Energy Material Technology Co ltd filed Critical Guangdong Jiecheng New Energy Material Technology Co ltd
Priority to CN202410040783.XA priority Critical patent/CN117559025B/en
Publication of CN117559025A publication Critical patent/CN117559025A/en
Application granted granted Critical
Publication of CN117559025B publication Critical patent/CN117559025B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • B09B3/35Shredding, crushing or cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/50Destroying solid waste or transforming solid waste into something useful or harmless involving radiation, e.g. electro-magnetic waves
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/52Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/15Electronic waste
    • B09B2101/16Batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The application relates to a battery material ageing mechanism and waste battery recovery unit, battery material ageing mechanism includes ageing box, material conveying component, ultraviolet light source subassembly, ozone generator and turns over the material subassembly. The material conveying assembly conveys broken battery materials along the conveying direction, the ultraviolet light source assembly is arranged in the aging cavity and is located above the material conveying assembly, the ozone generator can introduce ozone into the aging cavity, and the battery materials on the material conveying assembly can be located in an environment irradiated by ozone and ultraviolet light. Aging of the adhesive is realized under the irradiation of ozone and ultraviolet light, and the ultraviolet light can promote the generation or decomposition of the ozone, so that the oxidation effect is further enhanced. In the conveying process, the material turning component turns the battery material on the material conveying component, so that the battery material is in full contact with ozone and ultraviolet light, and the conveying of the material conveying component is not affected. The equipment has low requirements on high temperature resistance and low energy consumption.

Description

Battery material aging mechanism and waste battery recycling device
Technical Field
The application relates to the technical field of battery recovery, in particular to a battery material aging mechanism and a waste battery recovery device.
Background
Along with the wide application of new energy, the application of the battery in various fields is more and more common, and further, the recycling of the waste battery is also urgent from the aspects of environmental protection and sustainable development. Electrode material particles of positive and negative electrode plates of the battery are bonded on a current collector material through an organic binder, and the organic binder has excellent physical and chemical properties and can ensure that the electrode material particles cannot easily fall off from the current collector. And it is difficult to thoroughly peel the electrode material particles from the current collector by the conventional recycling method through the mechanical crushing method. Therefore, one way is to place the disassembled battery cell in an ultralow temperature environment, improve the brittleness of the battery material by utilizing the characteristics of the material after embrittlement at low temperature, and then break the battery material more easily during mechanical breaking, so as to improve the falling-off efficiency of the electrode material and further improve the separation efficiency. The other mode is pyrolysis, namely the electrode plate obtained by disassembly is pyrolyzed in a pyrolysis furnace, volatile substances in the binder can be evaporated or volatilized in a high-temperature environment, so that the binder is invalid, the electrode active substances are easy to fall off, and the organic binder is conveniently removed to obtain the electrode active material and the current collector material.
However, the above two types of embrittlement at low temperature or aging at high temperature often require high demands on external equipment, and there are safety problems in low-temperature and high-temperature environments, and thus demands on the safety of the equipment.
Disclosure of Invention
In view of the above, it is necessary to provide a battery material aging mechanism and a waste battery recycling apparatus that reduce the demands on equipment.
The battery material aging mechanism comprises an aging box body, a material conveying assembly, an ultraviolet light source assembly, an ozone generator and a turning assembly, wherein an aging cavity is formed in the aging box body, an air inlet and an air outlet are formed in the aging cavity, and the air inlet and the air outlet are communicated with the aging cavity; the material conveying assembly is arranged in the aging cavity and is used for conveying battery materials along the conveying direction; the ultraviolet light source component is arranged in the aging cavity and is positioned above the material conveying component, and the ultraviolet light source component is used for emitting ultraviolet light to the material conveying component; the ozone generator is used for generating ozone, and the exhaust end of the ozone generator is connected to the air inlet of the aging box body; the material turning assembly is arranged in the aging cavity and is used for turning the battery materials on the material conveying assembly.
In one embodiment, the material turning component comprises a rotating piece and a material turning piece, one side edge of the material turning piece is connected to the rotating piece, the rotating piece is used for driving the material turning piece to rotate relative to the material conveying component, and the rotating axis of the rotating piece is intersected with the conveying direction.
In one embodiment, the material turning member comprises a connecting portion and a hook portion, one side edge of the connecting portion is connected with the rotating member, the other opposite side edge is connected with the hook portion, when the material turning member rotates to the side, facing the material conveying assembly, of the rotating member, the direction of the concave surface in the hook portion is opposite to the conveying direction, and the rotating direction of the rotating member is consistent with the direction of the concave surface in the hook portion.
In one embodiment, the material turning component is located above the material conveying component, the material turning component further comprises an elastic component, the material turning component is connected to the rotating component through the elastic component, the elastic component is used for applying elastic force to the material turning component along a direction away from the rotating component, and when the material turning component rotates to a side, facing the material conveying component, of the rotating component, the material turning component can be abutted to the material conveying component.
In one embodiment, the number of the material conveying assemblies is at least two, each material conveying assembly is arranged at intervals up and down, the discharging end of the material conveying assembly above is opposite to the feeding end of the material conveying assembly below, and the material turning assembly is arranged between the discharging end of the material conveying assembly above and the feeding end of the material conveying assembly below; the number of the ultraviolet light source components is consistent with that of the material conveying components, and each ultraviolet light source component is used for emitting ultraviolet light to the corresponding material conveying component.
In one embodiment, the material turning component further comprises a material receiving hopper, an opening at one end of the material receiving hopper is in butt joint with a discharging end of the material conveying component located above, an opening at the other end of the material receiving hopper is in butt joint with a feeding end of the material conveying component located below, and the rotating piece and the material turning piece are both arranged in the material receiving hopper.
In one embodiment, the ultraviolet light source assembly includes a first ultraviolet light source and at least two second ultraviolet light sources, the first ultraviolet light source is configured to emit ultraviolet light with a wavelength of 170nm-200nm, the second ultraviolet light source is configured to emit ultraviolet light with a wavelength of 250nm-400nm, all the second ultraviolet light sources are disposed at intervals along the conveying direction, and the first ultraviolet light source is disposed between two adjacent second ultraviolet light sources.
In one embodiment, the air inlet is arranged at a position close to the discharging end of the material conveying assembly, and the air outlet is arranged at a position close to the feeding end of the material conveying assembly, so that the flowing direction of the ozone in the aging cavity is opposite to the conveying direction of the material conveying assembly; along the conveying direction, the length of the second ultraviolet light source tends to increase.
In one embodiment, the battery material aging mechanism further comprises a heating assembly disposed within the aging chamber, the heating assembly configured to heat the material handling assembly.
The waste battery recycling device comprises a crushing mechanism, the battery material aging mechanism and the screening mechanism, wherein the crushing mechanism is used for crushing waste batteries; the battery material aging mechanism is arranged at the downstream of the crushing mechanism, and the material loading end of the material conveying assembly is in butt joint with the material discharging end of the crushing mechanism; the screening mechanism is arranged at the downstream of the battery material aging mechanism, the discharging end of the material conveying assembly is in butt joint with the feeding end of the screening mechanism, and the screening mechanism is used for screening battery materials.
Above-mentioned battery material ageing mechanism and junked battery recovery unit will throw to the material loading end of material conveying subassembly after the breakage of broken mechanism, and then throw into ageing intracavity of ageing box, material conveying subassembly carries broken battery material along the direction of delivery. Because the ultraviolet light source component is arranged in the ageing cavity and is positioned above the material conveying component, the ozone generator can be used for introducing ozone into the ageing cavity, so that the battery material on the material conveying component is in an environment irradiated by ozone and ultraviolet light. The electrode particles in the battery material are generally adhered to the current collector through the adhesive, so that the adhesive can be oxidized and disabled rapidly under the action of ozone on one hand, and photo-oxidative aging of the adhesive is realized by ultraviolet irradiation on the other hand, and the ultraviolet light can promote the generation or decomposition of the ozone, so that the oxidation of the ozone is further enhanced, the aging of the adhesive is effectively accelerated, and the electrode material is more easily stripped from the current collector. In the process of conveying battery materials by the material conveying assembly, the battery materials on the material conveying assembly are turned through the turning assembly, so that the battery materials are in full contact with ozone and ultraviolet light, the ageing reliability of the binder is guaranteed, the conveying of the material conveying assembly is not affected, and the material conveying assembly is suitable for assembly line machining. The battery material aging mechanism and the waste battery recycling device can be used for avoiding low-temperature or high-temperature treatment, and also avoid the safety problem caused by high temperature or low temperature. The battery material aging mechanism and the waste battery recycling device have low requirements on high temperature resistance and low energy consumption.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention.
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings required for the description of the embodiments will be briefly described below, and it is apparent that the drawings in the following description are only some embodiments of the present invention, and other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
Moreover, the figures are not drawn to a 1:1 scale, and the relative sizes of various elements are merely exemplary in the figures, and are not necessarily drawn to true scale. In the drawings:
fig. 1 is a schematic structural view of a battery material aging mechanism in an embodiment.
Fig. 2 is a schematic structural view of the material turning assembly in fig. 1.
Fig. 3 is a side cross-sectional view of the battery material aging mechanism shown in fig. 1.
Fig. 4 is a partial schematic structural view of a battery material aging mechanism in another embodiment.
Fig. 5 is an enlarged view of a partial structure of the battery material aging mechanism shown in fig. 4.
FIG. 6 is a schematic diagram of an ozone generator, a heat pump assembly, and a cooling assembly in an embodiment.
Reference numerals illustrate:
a battery material aging mechanism 10; an aging box 100; an aging chamber 110; an air inlet 120; an exhaust port 130; a material conveying assembly 200; an ultraviolet light source assembly 300; a first ultraviolet light source 310; a second ultraviolet light source 320; an ozone generator 400; an exhaust end 410; a turning assembly 500; a rotating member 510; a material turning piece 520; a connecting portion 522; a hook 524; an elastic member 530; a receiving hopper 540; arcuate baffles 542; a receiving portion 544; a heating assembly 600; a first heater 610; a second heater 620; a heat pump assembly 700; a compressor 710; a condenser 720; a throttling element 730; an evaporator 740; a cooling assembly 800; a cooling unit 810; a first cooler 812; a second cooler 814; a heat exchanger 820; cooling drives pump 830.
Detailed Description
In order to make the above objects, features and advantages of the present application more comprehensible, embodiments accompanied with figures are described in detail below. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present application. This application is, however, susceptible of embodiment in many other forms than those described herein and similar modifications can be made by those skilled in the art without departing from the spirit of the application, and therefore the application is not to be limited to the specific embodiments disclosed below.
Referring to fig. 1, the waste battery recycling device in an embodiment of the present application can at least reduce the requirements of high temperature resistance and low temperature resistance of equipment, and reduce energy consumption. The waste battery recycling device comprises a crushing mechanism, a battery material aging mechanism 10 and a screening mechanism, wherein the crushing mechanism is used for crushing waste batteries; the battery material aging mechanism 10 is arranged at the downstream of the crushing mechanism, and the charging end of the battery material aging mechanism 10 is in butt joint with the discharging end of the crushing mechanism; the discharge end of the battery material aging mechanism 10 interfaces with the feed end of a screening mechanism for screening battery material.
The crushing mechanism can crush the waste batteries, crushed battery materials are thrown to the feeding end of the battery material aging mechanism 10 from the discharging end of the crushing mechanism, the battery material aging mechanism 10 is used for aging binders in the battery materials, the efficiency and the effect of separating electrode particles from a current collector are improved, and the screening mechanism can effectively separate the electrode particles from the current collector.
In one embodiment, the battery material aging mechanism 10 includes an aging box 100, a material conveying assembly 200, an ultraviolet light source assembly 300, an ozone generator 400 and a material turning assembly 500, an aging cavity 110 is formed in the aging box 100, an air inlet 120 and an air outlet 130 are formed in the aging cavity 110, and the air inlet 120 and the air outlet 130 are both communicated with the aging cavity 110. The material conveying assembly 200 is arranged in the ageing cavity 110, and the material conveying assembly 200 is used for conveying battery materials along the conveying direction a; the ultraviolet light source assembly 300 is disposed in the aging chamber 110 and above the material conveying assembly 200, and the ultraviolet light source assembly 300 is configured to emit ultraviolet light to the material conveying assembly 200; the ozone generator 400 is used for generating ozone, and the exhaust end 410 of the ozone generator 400 is connected to the air inlet 120 of the aging oven 100; the material turning assembly 500 is disposed in the aging chamber 110, and the material turning assembly 500 is used for turning the battery material on the material conveying assembly 200.
Specifically, the feeding end of the material conveying assembly 200 is abutted against the discharging end of the crushing mechanism, and the discharging end of the material conveying assembly 200 is abutted against the feeding end of the screening mechanism.
When the battery material conveying device is used, battery materials crushed by the crushing mechanism are thrown to the feeding end of the material conveying assembly 200, and then are thrown into the aging cavity 110 of the aging box body 100, and the material conveying assembly 200 conveys the crushed battery materials along the conveying direction a. Because the ultraviolet light source assembly 300 is disposed in the aging chamber 110 and above the material handling assembly 200, the ozone generator 400 is capable of supplying ozone to the aging chamber 110, such that the battery material on the material handling assembly 200 is in an environment where ozone and ultraviolet light are irradiated. The electrode particles in the battery material are generally adhered to the current collector through the adhesive, so that the adhesive can be oxidized and disabled rapidly under the action of ozone on one hand, and photo-oxidative aging of the adhesive is realized by ultraviolet irradiation on the other hand, and the ultraviolet light can promote the generation or decomposition of the ozone, so that the oxidation of the ozone is further enhanced, the aging of the adhesive is effectively accelerated, and the electrode material is more easily stripped from the current collector. In the process of conveying the battery material by the material conveying assembly 200, the battery material on the material conveying assembly 200 is turned by the turning assembly 500, so that the battery material is fully contacted with ozone and ultraviolet light, the reliability of aging of the binder is ensured, the conveying of the material conveying assembly 200 is not influenced, and the material conveying assembly is suitable for assembly line processing. The battery material aging mechanism 10 and the waste battery recycling device do not need to be subjected to low-temperature or high-temperature treatment, and the safety problem caused by high temperature or low temperature does not exist. The battery material aging mechanism 10 and the waste battery recycling device have low requirements on high temperature resistance and low energy consumption.
Referring to fig. 1 to 3, in an embodiment, the material turning assembly 500 is located above the material conveying assembly 200, so that the battery material is turned from above the material conveying assembly 200 by using the material turning assembly 500, and the aging effect on the adhesive is improved.
In an embodiment, the material turning assembly 500 includes a rotating member 510 and a material turning member 520, one side of the material turning member 520 is connected to the rotating member 510, the rotating member 510 is used for driving the material turning member 520 to rotate relative to the material conveying assembly 200, and a rotation axis of the rotating member 510 intersects with the conveying direction a. In the process of driving the turning piece 520 to rotate by the turning piece 510, the rotation axis of the turning piece 510 is intersected with the conveying direction a, so that the turning piece 520 can be utilized to stir or scoop up the battery material on the material conveying assembly 200, the battery material is turned over along with the rotation of the turning piece 510, or the scooped battery material is poured into the material conveying assembly 200 after rotating, the turning effect on the battery material is realized, and the contact effect between the battery material and ozone and ultraviolet light is enhanced.
In one embodiment, the number of the turning pieces 520 is at least two, and all the turning pieces 520 are spaced around the rotation axis of the rotating piece 510. Specifically, all of the turning pieces 520 are uniformly arranged around the rotation axis of the rotating piece 510. As shown in fig. 2, the number of the material turning pieces 520 is four. In other embodiments, the material turner 520 may be one.
In this embodiment, the material turning piece 520 includes a connecting portion 522 and a hook portion 524, one side of the connecting portion 522 is connected to the rotating member 510, the other opposite side is connected to the hook portion 524, and when the material turning piece 520 rotates to a side of the rotating member 510 facing the material conveying assembly 200, the concave surface of the hook portion 524 faces the conveying direction a. Specifically, the rotation direction of the rotation member 510 coincides with the direction of the concave surface in the hook portion 524. Since the concave surface of the hook portion 524 is opposite to the conveying direction a, the material conveying assembly 200 is capable of conveying the battery material into the hook portion 524 along the conveying direction a when the hook portion 524 contacts the material conveying assembly 200. Because the rotation direction of the rotating member 510 is consistent with the direction of the concave surface of the hook portion 524, the rotating member 510 can drive the hook portion 524 to rotate with the battery material and then to fall to the material conveying assembly 200, so as to achieve the effect of turning the battery material on the material conveying assembly 200. The provision of the hooks 524 facilitates improved reliability of battery material scooped up by the material handling assembly 200.
In other embodiments, the material turning piece 520 may be of other structural types, so long as the battery material on the material conveying assembly 200 can be turned in the process of driving the material turning piece 520 to rotate by the rotating piece 510, so as to achieve the purpose of turning.
In an embodiment, the material turning assembly 500 is located above the material conveying assembly 200, the material turning assembly 500 further includes an elastic member 530, the material turning member 520 is connected to the rotating member 510 through the elastic member 530, the elastic member 530 is configured to apply an elastic force to the material turning member 520 along a direction away from the rotating member 510, and when the material turning member 520 rotates to a side of the rotating member 510 facing the material conveying assembly 200, the material turning member 520 can be abutted against the material conveying assembly 200. When the turning piece 510 drives the turning piece 520 to rotate to one side facing the material conveying assembly 200, the elastic piece 530 can enable the turning piece 520 to contact with the material conveying assembly 200 at a certain rotation angle, so that the amount of battery materials scooped up by the turning piece 520 is increased, and the turning effect is improved. For example, when the material turning piece 520 is 5 degrees to 20 degrees from the vertical, the material turning piece 520 may contact the material conveying assembly 200. In other embodiments, the material mover 520 contacts the material delivery assembly 200 when the material mover 520 is at other angles to the vertical.
In this embodiment, the elastic member 530 may be an elastic structure such as a spring or a spring plate, so long as the material turning member 520 can be guaranteed to contact with the material conveying assembly 200 at a certain rotation angle.
In this embodiment, the number of the material turning assemblies 500 may be at least two, and each material turning assembly 500 is disposed at intervals along the conveying direction a. Through setting up two at least stirring subassemblies 500, can increase the stirring number of times, and then increase the stirring effect to battery material.
In one embodiment, the battery material aging mechanism 10 may further include a scraping assembly (not shown) disposed behind the material turning assembly 500 in the conveying direction a, the scraping assembly being disposed above the material conveying assembly 200 with a gap therebetween with the material conveying assembly 200. After the battery material is overturned by the overturning assembly and poured on the material conveying assembly 200, the material conveying assembly 200 drives the battery material to pass through the scraping assembly, the overturned battery material can be scraped on the material conveying assembly 200 by the scraping assembly, the contact area of the battery material with ozone and ultraviolet light is further improved, and the battery material is prevented from being stacked on the material conveying assembly 200 after being overturned.
In one embodiment, the screeding assembly may include a squeegee vertically disposed above the material delivery assembly 200 and having a gap with the material delivery assembly 200. In other embodiments, the screeding assembly may comprise a roller disposed above the material conveying assembly 200 with a gap between an outer surface of the roller and the material conveying assembly 200, the axis of rotation of the roller intersecting the conveying direction a.
Referring to fig. 4 and 5, in one embodiment, the number of the material conveying assemblies 200 is at least two, each material conveying assembly 200 is disposed at an upper and a lower interval, the discharging end of the material conveying assembly 200 located above is opposite to the feeding end of the material conveying assembly 200 located below, and the material turning assembly 500 is disposed between the discharging end of the material conveying assembly 200 above and the feeding end of the material conveying assembly 200 below. The number of uv light source assemblies 300 corresponds to the number of material transport assemblies 200, and each uv light source assembly 300 is configured to emit uv light toward a corresponding material transport assembly 200.
Because the aging of the battery material requires a certain time, and the material conveying assembly 200 is in the process of the production line, the material conveying assembly 200 needs to be started to continuously convey the battery material, and the material conveying assembly 200 needs a certain length to meet the aging time requirement of the battery material. By providing at least two material conveying assemblies 200, on the one hand, it is advantageous to reduce the length of a single material conveying assembly 200, and thus to facilitate a compact arrangement of the structure. On the other hand, if only one material handling assembly 200 is provided, ozone enters from one end of the material handling assembly 200 and flows along the length of the material handling assembly 200 to the other end, resulting in a greater concentration variation of ozone along the length of the material handling assembly 200. In this embodiment, the material conveying assembly 200 is arranged in at least two, the length of the single material conveying assembly 200 is shortened, and the distance from one end of the material conveying assembly 200 to the other end is shortened, so that the ozone concentration in the aging cavity 110 is more uniform, and oxidation of battery materials is facilitated. In this embodiment, the material turning assembly 500 is disposed at the joint between two material conveying assemblies 200, and the battery material is turned during the process of transferring from one material conveying assembly 200 to another material conveying assembly 200, so that not only the turning effect can be improved, but also the turning assembly can directly contact and rub with the material conveying assemblies 200, and the structural stability of the material conveying assemblies 200 is ensured.
For example, in this embodiment, the number of the material conveying assemblies 200 is three, the three material conveying assemblies 200 are arranged up and down at intervals, the number of the material turning assemblies 500 is two, and the two material turning assemblies 500 are respectively arranged at the connection positions of the two material conveying assemblies 200, so that two material turning can be realized. In other embodiments, the number of material handling assemblies 200 may be two, four, etc. as well.
In this embodiment, the scraping assembly is disposed behind the feeding end of the material conveying assembly 200 below, and a gap is formed between the scraping assembly and the corresponding material conveying assembly 200. When battery material falls behind the material loading end of material conveying assembly 200 of below by material conveying assembly 200 of top, material conveying assembly 200 of below drives battery material and scrapes the subassembly through scraping, utilizes and scrapes the subassembly and can scrape the battery material after overturning on material conveying assembly 200, avoids battery material to pile up on material conveying assembly 200.
In an embodiment, the material turning assembly 500 further includes a receiving hopper 540, one end opening of the receiving hopper 540 is abutted to the discharging end of the material conveying assembly 200 located above, the other end opening of the receiving hopper 540 is abutted to the feeding end of the material conveying assembly 200 located below, and the rotating member 510 and the material turning member 520 are both disposed in the receiving hopper 540. Through setting up the receiving hopper 540, can make the battery material flow to the material loading end of the material conveying assembly 200 that is located the below behind the stirring piece 520 effectively, guarantee battery material stirring and stability of forwarding.
Specifically, the receiving hopper 540 includes a curved baffle 542 and a receiving portion 544, the concave surface of the curved baffle 542 faces the discharging end of the upper material conveying assembly 200, and one side edge of the curved baffle 542 is located above the discharging end of the material conveying assembly 200, the other side edge is connected to the receiving portion 544, an opening above the receiving portion 544 is communicated with one side of the concave surface of the curved baffle 542, the cross-sectional dimension of the space in the receiving portion 544 tends to be reduced from top to bottom, and the rotating member 510 and the turning member 520 are both disposed in the receiving portion 544. By providing the arcuate baffle 542, it is possible to ensure that the battery material dropped from the discharge end of the upper material handling assembly 200 effectively falls into the receiving portion 544 and that the material turning member 520 does not turn the battery material out of the receiving hopper 540 when rotated. While the cross-sectional size of the space within the receiving portion 544 tends to decrease from top to bottom, ensuring the reliability of the battery material falling on the loading end of the lower material handling assembly 200.
In one embodiment, as shown in fig. 1, the air inlet 120 is disposed near the feeding end of the material conveying assembly 200, and the air outlet 130 is disposed near the feeding end of the material conveying assembly 200, so that the flowing direction b of ozone in the aging chamber 110 is opposite to the conveying direction a. By reversing the flow direction b of ozone in the aging chamber 110 to the transport direction a of the battery material, the battery material having a higher temperature after heating can be reacted with ozone having a higher concentration. At higher temperature, ozone can be rapidly decomposed into oxygen and active oxygen, and active oxygen atoms have strong oxidation, so that more effective and strong oxidation reaction can be generated with the binder with higher temperature, and the aging speed of the binder is improved. At the loading end of the material conveying assembly 200, the temperature of the battery material is relatively low, so that the ozone concentration is increased, on the one hand, the ozone decomposition effect is poor, and on the other hand, the oxidation reaction effect of the battery material at a lower temperature is also poor.
In another embodiment, as shown in fig. 4, the air inlet 120 is provided near the discharge end of the uppermost material handling assembly 200, and the air outlet 130 is provided near the feed end of the uppermost material handling assembly 200. Specifically, the number of the air inlets 120 and the air outlets 130 may be identical to the number of the material conveying assemblies 200, and the plurality of air inlets 120 and the air outlets 130 are arranged at intervals along the vertical direction, so that the stable ozone can circulate above each material conveying assembly 200.
As shown in fig. 1, in an embodiment, the uv light source assembly 300 includes a first uv light source 310 and at least two second uv light sources 320, the first uv light source 310 is configured to emit uv light with a wavelength of 170nm-200nm, the second uv light source 320 is configured to emit uv light with a wavelength of 250nm-400nm, all the second uv light sources 320 are disposed at intervals along the conveying direction a, and the first uv light source 310 is disposed between two adjacent second uv light sources 320. Because ozone generates oxygen and active oxygen atoms after decomposition, the concentration of ozone tends to decrease along the flowing direction b of ozone, and the concentration of oxygen increases as the reaction proceeds, oxygen can be further converted into ozone under the ultraviolet light of 170nm-200nm wavelength emitted by the first ultraviolet light source 310, so as to increase the concentration of ozone, and ozone can be further decomposed to obtain oxygen and active oxygen atoms under the ultraviolet light of 250nm-400nm wavelength emitted by the second ultraviolet light source 320. With the progress of the oxidation reaction, the concentration of ozone and the effect of the oxidation reaction can be effectively improved by arranging the second ultraviolet light source 320, the first ultraviolet light source 310 and the second ultraviolet light source 320 to sequentially and alternately decompose and generate ozone.
Specifically, the first ultraviolet light source 310 is configured to emit ultraviolet light having a wavelength of 185 nm. Or the first ultraviolet light source 310 may emit ultraviolet light at other wavelengths effective to promote ozone generation.
Specifically, the second ultraviolet light source 320 is configured to emit ultraviolet light having a wavelength of 300nm to 400nm, and at this wavelength, the second ultraviolet light source 320 can effectively promote photooxidation reaction of the adhesive, and at the same time has an effect of decomposing ozone. Alternatively, the second ultraviolet light source 320 is configured to emit ultraviolet light having a wavelength of 250nm to 300nm, at which the second ultraviolet light source 320 is capable of effectively promoting decomposition of ozone while simultaneously achieving photooxidation of the adhesive. In this embodiment, the binder is PVDF (polyvinylidene fluoride) and the second ultraviolet light source 320 is configured to emit ultraviolet light at a wavelength of 370 nm. In other embodiments, the wavelength emitted by the second ultraviolet light source 320 may also be selected based on the band of ultraviolet light to which the adhesive is susceptible to aging.
In the present embodiment, the length of the second ultraviolet light source 320 tends to increase along the conveying direction a. Since the concentration of ozone tends to increase along the conveying direction a, the length of the second uv light source 320 is increased at the position of the material conveying assembly 200 at or near the discharging end, which can increase the distance of the reaction of ozone decomposition oxidation and increase the effect of the second uv light source 320 on the photo-oxidation reaction of the binder. As the concentration of ozone decreases, the length of the second uv light source 320 needs to be decreased, increasing the number or length of the first uv light sources 310, and thus increasing the generation of ozone.
In this embodiment, the length of the second ultraviolet light source 320 is longer than that of the first ultraviolet light source 310, so as to ensure the photooxidation effect and the ozonolysis oxidation effect.
As shown in fig. 4, in this embodiment, when the number of the material transporting assemblies 200 is at least two and the number of the ultraviolet light source assemblies 300 is identical to the number of the material transporting assemblies 200, the length of the second ultraviolet light source 320 tends to decrease in the circulation direction b of ozone. As the concentration of ozone decreases, the length of the second uv light source 320 needs to be decreased, increasing the number or length of the first uv light sources 310, and thus increasing the generation of ozone.
In an embodiment, if the second uv light source 320 is a strip lamp, the length of the second uv light source 320 is the length of the strip lamp, and if the second uv light source 320 is composed of a plurality of lamp beads, the length of the second uv light source 320 is the arrangement length of the plurality of lamp beads.
Referring to fig. 1 and 4, in one embodiment, the battery material aging mechanism 10 further includes a heating element 600, the heating element 600 is disposed in the aging chamber 110, and the heating element 600 is used for heating the material conveying element 200.
Ozone can be rapidly decomposed into oxygen and active oxygen, and active oxygen atoms have strong oxidation effect and can be combined with unsaturated bonds in the adhesive, so that the molecular chains of the adhesive are broken in the combining stage, and the ageing of the high-molecular adhesive is caused. The adhesive will change in two ways after being heated: one is physical change, the thermoplastic resin with a linear structure is expressed as rotation and melting, and the thermosetting resin is expressed as larger deformation under the action of external force; the other is chemical change, which is mainly represented by thermal decomposition, and oxygen is generated in the oxidation reaction process due to ozone, and the binder is promoted to be simultaneously subjected to oxidative cleavage in the thermal decomposition state. Under the condition of heating and oxygen-containing, the binder is easier to generate photochemical reaction under ultraviolet light, the ultraviolet light can trigger the binder to generate photochemical reaction so that molecular chains are decomposed and crosslinked irreversibly to generate chemical change, and if chain decomposition is dominant, the binder can be softened; if crosslinking predominates, the binder becomes brittle. The aging mechanism 10 for battery material is enhanced by the mutual promotion of ozone, ultraviolet light and heat, so that the effect of using the three materials independently is achieved. In the embodiment, the method of accelerating the aging of the adhesive by ultraviolet irradiation in the ozone environment can improve the crushing and separation efficiency of the electrode material to more than 95%.
In this embodiment, the heating temperature of the heating element 600 may be lower than the heating temperature of the battery material aging mechanism 10 alone by using only the heating element 600, so that the same or better aging effect can be achieved.
As shown in fig. 1 and 4, in an embodiment, the heating assembly 600 includes a first heater 610 and at least two second heaters 620, all the second heaters 620 are disposed at intervals along the conveying direction a of the material conveying assembly 200, the first heater 610 is disposed between two adjacent second heaters 620, and the position of the first heater 610 corresponds to the position of the first uv light source 310, and the position of each second heater 620 corresponds to the position of one second uv light source 320. Under the heating condition, the decomposition of ozone can be promoted, so that the effect of promoting the oxidative aging of the adhesive can be ensured by keeping the second heater 620 on at the position corresponding to the second ultraviolet light source 320, and the generation of ozone by promoting oxygen is required at the position corresponding to the first ultraviolet light source 310, so that the first heater 610 can be selected to be turned off, so that the temperature of the position corresponding to the first ultraviolet light source 310 can be properly reduced, and the generation of ozone can be promoted.
In this embodiment, the material conveying assembly 200 includes a conveying belt 210, a driving wheel 220 and a driven wheel 230, the conveying belt 210 is wound around the driving wheel 220 and the driven wheel 230, the heating assembly 600 is disposed between the driving wheel 220 and the driven wheel 230 and between the upper conveying belt 210 and the lower conveying belt 210, and the first heater 610 and the second heater 620 are arranged along the length direction of the conveying belt 210. Since the battery material is placed on the upper conveyor belt 210, the distance between the first heater 610 and the second heater 620 and the battery material can be shortened by providing the first heater 610 and the second heater 620 between the upper conveyor belt 210 and the lower conveyor belt 210, and the heating effect on the battery material can be improved.
In other embodiments, the material conveying assembly 200 may be of other types of structures, such as roller conveying structures, so long as the conveyance of the battery material is enabled.
Referring to fig. 1 and 6, in an embodiment, the battery material aging mechanism 10 further includes a heat pump assembly 700 and a cooling assembly 800, the cooling assembly 800 is disposed on a side wall of the aging chamber 100 where the uv light source assembly 300 is disposed, and is used for cooling the uv light source assembly 300, and the heat pump assembly 700 is connected to the cooling assembly 800 and is used for cooling the cooling assembly 800. Because the uv light source assembly 300 is disposed in the aging chamber 110, and the heating assembly 600 is used for heating the aging chamber 110, the uv light source assembly 300 is affected by the heat of the uv light source assembly 300, and the temperature of the uv light source assembly 300 is high, which affects the stability of use. By providing the cooling assembly 800 to cool the uv light source assembly 300, the reliability of the use of the uv light source assembly 300 can be improved.
Specifically, cooling assembly 800 is further disposed on ozone generator 400 and is configured to cool ozone generator 400. Further, the ozone generator 400 is installed on the outer wall of the aging box 100 on the side where the ultraviolet light source assembly 300 is provided. The ozone generator 400 also needs to be cooled when in use, so that the ozone generator 400 is installed on the outer wall of the aging box 100 on the side where the ultraviolet light source assembly 300 is arranged, the installation space of the cooling assembly 800 can be saved, and the ozone generator 400 is cooled while the ultraviolet light source assembly 300 is cooled.
Further, the cooling assembly 800 includes a cooling unit 810, a heat exchanger 820 and a cooling driving pump 830, the cooling unit 810, the heat exchanger 820 and the cooling driving pump 830 are connected to form a cooling medium circulation loop, the cooling unit 810 is disposed on a side wall of the aging box 100, the heat pump assembly 700 is connected between the cooling unit 810 and the heat exchanger 820, and the cooling driving pump 830 is used for driving the cooling medium to flow in a direction from the heat exchanger 820 to the heat pump assembly 700, and the gas exhausted from the exhaust end 410 of the ozone generator 400 can enter the air inlet 120 of the aging box 100 through the heat exchanger 820. When the cooling device is used, the relatively hot cooling medium subjected to heat exchange by the cooling unit 810 enters the heat exchanger 820, and part of heat of the cooling medium can be absorbed by ozone discharged from the heat exchanger 820 and enters the aging cavity 110, so that heat recovery after heat exchange of the cooling medium is realized. The cooling medium passing through the heat exchanger 820 is cooled by the heat pump assembly 700 and then enters the cooling unit 810 again to cool the ultraviolet light source assembly 300 and the ozone generator 400. By providing the heat exchanger 820, heat recovery is effectively achieved, energy consumption in the aging chamber 110 is reduced, and energy consumption of the heat pump assembly 700 is reduced.
In the present embodiment, the heat exchanger 820 is disposed near the air inlet 120 of the aging oven 100. Because ozone is easily decomposed after being heated, so that the heated ozone can enter the aging cavity 110 at a short distance, the oxidation effect of the ozone decomposed active oxygen is ensured.
In one embodiment, the cooling unit 810 includes a first cooler 812 and a second cooler 814, the first cooler 812 and the second cooler 814 are connected in parallel in the cooling medium circulation loop, wherein the first cooler 812 is disposed on a sidewall of the aging oven 100 where the uv light source assembly 300 is disposed, and the second cooler 814 is disposed adjacent to the first cooler 812 and is mounted on the ozone generator 400. Specifically, the heat pump assembly 700 includes a compressor 710, a condenser 720, a throttling element 730, and an evaporator 740, wherein the compressor 710, the condenser 720, the throttling element 730, and the evaporator 740 are sequentially connected to form a refrigerant circulation loop, and the evaporator 740 is disposed between the heat exchanger 820 and the cooling unit 810. The first cooler 812 can cool the ultraviolet light source assembly 300, the second cooler 814 can cool the ozone generator 400, and the first cooler 812 and the second cooler 814 are arranged adjacently, so that the installation space can be reduced, and the compactness of the structure is facilitated.
In the description of the present application, it should be understood that, if there are terms such as "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc., these terms refer to the orientation or positional relationship based on the orientation or positional relationship shown in the drawings, for convenience of description and simplification of description only, and do not indicate or imply that the mechanism or element referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the present application.
Furthermore, the terms "first," "second," and the like, if any, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include at least one such feature. In the description of the present application, the terms "plurality" and "a plurality" if any, mean at least two, such as two, three, etc., unless specifically defined otherwise.
In this application, unless explicitly stated and limited otherwise, the terms "mounted," "connected," "secured," and the like are to be construed broadly. For example, the two parts can be fixedly connected, detachably connected or integrated; can be mechanically or electrically connected; either directly or indirectly, through intermediaries, or both, may be in communication with each other or in interaction with each other, unless expressly defined otherwise. The specific meaning of the terms in this application will be understood by those of ordinary skill in the art as the case may be.
In this application, unless expressly stated or limited otherwise, the meaning of a first feature being "on" or "off" a second feature, and the like, is that the first and second features are either in direct contact or in indirect contact through an intervening medium. Moreover, a first feature being "above," "over" and "on" a second feature may be a first feature being directly above or obliquely above the second feature, or simply indicating that the first feature is level higher than the second feature. The first feature being "under", "below" and "beneath" the second feature may be the first feature being directly under or obliquely below the second feature, or simply indicating that the first feature is less level than the second feature.
It will be understood that if an element is referred to as being "fixed" or "disposed" on another element, it can be directly on the other element or intervening elements may also be present. If an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. The terms "vertical," "horizontal," "upper," "lower," "left," "right," and the like as used herein, if any, are for descriptive purposes only and do not represent a unique embodiment.
The technical features of the above-described embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above-described embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The above examples only represent a few embodiments of the present application, which are described in more detail and are not to be construed as limiting the scope of the claims. It should be noted that it would be apparent to those skilled in the art that various modifications and improvements could be made without departing from the spirit of the present application, which would be within the scope of the present application. Accordingly, the scope of protection of the present application is to be determined by the claims appended hereto.

Claims (7)

1. A battery material aging mechanism, comprising:
the aging box body is internally provided with an aging cavity, the aging cavity is provided with an air inlet and an air outlet, and the air inlet and the air outlet are communicated with the aging cavity;
the material conveying assembly is arranged in the aging cavity and is used for conveying battery materials along the conveying direction;
the ultraviolet light source assembly is arranged in the aging cavity and is positioned above the material conveying assembly, and the ultraviolet light source assembly is used for emitting ultraviolet light to the material conveying assembly;
an exhaust end of the ozone generator is connected to an air inlet of the aging box body; the ozone generator is used for introducing ozone into the aging cavity, so that battery materials on the material conveying assembly are in an environment irradiated by ozone and ultraviolet light; and
The material turning assembly is arranged in the aging cavity and is positioned above the material conveying assembly, and the material turning assembly is used for turning battery materials on the material conveying assembly; the turning component comprises a rotating piece, a turning piece and an elastic piece, wherein the turning piece comprises a connecting part and a hook part, one side edge of the connecting part is connected to the rotating piece through the elastic piece, the other opposite side edge is connected with the hook part, the elastic piece is used for applying elastic force to the turning piece along the direction far away from the rotating piece, the rotating piece is used for driving the turning piece to rotate relative to the material conveying component, and the rotating axis of the rotating piece is intersected with the conveying direction; when the turning piece rotates to the side, facing the material conveying assembly, of the rotating piece, the turning piece can be abutted to the material conveying assembly, the direction of the concave surface in the hook portion is opposite to the conveying direction, and the rotating direction of the rotating piece is consistent with the direction of the concave surface in the hook portion.
2. The battery material aging mechanism according to claim 1, wherein the number of the material conveying assemblies is at least two, each material conveying assembly is arranged at intervals up and down, the discharging end of the material conveying assembly positioned above is opposite to the charging end of the material conveying assembly positioned below, and the material turning assembly is arranged between the discharging end of the material conveying assembly above and the charging end of the material conveying assembly below; the number of the ultraviolet light source components is consistent with that of the material conveying components, and each ultraviolet light source component is used for emitting ultraviolet light to the corresponding material conveying component.
3. The battery material aging mechanism of claim 2, wherein the material turning assembly further comprises a receiving hopper, wherein an opening at one end of the receiving hopper is in butt joint with a discharging end of the material conveying assembly above, an opening at the other end of the receiving hopper is in butt joint with a feeding end of the material conveying assembly below, and the rotating member and the material turning member are both arranged in the receiving hopper.
4. The battery material aging mechanism according to any one of claims 1 to 3, wherein the ultraviolet light source assembly comprises a first ultraviolet light source and at least two second ultraviolet light sources, the first ultraviolet light source is configured to emit ultraviolet light with a wavelength of 170nm to 200nm, the second ultraviolet light source is configured to emit ultraviolet light with a wavelength of 250nm to 400nm, all the second ultraviolet light sources are disposed at intervals along the conveying direction, and the first ultraviolet light source is disposed between two adjacent second ultraviolet light sources.
5. The battery material aging mechanism of claim 4, wherein the air inlet is provided at a position near a discharge end of the material conveying assembly, and the air outlet is provided at a position near a feed end of the material conveying assembly, so that a flow direction of the ozone in the aging chamber is opposite to a conveying direction of the material conveying assembly; along the conveying direction, the length of the second ultraviolet light source tends to increase.
6. The battery material aging mechanism of any one of claims 1-3, further comprising a heating assembly disposed within the aging chamber, the heating assembly configured to heat the material handling assembly.
7. The utility model provides a junk battery recovery unit which characterized in that, junk battery recovery unit includes:
the crushing mechanism is used for crushing the waste batteries;
the battery material aging mechanism of any one of claims 1-6, disposed downstream of the crushing mechanism, a loading end of the material delivery assembly interfacing a discharge end of the crushing mechanism; and
The screening mechanism is arranged at the downstream of the battery material aging mechanism, the discharging end of the material conveying assembly is in butt joint with the feeding end of the screening mechanism, and the screening mechanism is used for screening battery materials.
CN202410040783.XA 2024-01-11 2024-01-11 Battery material aging mechanism and waste battery recycling device Active CN117559025B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202410040783.XA CN117559025B (en) 2024-01-11 2024-01-11 Battery material aging mechanism and waste battery recycling device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202410040783.XA CN117559025B (en) 2024-01-11 2024-01-11 Battery material aging mechanism and waste battery recycling device

Publications (2)

Publication Number Publication Date
CN117559025A CN117559025A (en) 2024-02-13
CN117559025B true CN117559025B (en) 2024-03-29

Family

ID=89819008

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202410040783.XA Active CN117559025B (en) 2024-01-11 2024-01-11 Battery material aging mechanism and waste battery recycling device

Country Status (1)

Country Link
CN (1) CN117559025B (en)

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4238324A1 (en) * 1992-11-13 1994-05-19 Abb Research Ltd Removal of dangerous contaminants from oxygen-contg. gases - gas stream is treated with ozone as well as with UV-light
JPH08316185A (en) * 1995-05-15 1996-11-29 Japan Storage Battery Co Ltd Ultraviolet treatment apparatus
CN206163654U (en) * 2016-11-24 2017-05-10 荆门市格林美新材料有限公司 Retrieve cathode material's device in follow waste battery pole piece
CN106839694A (en) * 2017-03-21 2017-06-13 深圳市玖创科技有限公司 A kind of hydrogen storage battery electrode material mixing and drying device
CN208226042U (en) * 2018-05-23 2018-12-11 荆门市格林美新材料有限公司 A kind of resource reclaiming system of old and useless battery
CN109037821A (en) * 2018-07-24 2018-12-18 深圳市前海泓远控股有限公司 A kind of ternary cell positive material recovery method of plasma joint ozone
KR20190036627A (en) * 2017-09-28 2019-04-05 주식회사 엘지화학 The Method For Treating Surface Of Battery Separator
CN111477988A (en) * 2020-04-29 2020-07-31 合肥克米克科技有限公司 Battery electrode slice recovery device
CN214078437U (en) * 2020-12-08 2021-08-31 深圳市杰成镍钴新能源科技有限公司 A dismounting device for old and useless lithium cell is retrieved
JP2023159680A (en) * 2022-04-20 2023-11-01 日東電工株式会社 transparent conductive film
CN117019826A (en) * 2023-07-05 2023-11-10 安徽海创循环科技有限公司 Rotary kiln with crushing function for recycling waste lithium batteries
CN117157803A (en) * 2023-07-19 2023-12-01 广东邦普循环科技有限公司 Method for recycling waste lithium battery anode material through high-voltage pulse

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4238324A1 (en) * 1992-11-13 1994-05-19 Abb Research Ltd Removal of dangerous contaminants from oxygen-contg. gases - gas stream is treated with ozone as well as with UV-light
JPH08316185A (en) * 1995-05-15 1996-11-29 Japan Storage Battery Co Ltd Ultraviolet treatment apparatus
CN206163654U (en) * 2016-11-24 2017-05-10 荆门市格林美新材料有限公司 Retrieve cathode material's device in follow waste battery pole piece
CN106839694A (en) * 2017-03-21 2017-06-13 深圳市玖创科技有限公司 A kind of hydrogen storage battery electrode material mixing and drying device
KR20190036627A (en) * 2017-09-28 2019-04-05 주식회사 엘지화학 The Method For Treating Surface Of Battery Separator
CN208226042U (en) * 2018-05-23 2018-12-11 荆门市格林美新材料有限公司 A kind of resource reclaiming system of old and useless battery
CN109037821A (en) * 2018-07-24 2018-12-18 深圳市前海泓远控股有限公司 A kind of ternary cell positive material recovery method of plasma joint ozone
CN111477988A (en) * 2020-04-29 2020-07-31 合肥克米克科技有限公司 Battery electrode slice recovery device
CN214078437U (en) * 2020-12-08 2021-08-31 深圳市杰成镍钴新能源科技有限公司 A dismounting device for old and useless lithium cell is retrieved
JP2023159680A (en) * 2022-04-20 2023-11-01 日東電工株式会社 transparent conductive film
CN117019826A (en) * 2023-07-05 2023-11-10 安徽海创循环科技有限公司 Rotary kiln with crushing function for recycling waste lithium batteries
CN117157803A (en) * 2023-07-19 2023-12-01 广东邦普循环科技有限公司 Method for recycling waste lithium battery anode material through high-voltage pulse

Also Published As

Publication number Publication date
CN117559025A (en) 2024-02-13

Similar Documents

Publication Publication Date Title
JP2013505815A (en) Method and apparatus for aerobically air drying sludge filter cake
CN117559025B (en) Battery material aging mechanism and waste battery recycling device
CN111842410A (en) Waste power battery monomer full-component recovery system
CN212551007U (en) Waste power battery monomer full-component recovery system
CN111099807A (en) Efficient low-temperature closed crawler-type sludge drying machine and working method thereof
CN111996376A (en) Battery separator and battery recovery production line
CN117559026B (en) Battery material decomposition device and waste battery recycling system
CN110667020A (en) Casting machine for hydrocarbon polymer ion exchange membrane
KR100437874B1 (en) System for treating waste materials
CN214704788U (en) Easy open can recovery unit with preheat stoving function
CN215571599U (en) Raw material crushing and drying integrated equipment
CN213315002U (en) Novel production facility of water-retaining agent
CN210999587U (en) Waste plastic's recovery unit
CN210029310U (en) Coal transportation drying device
CN211566617U (en) High-efficient dust removal plastic waste cracking device
CN111530569A (en) Efficient recoverer and recovery method thereof
CN112581681A (en) Easy open can recovery unit with preheat stoving function
CN212720776U (en) Feeding device for microwave drying equipment
CN217677226U (en) Production mud for corrugated paper processing apparatus that recycles excels in
CN211246386U (en) Mixing device for producing improved high-nickel material
CN220507610U (en) Multi-layer dryer
CN212076808U (en) Drying machine heat pump mechanism capable of efficiently utilizing heat
CN220911941U (en) Calcium carbonate drying device
CN212076806U (en) Drier slitting granulator with material loading stirring structure
CN215162292U (en) Heparin sodium processing equipment

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant