CN117441736B - Compound preparation containing florasulam herbicide and agricultural coconut oil synergist - Google Patents
Compound preparation containing florasulam herbicide and agricultural coconut oil synergist Download PDFInfo
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- CN117441736B CN117441736B CN202311781287.1A CN202311781287A CN117441736B CN 117441736 B CN117441736 B CN 117441736B CN 202311781287 A CN202311781287 A CN 202311781287A CN 117441736 B CN117441736 B CN 117441736B
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- Prior art keywords
- alkyl glycoside
- herbicide
- polyoxyethylene ether
- agricultural
- florasulam
- Prior art date
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- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 55
- 239000004009 herbicide Substances 0.000 title claims abstract description 55
- 239000005529 Florasulam Substances 0.000 title claims abstract description 36
- QZXATCCPQKOEIH-UHFFFAOYSA-N Florasulam Chemical compound N=1N2C(OC)=NC=C(F)C2=NC=1S(=O)(=O)NC1=C(F)C=CC=C1F QZXATCCPQKOEIH-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000003240 coconut oil Substances 0.000 title claims abstract description 35
- 235000019864 coconut oil Nutrition 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 150000001875 compounds Chemical class 0.000 title claims abstract description 17
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 71
- 229930182470 glycoside Natural products 0.000 claims abstract description 71
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 46
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 46
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000004359 castor oil Substances 0.000 claims abstract description 12
- 235000019438 castor oil Nutrition 0.000 claims abstract description 12
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 20
- 239000012752 auxiliary agent Substances 0.000 claims description 18
- 239000002270 dispersing agent Substances 0.000 claims description 18
- 239000002562 thickening agent Substances 0.000 claims description 18
- 238000009736 wetting Methods 0.000 claims description 18
- 239000002518 antifoaming agent Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000013530 defoamer Substances 0.000 claims description 9
- 239000013523 DOWSIL™ Substances 0.000 claims description 8
- 229920013731 Dowsil Polymers 0.000 claims description 8
- 238000009472 formulation Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 150000003333 secondary alcohols Chemical class 0.000 claims description 8
- 229920001285 xanthan gum Polymers 0.000 claims description 8
- 239000000230 xanthan gum Substances 0.000 claims description 8
- 229940082509 xanthan gum Drugs 0.000 claims description 8
- 235000010493 xanthan gum Nutrition 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 229930182478 glucoside Natural products 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 239000004289 sodium hydrogen sulphite Substances 0.000 claims description 7
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 150000008131 glucosides Chemical class 0.000 claims description 6
- HELHAJAZNSDZJO-UHFFFAOYSA-L sodium tartrate Chemical compound [Na+].[Na+].[O-]C(=O)C(O)C(O)C([O-])=O HELHAJAZNSDZJO-UHFFFAOYSA-L 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 abstract description 16
- 239000000575 pesticide Substances 0.000 abstract description 10
- 239000001433 sodium tartrate Substances 0.000 abstract description 6
- 229960002167 sodium tartrate Drugs 0.000 abstract description 6
- 235000011004 sodium tartrates Nutrition 0.000 abstract description 6
- 229940080421 coco glucoside Drugs 0.000 abstract description 5
- 150000002191 fatty alcohols Chemical class 0.000 abstract description 5
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 abstract description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000361 pesticidal effect Effects 0.000 abstract description 4
- 210000001595 mastoid Anatomy 0.000 abstract description 3
- 231100000674 Phytotoxicity Toxicity 0.000 abstract description 2
- 239000001569 carbon dioxide Substances 0.000 abstract description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- 238000011056 performance test Methods 0.000 description 6
- 239000012747 synergistic agent Substances 0.000 description 6
- 210000002615 epidermis Anatomy 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- JBDHZKLJNAIJNC-LLVKDONJSA-N clodinafop-propargyl Chemical group C1=CC(O[C@H](C)C(=O)OCC#C)=CC=C1OC1=NC=C(Cl)C=C1F JBDHZKLJNAIJNC-LLVKDONJSA-N 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 238000009333 weeding Methods 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- 241000208195 Buxaceae Species 0.000 description 1
- 101100305924 Caenorhabditis elegans hoe-1 gene Proteins 0.000 description 1
- 235000014820 Galium aparine Nutrition 0.000 description 1
- 240000005702 Galium aparine Species 0.000 description 1
- 102000005548 Hexokinase Human genes 0.000 description 1
- 108700040460 Hexokinases Proteins 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001086 cytosolic effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 210000000473 mesophyll cell Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004114 suspension culture Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
Abstract
The invention relates to the technical field of pesticides, and in particular provides a compound preparation containing florasulam herbicide and agricultural coconut oil synergist, wherein the agricultural coconut oil synergist is prepared from the following raw materials: 1.3 parts of alkyl glycoside and derivative thereof, and 0.9 part of fatty alcohol polyoxyethylene ether and derivative thereof; wherein the alkyl glycoside and its derivatives include: coco alkyl glycoside, coco glucoside sodium tartrate, sulfonated alkyl glycoside; the fatty alcohol-polyoxyethylene ether and the derivative thereof comprise branched chain secondary alcohol-polyoxyethylene ether, laurinol-polyoxyethylene ether and castor oil polyoxyethylene ether. The compound preparation containing the florasulam herbicide and the agricultural coconut oil synergist provided by the invention can break through the mastoid structure on the plant surface after being used, so that the florasulam herbicide can keep hemispherical on the leaf surface, crops can be fully contacted with carbon dioxide and sunlight, the pesticide effect is improved, and meanwhile, the phytotoxicity is reduced.
Description
Technical Field
The invention relates to the technical field of pesticides, in particular to a compound preparation containing florasulam herbicide and agricultural coconut oil synergist.
Background
The agricultural chemical has changeable use scene, and the plant has its own protecting mode, so that it has epidermis comprising epidermis cell, stomata, epidermis fur, etc. The epidermis is often surrounded by a waxy cuticle, the major constituent of which is lipids. Due to the existence of the horny layer, the absorption efficiency of the plant is greatly reduced after the pesticide is sprayed on the surface of the leaf. Pesticide is a process of diffusion through the stratum corneum. The surfactant can alter the penetration properties of the plant's cuticle and increase the ability of the pesticide to penetrate through the cuticle.
Similarly, the existing agricultural coconut oil synergist often focuses on reducing the surface tension and improving the effects of pesticide or fertilizer penetration and the like; however, also, excessively decreasing the surface tension increases the probability of bouncing for a spray-type dosage form; meanwhile, in order to improve the pesticide effect, the permeability of the pesticide is required too high in the market at present, so that more penetration and accumulation are often caused to plants, and pesticide residues are caused.
Aiming at the situation, the invention provides the compound preparation containing the florasulam herbicide and the agricultural coconut oil synergist, which can effectively and moderately stimulate the absorption of plants, does not excessively stimulate the plants to absorb pesticides, and simultaneously can effectively improve the pesticide effect.
Disclosure of Invention
The invention provides a compound preparation containing florasulam herbicide and agricultural coconut oil synergist, which is prepared from the following raw materials: 1.3 parts of alkyl glycoside and derivative thereof, and 0.9 part of fatty alcohol polyoxyethylene ether and derivative thereof;
wherein the alkyl glycoside and its derivatives include: one or more of coco alkyl glycoside, coco glucoside sodium tartrate, sulfonated alkyl glycoside;
the fatty alcohol-polyoxyethylene ether and the derivative thereof comprise one or more of branched chain secondary alcohol-polyoxyethylene ether, laurinol-polyoxyethylene ether and castor oil polyoxyethylene ether.
The preparation method of the sulfonated alkyl glycoside comprises the following steps:
and (3) stirring and continuously reacting the C12C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12C14 alkyl glycoside for 3 hours at 50-90 ℃, dehydrating and drying to obtain the sulfonated alkyl glycoside.
The florasulam herbicide is prepared from the following raw materials: 5% of florasulam and 95% of auxiliary agent; the auxiliary agent comprises a wetting dispersant, an antifreezing agent, a defoaming agent and a thickening agent;
the wetting dispersant comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1; the antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1.
The florasulam herbicide is mixed with 5wt% of the agricultural coconut oil synergist when being used together with water.
By adopting the technical scheme, the invention has the following beneficial effects:
the compound preparation containing the florasulam herbicide and the agricultural coconut oil synergist provided by the invention can break through the mastoid structure on the plant surface, so that the florasulam herbicide can keep a hemispherical shape on the leaf surface, crops can fully contact with carbon dioxide and sunlight, the pesticide effect is improved, and meanwhile, the phytotoxicity is reduced.
Detailed Description
The following description of the present invention will be made clearly and fully, and it is apparent that the embodiments described are some, but not all, of the embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention provides a compound preparation containing florasulam herbicide and agricultural coconut oil synergist, which is prepared from the following raw materials: 1.3 parts of alkyl glycoside and derivative thereof, and 0.9 part of fatty alcohol polyoxyethylene ether and derivative thereof.
As an embodiment of the present invention, the alkyl glycoside and its derivative is selected from one or more of C12C14 alkyl glycoside, coco alkyl glycoside, C08C10 alkyl glycoside, coco glucoside sodium tartrate, sulfonated alkyl glycoside.
As an embodiment of the present invention, the alkyl glycoside and its derivative comprise one or more of coco alkyl glycoside, coco glucoside sodium tartrate, sulfonated alkyl glycoside.
As a more preferred mode of the present invention, the alkyl glycoside and its derivative include: cocoalkyl glycoside, coco glucoside sodium tartrate, sulfonated alkyl glycoside.
As one embodiment of the invention, the fatty alcohol polyoxyethylene ether and the derivative thereof are selected from one or more of branched secondary alcohol polyoxyethylene ether, laureth, isooctyl alcohol EO/PO polyether, fatty alcohol polyoxyethylene ether sodium sulfate AES and castor oil polyoxyethylene ether.
As an embodiment of the present invention, the fatty alcohol-polyoxyethylene ether and its derivative include one or more of branched secondary alcohol-polyoxyethylene ether, laurinol-polyoxyethylene ether, castor oil polyoxyethylene ether.
As an embodiment of the present invention, the fatty alcohol-polyoxyethylene ether and its derivative include branched secondary alcohol-polyoxyethylene ether, laurinol-polyoxyethylene ether, castor oil-polyoxyethylene ether.
As a preferred mode of the present invention, the agricultural coconut oil synergist comprises: cocoyl alkyl glycoside, cocoyl glucoside sodium tartrate, sulfonated alkyl glycoside, branched secondary alcohol polyoxyethylene ether, laurinol polyoxyethylene ether, and castor oil polyoxyethylene ether.
The agricultural coconut oil synergist comprises the following components in parts by mass: 1 part of cocoyl alkyl glycoside, 0.2 part of cocoyl glucoside tartrate sodium, 0.1 part of sulfonated alkyl glycoside, 0.5 part of branched secondary alcohol polyoxyethylene ether, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether.
As a preferred mode of the invention, the preparation method of the sulfonated alkyl glycoside comprises the following steps:
and (3) stirring and continuously reacting the C12C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12C14 alkyl glycoside for 3 hours at 50-90 ℃, dehydrating and drying to obtain the sulfonated alkyl glycoside.
The raw materials for preparing the florasulam herbicide comprise florasulam and an auxiliary agent; the herbicide is prepared from the following raw materials in percentage by mass: 5% of florasulam and 95% of auxiliary agents.
Wherein the 95% adjuvant comprises: 2-10% of wetting dispersant, 0.1-5% of antifreezing agent, 0.5-5% of thickening agent, 0.1-1% of defoaming agent and the balance of water.
As a preferred mode of the invention, considering the components of agricultural coconut oil synergistic agent, the wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913.
Antifreezing agent: the antifreezing agent comprises glycol and methylamine alcohol.
And (3) a thickening agent: the thickener in the invention is xanthan gum.
Defoaming agent: the defoamer in the invention is an organosilicon defoamer, in particular DOWSIL 62Additive.
The application method of the compound preparation containing the florasulam herbicide and the agricultural coconut oil synergist is that 5 weight percent of the agricultural coconut oil synergist is added to the florasulam herbicide for mixed use when water is added.
The synergist provided by the invention can play a role in quick drug effect; simultaneously can stimulate the stomata of plants to open, and can be absorbed by drug effect. In addition, the invention can not blindly stimulate the increase of air holes, and can not only be used as a conventional surface activity to reduce the surface tension, but also stimulate hexokinase after subsequent decomposition, and stimulate the synthesis and closing of air holes because the invention selects the bio-based alkyl glycoside as a synergist. Meanwhile, after the matched herbicide is matched with the synergist, the effect is quick and long, and the possible reason is that the herbicide can stimulate guard cells to cause cytoplasmic acidification or alkalization so as to control the closing of stomata. Thereby effectively solving the problem of pesticide accumulation. Meanwhile, experiments show that the effect of the fluorine-containing herbicide is better, and the glycol and the methylamine alcohol in the matched antifreezing agent can be very beneficial to reducing the surface tension of the fluorine-containing herbicide on some surface three-dimensional, especially mastoid structures, so that the efficacy is very high.
The invention is further illustrated with reference to specific embodiments.
Example 1
This example provides a combination formulation comprising a florasulam herbicide and an agricultural coconut oil synergist wherein
The agricultural coconut oil synergist is prepared from the following raw materials: 1 part of cocoyl alkyl glycoside, 0.2 part of cocoyl glucoside tartrate sodium, 0.1 part of sulfonated alkyl glycoside, 0.5 part of branched secondary alcohol polyoxyethylene ether, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether.
The preparation method of the sulfonated alkyl glycoside comprises the following steps:
and (3) stirring and continuously reacting the C12C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12C14 alkyl glycoside for 3 hours at 50-90 ℃, dehydrating and drying to obtain the sulfonated alkyl glycoside.
The florasulam herbicide comprises 5% florasulam and 95% auxiliary agent according to mass percentage.
The 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water. The wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1. The antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1. The thickener is xanthan gum. The defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive. The herbicide is in a suspension formulation.
The use method of the compound preparation in the embodiment is as follows: when the herbicide is diluted by adding water, 5wt% of the agricultural coconut oil synergistic agent is added.
Example 2
This example provides a combination formulation comprising a florasulam herbicide and an agricultural coconut oil synergist wherein
The agricultural coconut oil synergist is prepared from the following raw materials: 1 part of cocoyl alkyl glycoside, 0.2 part of cocoyl glucoside tartrate sodium, 0.5 part of branched secondary alcohol polyoxyethylene ether, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether.
The florasulam herbicide comprises the following preparation raw materials in percentage by mass: 5% of florasulam and 95% of auxiliary agents.
The 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water. The wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1. The antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1. The thickener is xanthan gum. The defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive. The herbicide is in the form of a suspending agent.
The use method of the compound preparation in the embodiment is as follows: when the herbicide is diluted by adding water, 5wt% of the agricultural coconut oil synergistic agent is added.
Example 3
This example provides a combination formulation comprising a florasulam herbicide and an agricultural coconut oil synergist wherein
The agricultural coconut oil synergist is prepared from the following raw materials: 1 part of cocoyl alkyl glycoside, 0.1 part of sulfonated alkyl glycoside, 0.5 part of branched secondary alcohol polyoxyethylene ether, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether.
The preparation method of the sulfonated alkyl glycoside comprises the following steps:
and (3) stirring and continuously reacting the C12C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12C14 alkyl glycoside for 3 hours at 50-90 ℃, dehydrating and drying to obtain the sulfonated alkyl glycoside.
The florasulam herbicide is prepared from the following raw materials in percentage by mass: 5% of florasulam and 95% of auxiliary agents.
The 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water. The wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1. The antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1. The thickener is xanthan gum. The defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive.
The use method of the compound preparation in the embodiment is as follows: when the herbicide is diluted by adding water, 5wt% of the agricultural coconut oil synergistic agent is added.
Example 4
This example provides a combination formulation comprising a florasulam herbicide and an agricultural coconut oil synergist wherein
The agricultural coconut oil synergist is prepared from the following raw materials: 1 part of cocoyl alkyl glycoside, 0.2 part of cocoyl glucoside tartrate sodium, 0.1 part of sulfonated alkyl glycoside, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether.
The preparation method of the sulfonated alkyl glycoside comprises the following steps:
and (3) stirring and continuously reacting the C12C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12C14 alkyl glycoside for 1-7 h at 50-90 ℃, dehydrating and drying to obtain the sulfonated alkyl glycoside.
The florasulam herbicide comprises the following preparation raw materials in percentage by mass: 5% of florasulam and 95% of auxiliary agents.
The 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water. The wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1. The antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1. The thickener is xanthan gum. The defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive. The herbicide is in a suspension formulation.
The use method of the compound preparation in the embodiment is as follows: when the herbicide is diluted by adding water, 5wt% of the agricultural coconut oil synergistic agent is added.
Example 5
The embodiment provides a compound preparation containing clodinafop-propargyl herbicide and agricultural coconut oil synergist, wherein
The agricultural coconut oil synergist is prepared from the following raw materials: 1 part of cocoyl alkyl glycoside, 0.2 part of cocoyl glucoside tartrate sodium, 0.1 part of sulfonated alkyl glycoside, 0.5 part of branched secondary alcohol polyoxyethylene ether, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether.
The preparation method of the sulfonated alkyl glycoside comprises the following steps:
and (3) stirring and continuously reacting the C12C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12C14 alkyl glycoside for 3 hours at 50-90 ℃, dehydrating and drying to obtain the sulfonated alkyl glycoside.
The clodinafop-propargyl herbicide comprises the following preparation raw materials in percentage by mass: 5% of clodinafop-propargyl and 95% of auxiliary agent.
The 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water. The wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1. The antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1. The thickener is xanthan gum. The defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive.
The use method of the compound preparation in the embodiment is as follows: when the herbicide is diluted by adding water, 5wt% of the agricultural coconut oil synergistic agent is added.
Example 6
The embodiment provides a herbicide suspending agent, which comprises 5% of florasulam and 95% of auxiliary agent according to mass percent.
The 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water. The wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1. The antifreezing agent comprises glycol and methylamine alcohol, and the mass ratio is 3:1. The thickener is xanthan gum. The defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive.
Performance test 1: testing in field
Selection of test subjects weeds: radix seu herba Myrtilli, herba Hedyotidis Diffusae, herba Galii Teneri, and herba Avenae Fatuae.
The test is carried out in a nursery garden of a soft town river branch Wang Dengpan contractor of Jiyuan city, the area is 25 mu, the planted seedlings are boxwood, the soil is clay, the pH value is 7.8, and the organic matter content is 1.7%.
Other conditions: manual weeding was performed in the last ten days of 8 months at the test site. Weeds developed heavier when applied.
Dosage of application: 40 g/mu. Spraying weed with stem and leaf, spraying clear water, spraying test agent uniformly, and keeping the spray head at 0.3 m from the ground; the manual weeding treatment is immediately carried out after the spraying of the pesticide, and the iron hoe is used for shallow hoe 1 time, so as to achieve uniformity.
= (number of weed plants in control group-number of weed plants in treated area)/number of weed plants in control group × 100.
TABLE 1 weed control efficacy in non-cultivated land- -post-drug control efficacy
Performance test 2:
the suspension rate measuring method comprises the following steps: see GB/T14825-2006.
Thermal storage stability test determination method: see GB/T19136-2003.
Cold storage stability test determination method: see GB/T19137-2003.
TABLE 2 test results of Performance test 2
Performance test 3 air hole opening observation
Mature leaves of the cleavers are selected, washed and placed in a buffer solution (containing KCl 50 mmol.L) containing Mes-KCl -1 ，Mes 10mmol · L -1 ，CaCl 2 0.1 mmol · L -1 In a Petri dish (. Phi.12 cm) at pH 6.4), the incubator (240 mol.m) was illuminated at 25 ℃ -2 · s -1 ) Culture medium was suspended for 2 h.
After transferring leaves of suspension culture 2 h to Mes-KCl buffer added with 0.01wt% herbicide of examples 1-11 for 2 h, 0.5 h was observed for 1 stomatal opening.
Before microscopic observation, the subleaf epidermis was gently removed with forceps, the adherent mesophyll cells were carefully removed with a blade and a brush, cut into strips (0.5 cm. Times.0.5. 0.5 cm), and the opening of the air holes was continuously observed under a Nikon TE100 light microscope (400X). And shooting a pore picture by using an image acquisition system (MShot Digital Imaging System), and measuring data by using a micrometer and Adobe Photoshop 6.0 software to obtain a pore opening value.
TABLE 3 test results of Performance test 3
The performance test 3 shows that the herbicide provided by the invention can control the opening and closing of the air holes and accelerate the absorption of the herbicide.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and not for limiting the same; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some or all of the technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the invention.
Claims (1)
1. A compound formulation comprising a florasulam herbicide and an agricultural coconut oil synergist, characterized in that the agricultural coconut oil synergist is prepared from the following raw materials: 1 part of cocoyl alkyl glycoside, 0.2 part of cocoyl glucoside tartrate sodium, 0.1 part of sulfonated alkyl glycoside, 0.5 part of branched secondary alcohol polyoxyethylene ether, 0.3 part of laurinol polyoxyethylene ether and 0.1 part of castor oil polyoxyethylene ether;
the preparation method of the sulfonated alkyl glycoside comprises the following steps: at 50-90 ℃, stirring and continuously reacting C12-C14 alkyl glycoside, sodium bisulphite accounting for 15% of the mass of the C12-C14 alkyl glycoside and formaldehyde accounting for 5% of the mass of the C12-C14 alkyl glycoside for 3 hours, dehydrating and drying to obtain sulfonated alkyl glycoside;
the florasulam herbicide is prepared from the following raw materials: 5% of florasulam and 95% of auxiliary agent;
the 95% auxiliary agent comprises: 4% of wetting dispersant, 4% of antifreezing agent, 1.5% of thickener, 0.5% of defoamer and the balance of water;
the wetting dispersant in the herbicide comprises Ackesu Morwet-D-110 and Atlox4913, and the mass ratio is 3:1;
the antifreezing agent comprises ethylene glycol and methylamine alcohol, and the mass ratio is 3:1;
the thickener is xanthan gum;
the defoaming agent is an organic silicon defoaming agent, and specifically is DOWSIL 62Additive;
the herbicide is in a suspension formulation;
the florasulam herbicide is mixed with 5wt% of the agricultural coconut oil synergist when being used together with water.
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Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2465350A1 (en) * | 2010-12-15 | 2012-06-20 | Basf Se | Pesticidal mixtures |
| CN102871921A (en) * | 2012-10-15 | 2013-01-16 | 金红叶纸业集团有限公司 | Hand cleaner composition |
| CN104274384A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Body perfumed shower gel containing biological bacteriostatic agent |
| CN105557717A (en) * | 2016-03-03 | 2016-05-11 | 江苏丰山集团股份有限公司 | Florasulam suspension agent and preparation method thereof |
| CN105685094A (en) * | 2016-03-11 | 2016-06-22 | 浙江天丰生物科学有限公司 | Compound herbicide composition |
| CN105875608A (en) * | 2014-11-04 | 2016-08-24 | 重庆市赛欧生态农业有限公司 | Bactericidal composition for crops |
| CN106561645A (en) * | 2016-10-20 | 2017-04-19 | 钟祥尤生农药有限公司 | Agricultural synergist, and preparation method and application of agricultural synergist |
| CN109042721A (en) * | 2018-09-17 | 2018-12-21 | 四川利尔作物科学有限公司 | Herbicidal combinations and its application |
| CN109694699A (en) * | 2017-10-23 | 2019-04-30 | 中石化石油工程技术服务有限公司 | A kind of shale oil air water horizontal well water-base drilling fluid |
| CN109705996A (en) * | 2019-01-23 | 2019-05-03 | 蓝思科技（长沙）有限公司 | A kind of cleaning agent and preparation method thereof |
| CN111320661A (en) * | 2018-12-13 | 2020-06-23 | 中石化石油工程技术服务有限公司 | Polyamino sulfonated alkyl glycoside, preparation method thereof and drilling fluid |
| CN113164361A (en) * | 2018-12-06 | 2021-07-23 | 高露洁-棕榄公司 | Personal care compositions |
| CN113455500A (en) * | 2021-07-27 | 2021-10-01 | 济南天邦化工有限公司 | Pesticide synergist and preparation method and application thereof |
| WO2022224275A1 (en) * | 2021-04-20 | 2022-10-27 | Rajdhani Petrochemicals Private Limited | Synergistic agrochemical oil dispersion formulation |
| WO2022229654A1 (en) * | 2021-04-30 | 2022-11-03 | UPL Corporation Limited | Herbicidal compositions with enhanced soil mobility |
-
2023
- 2023-12-22 CN CN202311781287.1A patent/CN117441736B/en active Active
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2465350A1 (en) * | 2010-12-15 | 2012-06-20 | Basf Se | Pesticidal mixtures |
| CN102871921A (en) * | 2012-10-15 | 2013-01-16 | 金红叶纸业集团有限公司 | Hand cleaner composition |
| CN104274384A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Body perfumed shower gel containing biological bacteriostatic agent |
| CN105875608A (en) * | 2014-11-04 | 2016-08-24 | 重庆市赛欧生态农业有限公司 | Bactericidal composition for crops |
| CN105557717A (en) * | 2016-03-03 | 2016-05-11 | 江苏丰山集团股份有限公司 | Florasulam suspension agent and preparation method thereof |
| CN105685094A (en) * | 2016-03-11 | 2016-06-22 | 浙江天丰生物科学有限公司 | Compound herbicide composition |
| CN106561645A (en) * | 2016-10-20 | 2017-04-19 | 钟祥尤生农药有限公司 | Agricultural synergist, and preparation method and application of agricultural synergist |
| CN109694699A (en) * | 2017-10-23 | 2019-04-30 | 中石化石油工程技术服务有限公司 | A kind of shale oil air water horizontal well water-base drilling fluid |
| CN109042721A (en) * | 2018-09-17 | 2018-12-21 | 四川利尔作物科学有限公司 | Herbicidal combinations and its application |
| CN113164361A (en) * | 2018-12-06 | 2021-07-23 | 高露洁-棕榄公司 | Personal care compositions |
| CN111320661A (en) * | 2018-12-13 | 2020-06-23 | 中石化石油工程技术服务有限公司 | Polyamino sulfonated alkyl glycoside, preparation method thereof and drilling fluid |
| CN109705996A (en) * | 2019-01-23 | 2019-05-03 | 蓝思科技（长沙）有限公司 | A kind of cleaning agent and preparation method thereof |
| WO2022224275A1 (en) * | 2021-04-20 | 2022-10-27 | Rajdhani Petrochemicals Private Limited | Synergistic agrochemical oil dispersion formulation |
| WO2022229654A1 (en) * | 2021-04-30 | 2022-11-03 | UPL Corporation Limited | Herbicidal compositions with enhanced soil mobility |
| CN113455500A (en) * | 2021-07-27 | 2021-10-01 | 济南天邦化工有限公司 | Pesticide synergist and preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 50g/L双氟磺草胺悬浮剂配方筛选;高亮;姜斌;王丽颖;;农药;20160510(第05期);25-27 * |
| 烷基糖苷与阴离子表面活性剂复配体系的泡沫和润湿性能;沈琼霞;张威;;日用化学品科学;20160925(第09期);24-27，33 * |
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