CN109207104A - A kind of fire-retardant flocking adhesive - Google Patents
A kind of fire-retardant flocking adhesive Download PDFInfo
- Publication number
- CN109207104A CN109207104A CN201811028740.0A CN201811028740A CN109207104A CN 109207104 A CN109207104 A CN 109207104A CN 201811028740 A CN201811028740 A CN 201811028740A CN 109207104 A CN109207104 A CN 109207104A
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- Prior art keywords
- fire
- retardant
- monomer
- parts
- flocking adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses adhesive technology fields, specific field is a kind of fire-retardant flocking adhesive, the fire-retardant flocking adhesive is grouped as by the group of following mass fraction: 80~90 parts of monomer, 7~9 parts of crosslinking agent, 2.4~3 parts of emulsifier, 0.5~1 part and 0.3~0.4 part of initiator of fire retardant, fire-retardant flocking adhesive prepared by the present invention is by monomer, crosslinking agent, emulsifier, fire retardant and initiator are prepared, monomer has hard monomer and soft monomer to mix, so that this fire-retardant flocking adhesive has preferable flexibility, durability and structural strength, monomer is dispersed into droplet in system, monomer surface is adsorbed on by emulsifier, play protection stabilization, under the action of initiator, monomer polymerize with crosslinking agent, form adhesive, using ammonium polyphosphate as organic fire-retardant, with preferable Flame retardant property, the present invention it is low in cost, raw material is easy to get, and function admirable has good stability, and is with a wide range of applications.
Description
Technical field
The present invention relates to field of adhesive technology, specific field is a kind of fire-retardant flocking adhesive.
Background technique
Adhesive is also known as binder, abbreviation glue, is that one kind by adhesion is bonded in material to be bonded body or material
Substance together, have following characteristics: 1, use scope is wide, can connect the material of different performance, have welding, be spirally connected,
Performance not available for the connection types such as riveting；2, mitigate weight, since adhesive weight itself is far below rivet and bolt etc.
Metal can mitigate the weight of object entirety；3, manufacturing cost is low；4, bonded structure long service life, especially gluing area
Greatly, so that abutting edge uniform force, a possibility that dropping stress concentration, increase its service life；5, simple process and type are rich
Richness, bonding process is simple, time saving and energy saving, is conducive to large-scale application, and variety diversity may be used at a variety of occasions；6, its is close
Sealing property and chemical-resistance are good, adhesive adhesives, so that its surrounding is glued, overall sealing performance is good, and glue
Glutinous agent itself has the advantages that resistant to chemical etching.However the fire retardancy of existing flocking adhesive is poor, for this purpose, we have proposed
A kind of fire-retardant flocking adhesive.
Summary of the invention
The purpose of the present invention is to provide a kind of fire-retardant flocking adhesive, to solve mentioned above in the background art ask
Topic.
To achieve the above object, the invention provides the following technical scheme: a kind of fire-retardant flocking adhesive, fire-retardant flocking gluing
Agent is composed of the following components:
Monomer, crosslinking agent, emulsifier, fire retardant, initiator.
Preferably, component is made of following mass fraction:
80~90 parts of monomer, 7~9 parts of crosslinking agent, 2.4~3 parts of emulsifier, 0.5~1 part of fire retardant, initiator 0.3~
0.4 part.
Preferably, the monomer is grouped as by the group of following mass fraction:
60~70 parts of butyl acrylate, 5~10 parts of methyl methacrylate, 5~10 parts of methacrylic acid.
Preferably, the emulsifier is yin/nonionic emulsifier, and the emulsifier is grouped by the group of following mass fraction
At:
0.8~1.2 part of spermaceti alcohol radical sodium sulphate, 1.5~1.8 parts of nonylphenol polyoxyethylene ether.
Preferably, the crosslinking agent is to be grouped as by the group of following mass fraction:
3~4 parts of N hydroxymethyl acrylamide, 4~5 parts of hydroxy-ethyl acrylate.
Preferably, the fire retardant is ammonium polyphosphate.
Preferably, the initiator is ammonium persulfate/sodium hydrogensulfite.
Compared with prior art, the beneficial effects of the present invention are: a kind of fire-retardant flocking adhesive, prepared by the present invention fire-retardant
Flocking adhesive is prepared by monomer, crosslinking agent, emulsifier, fire retardant and initiator, and monomer has hard monomer and soft monomer mixed
It closes, so that this fire-retardant flocking adhesive has preferable flexibility, durability and structural strength, monomer disperses in system
At droplet, monomer surface is adsorbed on by emulsifier, plays protection stabilization, under the action of initiator, monomer and crosslinking
Agent polymerize, and forms adhesive, using ammonium polyphosphate as organic fire-retardant, has preferable flame retardant property, prepared by the present invention
For fire-retardant flocking adhesive peak viscosity up to 136 centipoises, maximum solids content up to 76.4%, maximum monomer conversion is reachable
98.5%, stablize storage number of days and be greater than 60 days, the present invention is low in cost, and flame retardant property is good, and raw material is easy to get, function admirable, surely
It is qualitative good, it is with a wide range of applications.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution of the present invention is clearly and completely described, it is clear that institute
The embodiment of description is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention,
Every other embodiment obtained by those of ordinary skill in the art without making creative efforts, belongs to this hair
The range of bright protection.
Embodiment 1: a kind of fire-retardant flocking adhesive, fire-retardant flocking adhesive are grouped as by the group of following quality:
60 grams of butyl acrylate, 5 grams of methyl methacrylate, 5 grams of methacrylic acid, 3 grams of N hydroxymethyl acrylamide, third
4 grams of olefin(e) acid hydroxyl ethyl ester, 0.8 gram of spermaceti alcohol radical sodium sulphate, 1.5 grams of nonylphenol polyoxyethylene ether, 0.5 gram of ammonium polyphosphate, persulfuric acid
0.3 gram of ammonium/sodium hydrogensulfite.
The emulsifier (spermaceti alcohol radical sodium sulphate and nonylphenol polyoxyethylene ether) of above-mentioned quality is added in three-necked flask, and
Deionized water is added to be dissolved, the bottleneck of three-necked flask is connected separately with reflux condensing tube and constant pressure funnel, uses collection
Hot type constant-temperature heating magnetic stirring apparatus carries out constant temperature stirring to it, and temperature is 45 degrees Celsius, and mixing time is 10 minutes, then will
Temperature rises to 75 degrees Celsius, and monomer (butyl acrylate, methyl methacrylate and the metering system of 1/3 above-mentioned quality is added
Acid), crosslinking agent (N hydroxymethyl acrylamide and hydroxy-ethyl acrylate), initiator (ammonium persulfate/sodium hydrogensulfite) and fire-retardant
Agent (ammonium polyphosphate), after isothermal reaction 30 minutes, using constant pressure funnel by remaining monomer, crosslinking agent, initiator and resistance
Combustion agent instills in three-necked flask in 150 minutes, isothermal reaction 30 minutes, temperature is then risen to 85 degrees Celsius, isothermal reaction
It 30 minutes, cools, adjusts pH, can be prepared by fire-retardant flocking adhesive.
Embodiment 2: a kind of fire-retardant flocking adhesive, fire-retardant flocking adhesive are grouped as by the group of following quality:
63 grams of butyl acrylate, 7 grams of methyl methacrylate, 7 grams of methacrylic acid, 3.2 grams of N hydroxymethyl acrylamide,
4.2 grams of hydroxy-ethyl acrylate, 0.9 gram of spermaceti alcohol radical sodium sulphate, 1.6 grams of nonylphenol polyoxyethylene ether, 0.6 gram of ammonium polyphosphate, mistake
0.32 gram of ammonium sulfate/sodium hydrogensulfite.
The emulsifier (spermaceti alcohol radical sodium sulphate and nonylphenol polyoxyethylene ether) of above-mentioned quality is added in three-necked flask, and
Deionized water is added to be dissolved, the bottleneck of three-necked flask is connected separately with reflux condensing tube and constant pressure funnel, uses collection
Hot type constant-temperature heating magnetic stirring apparatus carries out constant temperature stirring to it, and temperature is 45 degrees Celsius, and mixing time is 10 minutes, then will
Temperature rises to 75 degrees Celsius, and monomer (butyl acrylate, methyl methacrylate and the metering system of 1/3 above-mentioned quality is added
Acid), crosslinking agent (N hydroxymethyl acrylamide and hydroxy-ethyl acrylate), initiator (ammonium persulfate/sodium hydrogensulfite) and fire-retardant
Agent (ammonium polyphosphate), after isothermal reaction 30 minutes, using constant pressure funnel by remaining monomer, crosslinking agent, initiator and resistance
Combustion agent instills in three-necked flask in 150 minutes, isothermal reaction 30 minutes, temperature is then risen to 85 degrees Celsius, isothermal reaction
It 30 minutes, cools, adjusts pH, can be prepared by fire-retardant flocking adhesive.
Embodiment 3: a kind of fire-retardant flocking adhesive, fire-retardant flocking adhesive are grouped as by the group of following quality:
65 grams of butyl acrylate, 7 grams of methyl methacrylate, 8 grams of methacrylic acid, 3.4 grams of N hydroxymethyl acrylamide,
4.4 grams of hydroxy-ethyl acrylate, 1.0 grams of spermaceti alcohol radical sodium sulphate, 1.6 grams of nonylphenol polyoxyethylene ether, 0.6 gram of ammonium polyphosphate, mistake
0.34 gram of ammonium sulfate/sodium hydrogensulfite.
The emulsifier (spermaceti alcohol radical sodium sulphate and nonylphenol polyoxyethylene ether) of above-mentioned quality is added in three-necked flask, and
Deionized water is added to be dissolved, the bottleneck of three-necked flask is connected separately with reflux condensing tube and constant pressure funnel, uses collection
Hot type constant-temperature heating magnetic stirring apparatus carries out constant temperature stirring to it, and temperature is 45 degrees Celsius, and mixing time is 10 minutes, then will
Temperature rises to 75 degrees Celsius, and monomer (butyl acrylate, methyl methacrylate and the metering system of 1/3 above-mentioned quality is added
Acid), crosslinking agent (N hydroxymethyl acrylamide and hydroxy-ethyl acrylate), initiator (ammonium persulfate/sodium hydrogensulfite) and fire-retardant
Agent (ammonium polyphosphate), after isothermal reaction 30 minutes, using constant pressure funnel by remaining monomer, crosslinking agent, initiator and resistance
Combustion agent instills in three-necked flask in 150 minutes, isothermal reaction 30 minutes, temperature is then risen to 85 degrees Celsius, isothermal reaction
It 30 minutes, cools, adjusts pH, can be prepared by fire-retardant flocking adhesive.
Embodiment 4: a kind of fire-retardant flocking adhesive, fire-retardant flocking adhesive are grouped as by the group of following quality:
68 grams of butyl acrylate, 8 grams of methyl methacrylate, 9 grams of methacrylic acid, 3.8 grams of N hydroxymethyl acrylamide,
4.7 grams of hydroxy-ethyl acrylate, 1.1 grams of spermaceti alcohol radical sodium sulphate, 1.7 grams of nonylphenol polyoxyethylene ether, 0.8 gram of ammonium polyphosphate, mistake
0.37 gram of ammonium sulfate/sodium hydrogensulfite.
The emulsifier (spermaceti alcohol radical sodium sulphate and nonylphenol polyoxyethylene ether) of above-mentioned quality is added in three-necked flask, and
Deionized water is added to be dissolved, the bottleneck of three-necked flask is connected separately with reflux condensing tube and constant pressure funnel, uses collection
Hot type constant-temperature heating magnetic stirring apparatus carries out constant temperature stirring to it, and temperature is 45 degrees Celsius, and mixing time is 10 minutes, then will
Temperature rises to 75 degrees Celsius, and monomer (butyl acrylate, methyl methacrylate and the metering system of 1/3 above-mentioned quality is added
Acid), crosslinking agent (N hydroxymethyl acrylamide and hydroxy-ethyl acrylate), initiator (ammonium persulfate/sodium hydrogensulfite) and fire-retardant
Agent (ammonium polyphosphate), after isothermal reaction 30 minutes, using constant pressure funnel by remaining monomer, crosslinking agent, initiator and resistance
Combustion agent instills in three-necked flask in 150 minutes, isothermal reaction 30 minutes, temperature is then risen to 85 degrees Celsius, isothermal reaction
It 30 minutes, cools, adjusts pH, can be prepared by fire-retardant flocking adhesive.
Embodiment 5:
A kind of fire-retardant flocking adhesive, fire-retardant flocking adhesive are grouped as by the group of following quality:
70 grams of butyl acrylate, 10 grams of methyl methacrylate, 10 grams of methacrylic acid, 4 grams of N hydroxymethyl acrylamide,
5 grams of hydroxy-ethyl acrylate, 1.2 grams of spermaceti alcohol radical sodium sulphate, 1.8 grams of nonylphenol polyoxyethylene ether, 1 gram of ammonium polyphosphate, persulfuric acid
0.4 gram of ammonium/sodium hydrogensulfite.
The emulsifier (spermaceti alcohol radical sodium sulphate and nonylphenol polyoxyethylene ether) of above-mentioned quality is added in three-necked flask, and
Deionized water is added to be dissolved, the bottleneck of three-necked flask is connected separately with reflux condensing tube and constant pressure funnel, uses collection
Hot type constant-temperature heating magnetic stirring apparatus carries out constant temperature stirring to it, and temperature is 45 degrees Celsius, and mixing time is 10 minutes, then will
Temperature rises to 75 degrees Celsius, and monomer (butyl acrylate, methyl methacrylate and the metering system of 1/3 above-mentioned quality is added
Acid), crosslinking agent (N hydroxymethyl acrylamide and hydroxy-ethyl acrylate), initiator (ammonium persulfate/sodium hydrogensulfite) and fire-retardant
Agent (ammonium polyphosphate), after isothermal reaction 30 minutes, using constant pressure funnel by remaining monomer, crosslinking agent, initiator and resistance
Combustion agent instills in three-necked flask in 150 minutes, isothermal reaction 30 minutes, temperature is then risen to 85 degrees Celsius, isothermal reaction
It 30 minutes, cools, adjusts pH, can be prepared by fire-retardant flocking adhesive.
Basic performance test is carried out to the fire-retardant flocking adhesive of Examples 1 to 5 preparation, test result is as follows table 1:
The result shows that a kind of fire-retardant flocking adhesive prepared by the embodiment of the present invention 1~5, wherein fire-retardant flocking adhesive
Viscosity reach 125 centipoises or more, monomer conversion reaches 95% or more, and solid content reaches 70% or more, and storage number of days is big
In 60 days, in addition, the present invention also has certain flame retardant effect, the present invention is low in cost, and raw material is easy to get, and flame retardant property is good,
Function admirable has good stability, and is with a wide range of applications.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of fire-retardant flocking adhesive, it is characterised in that: fire-retardant flocking adhesive is composed of the following components:
Monomer, crosslinking agent, emulsifier, fire retardant, initiator.
2. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: its component is by following mass parts array
At:
80~90 parts of monomer, 7~9 parts of crosslinking agent, 2.4~3 parts of emulsifier, 0.5~1 part of fire retardant, 0.3~0.4 part of initiator.
3. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the monomer is by following mass fraction
Group be grouped as:
60~70 parts of butyl acrylate, 5~10 parts of methyl methacrylate, 5~10 parts of methacrylic acid.
4. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the emulsifier is yin/nonionic
Emulsifier, the emulsifier are grouped as by the group of following mass fraction:
0.8~1.2 part of spermaceti alcohol radical sodium sulphate, 1.5~1.8 parts of nonylphenol polyoxyethylene ether.
5. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the crosslinking agent is by following quality
The group of number is grouped as:
3~4 parts of N hydroxymethyl acrylamide, 4~5 parts of hydroxy-ethyl acrylate.
6. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the fire retardant is ammonium polyphosphate.
7. a kind of fire-retardant flocking adhesive according to claim 1, it is characterised in that: the initiator be ammonium persulfate/
Sodium hydrogensulfite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811028740.0A CN109207104A (en) | 2018-09-05 | 2018-09-05 | A kind of fire-retardant flocking adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811028740.0A CN109207104A (en) | 2018-09-05 | 2018-09-05 | A kind of fire-retardant flocking adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109207104A true CN109207104A (en) | 2019-01-15 |
Family
ID=64986261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811028740.0A Pending CN109207104A (en) | 2018-09-05 | 2018-09-05 | A kind of fire-retardant flocking adhesive |
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| CN (1) | CN109207104A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115141526A (en) * | 2022-07-27 | 2022-10-04 | 浙江睿高新材料股份有限公司 | Preparation method of flame-retardant sponge spray glue |
| CN115160961A (en) * | 2022-07-27 | 2022-10-11 | 浙江睿高新材料股份有限公司 | Preparation method of flame-retardant adhesive for shoes |
| WO2023031825A1 (en) * | 2021-08-31 | 2023-03-09 | 3M Innovative Properties Company | Fire-retardant pressure sensitive adhesives, articles, and uses |
| CN117467370A (en) * | 2023-11-04 | 2024-01-30 | 惠州市立成涂料有限公司 | Water-based flame-retardant flocking adhesive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105294925A (en) * | 2015-11-24 | 2016-02-03 | 辽宁恒星精细化工有限公司 | Electrostatic flocking adhesive for high fastness carpet and preparation method thereof |
-
2018
- 2018-09-05 CN CN201811028740.0A patent/CN109207104A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105294925A (en) * | 2015-11-24 | 2016-02-03 | 辽宁恒星精细化工有限公司 | Electrostatic flocking adhesive for high fastness carpet and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 吴海婷等: "环保阻燃型静电植绒黏合剂的合成及其应用", 《纺织学报》 * |
| 李秀颖等: "高牢度地毯用静电植绒粘合剂的研制", 《染整技术》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023031825A1 (en) * | 2021-08-31 | 2023-03-09 | 3M Innovative Properties Company | Fire-retardant pressure sensitive adhesives, articles, and uses |
| CN115141526A (en) * | 2022-07-27 | 2022-10-04 | 浙江睿高新材料股份有限公司 | Preparation method of flame-retardant sponge spray glue |
| CN115160961A (en) * | 2022-07-27 | 2022-10-11 | 浙江睿高新材料股份有限公司 | Preparation method of flame-retardant adhesive for shoes |
| CN117467370A (en) * | 2023-11-04 | 2024-01-30 | 惠州市立成涂料有限公司 | Water-based flame-retardant flocking adhesive |
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Application publication date: 20190115 |