CN117467370A - Water-based flame-retardant flocking adhesive - Google Patents

Water-based flame-retardant flocking adhesive Download PDF

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Publication number
CN117467370A
CN117467370A CN202311457812.4A CN202311457812A CN117467370A CN 117467370 A CN117467370 A CN 117467370A CN 202311457812 A CN202311457812 A CN 202311457812A CN 117467370 A CN117467370 A CN 117467370A
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CN
China
Prior art keywords
water
flame retardant
stirring
flocking adhesive
adhesive according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311457812.4A
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Chinese (zh)
Inventor
武霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Licheng Coatings Co ltd
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Huizhou Licheng Coatings Co ltd
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Priority to CN202311457812.4A priority Critical patent/CN117467370A/en
Publication of CN117467370A publication Critical patent/CN117467370A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/04—Starch derivatives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • C09J125/02—Homopolymers or copolymers of hydrocarbons
    • C09J125/04—Homopolymers or copolymers of styrene
    • C09J125/08—Copolymers of styrene
    • C09J125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
    • C09J143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/324—Alkali metal phosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a water-based flame-retardant flocking adhesive which is characterized by comprising the following components in percentage by weight: 15-70% of water-based main material, 2-16% of flame retardant, 0-6% of PH value regulator, 0-3% of thickener, 15-65% of diluent and 0.02-0.2% of preservative. Compared with the prior art, the invention has the advantages that: the water-based adhesive has the advantages of fire resistance, flame retardance, V0 grade reaching GB/T2408-2008 standard, strong permeability to cotton staple fibers, good binding power, simplicity in operation and the like because the simulated snowflake and snow scenery are pure white, and the adhesive also has the anti-yellowing function.

Description

Water-based flame-retardant flocking adhesive
Technical Field
The invention relates to the field of Christmas gum adhesives, in particular to an aqueous flame-retardant flocking adhesive.
Background
Along with the development of economy, the life rhythm of people is accelerated, the requirement of human activity and environment beautification is continuously improved, more and more people select decorations such as simulated plants (flowers, fruits, trees, bonsais), christmas trees and the like, and the decorations are favored by more and more people to be touted because the decorations do not need to be manually nursed every day.
The environment-friendly healthy and various degradable water-based flame-retardant flocking adhesives have very broad market application prospect, and also exactly meet the national 'green cycle low-carbon development' time demand, cotton short fibers are adhered to simulated plants, christmas trees or Christmas decorations by using the adhesives through flocking technology to manufacture realistic snowing, frosting, snow melting and other different snow scene effects, natural snow is white, the adhesive for manufacturing the simulated snow scene effects is required to have the anti-yellowing function, and the adhesive for manufacturing the snow scene effects is required to be provided with the functions of fire prevention, flame retardance and the like when people in the western world wear christmas days. The combination of water-based, environment-friendly, anti-yellowing, fire-resistant, flame-retardant, adhesive strength and the like places high demands on the adhesive, which can be determined by a great deal of experiments.
Disclosure of Invention
The invention aims to solve the technical problem of providing a water-based flame-retardant flocking adhesive.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: the water-based flame-retardant flocking adhesive is characterized by comprising the following components in percentage by weight: 15-70% of water-based main material, 2-16% of flame retardant, 0-6% of PH value regulator, 0-3% of thickener, 15-65% of diluent and 0.02-0.2% of preservative.
As an improvement, the water-based main materials comprise one or more of polyvinyl acetate emulsion, ethylene-vinyl acetate emulsion, acrylic emulsion/resin (vinyl acetate, pure acrylic, styrene acrylic and silicone acrylic), polyurethane emulsion and starch/modified starch (gelatinized by water or heated gelatinization for standby), wherein the main materials are matched.
As an improvement, the flame retardant is phosphorus/phosphonate/phosphite and derivatives thereof, phosphate/condensed phosphates (including potassium salt, sodium salt and ammonium salt) and derivatives thereof, ammonium polyphosphate, phosphorus-nitrogen synergic phosphate flame retardant and the like. One or more of the flame retardants are matched.
As an improvement, the PH regulator comprises sodium bicarbonate, sodium carbonate, ammonium bicarbonate, ammonia water, caustic soda, and organic amine, wherein one or more of the above components are matched.
As an improvement, the thickening agent is cellulose, acrylamide, acrylic acid or polyurethane, and one or more of the thickening agents are matched.
As an improvement, the diluent is water (deionized water, distilled water, pure tap water).
As an improvement, the preservative is isothiazolinone compounds, benzoic acid/sodium benzoate, sorbic acid/potassium sorbate, p-hydroxybenzoates, sodium dehydroacetate, sodium diacetate and glucono-delta-lactone, wherein one or more of the above compounds are matched.
As an improvement, the preparation method comprises the following steps:
(1) introducing deionized water into a stirring tank or a stirring kettle according to a proportion;
(2) adding the flame retardant of the required components, starting a stirring mode, and stirring for 20 minutes until the flame retardant is fully dissolved;
(3) adding main materials in a required proportion, and continuously stirring for 30 minutes to uniformly disperse the main materials;
(4) adding pH regulator, stirring for 10 min, testing pH value, adding thickener and antiseptic, stirring for 20 min, and packaging after the test viscosity is qualified.
The water-base flame-retardant flocking adhesive can also be added with pigment according to the requirement to prepare colored water-base flame-retardant flocking adhesive or Christmas tree branches to be used as colored coating.
Compared with the prior art, the invention has the advantages that: the water-based adhesive has the function of resisting yellowing, has strong binding power to cotton fibers, has flame retardance and fire resistance, and achieves the V0 level of GB/T2408-2008 standard, and is characterized in that phosphate and phosphate flame retardants are used, toxic and harmful elements such as bromine and halogen are not contained, and the water-based adhesive is environment-friendly, economical, water-based and degradable, and is an ideal adhesive for manufacturing artificial snowflakes and snowscapes from cotton staple fibers for simulation plants, christmas trees and Christmas ornaments.
Detailed Description
The present invention will be described in further detail below.
When the invention is implemented, the water-based flame-retardant flocking adhesive comprises the following components:
aqueous main material: one or more of them is matched with 15-70%
Polyvinyl acetate emulsion and ethylene-vinyl acetate emulsion
Acrylic emulsion/resin (Acetoram, pure acrylic, styrene acrylic, silicone acrylic)
Polyurethane emulsion
Starch/modified starch (gelatinized with water or heated for later use).
Flame retardant: one or more of the following components with a proportion of 2-16%
Phosphate/phosphonate/phosphite and derivatives thereof,
Phosphate/condensed phosphates (including potassium, sodium, ammonium salts) and derivatives thereof,
Ammonium polyphosphate,
Phosphorus-nitrogen synergic and other phosphoric acid flame retardants.
pH regulator: one or more of the following components with a ratio of 0-6%
Baking soda, sodium carbonate, ammonium bicarbonate, ammonia water, caustic soda and organic amines.
And (3) a thickening agent: one or more of the following components with a ratio of 0-3%
Celluloses, acrylamides, acrylics, polyurethanes;
a diluent: water (deionized water, distilled water and pure tap water) accounting for 15-65 percent;
preservative: one or more of the following components is/are arranged, and the ratio is 0.02-0.2%.
Isothiazolinone compound and derivative, benzoic acid/sodium benzoate, sorbic acid/potassium sorbate, p-hydroxybenzoate, and process for producing the same,
Sodium dehydroacetate, sodium diacetate, glucono-delta-lactone.
The preparation method of the water-based flame-retardant fireproof adhesive comprises the following steps:
introducing deionized water into a stirring tank or a stirring kettle according to a proportion; adding the flame retardant of the required components, starting a stirring mode, and stirring for 20 minutes until the flame retardant is fully dissolved; adding the water-based main material with the required proportion, and continuously stirring for 30 minutes;
adding pH regulator, stirring for 10 min, testing pH value, adding thickener and antiseptic, stirring for 20 min, and packaging after the test viscosity is qualified.
The water-based flame-retardant flocking fireproof adhesive can also be added with pigment according to the requirement to prepare a colored water-based flame-retardant flocking adhesive or Christmas tree branches to be used as colored coatings.
The working principle of the invention is as follows: the adhesive has the properties of yellowing resistance, flame retardance, fire resistance and the like, and is an ideal adhesive for manufacturing various snowflakes and snowscapes by simulating plants, christmas trees and christmas ornaments.
Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature, and in the description of the invention, "a plurality" means two or more, unless otherwise specifically and clearly defined.
In the present invention, unless explicitly specified and limited otherwise, the terms "mounted," "connected," "secured," and the like are to be construed broadly and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art according to the specific circumstances.
In the present invention, unless expressly stated or limited otherwise, a first feature "above" or "below" a second feature may include both the first and second features being in direct contact, as well as the first and second features not being in direct contact but being in contact with each other through additional features therebetween. Moreover, a first feature being "above," "over" and "on" a second feature includes the first feature being directly above and obliquely above the second feature, or simply indicating that the first feature is higher in level than the second feature. The first feature being "under", "below" and "beneath" the second feature includes the first feature being directly under and obliquely below the second feature, or simply means that the first feature is less level than the second feature.
In the description of the present specification, a description referring to terms "one embodiment," "some embodiments," "examples," "specific examples," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
Although embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are illustrative and not to be construed as limiting the invention, and that variations, modifications, alternatives, and variations may be made in the above embodiments by those skilled in the art without departing from the spirit and principles of the invention.

Claims (8)

1. The water-based flame-retardant flocking adhesive is characterized by comprising the following components in percentage by weight: 15-70% of water-based main material, 2-16% of flame retardant, 0-6% of PH value regulator, 0-3% of thickener, 15-65% of diluent and 0.02-0.2% of preservative.
2. An aqueous flame retardant flocking adhesive according to claim 1, wherein: the water-based main material comprises one or more of polyvinyl acetate emulsion, acrylic emulsion/resin (vinyl acetate, pure acrylic, styrene-acrylic, silicone-acrylic), ethylene-vinyl acetate emulsion, polyurethane emulsion, and starch/modified starch (gelatinized with water or heated for use).
3. An aqueous flame retardant flocking adhesive according to claim 1, wherein: the flame retardant comprises phosphorus/phosphonate/phosphite and derivatives thereof, phosphate/condensed phosphates (including potassium salt, sodium salt and ammonium salt) and derivatives thereof, ammonium polyphosphate, phosphorus-nitrogen synergic phosphate flame retardant and the like. One or more of the flame retardants are matched.
4. An aqueous flame retardant flocking adhesive according to claim 1, wherein: the pH regulator comprises sodium bicarbonate, sodium carbonate, ammonium bicarbonate, ammonia water, caustic soda and organic amine. One or more of them.
5. An aqueous flame retardant flocking adhesive according to claim 1, wherein: the thickener is one or more of cellulose, acrylamide, acrylic acid and polyurethane.
6. An aqueous flame retardant flocking adhesive according to claim 1, wherein: the diluent is water (deionized water, distilled water, pure tap water).
7. An aqueous flame retardant flocking adhesive according to claim 1, wherein: the preservative comprises one or more of isothiazolinone compounds and derivatives thereof, benzoic acid/sodium benzoate, sorbic acid/potassium sorbate, p-hydroxybenzoate, sodium dehydroacetate, sodium diacetate and glucono-delta-lactone.
8. An aqueous flame retardant flocking adhesive according to claim 1, characterized in that it is prepared by the following method:
(1) introducing deionized water into a stirring tank or a stirring kettle according to a proportion;
(2) adding the flame retardant of the required components, starting a stirring mode, and stirring for 20 minutes until the flame retardant is fully dissolved;
(3) adding the base materials with the required proportion, and continuously stirring for 30 minutes;
(4) adding pH regulator, stirring for 10 min, testing pH value, adding thickener and antiseptic, stirring for 20 min, and packaging after the test viscosity is qualified.
CN202311457812.4A 2023-11-04 2023-11-04 Water-based flame-retardant flocking adhesive Pending CN117467370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311457812.4A CN117467370A (en) 2023-11-04 2023-11-04 Water-based flame-retardant flocking adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311457812.4A CN117467370A (en) 2023-11-04 2023-11-04 Water-based flame-retardant flocking adhesive

Publications (1)

Publication Number Publication Date
CN117467370A true CN117467370A (en) 2024-01-30

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Application Number Title Priority Date Filing Date
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105294925A (en) * 2015-11-24 2016-02-03 辽宁恒星精细化工有限公司 Electrostatic flocking adhesive for high fastness carpet and preparation method thereof
CN107286868A (en) * 2017-06-28 2017-10-24 陈林梭 Low-temperature curing environment-friendly water-based flocking adhesive
CN107936899A (en) * 2017-12-18 2018-04-20 东莞智炜新材料股份有限公司 A kind of mail frame electrostatic spinning aqueous adhesive and preparation method thereof
CN109207104A (en) * 2018-09-05 2019-01-15 嘉善凝红绒业有限公司 A kind of fire-retardant flocking adhesive
CN109796915A (en) * 2019-02-26 2019-05-24 浙江久大纺织科技有限公司 A kind of imvite modified PVAc adhesive and preparation method thereof
CN116396710A (en) * 2022-12-20 2023-07-07 山东华诚高科胶粘剂有限公司 Water-based electrostatic flocking adhesive for automobile interior storage box, and preparation method and application thereof

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Publication number Priority date Publication date Assignee Title
CN105294925A (en) * 2015-11-24 2016-02-03 辽宁恒星精细化工有限公司 Electrostatic flocking adhesive for high fastness carpet and preparation method thereof
CN107286868A (en) * 2017-06-28 2017-10-24 陈林梭 Low-temperature curing environment-friendly water-based flocking adhesive
CN107936899A (en) * 2017-12-18 2018-04-20 东莞智炜新材料股份有限公司 A kind of mail frame electrostatic spinning aqueous adhesive and preparation method thereof
CN109207104A (en) * 2018-09-05 2019-01-15 嘉善凝红绒业有限公司 A kind of fire-retardant flocking adhesive
CN109796915A (en) * 2019-02-26 2019-05-24 浙江久大纺织科技有限公司 A kind of imvite modified PVAc adhesive and preparation method thereof
CN116396710A (en) * 2022-12-20 2023-07-07 山东华诚高科胶粘剂有限公司 Water-based electrostatic flocking adhesive for automobile interior storage box, and preparation method and application thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
吴海婷;蒋小娟;蔡再生;: "环保阻燃型静电植绒黏合剂的合成及其应用", 纺织学报, no. 06, 15 June 2018 (2018-06-15), pages 96 - 100 *
张江滨: "EVA乳液的改性及应用", 印染助剂, no. 06, 20 December 1998 (1998-12-20), pages 29 - 31 *

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