CN117486653A - Amino acid water-soluble biological fertilizer and preparation process thereof - Google Patents
Amino acid water-soluble biological fertilizer and preparation process thereof Download PDFInfo
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- CN117486653A CN117486653A CN202311452382.7A CN202311452382A CN117486653A CN 117486653 A CN117486653 A CN 117486653A CN 202311452382 A CN202311452382 A CN 202311452382A CN 117486653 A CN117486653 A CN 117486653A
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- amino acid
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- biofertilizer
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- 150000001413 amino acids Chemical class 0.000 title claims abstract description 63
- 239000003337 fertilizer Substances 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011573 trace mineral Substances 0.000 claims abstract description 30
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003516 soil conditioner Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 150000002596 lactones Chemical class 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 13
- -1 amino acid compound Chemical class 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 4
- 230000008569 process Effects 0.000 claims abstract description 3
- 235000001014 amino acid Nutrition 0.000 claims description 64
- 239000000463 material Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- 239000003381 stabilizer Substances 0.000 claims description 14
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000011591 potassium Substances 0.000 claims description 12
- 229910052700 potassium Inorganic materials 0.000 claims description 12
- 230000000749 insecticidal effect Effects 0.000 claims description 10
- 235000016709 nutrition Nutrition 0.000 claims description 9
- 229920002101 Chitin Polymers 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 230000035764 nutrition Effects 0.000 claims description 8
- 235000010443 alginic acid Nutrition 0.000 claims description 7
- 239000000783 alginic acid Substances 0.000 claims description 7
- 229960001126 alginic acid Drugs 0.000 claims description 7
- 229920000615 alginic acid Polymers 0.000 claims description 7
- 150000004781 alginic acids Chemical group 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 235000020939 nutritional additive Nutrition 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 235000013343 vitamin Nutrition 0.000 claims description 7
- 239000011782 vitamin Substances 0.000 claims description 7
- 229940088594 vitamin Drugs 0.000 claims description 7
- 229930003231 vitamin Natural products 0.000 claims description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 244000166675 Cymbopogon nardus Species 0.000 claims description 4
- 235000018791 Cymbopogon nardus Nutrition 0.000 claims description 4
- 241000830536 Tripterygium wilfordii Species 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- RDMZIKMKSGCBKK-UHFFFAOYSA-N disodium;(9,11-dioxido-5-oxoboranyloxy-2,4,6,8,10,12,13-heptaoxa-1,3,5,7,9,11-hexaborabicyclo[5.5.1]tridecan-3-yl)oxy-oxoborane;tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].O1B(OB=O)OB(OB=O)OB2OB([O-])OB([O-])OB1O2 RDMZIKMKSGCBKK-UHFFFAOYSA-N 0.000 claims description 4
- 235000015393 sodium molybdate Nutrition 0.000 claims description 4
- 239000011684 sodium molybdate Substances 0.000 claims description 4
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 4
- 235000015398 thunder god vine Nutrition 0.000 claims description 4
- 239000004475 Arginine Substances 0.000 claims description 3
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 3
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 3
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 3
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 3
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 claims description 3
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004472 Lysine Substances 0.000 claims description 3
- 235000009697 arginine Nutrition 0.000 claims description 3
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 3
- 235000003704 aspartic acid Nutrition 0.000 claims description 3
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 235000013922 glutamic acid Nutrition 0.000 claims description 3
- 239000004220 glutamic acid Substances 0.000 claims description 3
- 235000018977 lysine Nutrition 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 241000411851 herbal medicine Species 0.000 claims description 2
- 235000015097 nutrients Nutrition 0.000 abstract description 20
- 239000002689 soil Substances 0.000 abstract description 19
- 238000010521 absorption reaction Methods 0.000 abstract description 17
- 230000000813 microbial effect Effects 0.000 abstract description 4
- 230000003993 interaction Effects 0.000 abstract description 2
- 239000002609 medium Substances 0.000 abstract 1
- 230000012010 growth Effects 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 12
- 240000008067 Cucumis sativus Species 0.000 description 9
- 230000009920 chelation Effects 0.000 description 9
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 241000209140 Triticum Species 0.000 description 7
- 235000021307 Triticum Nutrition 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- TVQGDYNRXLTQAP-UHFFFAOYSA-N heptanoic acid ethyl ester Natural products CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- WHBMMWSBFZVSSR-UHFFFAOYSA-M 3-hydroxybutyrate Chemical compound CC(O)CC([O-])=O WHBMMWSBFZVSSR-UHFFFAOYSA-M 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000878007 Miscanthus Species 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 230000000536 complexating effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 2
- 241001326934 Triarrhena Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- 229960000355 copper sulfate Drugs 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- UJSRNPWHNTUQEH-UHFFFAOYSA-N ethyl 7-aminoheptanoate;hydrochloride Chemical compound Cl.CCOC(=O)CCCCCCN UJSRNPWHNTUQEH-UHFFFAOYSA-N 0.000 description 2
- 229960001781 ferrous sulfate Drugs 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 229940099596 manganese sulfate Drugs 0.000 description 2
- 235000007079 manganese sulphate Nutrition 0.000 description 2
- 239000011702 manganese sulphate Substances 0.000 description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 239000002881 soil fertilizer Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229930192334 Auxin Natural products 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000002390 cell membrane structure Anatomy 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 230000009758 senescence Effects 0.000 description 1
- 239000002364 soil amendment Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000018648 unbalanced nutrition Nutrition 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/04—Fertilisers containing other nitrates containing calcium nitrate
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The application relates to the technical field of water-soluble fertilizers, and particularly discloses an amino acid water-soluble biological fertilizer and a preparation process thereof. An amino acid water-soluble biological fertilizer comprises the following raw materials in parts by weight: 40-60 parts of amino acid compound liquid, 5-15 parts of trace elements, 5-10 parts of medium elements, 5-8 parts of triarrhenamine lactone, 50-60 parts of water and 3-5 parts of soil conditioner. The amino acid water-soluble biological fertilizer improves the stability of medium and trace elements in the absorption and transportation processes through the interaction of amino acid and medium and trace elements, improves the microbial environment of crop root system soil through the soil conditioner and the triarrhenamine, promotes crops to better absorb nutrients, and improves the crop yield and quality.
Description
Technical Field
The application relates to the technical field of water-soluble fertilizers, in particular to an amino acid water-soluble biological fertilizer and a preparation process thereof.
Background
The water-soluble fertilizer can be a water-borne fertilizer, is rich in nutrient elements required by crops, and has the advantages of low consumption, convenience in use and low use cost. Compared with the traditional compound fertilizer, the water-soluble fertilizer is easier to be absorbed by crops, and the absorption and utilization rate is relatively high.
However, under the conventional concept of long-term cultivation, major elements are mainly used in the fertilizer, so that the proportion of the major elements to the trace elements is seriously unbalanced, and the quality of crops is reduced, and the yield of the crops is reduced.
Disclosure of Invention
In order to solve the problem of unbalanced nutrition in the traditional fertilizer, the application provides an amino acid water-soluble biological fertilizer and a preparation process thereof.
In a first aspect, the present application provides an amino acid water-soluble biofertilizer, which adopts the following technical scheme:
an amino acid water-soluble biological fertilizer comprises the following raw materials in parts by weight: 40-60 parts of amino acid compound liquid, 5-15 parts of trace elements, 5-10 parts of medium elements, 5-8 parts of triarrhenamine lactone, 50-60 parts of water and 3-5 parts of soil conditioner.
Through adopting above-mentioned technical scheme, the amino acid water-soluble bio-fertilizer of this application is rich in microelement and middling element, carries out the chelation with amino acid simultaneously, promotes the fertilizer that forms and can stably provide the nutrient composition for crops, improves crop yield. The addition of proper amount of triarrhenamine lactone in the fertilizer can promote the growth of crops, raise the content of endogenous auxin in crops, regulate the distribution of nutrient matters in crops, delay the senescence of in vitro cells of crops and further promote the growth and yield increase of crops. Amino acid belongs to natural pollution-free fertilizer, can promote crop growth, improve crop yield and quality, has certain chelation effect with medium/trace elements, and promotes the absorption and transportation efficiency of the medium/trace elements of crops to be higher and more stable.
Preferably, the trace elements include Fe, mn, zn, cu, mo, B, the Fe, mn, zn, cu component is derived from sulfate, the Mo is derived from sodium molybdate, and the B is derived from disodium octaborate tetrahydrate.
By adopting the technical scheme, fe, mn, zn, cu is derived from ferrous sulfate, manganese sulfate, zinc sulfate and copper sulfate, and the cost is low. Sodium molybdate has higher dissolution rate in water-soluble biological fertilizer, is extremely easy to permeate into soil, can sample molybdenum oxide and other nutrients to be conveyed to the root of crops, reduces runoff, improves fertilizer utilization efficiency, reduces loss of nutrient components, reduces soil hardening phenomenon, and further promotes crop growth and yield increase. The disodium octaborate tetrahydrate can provide boron element, and has high dissolution rate and high crop absorption efficiency, thereby improving the utilization rate of the fertilizer.
Preferably, the medium elements include Ca and Mg, and the Ca and the Mg are derived from magnesium sulfate and calcium nitrate.
By adopting the technical scheme, the calcium can stabilize the cell membrane structure, maintain the integrity of plant cells and accelerate root growth. Magnesium is a component of chlorophyll and can be of great significance to photosynthesis of crop plants, thereby promoting crop growth.
Preferably, the amino acid complex comprises glutamic acid, arginine, aspartic acid and lysine.
By adopting the technical scheme, the different physiological functions of crops can be enhanced by using the combination of multiple amino acids, meanwhile, the amino acids have cooperativity, the stress resistance and continuous growth of the crops can be improved, the photosynthesis of the crops is enhanced, and the growth and the yield of the crops are further enhanced.
Preferably, the soil improvement agent comprises potassium humate and potassium fulvate.
By adopting the technical scheme, the potassium humate has better complexing capacity, adsorptivity and soil improvement capacity, and can complex medium/trace elements, promote the absorption of crops to nutrient elements and further promote the growth of crops. Meanwhile, the potassium humate has a sponge space structure with an ultra-large specific surface area, and can lock water in soil, so that drought resistance of crops is improved. The potassium fulvate has better acid and alkali resistance, can be directly absorbed and utilized by crops, improves the soil fertilizer efficiency, and accelerates the growth of the crops with amino acid and medium/trace elements.
Preferably, the fertilizer raw material further comprises 1-3 parts of a nutrition additive and 0.3-0.5 part of a stabilizer; the nutritional additive is alginic acid, vitamins, chitin and insecticidal Chinese medicinal materials.
By adopting the technical scheme, the chitin and the insecticidal Chinese medicinal materials in the fertilizer can reduce the problems of crop diseases and insect pests, the chitin can inhibit harmful flora, improve the soil microbial environment, and simultaneously promote the combination of crop root systems and soil and accelerate the growth of crops. Alginic acid and vitamins can regulate crop growth, provide more comprehensive nutrients for crop growth, and improve root stress resistance.
Preferably, the insecticidal Chinese medicinal materials are Chinese herbal medicine extracts prepared by grinding tripterygium wilfordii, side primary leaves and citronella grass into powder, adding the powder into water and filtering.
Preferably, the stabilizer is DL-3-hydroxy calcium butyrate and 7-amino ethyl heptanoate hydrochloride.
By adopting the technical scheme, the DL-3-calcium hydroxybutyrate can reduce the oxidation injury of crop cells, relieve the poison of harmful media in soil, improve the stress resistance of crops and enhance the growth stability of crops. The DL-3-hydroxybutyrate calcium can also form a complex structure with amino acid and medium/trace elements in the fertilizer, thereby improving the complexing efficiency of the fertilizer, accelerating the absorption of nutrient components, increasing the root system volume and absorption area of crops and promoting the growth and development of the crops.
The 7-amino ethyl heptanoate hydrochloride can be firmly combined in soil, so that the interaction between nutrient elements in the fertilizer and soil particles is enhanced, the absorption efficiency of the nutrient elements in the fertilizer is promoted, and the content and stability of organic nutrient substances in the soil are improved.
In a second aspect, the present application provides a preparation process of an amino acid water-soluble biofertilizer, which adopts the following technical scheme:
the preparation process of the amino acid water-soluble biological fertilizer comprises the following specific steps:
mixing the amino acid composite liquid with water in advance, adding trace elements, mixing and stirring, adding the intermediate elements, mixing, finally adding the soil conditioner and the triarrhenamine lactone, mixing, and stirring uniformly to form the amino acid water-soluble biofertilizer.
By adopting the technical scheme, the mixing sequence of the amino acid compound liquid and the medium/trace elements is controlled, so that the amino acid compound liquid can be better chelated with the medium/trace elements, the chelating rate of the amino acid is improved, the absorption of crops to nutrient components is further promoted, and the growth and development of the crops are promoted.
In summary, the present application has the following beneficial effects:
1. because the amino acid compound liquid is adopted to carry out chelation with the medium and trace elements, the formed amino acid water-soluble biological fertilizer can promote the nutrient components to be better absorbed and utilized by crops, improves the absorption and transportation efficiency of the medium and trace elements, and further enhances the growth and the yield of the crops.
2. In the application, the nutrient additive and the stabilizer are added into the fertilizer, so that the mediums such as harmful diseases and insects, harmful bacteria and the like in the soil can be reduced through the chitin and the insecticidal traditional Chinese medicinal materials, and the microbial environment of the soil can be improved. Meanwhile, the soil nutrition content is improved through alginic acid and vitamins, enough nutrition components are provided for the growth of crops, and the absorption and combination effects between the nutrition components and the crops are enhanced by using the stabilizing agent, so that the growth of the crops is promoted. Improving the yield and quality of crops.
Detailed Description
The present application is described in further detail below with reference to examples.
The triarrhenamine lactone was purchased from triarrhena agroforestry biotechnology limited in the united states.
Examples
Example 1
The embodiment provides an amino acid water-soluble biological fertilizer which comprises the following raw materials in parts by weight: 50kg of amino acid complex liquid, 10kg of trace elements, 8kg of medium elements, 7kg of triarrhena, 55kg of water and 4kg of soil conditioner. Wherein the amino acid complex liquid is glutamic acid, arginine, aspartic acid and lysine with the mass ratio of 1:1:1:1, wherein trace elements are ferrous sulfate, manganese sulfate, zinc sulfate, copper sulfate, sodium molybdate and disodium octaborate tetrahydrate with the mass ratio of 1:1:1:1:1:1, wherein the mass ratio of the medium elements of the magnesium sulfate to the calcium nitrate is 1:1, and the soil conditioner is potassium humate.
The preparation process of the amino acid water-soluble biological fertilizer comprises the following specific steps:
mixing the amino acid composite liquid with water, uniformly stirring, adding trace elements, stirring at a speed of 150r/min for 2 hours, completing the chelation reaction of iron, manganese, zinc, copper, molybdenum and boron, then adding the medium elements, continuously stirring for 3 hours, completing the chelation reaction, finally adding silvergrass lactone and a soil conditioner, stirring for 1 hour, and filtering to obtain the amino acid water-soluble biofertilizer.
Example 2
Example 2 differs from example 1 in that the amino acid complex in the amino acid water-soluble biofertilizer material was 40kg, the trace elements were 15kg, the medium elements were 5kg, the triarrhenamine lactone was 8kg, the water was 60kg, and the soil conditioner was 3kg.
Example 3
Example 3 differs from example 1 in that the amino acid complex in the amino acid water-soluble biofertilizer material was 60kg, the trace elements were 5kg, the medium elements were 10kg, the triarrhenamine lactone was 5kg, the water was 50kg, and the soil conditioner was 5kg.
Example 4
Example 4 differs from example 1 in that the soil amendment in the amino acid water-soluble bio-fertilizer raw material is a mixture of potassium fulvate and potassium humate in a mass ratio of 1:1.
Example 5
Example 5 differs from example 4 in that the amino acid water-soluble biofertilizer material further comprises 2kg of a nutritional additive, wherein the nutritional additive is alginic acid and vitamin in a mass ratio of 1:1.
the preparation process of the amino acid water-soluble biological fertilizer comprises the following specific steps:
mixing the amino acid composite liquid with water, stirring uniformly, adding trace elements, stirring at a speed of 150r/min for 2 hours, completing the chelation reaction of iron, manganese, zinc, copper, molybdenum and boron, then adding the medium elements, continuing stirring for 3 hours, completing the chelation reaction, finally adding silvergrass lactone, a soil conditioner and a nutrition additive, stirring for 1 hour, and filtering to obtain the amino acid water-soluble biofertilizer.
Example 6
Example 6 differs from example 5 in that the amount of nutritional additive used in the amino acid water-soluble biofertilizer material is 1kg.
Example 7
Example 7 differs from example 5 in that the amount of nutritional additive used in the amino acid water-soluble biofertilizer material is 3kg.
Example 8
The difference between the embodiment 8 and the embodiment 5 is that the nutrition additive in the amino acid water-soluble bio-fertilizer raw material is a mixture of alginic acid, vitamins, chitin and insecticidal Chinese medicinal materials in a mass ratio of 1:1:1:1. Wherein the insecticidal Chinese medicinal materials are ground into grinding powder by using tripterygium wilfordii, side primary leaves and citronella grass, the mass ratio of the tripterygium wilfordii, the side primary leaves and the citronella grass is 1:1:1, the grinding powder is mixed with water, the mass ratio of the water to the grinding powder is 4:1, and the traditional Chinese medicinal extract is obtained by filtering.
Example 9
Example 9 differs from example 8 in that the amino acid water-soluble biofertilizer material further comprises 0.4kg of a stabilizer, wherein the stabilizer is 7-amino ethyl heptanoate hydrochloride.
The preparation process of the amino acid water-soluble biological fertilizer comprises the following specific steps:
mixing the amino acid compound liquid with water, uniformly stirring, adding trace elements, stirring at a speed of 150r/min for 2 hours, completing the chelation reaction of iron, manganese, zinc, copper, molybdenum and boron, then adding the medium elements, continuously stirring for 3 hours, completing the chelation reaction, finally adding silvergrass lactone, a soil conditioner, a stabilizer and a nutrition additive, stirring for 1 hour, and filtering to obtain the amino acid water-soluble biofertilizer.
Example 10
Example 10 differs from example 9 in that the amount of stabilizer used in the amino acid-soluble bio-fertilizer raw material was 0.3kg.
Example 11
Example 11 differs from example 9 in that the amount of stabilizer used in the amino acid-soluble bio-fertilizer raw material was 0.5kg.
Example 12
Example 12 differs from example 9 in that the stabilizer in the amino acid water-soluble biofertilizer material is a mixture of calcium DL-3-hydroxybutyrate and ethyl 7-aminoheptanoate hydrochloride in a mass ratio of 1:1.
Comparative example
Comparative example 1
Comparative example 1 differs from example 1 in that no medium elements are used in the amino acid-soluble bio-fertilizer raw material.
Comparative example 2
Comparative example 2 is different from example 1 in that no medium elements and no soil conditioner are used in the amino acid water-soluble bio-fertilizer raw material.
Comparative example 3
Comparative example 3 differs from example 1 in that the triarrhenamine lactone is not used in the amino acid-soluble bio-fertilizer raw material.
Performance test
The following performance tests were carried out on the amino acid water-soluble biofertilizer provided in examples 1 to 12 and comparative examples 1 to 3 according to the present application, and the specific test results are shown in table 1.
Detection method
1. Wheat planting experiment
The amino acid water-soluble biological fertilizer prepared by the application is diluted by 500 times by water, and then 5m is taken 2 Soil is used as a test sample, spring wheat (Chuanyu No. 9) is planted in each sample, fertilizer is applied in a foliar spray mode in the seedling stage, the tillering stage and the grouting stage of the spring wheat respectively, clear water is used for fertilization in a control area, 400ml of each sample is applied each time, and the growth condition of crops is measured in real time.
2. Cucumber planting experiment
30mL of the amino acid water-soluble biofertilizer prepared by the application is taken as an experimental fertilizer for 30kg of water, the variety of the experimental crop cucumber is Jinyou No. 1, the experimental area is 30 square meters, the water is sprayed 1 time in the seedling stage and the flowering stage of the cucumber respectively, 2 times in total, the control group is sprayed with the same amount of clear water, the accumulated yield is collected for multiple times during harvesting, and the cucumber yield and quality are inspected.
Table 1: yield results table for wheat and cucumber crops
From the results of the yields of the two crops, the yield of the wheat crops is obviously increased compared with the yield of the control group, and the yield and quality of the cucumbers are improved in the cucumber experiment. According to the application, the amino acid is compounded with the medium elements and the trace elements, and the soil conditioner and the triarrhenamine lactone are added, so that the formed amino acid water-soluble biological fertilizer has good absorption efficiency, can stably provide nutritional ingredients for crops, and improves the crop yield and quality. In examples 1-3, the amounts of the components used in the fertilizer raw materials were different, with the overall effect of example 1 being better.
As is clear from the comparison between the soil conditioner used in example 4 and the soil conditioner used in example 1, the soil conditioner used in example 4 is better, and further shows that the potassium humate and the potassium fulvate are compounded and can be complexed with medium and trace elements in the fertilizer, so that the absorption of crops to nutrients is promoted, the soil fertilizer is improved, and the growth of crops is promoted.
In examples 5-7, the yield of cucumber and wheat was increased as seen from the yield results of both crops by adding appropriate amounts of nutritional additives to the fertilizer raw material. Further illustrates that the addition of proper amount of alginic acid and vitamins into the fertilizer can improve the growth of crops. Meanwhile, compared with the embodiment 8 and the embodiment 5, the embodiment 8 is added with chitin and insecticidal Chinese medicinal materials, the cucumber and wheat crop yield of the embodiment 8 is obviously increased, and further the insecticidal Chinese medicinal materials and the chitin can improve the soil microorganism environment, strengthen the combination of plant root systems and soil, thereby promoting the absorption of crop nutrients and accelerating the growth of crops.
In examples 9 to 12, a proper amount of stabilizer was added to the fertilizer material, and the stabilizer used in example 12 was calcium DL-3-hydroxybutyrate and ethyl 7-aminoheptanoate hydrochloride, and as seen from the results of the yields of both crops, the yields and quality of the crops in example 12 were better. Further, the DL-3-calcium hydroxybutyrate and 7-amino ethyl heptanoate hydrochloride are compounded, so that a complex structure can be formed with medium and trace elements in the fertilizer, the complexing rate of the fertilizer is improved, the stability of nutrient components in the absorption and transportation processes is improved, the root system volume and the absorption area of crops are increased, the growth and development of the crops are promoted, and the yield is increased.
As can be seen from a comparison of comparative examples 1, 2, 3 and example 1, the use of no medium elements in comparative example 1, the use of no medium elements and no soil improvement agent in comparative example 2, and the use of no triarrhenamine in comparative example 3, both crop yields and quality were reduced. It is further proved that the addition of a proper amount of medium elements in the fertilizer can make up the defects of the traditional single trace elements and promote the plants to absorb more comprehensive nutrients. The soil conditioner and the triarrhenamine can improve the microbial environment of the root of the crops, promote the absorption of the crops to nutrients, promote the growth of the crops and improve the yield and quality of the crops.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.
Claims (9)
1. The amino acid water-soluble biological fertilizer is characterized by comprising the following raw materials in parts by weight: 40-60 parts of amino acid compound liquid, 5-15 parts of trace elements, 5-10 parts of medium elements, 5-8 parts of triarrhenamine lactone, 50-60 parts of water and 3-5 parts of soil conditioner.
2. The amino acid water-soluble biofertilizer of claim 1, wherein: the trace elements comprise Fe, mn, zn, cu, mo, B, the Fe, mn, zn, cu component is derived from sulfate, the Mo component is derived from sodium molybdate, and the B component is derived from disodium octaborate tetrahydrate.
3. The amino acid water-soluble biofertilizer of claim 1, wherein: the medium elements comprise Ca and Mg, wherein the Ca and the Mg are derived from magnesium sulfate and calcium nitrate.
4. The amino acid water-soluble biofertilizer of claim 1, wherein: the amino acid complex solution comprises glutamic acid, arginine, aspartic acid and lysine.
5. The amino acid water-soluble biofertilizer of claim 1, wherein: the soil conditioner comprises potassium humate and potassium fulvate.
6. The amino acid water-soluble biofertilizer of claim 1, wherein: the fertilizer raw material also comprises 1-3 parts of a nutrition additive and 0.3-0.5 part of a stabilizer; the nutritional additive is alginic acid, vitamins, chitin and insecticidal Chinese medicinal materials.
7. The amino acid water-soluble biofertilizer of claim 6, wherein: the insecticidal Chinese medicinal materials are Chinese herbal medicine extracts prepared by grinding tripterygium wilfordii, side primary leaves and citronella grass into powder, adding the powder into water and filtering.
8. The amino acid water-soluble biofertilizer of claim 6, wherein: the stabilizer is DL-3-calcium hydroxybutyrate and 7-ethyl amino heptanoate hydrochloride.
9. A process for the preparation of an amino acid-soluble biofertilizer according to any of claims 1 to 8, characterised in that: the method comprises the following specific steps:
mixing the amino acid composite liquid with water in advance, adding trace elements, mixing and stirring, adding the intermediate elements, mixing, finally adding the soil conditioner and the triarrhenamine lactone, mixing, and stirring uniformly to form the amino acid water-soluble biofertilizer.
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