CN109042721A - Herbicidal combinations and its application - Google Patents
Herbicidal combinations and its application Download PDFInfo
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- CN109042721A CN109042721A CN201811080587.6A CN201811080587A CN109042721A CN 109042721 A CN109042721 A CN 109042721A CN 201811080587 A CN201811080587 A CN 201811080587A CN 109042721 A CN109042721 A CN 109042721A
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- grass
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
- A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Abstract
The invention discloses a kind of Herbicidal combinations and its applications.The Herbicidal combinations include active components A and active constituent B.Wherein, the active components A is smart glufosinate-ammonium, and the active constituent B includes dicamba.The active components A and the weight ratio of active constituent B are 80:1~1:80.The Herbicidal combinations can be used for preventing and treating perennial grass weeds, broadleaf weeds and nutgrass flatsedge weeds.By the compounding of a variety of active ingredients, the efficiency of preventing and kill off of elder weed is improved, low temperature preventive effect is improved, reduces the dosage of herbicidal active component, improves the quick-acting of medicament, reduces dosage.
Description
Technical field
The present invention relates to a kind of Herbicidal combinations, in particular to a kind of Herbicidal combinations comprising smart glufosinate-ammonium, and its
Application in agricultural.
Background technique
The chemical name of smart glufosinate-ammonium is 4- [hydroxyl (methyl) phosphono]-L- high lactamine, soluble easily in water, is not readily dissolved in
Organic solvent stablizes light, and fusing point is 214-216 DEG C, molecular formula are as follows: C5H12NO4P；Molecular weight: 181.1；Structural formula are as follows:
Smart glufosinate-ammonium belongs to non-conducting contact killing type herbicide, controlling weeds be by inhibiting glutamine synthelase,
Lead to nitrogen metabolism disorder in plant, the accumulative poisoning of nitrogen, and then chloroplaset synthesis and photosynthesis is made to be obstructed, eventually leads to plant
It is dead.The advantages that smart glufosinate-ammonium has toxicity low, and highly-safe, herbicidal spectrum is wide, and activity is high, and weeding speed is fast.Moreover, essence grass ammonium
Phosphine good water solubility facilitates processing and is used in combination.
Dicamba (Dicamba, 3,6- bis- chloro- O-Anisic Acids) is benzoic acid herbicide, chemical structural formula
It is as follows:
Dicamba has uptake and translocation effect, has significant preventive effect to annual and perennial broadleaf weed, is used for wheat, jade
The gramineous crops such as rice, millet, rice prevent and kill off clearvers, corn-bind, Chenopodiaceae, ox chickweed, common vetch, broadcast ma's lettuce, Siberian cocklebur, Bao Shuo
Grass, field bindweed, field thistle, meadow pine, carp intestines etc., spraying after seedling, medicament is absorbed by the stem, leaf, root of weeds, by bast and
Xylem conducts up and down, hinders the normal activity of plant hormone, to make its death.
In addition, smart glufosinate-ammonium or dicamba single dose, which is used for a long time, can be easy to cause drug resistance, dosage is caused to increase, ring
Border influences to increase, and control efficiency reduces, and drug cost increases.
Summary of the invention
In view of this, the main purpose of the present invention is to provide a kind of Herbicidal combinations, by including smart glufosinate-ammonium conduct
One of active constituent is compounded with dicamba, and that improves elder weed prevents and kill off efficiency, reduces the dosage of herbicidal active component, is improved
The quick-acting of medicament reduces dosage.
According on one side, the present invention provides a kind of Herbicidal combinations, including active components A and active constituent B,
In, the active components A is smart glufosinate-ammonium, and the active constituent B includes dicamba, wherein the active components A and activity at
The weight ratio for dividing B is 100:1~1:100.
Based on the total weight of the Herbicidal combinations, the weight percent of the active components A and active constituent B is 1~
60%.
According to a specific embodiment, the effective dose of the Herbicidal combinations is 1~150g (a.i.)/ha.
According to another embodiment, based on the total weight of the Herbicidal combinations, the Herbicidal combinations include:
Smart glufosinate-ammonium 1~30%, dicamba 1~15%, composite assistant 1~35%.
According to a specific embodiment, the active constituent B further includes one of following herbicide or a variety of: weed eradication
Pine, haloxyfop-r-methyl, Quizalotop-ethyl, clethodim, trichlopyr, Acetochlor, butachlor, alachlor, propisochlor,
The left-handed naphthalene propionyl grass amine of isopropyl methoxalamine, S-metolachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R-, enemy
Barnyard grass, mefenacet, diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromobutide, dimethenamid,
DimethenamidP, ethobenzanid, flufenacet, thenylchlor, metazachlor, isoxaben, flampropMmethyl,
FlampropMisopropyl, allidochlor, pethoxamid, chloranocryl, ring pretilachlor, mefluidide, monalide, isobutyl grass
Amine, prynachlor, terbuchlor, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, clomeprop, alkynes benzoyl
Careless amine, valeryl benzene grass amine block careless amine, suffer, tricyclic match careless amine, butenachlor, tebutam, benzyl grass amine, quinone duckweed amine, benzene fluorine sulphur
Amine, naproanilide, acetyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, benzene grass more grams of dead, chlorothiamid, chlorine phthalimides, fourth amidine
Amine, fluorine metazachlor, atrazine, Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine, dipropetryn, flur, spy
Ding Jing, Garagard, triaziflam, cyprazine, proglinazine, trietazine, prometon, Gesadrual, nitrine be net, desmetryn, isoamyl
Second is net, the green saliva of cyclopropyl, green bristlegrass of going out saliva, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third are net, cyanatryn, ipazine, chlorazine, green bristlegrass are gone
It is logical, weed eradication is logical, Radix Glycyrrhizae saliva, cyanuric acid, indaziflam grass amine, green sulphur are grand, metsulfuron-methyl, bensulfuron-methyl, chlorimuron, tribenuron-methyl,
Thifensulfuron methyl, pyrazosulfuron, mesosulfuron, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, cinosulfuron, triasulfuron, first are phonetic
Sulphur is grand, ethametsulfuron, amidosulfuron, ethoxysulfuron, cypromisulfuron, azimsulfuron, pyridine ethyl methyl, monosulfmeturon, list
Phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, primisulfuronmethyl, propyl benzene sulphur
Grand, prosulfuron, Sulfosulfuron, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, flucetosulfuron, first
Sulphur Sulfometuron Methyl, orthosulfamuron, proxazuron-methyl, piperazine pyrazosulfuron, acifluorfen, lactofen, Mo 9 granular, benzene grass
Ether, ethoxyfen-ethyl, bifenox, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorination nitrofen, fluorine furan grass
Ether, nitrofen, first grass ether, diformazan grass ether, fluorine lactazone grass ether, fluofazone ester, fluorine nitre sulfonamide, chlortoluron, isoproturon, Li Gu
Grand, diuron, Sha flutter grand, fluometuron, benzthiazuron, methabenzthiazuron, cumyluron, ethidimuron, isouron, terbufos benzthiazuron, alkynes
The grand, bromax of grass, methyldymron, phenobenzuron, methoxy daimuron, metobromuron, metoxuron, afesin, telvar, Tupersan,
Fenuron, fluorine sulphur is grand, neburea, chloroxifenidium, herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron, difenoxuron, to fluorine
Grand, methylamine methabenz thiazuron, Long Caote, front three isourea, dimefuron, special dimefuron, dredge grand grand grass, methiuron, ethoxy benzene, four fluon,
The careless spirit of phenmedipham, phenmedipham-ethyl ester, desmedipham, sulphur, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, is gone out at terbucarb
Careless spirit, chlorbufam, special oxazole prestige, grass lose dead, acyl benzene sulphur prestige, BCPC, CPPC, kappa grass spirit, Ding Caote, benthiocarb, vernolate,
Molinate, tri-allate, dimepiperate, esprocarb, pyributicarb, cycloate, Avadex, bactericide, second sulphur careless spy, orbencarb, gram grass
Suddenly, prosulfocarb, tiocarbazil, sulfuric acid, dimexan, nitrogen Bi grass, first sulphur benzene prestige, the different monooctyl ester butyl ester of 2,4-D, 2,4-D, 2,4-D
The different monooctyl ester of different monooctyl ester, the different monooctyl ester sodium salt of 2,4-D, the different monooctyl ester dimethylamine salt of 2,4-D, the different monooctyl ester propionic acid of 2,4-D, the different monooctyl ester of 2,4-D
Butyric acid, 2,4,5- tears, 2,4,5- tears propionic acid, 2,4,5- tears butyric acid, erbon, Fenac, match pine, trichlorobenzoic acid, hydrazine dichloride benzene
Acid, methoxy trichlorobenzoic acid, diclofop-methyl, fluazifop, efficient fluazifop, efficient haloxyfop, fenoxaprop-P, essence are disliked
Azoles diclofop-methyl, propaquizafop, cyhalofop-butyl, clodinafop-propargyl, diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of penta standing grain of hydroxyl, trifluoro dogstail oxime, different evil grass
Ether, paraquat, diquat dibromide, oryzalin, ethalfluralin, isopropalin, nitralin, profluralin, prodiamine, second fourth
Fluorine spirit, fluchloraline, the spirit of amino second fluorine, dipropalin, chloroethene dipropalin, fluorine alkene nitre grass, the third nitre phenol, Sha barnyard grass phosphine, amiprophos-methyl,
Sulphosate, bialaphos, bensulide, butamifos, creeping weed phosphorus, cuts down ridge phosphorus, double first amiprophos, dow crabgrass killer, imidazoles cigarette at piperazine grass phosphine
Acid, imazethapyr, imazaquin, imazamox, imazamox ammonium salt, AC 263222, miaow grass ester, chlorine fluorine pyrrole oxygen
The different monooctyl ester of acetic acid, fluroxypyr, dithiopyr, halogen grass be fixed, phenolate trichloropyridine, thiazopyr, fluridone, diflufenzopyr,
Triclopyr butoxyethyl ester, iodine chlorine pyridine ester, sethoxydim, cycloxydim, alloxydimsodium, clefoxidim, butroxydim, oxime grass
Ketone, tepraloxydim, special imidazoles grass, metribuzin, hexazinone, metamitron, ethiozin, special saliva ketone, special grass piperazine ketone, Brominal,
Bromoxynil octanoate, ioxynil octanoate, ioxynil, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil, azoles are phonetic
Sulphur grass amine, florasulam, metosulam, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, pyribenzoxim,
Pyriftalid, KIH 6127, pyrithiobacsodium, benzobicylon, mesotrione, sulphur humulone, tembotrions, special furan triketone, fluorine benzofenap,
Ketodpiradox, isoxaflutole, isoxachlorotole, Fenoxasulfone, Methiozolin, fluazolate, pyrrole grass
Ether, difenzoquat, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, sulphonyl grass pyrazoles, topramezone, sends Roc herbicide sulfone, azoles grass at pyrazolate
Amine, flupoxam, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone, Bencarbazone, the phonetic grass of double benzene
Ketone, butafenacil, bromacil, isoprocil, lenacil, terbacil, Flupropacil, cinidon-ethyl, Flumiclorac pentyl, third
Alkynes benfluralin, alkynes grass amine, phthalein benzyl oxide, trifluoro oxazines, pentachlorophenol (sodium), dinoseb, dinoterb, dinoterb acetate, dinosam, dinitro
Phenol, chlorine nitre phenol, medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, profluazol, fluthiacet, tetrazolium
It is chloro- that acyl grass amine, flufenpyrethyl, pyrazon, brompyrazon, diformazan reach rattle away pine, norflurazon, 6- of careless volt, Kusakira, grass pyridazone, grass
3- phenyl -4- alcohol pyridazines, dichloro quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, clomazone,
Cinmethylin, iso-propyl-ester nitrofen, propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone,
Tetrafluoro propionic acid, herbage are fast, bromofenoxim, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine phthalandione, fluorine
Cough up humulone, barnyard grass, methacrylaldehyde, bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, dioxybenzone,
Chlorine acyl grass phosphine, chloropon, pentachloro- oxopentanoic acid, diethyl weeding be double, ethamine grass ether, Bing Caoding, three azole amides, thiophene ketone sulphur are grand,
Pyrimisulfan, fluorine be phonetic to kill, indanofan, a word used for translation sulphur in heptan ester, first sulphur nitralin, dimethachlor ester, cyclopropyl pyrimidine acid, sulphur benzonitrile
Amine, fenclorim, flurazole, fenchlorazole, solves careless quinoline, oxabetrinil, oxalane, cyometrinil, desorpenic, pyrazoles solution grass at benoxacor
Ester, furilazole, fluxofenim, isoxadifen, allyl dichloride amine, UBH-509, D489, LS 82-556, KPP-300, NC-
324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、
KIH-9201, ET-751, KIH-6127 and KIH-2023.
According to another embodiment, the composite assistant include selected from filler, emulsifier, thickener, antifreezing agent,
Dispersing agent, binder, stabilizer, safener, two or more in synergist.
Optionally, the composite assistant is selected from cocamide glycine betaine, fatty alcohol polyoxyethylene ether sulfate, alkyl sugar
Glycosides, alkylsulfonate, alcohol ether glucoside, aliphatic alcohol sulfate, anhydrous sorbitol mono fatty acid glyceride, castor oil polyoxyethylene
Ether, aliphatic alcohol polyoxyvinethene phosphate, lignosulfonates, polycarboxylate, naphthalene sulfonate and PULLRONIC F68 are embedding
Section polyethers.
It is outstanding that the dosage form of the Herbicidal combinations is selected from aqua, pulvis, granule, microemulsion, aqueous emulsion, oil-suspending agent, water
Floating agent and microcapsule formulations.
According to another aspect of the present invention, the present invention also provides the applications that the Herbicidal combinations are used for management of weeds.
Herbicidal combinations according to the present invention because containing smart glufosinate-ammonium in component, by with dicamba, it is optional other
Herbicide, and matched with above-mentioned composite assistant, it has the advantage that
The efficient and splendid water solubility of smart glufosinate-ammonium is made full use of, it is especially more using dicamba to gramineae weed
The highly selective and quick-acting of year raw weeds；By interacting between smart glufosinate-ammonium, dicamba and composite assistant, plant is improved
The conduction efficiency of surface absorption of drugs efficiency and inside plants, so that the activity of weeding of smart glufosinate-ammonium and dicamba
Performance is more rapidly abundant, to reduce the dosage of pesticidal preparations, expands insecticidal spectrum, further improves above-mentioned compounding
Herbicidal combinations extend the lasting period, to expand the use scope of pesticide to the prevention and treatment efficiency of perennial weeds.
Therefore, Herbicidal combinations according to the present invention have more compared with the smart glufosinate-ammonium and dicamba of exclusive use
Significant synergistic effect.Specifically, Herbicidal combinations according to the present invention are particularly suitable for preventing and kill off asparagus, corn, height
Annual and perennial broadleaf weed in the crop fields such as fine strain of millet, wheat, sugarcane is also used for preventing and kill off the woody brush clump of crop ped location, example
As for preventing and kill off clearvers, corn-bind, Chenopodiaceae, ox chickweed, common vetch, broadcasting ma's lettuce, Siberian cocklebur, Bao Shuocao, field bindweed, thorn
Dish, meadow pine, carp intestines etc..
Specific embodiment
Herbicidal combinations according to the present invention include active components A and active constituent B, and wherein active components A is the careless ammonium of essence
Phosphine, active constituent B include dicamba.
Wherein, the weight ratio of active components A and active constituent B can be 100:1~1:100, preferably 80:1~1:80, more excellent
60:1~1:60, most preferably 30:1~1:30 are selected, may be, for example, 20:1,10:1,5:1,1:1,1:5,1:10,1:20.
According to a specific embodiment, above-mentioned Herbicidal combinations further include composite assistant.Based on the Herbicidal combinations
Total weight, the Herbicidal combinations include: smart glufosinate-ammonium 1~30% (preferably 5~25%, more preferable 10~20%), wheat straw
Fear 1~15% (preferably 1~10%, it is more preferable 5%), composite assistant 1~35% (preferably 5~25%, more preferable 10~20%,
Such as 15%).
Preferably, active constituent B further includes one of following herbicide or a variety of: bentazone, haloxyfop-r-methyl,
Quizalotop-ethyl, clethodim, trichlopyr, Acetochlor, butachlor, alachlor, propisochlor, isopropyl methoxalamine, smart isopropyl
The left-handed naphthalene propionyl grass amine of alachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R-, propanil, mefenacet, double benzene
Acyl grass amine, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromobutide, dimethenamid, dimethenamidP, ethoxy
Benzene grass amine, flufenacet, thenylchlor, metazachlor, isoxaben, flampropMmethyl, flampropMisopropyl, dipropyl
Pethoxamid, pethoxamid, chloranocryl, ring pretilachlor, mefluidide, monalide, delachlor, prynachlor, special fourth grass
Amine, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, clomeprop, propyzamide, valeryl benzene grass amine, card
Careless amine, suffer, tricyclic match careless amine, butenachlor, tebutam, benzyl grass amine, quinone duckweed amine, dichlofluanid, naproanilide, acetyl first grass
Amine, quinclorac, fenacet, pyrrole cyanogen grass amine, more grams of benzene grass be dead, chlorothiamid, chlorine phthalimide, fourth amidine amine, fluorine metazachlor, atrazine,
Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine, dipropetryn, flur, terbutryn, Garagard, triazine fluorine
Careless amine, cyprazine, proglinazine, trietazine, prometon, Gesadrual, nitrine be net, desmetryn, dimethametryn, cyclopropyl blueness saliva, green bristlegrass of going out
Saliva, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third be net, cyanatryn, ipazine, chlorazine, atraton, weed eradication are logical, Radix Glycyrrhizae saliva, three
Paracyanogen acid, indaziflam grass amine, green sulphur is grand, metsulfuron-methyl, bensulfuron-methyl, chlorimuron, tribenuron-methyl, thifensulfuron methyl, pyrazosulfuron, methyl
Two sulphurs are grand, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, cinosulfuron, triasulfuron, sulfometuronmethyl, ethametsulfuron, the phonetic sulphur of acyl
Grand, ethoxysulfuron, cypromisulfuron, azimsulfuron, pyridine ethyl methyl, monosulfmeturon, single phonetic sulphur ester, flucarbazone, fluorine pyridine
Sulfometuron Methyl, fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, primisulfuronmethyl, procarbazone, prosulfuron, sulfo nyl
Grand, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, flucetosulfuron, Sulfonylurea, orthosulfamuron,
Proxazuron-methyl, piperazine pyrazosulfuron, acifluorfen, lactofen, Mo 9 granular, aclonifen, ethoxyfen-ethyl, first carboxylic remove
Careless ether, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorination nitrofen, fluorine furan grass ether, nitrofen, first grass ether, diformazan
Careless ether, fluorine lactazone grass ether, fluofazone ester, fluorine nitre sulfonamide, chlortoluron, isoproturon, linuron, diuron, Sha flutter that grand, fluorine is careless
Grand, benzthiazuron, methabenzthiazuron, cumyluron, ethidimuron, isouron, terbufos benzthiazuron, buturon, bromax, methyl herbicide
Grand, phenobenzuron, methoxy daimuron, metobromuron, metoxuron, afesin, telvar, Tupersan, fenuron, fluorine sulphur is grand, neburea,
Chloroxifenidium, herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron, difenoxuron, to fluon, methylamine methabenz thiazuron, Long Caote,
Front three isourea, special dimefuron, dredges that grand grass, methiuron, ethoxy benzene is grand, four fluon, phenmedipham, phenmedipham-ethyl ester, sweet tea at dimefuron
Dish peace, the careless spirit of sulphur, terbucarb, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, swep, chlorbufam, spy's oxazole prestige,
Grass lose dead, the careless spirit of acyl benzene sulphur prestige, BCPC, CPPC, kappa, Ding Caote, benthiocarb, vernolate, molinate, tri-allate, dimepiperate,
Esprocarb, pyributicarb, cycloate, Avadex, bactericide, second sulphur careless spy, orbencarb, pebulate, prosulfocarb, tiocarbazil, sulphur alkene
Careless pellet, dimexan, nitrogen Bi grass, first sulphur benzene prestige, the different monooctyl ester butyl ester of 2,4-D, 2,4-D, the different monooctyl ester of the different monooctyl ester of 2,4-D, 2,4-D are different pungent
The different monooctyl ester dimethylamine salt of ester sodium salt, 2,4-D, the different monooctyl ester propionic acid of 2,4-D, the different monooctyl ester butyric acid of 2,4-D, 2,4,5- tears, 2,4,5- tears
Propionic acid, 2,4,5- tears butyric acid, erbon, Fenac, match pine, trichlorobenzoic acid, chloramben, methoxy trichlorobenzoic acid, diclofop-methyl,
Fluazifop, efficient fluazifop, efficient haloxyfop, fenoxaprop-P, fenoxapropPethyl, propaquizafop, cyanogen fluorine grass
Ester, clodinafop-propargyl, diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of penta standing grain of hydroxyl, trifluoro dogstail oxime, isoxapyrifop, paraquat, diquat dibromide, peace sulphur
Spirit, ethalfluralin, isopropalin, nitralin, profluralin, prodiamine, benfluralin, fluchloraline, amino second
Fluorine spirit, dipropalin, chloroethene dipropalin, fluorine alkene nitre grass, the third nitre phenol, Sha barnyard grass phosphine, amiprophos-methyl, sulphosate, piperazine grass phosphine, double third ammonia
Phosphine, butamifos, creeping weed phosphorus, cuts down ridge phosphorus, double first amiprophos, dow crabgrass killer, imazapyr, imazethapyr, imidazole quinoline at bensulide
Acid, imazamox, imazamox ammonium salt, AC 263222, miaow grass ester, fluroxypyr, fluroxypyr are different pungent
Ester, dithiopyr, halogen grass be fixed, phenolate trichloropyridine, thiazopyr, fluridone, diflufenzopyr, trichlopyr butoxy second
Ester, iodine chlorine pyridine ester, sethoxydim, cycloxydim, alloxydimsodium, clefoxidim, butroxydim, tralkoxydim, tepraloxydim, special imidazoles grass,
Metribuzin, hexazinone, metamitron, ethiozin, special saliva ketone, special careless piperazine ketone, Brominal, bromoxynil octanoate, ioxynil octanoate,
Ioxynil, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil, Flumetsulam, florasulam, sulphur grass
Azoles amine, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, pyribenzoxim, pyriftalid, KIH 6127, phonetic sulphur grass
Ether, benzobicylon, mesotrione, sulphur humulone, tembotrions, special furan triketone, fluorine benzofenap, Ketodpiradox, isoxazole grass
Ketone, isoxachlorotole, Fenoxasulfone, Methiozolin, fluazolate, pyraflufen-ethyl, pyrazolate, difenzoquat, benzyl grass
Azoles, pyrrole chlorine grass amine, sulphonyl grass pyrazoles, topramezone, sends Roc herbicide sulfone, cafenstrole, flupoxam, Amrol, ammonia at benzofenap
Azoles humulone, azafenidin, profluazone, sulfentrazone, Bencarbazone, benzfendizone, butafenacil, bromacil,
Isoprocil, lenacil, terbacil, Flupropacil, cinidon-ethyl, Flumiclorac pentyl, flumioxazin, alkynes grass amine, phthalein benzyl
Ether, trifluoro oxazines, pentachlorophenol (sodium), dinoseb, dinoterb, dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, medinoterb acetate, it is happy
Spy, oxadiazon, pentoxazone, profluazol, fluthiacet, fentrazamide, flufenpyrethyl, kills at oxadiargyl
The quick, brompyrazon of grass, diformazan reach careless volt, Kusakira, grass pyridazone, grass and rattle away the chloro- 3- phenyl -4- alcohol pyridazines of pine, norflurazon, 6-, dichloro
Quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, clomazone, cinmethylin, iso-propyl-ester nitrofen,
Propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoro propionic acid, herbage is fast, bromine phenol
Oxime, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde,
Bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, dioxybenzone, chlorine acyl grass phosphine, chloropon, pentachloro-
Oxopentanoic acid, diethyl weeding be double, ethamine grass ether, Bing Caoding, three azole amides, thiophene ketone sulphur are grand, Pyrimisulfan, fluorine it is phonetic kill, indenes
Humulone, a word used for translation sulphur in heptan ester, first sulphur nitralin, dimethachlor ester, cyclopropyl pyrimidine acid, rodethanii, benoxacor, fenclorim, flurazole,
Fenchlorazole solves careless quinoline, oxabetrinil, oxalane, cyometrinil, desorpenic, mefenpyrdiethyl, furilazole, fluxofenim, double benzene
Oxazole acid, allyl dichloride amine, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-
N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-
6127 and KIH-2023.
Based on the total weight of the Herbicidal combinations, the weight percent of the active components A and active constituent B is 1~
60%, preferably 10~50%, more preferable 20~40%.
Above-mentioned composite assistant can be selected from cocamide glycine betaine, fatty alcohol polyoxyethylene ether sulfate, alkyl glycosides, alkane
Base sulfonate, alcohol ether glucoside, aliphatic alcohol sulfate, anhydrous sorbitol mono fatty acid glyceride, castor oil polyoxyethylene ether, fat
Alcohol polyoxyethylene ether phosphate, lignosulfonates, polycarboxylate, naphthalene sulfonate and PULLRONIC F68 block polyether.
Alkyl in abovementioned alkyl glucosides and alkylsulfonate may be, for example, C6~C12 alkyl, preferably dodecyl.
Preferably, Herbicidal combinations of the invention may also include the organic solvent of 1~5% weight, preferably 1.5~3.5%,
Such as 2%.
Above-mentioned organic solvent can be selected from ethyl alcohol, methanol, N,N-dimethylformamide, dimethyl sulfoxide, cyclohexanone, toluene.
Herbicidal combinations of the invention may also include the oleaginous bases such as methyl oleate, be used to prepare the dosage forms such as oil emu.
Further, above-mentioned Herbicidal combinations may also include filler, emulsifier, thickener, antifreezing agent, dispersing agent, bonding
One of agent, stabilizer, safener, synergist or a variety of adjuvants.
Filler for use in the present invention can be selected from kaolin, bentonite, white carbon black, light calcium, diatomite.
Based on the total weight of the Herbicidal combinations, the percentage of the active constituent is 1~55%, preferably 5~40%,
More preferable 7~35%, such as 30%, 25% or 15%.
It is outstanding that the dosage form of the Herbicidal combinations is selected from aqua, pulvis, granule, microemulsion, aqueous emulsion, oil-suspending agent, water
Floating agent and microcapsule formulations.
Above-mentioned Herbicidal combinations are preferably aqua, using it is preceding be watered dilution after be sprayed on target, can quickly form medicine
Film.Herbicidal combinations uptake and translocation according to the present invention is strong, extends efficiency time, low temperature drug effect is high, so that medicament is sharp
It is high with rate and selectivity, pharmaceutical use is reduced, environmental-protection function is more significant.
The effective dose of the Herbicidal combinations be 1~150g (a.i.)/ha, preferably 10~120g (a.i.)/ha, 15~
100g (a.i.)/ha, such as 75g (a.i.)/ha.
Herbicidal combinations according to the present invention can be provided in the form of finished product preparation, i.e., each ingredient has mixed in composition,
Perhaps each ingredient of composition can also be provided with unit dose form is directly directly mixed in bucket or tank using preceding, then dilute
It releases to required concentration.
Herbicidal combinations according to the present invention pass through compounding for smart glufosinate-ammonium and dicamba, can be used for ploughing or bare place
Gramineae weed, broadleaf weeds and nutgrass flatsedge control of weeds, especially for the highly selective prevention and treatment of perennial gramineae weed,
Good preventive effect is still maintained under high temperature and low temperature, and just there is obvious better control efficiency under significant low dosage.
Further, by smart glufosinate-ammonium, the combination of dicamba and specific composite assistant, improve drug drop with
The way of contact of plant surface, improves conduction efficiency.Therefore, the specific combination of smart glufosinate-ammonium, dicamba and composite assistant is more
Further improve the weeding ratio of above-mentioned Herbicidal combinations.
Specific embodiment will be enumerated below, and embodiment of the present invention is illustrated with representativeness.
The present composition with smart glufosinate-ammonium for a kind of effective component (A), dicamba and other optional Herbicidal compositions
For effective component (B), binary or more member compounding is formed, the combination between them has weed control apparent synergistic
Effect.
(1) indoor toxicity determination test
Measuring method: indoor pot method carries out cauline leaf process with spray tower to clearvers, Chenopodiaceae.15d measures fresh weight suppression after medicine
Rate processed calculates ED50Value, co-toxicity coefficient, the activity of weeding of reagent is evaluated with this.
Binary combined action of herbicide is evaluated with Sun Pei cloud co-toxicity coefficient method, formula is as follows:
In formula:
ATI-mixture surveys toxicity index；
S-standard agent ED50/90；
M-mixture ED50/90；
TTI=A × PA+B×PB
In formula:
TTI-mixtures theoretical toxicity index；
A-A medicament toxicity index；
B-B medicament toxicity index；
Percentage composition of PA-A medicament in mixture；
Percentage composition of PB-B medicament in mixture；
In formula:
CTC-co-toxicity coefficient；
ATI-mixture surveys toxicity index；
TTI-mixtures theoretical toxicity index.
Criterion: CTC > 120 is synergistic effect；CTC < 80 is antagonism；80 < CTC < 120 are summation action.
Embodiment
Smart glufosinate-ammonium+the dicamba of embodiment 1
It is tested according to compound drug of the above-mentioned indoor toxicity determination test to smart glufosinate-ammonium and dicamba, and according to grandson
Abundant cloud co-toxicity coefficient method calculates co-toxicity coefficient, is as a result shown in Table 1.
The smart glufosinate-ammonium of table 1 compounds the toxicity test result to clearvers fresh weight with dicamba
Smart glufosinate-ammonium+dicamba+the bentazone of embodiment 2
It is tested according to compound drug of the above-mentioned indoor toxicity determination test to smart glufosinate-ammonium and dicamba, bentazone,
And co-toxicity coefficient is calculated according to Sun Pei cloud co-toxicity coefficient method, as a result it is shown in Table 2.
The smart glufosinate-ammonium of table 2 compounds the toxicity test result to clearvers fresh weight with dicamba, clethodim
It can by the toxicity test result of the smart glufosinate-ammonium formulation agents according to Examples 1 and 2 shown in the above Tables 1 and 2
Find out, the binary built reagent of smart glufosinate-ammonium and dicamba, and the ternary built reagent of smart glufosinate-ammonium and dicamba, clethodim
The co-toxicity coefficient greater than 120 is all had, i.e. these formulation agents all have significant synergistic function.
(2) field weeding pharmacodynamic test
Pesticidal preparations will be made in accordance with the following methods according to the formulation agents of previous embodiment 1 and 2, and in test area
Application, to evaluate the drug effect of these pesticidal preparations.
The preparation of pesticidal preparations:
In mass ratio respectively by 20% formulation agents according to Examples 1 and 2, smart glufosinate-ammonium single dose, dicamba single dose
It is mixed with the water of 12% ethylene glycol, 9% dodecyl sodium sulfate, 6% fatty alcohol polyoxyethylene ether and surplus with clethodim single dose
It is even, it is configured to aqua.
Test method: according to the area of trial zone, the good each medicament of precise after being watered dilution, utilizes knapsack spraying
Device carries out even spraying.The dedicated Fan spray head of sprinkler selection weeding, the afternoon for selecting fine day calm are sprayed.When spraying
Medical fluid is uniformly sprayed application in experimental plot, accomplishes not respray, drain spray.
After the test, 30d, 45d observe weeds death condition after medicine respectively, and take 1 square meter at random from each cell
Weeds mortality survey is carried out, preventive effect is calculated.
3 field control effectiveness test of table
Test result as shown in table 3 shows that the present invention is multiple by smart glufosinate-ammonium and dicamba, and with dicamba and clethodim
After matching, 30d, 45d preventive effect expand prevention and treatment grass spectrum, prevent weeds especially clearvers, Chenopodiaceae compared with respective single dose after medicine
Except effect greatly improves, and the preventive effect of mixture preparation is better than each single dose medicament of comparative example.
Claims (9)
1. a kind of Herbicidal combinations, which is characterized in that the Herbicidal combinations include active components A and active constituent B, wherein
The active components A is smart glufosinate-ammonium, and the active constituent B includes dicamba, and the active components A and active constituent B
Weight ratio is 100:1~1:100.
2. Herbicidal combinations according to claim 1, wherein the total weight based on the Herbicidal combinations, the activity
The weight percent of ingredient A and active constituent B are 1~60%.
3. Herbicidal combinations according to claim 1 or 2, wherein the effective dose of the Herbicidal combinations is 1~150g
(a.i.)/ha。
4. Herbicidal combinations according to claim 1 or 2, wherein the total weight based on the Herbicidal combinations, it is described to remove
Careless composition includes: smart glufosinate-ammonium 1~30%, dicamba 1~15%, composite assistant 1~35%.
5. Herbicidal combinations according to claim 4, wherein the active constituent B further includes one in following herbicide
Kind is a variety of: bentazone, haloxyfop-r-methyl, Quizalotop-ethyl, clethodim, trichlopyr, Acetochlor, butachlor, first
Careless amine, propisochlor, isopropyl methoxalamine, S-metolachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R- are left-handed
Naphthalene propionyl grass amine, propanil, mefenacet, diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromine butyryl grass
Amine, dimethenamid, dimethenamidP, ethobenzanid, flufenacet, thenylchlor, metazachlor, isoxaben,
FlampropMmethyl, flampropMisopropyl, allidochlor, pethoxamid, chloranocryl, ring pretilachlor, mefluidide,
Monalide, delachlor, prynachlor, terbuchlor, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, chlorine
Formyl grass amine, valeryl benzene grass amine, blocks careless amine, suffer, the careless amine of tricyclic match, butenachlor, tebutam, benzyl grass at propyzamide
Careless more grams dead, grass gram of amine, quinone duckweed amine, dichlofluanid, naproanilide, acetyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, benzene
Pleasure, chlorine phthalimide, fourth amidine amine, fluorine metazachlor, atrazine, Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine,
Dipropetryn, terbutryn, Garagard, triaziflam, cyprazine, proglinazine, trietazine, prometon, Gesadrual, is folded at flur
Nitrogen is net, desmetryn, dimethametryn, cyclopropyl blueness saliva, green bristlegrass of going out saliva, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third are net, cyanatryn, suppression
Kusatsu, chlorazine, atraton, weed eradication be logical, Radix Glycyrrhizae saliva, cyanuric acid, indaziflam grass amine, green sulphur are grand, metsulfuron-methyl, bensulfuron-methyl,
Chlorimuron, tribenuron-methyl, thifensulfuron methyl, pyrazosulfuron, mesosulfuron, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, ether sulphur
Grand, triasulfuron, sulfometuronmethyl, ethametsulfuron, amidosulfuron, ethoxysulfuron, cypromisulfuron, azimsulfuron, pyridine are phonetic
Huang Long, monosulfmeturon, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, fluorine pyrazosulfuron, oxasulfuron, imazosulfuron,
Primisulfuronmethyl, procarbazone, prosulfuron, Sulfosulfuron, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium
Salt, flucetosulfuron, Sulfonylurea, orthosulfamuron, proxazuron-methyl, piperazine pyrazosulfuron, acifluorfen, newborn fluorine dogstail
Spirit, Mo 9 granular, aclonifen, ethoxyfen-ethyl, bifenox, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorine
Change nitrofen, fluorine furan grass ether, nitrofen, first grass ether, diformazan grass ether, fluorine lactazone grass ether, fluofazone ester, fluorine nitre sulfonamide, green wheat
Grand, isoproturon, linuron, diuron, Sha flutter grand, fluometuron, benzthiazuron, methabenzthiazuron, cumyluron, ethidimuron, isouron,
Terbufos benzthiazuron, bromax, methyldymron, phenobenzuron, methoxy daimuron, metobromuron, metoxuron, afesin, goes out at buturon
The grand, Tupersan of grass, fenuron, fluorine sulphur is grand, neburea, chloroxifenidium, herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron,
Difenoxuron, to fluon, methylamine methabenz thiazuron, Long Caote, front three isourea, dimefuron, special dimefuron, dredge careless grand, methiuron, ethoxy benzene
Grand, four fluon, phenmedipham, phenmedipham-ethyl ester, desmedipham, sulphur careless spirit, terbucarb, oatax, Chem hoe, chlorpropham, dichloro
Benzyl grass ester, swep, chlorbufam, special oxazole prestige, grass lose dead, acyl benzene sulphur prestige, BCPC, CPPC, kappa careless spirit, Ding Caote, dogstail
Pellet, vernolate, molinate, tri-allate, dimepiperate, esprocarb, pyributicarb, cycloate, Avadex, bactericide, second sulphur Cao Te, level ground
Careless pellet, pebulate, prosulfocarb, tiocarbazil, sulfuric acid, dimexan, nitrogen Bi grass, first sulphur benzene prestige, the different monooctyl ester fourth of 2,4-D, 2,4-D
The different monooctyl ester sodium salt of the different monooctyl ester of the different monooctyl ester of ester, 2,4-D, 2,4-D, the different monooctyl ester dimethylamine salt of 2,4-D, the different monooctyl ester propionic acid of 2,4-D, 2,4-
The different monooctyl ester butyric acid of D, 2,4,5- tears, 2,4,5- tears propionic acid, 2,4,5- tears butyric acid, erbon, Fenac, match pine, trichlorobenzoic acid, ammonia
Dichloro benzoic acid, methoxy trichlorobenzoic acid, diclofop-methyl, fluazifop, efficient fluazifop, efficient haloxyfop, oxazole dogstail
Spirit, fenoxapropPethyl, propaquizafop, cyhalofop-butyl, clodinafop-propargyl, diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of penta standing grain of hydroxyl, trifluoro dogstail oxime,
Isoxapyrifop, paraquat, diquat dibromide, oryzalin, ethalfluralin, isopropalin, nitralin, profluralin, aminopropan fluorine
Spirit, benfluralin, fluchloraline, the spirit of amino second fluorine, dipropalin, chloroethene dipropalin, fluorine alkene nitre grass, the third nitre phenol, Sha barnyard grass phosphine, methyl
Amiprophos, sulphosate, piperazine grass phosphine, bialaphos, bensulide, butamifos, creeping weed phosphorus, cut down ridge phosphorus, double first amiprophos, dow crabgrass killer,
Imazapyr, imazethapyr, imazaquin, imazamox, imazamox ammonium salt, AC 263222, miaow grass ester, chlorine
Fluorine pyrrole fluoroacetic acid, the different monooctyl ester of fluroxypyr, dithiopyr, halogen grass be fixed, phenolate trichloropyridine, thiazopyr, fluridone, fluorine pyrrole
Careless hydrazone, triclopyr butoxyethyl ester, iodine chlorine pyridine ester, sethoxydim, cycloxydim, alloxydimsodium, clefoxidim, butroxydim,
Tralkoxydim, tepraloxydim, special imidazoles grass, metribuzin, hexazinone, metamitron, ethiozin, special saliva ketone, special careless piperazine ketone, bromobenzene
Nitrile, bromoxynil octanoate, ioxynil octanoate, ioxynil, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil,
Flumetsulam, florasulam, metosulam, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, pyrimidine oxime grass
Ether, pyriftalid, KIH 6127, pyrithiobacsodium, benzobicylon, mesotrione, sulphur humulone, tembotrions, special furan triketone, fluorine pyrrole grass
Ketone, Ketodpiradox, isoxaflutole, isoxachlorotole, Fenoxasulfone, Methiozolin, fluazolate, pyrrole
Careless ether, difenzoquat, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, sulphonyl grass pyrazoles, topramezone, sends Roc herbicide sulfone, azoles at pyrazolate
Careless amine, flupoxam, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone, Bencarbazone, double benzene are phonetic
Humulone, butafenacil, bromacil, isoprocil, lenacil, terbacil, Flupropacil, cinidon-ethyl, Flumiclorac pentyl,
Flumioxazin, alkynes grass amine, phthalein benzyl oxide, trifluoro oxazines, pentachlorophenol (sodium), dinoseb, dinoterb, dinoterb acetate, dinosam, dinitro
Phenol, chlorine nitre phenol, medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, profluazol, fluthiacet, tetrazolium
It is chloro- that acyl grass amine, flufenpyrethyl, pyrazon, brompyrazon, diformazan reach rattle away pine, norflurazon, 6- of careless volt, Kusakira, grass pyridazone, grass
3- phenyl -4- alcohol pyridazines, dichloro quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, clomazone,
Cinmethylin, iso-propyl-ester nitrofen, propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone,
Tetrafluoro propionic acid, herbage are fast, bromofenoxim, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine phthalandione, fluorine
Cough up humulone, barnyard grass, methacrylaldehyde, bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, dioxybenzone,
Chlorine acyl grass phosphine, chloropon, pentachloro- oxopentanoic acid, diethyl weeding be double, ethamine grass ether, Bing Caoding, three azole amides, thiophene ketone sulphur are grand,
Pyrimisulfan, fluorine be phonetic to kill, indanofan, a word used for translation sulphur in heptan ester, first sulphur nitralin, dimethachlor ester, cyclopropyl pyrimidine acid, sulphur benzonitrile
Amine, fenclorim, flurazole, fenchlorazole, solves careless quinoline, oxabetrinil, oxalane, cyometrinil, desorpenic, pyrazoles solution grass at benoxacor
Ester, furilazole, fluxofenim, isoxadifen, allyl dichloride amine, UBH-509, D489, LS 82-556, KPP-300, NC-
324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、
KIH-9201, ET-751, KIH-6127 and KIH-2023.
6. Herbicidal combinations according to claim 4, wherein the composite assistant includes two kinds in following auxiliary agent
Or more: filler, emulsifier, thickener, antifreezing agent, dispersing agent, binder, stabilizer, safener, synergist.
7. Herbicidal combinations according to claim 4, wherein the composite assistant is selected from cocamide glycine betaine, rouge
Fat alcohol polyoxyethylene ether sulfate, alkyl glycosides, alkylsulfonate, alcohol ether glucoside, aliphatic alcohol sulfate, anhydrous sorbitol monoester
Fatty acid glyceride, castor oil polyoxyethylene ether, aliphatic alcohol polyoxyvinethene phosphate, lignosulfonates, polycarboxylate, naphthalene sulphur
Hydrochlorate and PULLRONIC F68 block polyether.
8. Herbicidal combinations according to claim 1 or 2, wherein the dosage form of the Herbicidal combinations is selected from aqua, powder
Agent, granule, microemulsion, aqueous emulsion, oil-suspending agent, aqueous suspension agent and microcapsule formulations.
9. the application that Herbicidal combinations according to any one of claim 1 to 8 are used for management of weeds.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111466377A (en) * | 2020-05-29 | 2020-07-31 | 广东省科学院产业技术育成中心 | Herbicide adjuvant and preparation method thereof |
| CN112471141A (en) * | 2020-12-17 | 2021-03-12 | 广东方中高新材料有限公司 | Glufosinate-ammonium aqueous agent additive and use method thereof |
| CN112741102A (en) * | 2020-12-30 | 2021-05-04 | 浙江新安化工集团股份有限公司 | Fine glufosinate-ammonium herbicide |
| CN115104624A (en) * | 2021-03-22 | 2022-09-27 | 江苏七洲绿色化工股份有限公司 | Compound composition of glufosinate-ammonium and imazapyr |
| CN117441736A (en) * | 2023-12-22 | 2024-01-26 | 山东科赛基农生物工程有限公司 | Compound preparation containing florasulam herbicide and agricultural coconut oil synergist |
-
2018
- 2018-09-17 CN CN201811080587.6A patent/CN109042721A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111466377A (en) * | 2020-05-29 | 2020-07-31 | 广东省科学院产业技术育成中心 | Herbicide adjuvant and preparation method thereof |
| CN112471141A (en) * | 2020-12-17 | 2021-03-12 | 广东方中高新材料有限公司 | Glufosinate-ammonium aqueous agent additive and use method thereof |
| CN112741102A (en) * | 2020-12-30 | 2021-05-04 | 浙江新安化工集团股份有限公司 | Fine glufosinate-ammonium herbicide |
| CN115104624A (en) * | 2021-03-22 | 2022-09-27 | 江苏七洲绿色化工股份有限公司 | Compound composition of glufosinate-ammonium and imazapyr |
| CN115104624B (en) * | 2021-03-22 | 2024-04-23 | 江苏七洲绿色化工股份有限公司 | Compound composition of glufosinate-ammonium and imazethapyr |
| CN117441736A (en) * | 2023-12-22 | 2024-01-26 | 山东科赛基农生物工程有限公司 | Compound preparation containing florasulam herbicide and agricultural coconut oil synergist |
| CN117441736B (en) * | 2023-12-22 | 2024-03-29 | 山东科赛基农生物工程有限公司 | Compound preparation containing florasulam herbicide and agricultural coconut oil synergist |
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Application publication date: 20181221 |